CN106349865A - Environment-friendly flame-retardant acid- and alkali-resistant treating coating for building materials - Google Patents

Environment-friendly flame-retardant acid- and alkali-resistant treating coating for building materials Download PDF

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CN106349865A
CN106349865A CN201610737239.6A CN201610737239A CN106349865A CN 106349865 A CN106349865 A CN 106349865A CN 201610737239 A CN201610737239 A CN 201610737239A CN 106349865 A CN106349865 A CN 106349865A
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ester
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袁华
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袁华
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/32Modified amine-aldehyde condensates
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention relates to environment-friendly flame-retardant acid- and alkali-resistant treating coating for building materials, made from methylated amino resin, heat-vulcanized silicone rubber, brominated bisphenol A epoxy resin, wintergreen oil, walnut oil, tangerine oil, rose essential oil, lemon oil, stearamidopropyl pyrrolidonylmethyl dimethyl ammonium chloride, nano sliver, penicillin, chitosan, lead difluoride powder, titanium dioxide powder, flyash, aluminum fluoride powder, corundum powder, zirconite powder, wollastonite powder, zirconium silicate powder, nano zinc oxide, tris(butoxyethyl)phosphate, hexabromo-benzene, sodium stannate, triallyl cyanurate, triethyl citrate, glutathione, Upsilon-mercaptopropyltriethoxysilane, hydroxyethyl methacrylate phosphate, and p-chlorophenol. The environment-friendly flame-retardant acid- and alkali-resistant treating coating for building materials has excellent flame retardance, acid and alkali resistance, and mildew-proof and antibacterial properties, and the properties of the coating are improved.

Description

A kind of acidproof alkali process coating of construction material environmental protection flame retardant
Technical field
The present invention relates to a kind of acidproof alkali process coating of construction material environmental protection flame retardant, belong to building materials technical field of coatings.
Background technology
Building materials are the general designations of material used in civil engineering and architectural engineering, can be divided into structural material, ornament materials and Some proprietary materials.Proprietary material refers to for waterproof, protection against the tide, anti-corrosion, fire prevention, fire-retardant, sound insulation, heat-insulated, insulation, sealing etc..Every Sound material refers to the isolation of noise, cut-off, a kind of detached material, component or the structure that in the air is propagated.Sound insulating material material Requirement be closely knit imporosity or gap;There is larger weight.Due to this kind of sound insulating material closely knit it is difficult to absorb and pass through acoustic energy And it is strong, so its sound absorbing capabilities are poor to reflect energy.Fire proofing be can suppress or retardation burning and oneself be not easy to fire The material burning, is widely used in the fields such as clothing, oil, chemical industry, metallurgy, shipbuilding, fire-fighting, national defence.
Content of the invention
It is an object of the invention to provide a kind of acidproof alkali process coating of construction material environmental protection flame retardant, to be better achieved The use function of construction material environmental protection flame retardant acidproof alkali process coating, makes product have fire-retardant, acid and alkali-resistance, anti-mildew antibiotic property Can, improve product serviceability.
To achieve these goals, technical scheme is as follows.
A kind of acidproof alkali process coating of construction material environmental protection flame retardant, is grouped into by the group of following mass fraction: methyl-etherified ammonia 24~28 parts of base resin, 22~26 parts of heat vulcanized silicone rubber, 22~26 parts of bromo propanepoxy resin, wintergreen oil 20~ 24 parts, 22~26 parts of walnut oil, 22~26 parts of mandarin oil, 20~24 parts of rose ethereal oil, 22~26 parts of Fructus Citri Limoniae oil, stearmide 22~26 parts of propyl pyrrole alkanone methyl dimethoxy ammonium chloride, 20~24 parts of nanometer silver, 20~24 parts of penicillin, deacetylated carapace 20~24 parts of matter, 22~26 parts of Plumbous Fluoride powder, 20~24 parts of titania powder, 18~22 parts of flyash, aluminium fluoride powder 22~26 parts of end, 20~24 parts of schmigel, 18~22 parts of zircon powder, 20~24 parts of wollastonite powder, Zirconium orthosilicate. powder 18 ~22 parts, 18~22 parts of nano zine oxide, 18~22 parts of tricresyl phosphate (butoxyethyl group) ester, 16~20 parts of HBB, sodium stannate 12~16 parts, 10~14 parts of triallyl cyanurate, 10~14 parts of triethyl citrate, 10~14 parts of Glutathione, γ-mercapto 10~14 parts of propyl-triethoxysilicane, 10~14 parts of hydroxyethyl meth acrylate phosphate ester, 10~14 parts of parachlorophenol.
Further, the acidproof alkali process coating of above-mentioned construction material environmental protection flame retardant, is grouped into by the group of following mass fraction: 24 parts of Amino resin, 22 parts of heat vulcanized silicone rubber, 22 parts of bromo propanepoxy resin, 20 parts of wintergreen oil, core 22 parts of Fructus Persicae oil, 22 parts of mandarin oil, 20 parts of rose ethereal oil, 22 parts of Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base 22 parts of ammonium chloride, 20 parts of nanometer silver, 20 parts of penicillin, 20 parts of chitosan, 22 parts of Plumbous Fluoride powder, titanium dioxide powder 20 parts of end, 18 parts of flyash, 22 parts of aluminium fluoride powder, 20 parts of schmigel, 18 parts of zircon powder, 20 parts of wollastonite powder, silicon 18 parts of sour zirconium powder, 18 parts of nano zine oxide, 18 parts of tricresyl phosphate (butoxyethyl group) ester, 16 parts of HBB, 12 parts of sodium stannate, three Paracyanogen 10 parts of triallyl of acid, 10 parts of triethyl citrate, 10 parts of Glutathione, 10 parts of gamma-mercaptopropyltriethoxysilane, hydroxyl 10 parts of ethylmethyl acrylate phosphate ester, 10 parts of parachlorophenol.
Further, the acidproof alkali process coating of above-mentioned construction material environmental protection flame retardant, is grouped into by the group of following mass fraction: 26 parts of Amino resin, 24 parts of heat vulcanized silicone rubber, 24 parts of bromo propanepoxy resin, 22 parts of wintergreen oil, core 24 parts of Fructus Persicae oil, 24 parts of mandarin oil, 22 parts of rose ethereal oil, 24 parts of Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base 24 parts of ammonium chloride, 22 parts of nanometer silver, 22 parts of penicillin, 22 parts of chitosan, 24 parts of Plumbous Fluoride powder, titanium dioxide powder 22 parts of end, 20 parts of flyash, 24 parts of aluminium fluoride powder, 22 parts of schmigel, 20 parts of zircon powder, 22 parts of wollastonite powder, silicon 20 parts of sour zirconium powder, 20 parts of nano zine oxide, 20 parts of tricresyl phosphate (butoxyethyl group) ester, 18 parts of HBB, 14 parts of sodium stannate, three Paracyanogen 12 parts of triallyl of acid, 12 parts of triethyl citrate, 12 parts of Glutathione, 12 parts of gamma-mercaptopropyltriethoxysilane, hydroxyl 12 parts of ethylmethyl acrylate phosphate ester, 12 parts of parachlorophenol.
Further, the acidproof alkali process coating of above-mentioned construction material environmental protection flame retardant, is grouped into by the group of following mass fraction: 28 parts of Amino resin, 26 parts of heat vulcanized silicone rubber, 26 parts of bromo propanepoxy resin, 24 parts of wintergreen oil, core 26 parts of Fructus Persicae oil, 26 parts of mandarin oil, 24 parts of rose ethereal oil, 26 parts of Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base 26 parts of ammonium chloride, 24 parts of nanometer silver, 24 parts of penicillin, 24 parts of chitosan, 26 parts of Plumbous Fluoride powder, titanium dioxide powder 24 parts of end, 22 parts of flyash, 26 parts of aluminium fluoride powder, 24 parts of schmigel, 22 parts of zircon powder, 24 parts of wollastonite powder, silicon 22 parts of sour zirconium powder, 22 parts of nano zine oxide, 22 parts of tricresyl phosphate (butoxyethyl group) ester, 20 parts of HBB, 16 parts of sodium stannate, three Paracyanogen 14 parts of triallyl of acid, 14 parts of triethyl citrate, 14 parts of Glutathione, 14 parts of gamma-mercaptopropyltriethoxysilane, hydroxyl 14 parts of ethylmethyl acrylate phosphate ester, 14 parts of parachlorophenol.
Further, the acidproof alkali process coating production step of above-mentioned construction material environmental protection flame retardant is as follows:
(1) by the Amino resin of described mass fraction, heat vulcanized silicone rubber, bromo diphenol propane asphalt mixtures modified by epoxy resin Fat, wintergreen oil, walnut oil, mandarin oil, rose ethereal oil, Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base chlorination Ammonium, nanometer silver, penicillin, chitosan, Plumbous Fluoride powder, titania powder, flyash, aluminium fluoride powder, just Beautiful powder, zircon powder, wollastonite powder, Zirconium orthosilicate. powder are mixed, the dispersion of ultrasonic high speed, and ultrasonic frequency is 20~ 40khz, rate of dispersion 5000~5400r/min about, jitter time is 30~60min;
(2) add the nano zine oxide of described mass fraction, tricresyl phosphate (butoxyethyl group) ester, HBB, sodium stannate, three Paracyanogen acid triallyl, ultrasonic high speed dispersion, ultrasonic frequency is 20~35khz, and rate of dispersion 4800~5200r/min is left The right side, jitter time is 30~50min;
(3) triethyl citrate of the described mass fraction of addition, Glutathione, gamma-mercaptopropyltriethoxysilane, hydroxyl second Methyl acrylate phosphate ester, parachlorophenol, ultrasonic high speed dispersion, ultrasonic frequency is 20~30khz, rate of dispersion 4600 ~4800r/min about, jitter time is 20~40min;This product is obtained after mix homogeneously.
This beneficial effect of the invention is: the construction material environmental protection flame retardant acidproof alkali process coating in the present invention, by following Group is grouped into: Amino resin, heat vulcanized silicone rubber, bromo propanepoxy resin, wintergreen oil, walnut oil, Fructus Citri tangerinae Seed oil, rose ethereal oil, Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride, nanometer silver, penicillin, de- Acetyl chitin, Plumbous Fluoride powder, titania powder, flyash, aluminium fluoride powder, schmigel, zircon powder, silicon ash Stone powder, Zirconium orthosilicate. powder, nano zine oxide, tricresyl phosphate (butoxyethyl group) ester, HBB, sodium stannate, cyanuric acid triolefin Propyl ester, triethyl citrate, Glutathione, gamma-mercaptopropyltriethoxysilane, hydroxyethyl meth acrylate phosphate ester, right Chlorophenol.Product of the present invention has more superior fire-retardant, acid and alkali-resistance, anti-mildew anti-microbial property, improves properties of product.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is described, to be better understood from the present invention.
Embodiment 1
Construction material environmental protection flame retardant acidproof alkali process coating in the present embodiment, is grouped into by the group of following mass fraction: 24 parts of Amino resin, 22 parts of heat vulcanized silicone rubber, 22 parts of bromo propanepoxy resin, 20 parts of wintergreen oil, core 22 parts of Fructus Persicae oil, 22 parts of mandarin oil, 20 parts of rose ethereal oil, 22 parts of Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base 22 parts of ammonium chloride, 20 parts of nanometer silver, 20 parts of penicillin, 20 parts of chitosan, 22 parts of Plumbous Fluoride powder, titanium dioxide powder 20 parts of end, 18 parts of flyash, 22 parts of aluminium fluoride powder, 20 parts of schmigel, 18 parts of zircon powder, 20 parts of wollastonite powder, silicon 18 parts of sour zirconium powder, 18 parts of nano zine oxide, 18 parts of tricresyl phosphate (butoxyethyl group) ester, 16 parts of HBB, 12 parts of sodium stannate, three Paracyanogen 10 parts of triallyl of acid, 10 parts of triethyl citrate, 10 parts of Glutathione, 10 parts of gamma-mercaptopropyltriethoxysilane, hydroxyl 10 parts of ethylmethyl acrylate phosphate ester, 10 parts of parachlorophenol.
The acidproof alkali process coating production step of above-mentioned construction material environmental protection flame retardant is as follows:
(1) by the Amino resin of described mass fraction, heat vulcanized silicone rubber, bromo diphenol propane asphalt mixtures modified by epoxy resin Fat, wintergreen oil, walnut oil, mandarin oil, rose ethereal oil, Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base chlorination Ammonium, nanometer silver, penicillin, chitosan, Plumbous Fluoride powder, titania powder, flyash, aluminium fluoride powder, just Beautiful powder, zircon powder, wollastonite powder, Zirconium orthosilicate. powder are mixed, ultrasonic high speed dispersion, and ultrasonic frequency is 20khz, Rate of dispersion 5400r/min about, jitter time is 60min;
(2) add the nano zine oxide of described mass fraction, tricresyl phosphate (butoxyethyl group) ester, HBB, sodium stannate, three Paracyanogen acid triallyl, ultrasonic high speed dispersion, ultrasonic frequency is 20khz, rate of dispersion 5200r/min about, jitter time For 50min;
(3) triethyl citrate of the described mass fraction of addition, Glutathione, gamma-mercaptopropyltriethoxysilane, hydroxyl second Methyl acrylate phosphate ester, parachlorophenol, ultrasonic high speed dispersion, ultrasonic frequency is 20khz, rate of dispersion 4800r/ Min about, jitter time is 40min;This product is obtained after mix homogeneously.
Embodiment 2
Construction material environmental protection flame retardant acidproof alkali process coating in the present embodiment, is grouped into by the group of following mass fraction: 26 parts of Amino resin, 24 parts of heat vulcanized silicone rubber, 24 parts of bromo propanepoxy resin, 22 parts of wintergreen oil, core 24 parts of Fructus Persicae oil, 24 parts of mandarin oil, 22 parts of rose ethereal oil, 24 parts of Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base 24 parts of ammonium chloride, 22 parts of nanometer silver, 22 parts of penicillin, 22 parts of chitosan, 24 parts of Plumbous Fluoride powder, titanium dioxide powder 22 parts of end, 20 parts of flyash, 24 parts of aluminium fluoride powder, 22 parts of schmigel, 20 parts of zircon powder, 22 parts of wollastonite powder, silicon 20 parts of sour zirconium powder, 20 parts of nano zine oxide, 20 parts of tricresyl phosphate (butoxyethyl group) ester, 18 parts of HBB, 14 parts of sodium stannate, three Paracyanogen 12 parts of triallyl of acid, 12 parts of triethyl citrate, 12 parts of Glutathione, 12 parts of gamma-mercaptopropyltriethoxysilane, hydroxyl 12 parts of ethylmethyl acrylate phosphate ester, 12 parts of parachlorophenol.
The acidproof alkali process coating production step of above-mentioned construction material environmental protection flame retardant is as follows:
(1) by the Amino resin of described mass fraction, heat vulcanized silicone rubber, bromo diphenol propane asphalt mixtures modified by epoxy resin Fat, wintergreen oil, walnut oil, mandarin oil, rose ethereal oil, Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base chlorination Ammonium, nanometer silver, penicillin, chitosan, Plumbous Fluoride powder, titania powder, flyash, aluminium fluoride powder, just Beautiful powder, zircon powder, wollastonite powder, Zirconium orthosilicate. powder are mixed, ultrasonic high speed dispersion, and ultrasonic frequency is 30khz, Rate of dispersion 5200r/min about, jitter time is 45min;
(2) add the nano zine oxide of described mass fraction, tricresyl phosphate (butoxyethyl group) ester, HBB, sodium stannate, three Paracyanogen acid triallyl, ultrasonic high speed dispersion, ultrasonic frequency is 27khz, rate of dispersion 5000r/min about, jitter time For 40min;
(3) triethyl citrate of the described mass fraction of addition, Glutathione, gamma-mercaptopropyltriethoxysilane, hydroxyl second Methyl acrylate phosphate ester, parachlorophenol, ultrasonic high speed dispersion, ultrasonic frequency is 25khz, rate of dispersion 4700r/ Min about, jitter time is 30min;This product is obtained after mix homogeneously.
Embodiment 3
Construction material environmental protection flame retardant acidproof alkali process coating in the present embodiment, is grouped into by the group of following mass fraction: 28 parts of Amino resin, 26 parts of heat vulcanized silicone rubber, 26 parts of bromo propanepoxy resin, 24 parts of wintergreen oil, core 26 parts of Fructus Persicae oil, 26 parts of mandarin oil, 24 parts of rose ethereal oil, 26 parts of Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base 26 parts of ammonium chloride, 24 parts of nanometer silver, 24 parts of penicillin, 24 parts of chitosan, 26 parts of Plumbous Fluoride powder, titanium dioxide powder 24 parts of end, 22 parts of flyash, 26 parts of aluminium fluoride powder, 24 parts of schmigel, 22 parts of zircon powder, 24 parts of wollastonite powder, silicon 22 parts of sour zirconium powder, 22 parts of nano zine oxide, 22 parts of tricresyl phosphate (butoxyethyl group) ester, 20 parts of HBB, 16 parts of sodium stannate, three Paracyanogen 14 parts of triallyl of acid, 14 parts of triethyl citrate, 14 parts of Glutathione, 14 parts of gamma-mercaptopropyltriethoxysilane, hydroxyl 14 parts of ethylmethyl acrylate phosphate ester, 14 parts of parachlorophenol.
The acidproof alkali process coating production step of above-mentioned construction material environmental protection flame retardant is as follows:
(1) by the Amino resin of described mass fraction, heat vulcanized silicone rubber, bromo diphenol propane asphalt mixtures modified by epoxy resin Fat, wintergreen oil, walnut oil, mandarin oil, rose ethereal oil, Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy base chlorination Ammonium, nanometer silver, penicillin, chitosan, Plumbous Fluoride powder, titania powder, flyash, aluminium fluoride powder, just Beautiful powder, zircon powder, wollastonite powder, Zirconium orthosilicate. powder are mixed, ultrasonic high speed dispersion, and ultrasonic frequency is 40khz, Rate of dispersion 5000r/min, jitter time is 30min;
(2) add the nano zine oxide of described mass fraction, tricresyl phosphate (butoxyethyl group) ester, HBB, sodium stannate, three Paracyanogen acid triallyl, ultrasonic high speed dispersion, ultrasonic frequency is 35khz, rate of dispersion 4800r/min, and jitter time is 30min;
(3) triethyl citrate of the described mass fraction of addition, Glutathione, gamma-mercaptopropyltriethoxysilane, hydroxyl second Methyl acrylate phosphate ester, parachlorophenol, ultrasonic high speed dispersion, ultrasonic frequency is 30khz, rate of dispersion 4600r/ Min about, jitter time is 20min;This product is obtained after mix homogeneously.
Carry out performance measurement for the product in embodiment 1, embodiment 2 and embodiment 3 and certain commercially available prod, measured Data is as shown in table 1.Fire protection flame retarding level estimate adopts ul94 standard.
Table 1 the performance test results
It can be seen that, product of the present invention has preferably corrosion-resistant, fire protection flame retarding, anti-mildew, anti-microbial property.
The above is the preferred embodiment of the present invention it is noted that for those skilled in the art For, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as Protection scope of the present invention.

Claims (5)

1. a kind of acidproof alkali process coating of construction material environmental protection flame retardant it is characterised in that: be grouped into by the group of following mass fraction: 24~28 parts of Amino resin, 22~26 parts of heat vulcanized silicone rubber, 22~26 parts of bromo propanepoxy resin, winter 20~24 parts of blue or green oil, 22~26 parts of walnut oil, 22~26 parts of mandarin oil, 20~24 parts of rose ethereal oil, 22~26 parts of Fructus Citri Limoniae oil, 22~26 parts of stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride, 20~24 parts of nanometer silver, 20~24 parts of penicillin, de- 20~24 parts of acetyl chitin, 22~26 parts of Plumbous Fluoride powder, 20~24 parts of titania powder, 18~22 parts of flyash, 22~26 parts of aluminium fluoride powder, 20~24 parts of schmigel, 18~22 parts of zircon powder, 20~24 parts of wollastonite powder, silicic acid 18~22 parts of zirconium powder, 18~22 parts of nano zine oxide, 18~22 parts of tricresyl phosphate (butoxyethyl group) ester, HBB 16~20 Part, 12~16 parts of sodium stannate, 10~14 parts of triallyl cyanurate, 10~14 parts of triethyl citrate, Glutathione 10~ 14 parts, 10~14 parts of gamma-mercaptopropyltriethoxysilane, 10~14 parts of hydroxyethyl meth acrylate phosphate ester, parachlorophenol 10~14 parts.
2. the acidproof alkali process coating of construction material environmental protection flame retardant according to claim 1 it is characterised in that: described Building wood Material environmental protection flame retardant acidproof alkali process coating is grouped into by the group of following mass fraction: 24 parts of Amino resin, heat cure silicon 22 parts of rubber, 22 parts of bromo propanepoxy resin, 20 parts of wintergreen oil, 22 parts of walnut oil, 22 parts of mandarin oil, Flos Rosae Rugosae HUAJING 20 parts of oil, 22 parts of Fructus Citri Limoniae oil, 22 parts of stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride, 20 parts of nanometer silver, penicillin 20 parts, 20 parts of chitosan, 22 parts of Plumbous Fluoride powder, 20 parts of titania powder, 18 parts of flyash, aluminium fluoride powder 22 parts, 20 parts of schmigel, 18 parts of zircon powder, 20 parts of wollastonite powder, 18 parts of Zirconium orthosilicate. powder, 18 parts of nano zine oxide, 18 parts of tricresyl phosphate (butoxyethyl group) ester, 16 parts of HBB, 12 parts of sodium stannate, 10 parts of triallyl cyanurate, citric acid three 10 parts of ethyl ester, 10 parts of Glutathione, 10 parts of gamma-mercaptopropyltriethoxysilane, 10 parts of hydroxyethyl meth acrylate phosphate ester, 10 parts of parachlorophenol.
3. the construction material environmental protection flame retardant acidproof alkali process coating according to claim 1 to 2 it is characterised in that: described build Build the fire-retardant acidproof alkali process coating of material environment friendly to be grouped into by the group of following mass fraction: 26 parts of Amino resin, hot sulfur 24 parts of SiClx rubber, 24 parts of bromo propanepoxy resin, 22 parts of wintergreen oil, 24 parts of walnut oil, 24 parts of mandarin oil, Flos Rosae Rugosae 22 parts of flower essential oil, 24 parts of Fructus Citri Limoniae oil, 24 parts of stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride, 22 parts of nanometer silver, green grass or young crops 22 parts of mycin, 22 parts of chitosan, 24 parts of Plumbous Fluoride powder, 22 parts of titania powder, 20 parts of flyash, aluminium fluoride 24 parts of powder, 22 parts of schmigel, 20 parts of zircon powder, 22 parts of wollastonite powder, 20 parts of Zirconium orthosilicate. powder, nano zine oxide 20 Part, 20 parts of tricresyl phosphate (butoxyethyl group) ester, 18 parts of HBB, 14 parts of sodium stannate, 12 parts of triallyl cyanurate, citric acid 12 parts of triethyl, 12 parts of Glutathione, 12 parts of gamma-mercaptopropyltriethoxysilane, hydroxyethyl meth acrylate phosphate ester 12 Part, 12 parts of parachlorophenol.
4. the construction material environmental protection flame retardant acidproof alkali process coating according to claims 1 to 3 it is characterised in that: described build Build the fire-retardant acidproof alkali process coating of material environment friendly to be grouped into by the group of following mass fraction: 28 parts of Amino resin, hot sulfur 26 parts of SiClx rubber, 26 parts of bromo propanepoxy resin, 24 parts of wintergreen oil, 26 parts of walnut oil, 26 parts of mandarin oil, Flos Rosae Rugosae 24 parts of flower essential oil, 26 parts of Fructus Citri Limoniae oil, 26 parts of stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride, 24 parts of nanometer silver, green grass or young crops 24 parts of mycin, 24 parts of chitosan, 26 parts of Plumbous Fluoride powder, 24 parts of titania powder, 22 parts of flyash, aluminium fluoride 26 parts of powder, 24 parts of schmigel, 22 parts of zircon powder, 24 parts of wollastonite powder, 22 parts of Zirconium orthosilicate. powder, nano zine oxide 22 Part, 22 parts of tricresyl phosphate (butoxyethyl group) ester, 20 parts of HBB, 16 parts of sodium stannate, 14 parts of triallyl cyanurate, citric acid 14 parts of triethyl, 14 parts of Glutathione, 14 parts of gamma-mercaptopropyltriethoxysilane, hydroxyethyl meth acrylate phosphate ester 14 Part, 14 parts of parachlorophenol.
5. the acidproof alkali process coating of construction material environmental protection flame retardant according to claim 1 it is characterised in that: described Building wood Material environmental protection flame retardant acidproof alkali process coating production step is as follows:
(1) by the Amino resin of described mass fraction, heat vulcanized silicone rubber, bromo propanepoxy resin, winter Blue or green oil, walnut oil, mandarin oil, rose ethereal oil, Fructus Citri Limoniae oil, stearamide propyl ketopyrrolidine methyl dimethoxy ammonium chloride, receive Meter Yin, penicillin, chitosan, Plumbous Fluoride powder, titania powder, flyash, aluminium fluoride powder, schmigel, Zircon powder, wollastonite powder, Zirconium orthosilicate. powder are mixed, ultrasonic high speed dispersion, and ultrasonic frequency is 20~40khz, Rate of dispersion about 5000~5400r/min, jitter time is 30~60min;
(2) nano zine oxide of the described mass fraction of addition, tricresyl phosphate (butoxyethyl group) ester, HBB, sodium stannate, melamine Sour triallyl, ultrasonic high speed dispersion, ultrasonic frequency is 20~35khz, and rate of dispersion is about 4800~5200r/min, point Scattered time is 30~50min;
(3) triethyl citrate of the described mass fraction of addition, Glutathione, gamma-mercaptopropyltriethoxysilane, ethoxy first Base acrylate phosphate, parachlorophenol, ultrasonic high speed dispersion, ultrasonic frequency is 20~30khz, and rate of dispersion is about 4600 ~4800r/min, jitter time is 20~40min;This product is obtained after mix homogeneously.
CN201610737239.6A 2016-08-26 2016-08-26 Environment-friendly flame-retardant acid- and alkali-resistant treating coating for building materials Pending CN106349865A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107987712A (en) * 2017-12-21 2018-05-04 珠海智星荟科技服务有限公司 There is aqueous epoxy floor coating of anti-corrosive antibacterial and preparation method thereof
CN110982431A (en) * 2019-12-18 2020-04-10 广东鸿业家具制造有限公司 Preparation method of odorless environment-friendly paint

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CN1500845A (en) * 2002-11-12 2004-06-02 刘恩禄 Bi component paint used as top coating, producing process and usage thereof
CN1500844A (en) * 2002-11-12 2004-06-02 刘恩禄 Bi component paint used as priming lacquer, producing process and usage thereof
CN104946082A (en) * 2015-06-26 2015-09-30 芜湖县双宝建材有限公司 Special high-property coating for chemical equipment

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Publication number Priority date Publication date Assignee Title
CN1500845A (en) * 2002-11-12 2004-06-02 刘恩禄 Bi component paint used as top coating, producing process and usage thereof
CN1500844A (en) * 2002-11-12 2004-06-02 刘恩禄 Bi component paint used as priming lacquer, producing process and usage thereof
CN104946082A (en) * 2015-06-26 2015-09-30 芜湖县双宝建材有限公司 Special high-property coating for chemical equipment

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107987712A (en) * 2017-12-21 2018-05-04 珠海智星荟科技服务有限公司 There is aqueous epoxy floor coating of anti-corrosive antibacterial and preparation method thereof
CN107987712B (en) * 2017-12-21 2020-06-02 珠海智星荟科技服务有限公司 Water-based epoxy floor coating with anticorrosion and antibacterial functions and preparation method thereof
CN110982431A (en) * 2019-12-18 2020-04-10 广东鸿业家具制造有限公司 Preparation method of odorless environment-friendly paint

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