CN108505399A - Environmental protection wall paper and preparation method thereof - Google Patents
Environmental protection wall paper and preparation method thereof Download PDFInfo
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- CN108505399A CN108505399A CN201810471854.6A CN201810471854A CN108505399A CN 108505399 A CN108505399 A CN 108505399A CN 201810471854 A CN201810471854 A CN 201810471854A CN 108505399 A CN108505399 A CN 108505399A
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-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
- D21B1/06—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods
- D21B1/063—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by dry methods using grinding devices
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F13/00—Making discontinuous sheets of paper, pulpboard or cardboard, or of wet web, for fibreboard production
- D21F13/10—Making discontinuous sheets of paper, pulpboard or cardboard, or of wet web, for fibreboard production using board presses
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/02—Material of vegetable origin
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/52—Epoxy resins
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2200/00—Wooden materials to be treated
- B27K2200/15—Pretreated particles or fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- Forests & Forestry (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of environmental protection wall paper and preparation method thereof, the preparation method includes:Plant fiber is placed in aqueous acetic acid, is ground after immersion, plant fiber powder is obtained;The first mixing material is obtained after plant fiber powder, HMMM resin, epoxy resin, methacrylate, butyl glycol ether and coupling agent are mixed;The second mixing material is obtained after wood pulp, mica powder, diatomite, lignocellulose, polyethylene glycol, nano zine oxide, dibutyl tin laurate, thickener and water are mixed;After first mixing material and the second mixing material are mixed, environmental protection wall paper is obtained through hot press molding;Solves in the prior art the problem of flame retardant property of wallpaper and anti-microbial property are poor, cannot be satisfied demand in actual use.
Description
Technical field
The present invention relates to wallpaper fields, and in particular, to a kind of environmental protection wall paper and preparation method thereof.
Background technology
Wallpaper usually produces body paper, then the working process through different processes, such as coating, printing, pressure with bleached wood pulp
Modeling is covered on line or surface, is dispatched from the factory after last cut, packaging.Because with certain intensity, beautiful appearance and good water resistant
Performance is widely used in the interior decoration etc. of house, office, hotel.The flame retardant property and antibacterial of wallpaper in the prior art
Performance is poor, cannot be satisfied demand in actual use.
Invention content
The object of the present invention is to provide a kind of environmental protection wall paper and preparation method thereof, solve the fire-retardant of wallpaper in the prior art
Performance and anti-microbial property are poor, the problem of cannot be satisfied demand in actual use.
To achieve the goals above, the present invention provides a kind of preparation method of environmental protection wall paper, the preparation method includes:
(1) plant fiber is placed in aqueous acetic acid, is ground after immersion, obtain plant fiber powder;
(2) by plant fiber powder, HMMM resin, epoxy resin, methacrylate, second two
The first mixing material is obtained after alcohol butyl ether and coupling agent mixing;
(3) by wood pulp, mica powder, diatomite, lignocellulose, polyethylene glycol, nano zine oxide, two fourth of tin dilaurate
The second mixing material is obtained after Ji Xi, thickener and water mixing;
(4) after mixing the first mixing material and the second mixing material, environmental protection wall paper is obtained through hot press molding.
The present invention also provides a kind of environmental protection wall paper, the environmental protection wall paper is made by above-mentioned preparation method.
Through the above technical solutions, the present invention provides a kind of environmental protection wall paper and preparation method thereof, the preparation method packet
It includes:Plant fiber is placed in aqueous acetic acid, is ground after immersion, plant fiber powder is obtained;By plant fiber powder,
The is obtained after HMMM resin, epoxy resin, methacrylate, butyl glycol ether and coupling agent mixing
One mixing material;By wood pulp, mica powder, diatomite, lignocellulose, polyethylene glycol, nano zine oxide, two fourth of tin dilaurate
The second mixing material is obtained after Ji Xi, thickener and water mixing;After first mixing material and the second mixing material are mixed, through heat
It is molded to obtain environmental protection wall paper;Pass through the synergistic effect between each raw material so that environmental protection wall paper obtained has excellent antibacterial
Performance and flame retardant property, while the method for being used to prepare the environmental protection wall paper is simple, raw material is easy to get.
Other features and advantages of the present invention will be described in detail in subsequent specific embodiment part.
Specific implementation mode
The specific implementation mode of the present invention is described in detail below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
The endpoint of disclosed range and any value are not limited to the accurate range or value herein, these ranges or
Value should be understood as comprising the value close to these ranges or value.For numberical range, between the endpoint value of each range, respectively
It can be combined with each other between the endpoint value of a range and individual point value, and individually between point value and obtain one or more
New numberical range, these numberical ranges should be considered as specific open herein.
The present invention provides a kind of preparation method of environmental protection wall paper, the preparation method includes:
(1) plant fiber is placed in aqueous acetic acid, is ground after immersion, obtain plant fiber powder;
(2) by plant fiber powder, HMMM resin, epoxy resin, methacrylate, second two
The first mixing material is obtained after alcohol butyl ether and coupling agent mixing;
(3) by wood pulp, mica powder, diatomite, lignocellulose, polyethylene glycol, nano zine oxide, two fourth of tin dilaurate
The second mixing material is obtained after Ji Xi, thickener and water mixing;
(4) after mixing the first mixing material and the second mixing material, environmental protection wall paper is obtained through hot press molding.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, relative to the plant fiber of 100 parts by weight, the dosage of the aqueous acetic acid is 400-500 parts by weight;With/
Or
The volumetric concentration of aqueous acetic acid is 30-50%.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, relative to the plant fiber powder of 100 parts by weight, the dosage of the HMMM resin is
The dosage of 10-30 parts by weight, the epoxy resin is 2-15 parts by weight, and the dosage of the methacrylate is 5-15 weight
Part, the dosage of the butyl glycol ether is 50-90 parts by weight, and the dosage of the coupling agent is 2-8 parts by weight;
Relative to the wood pulp of 100 parts by weight, the dosage of the mica powder is 10-20 parts by weight, the diatomaceous dosage
Dosage for 5-15 parts by weight, the lignocellulose is 3-10 parts by weight, and the dosage of the polyethylene glycol is 30-80 weight
Part, the dosage of the nano zine oxide is 2-7 parts by weight, and the dosage of the dibutyl tin laurate is 2-10 parts by weight, institute
The dosage for stating thickener is 3-9 parts by weight, and the dosage of the water is 200-400 parts by weight.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, the first mixing material and the second mixing material are 1 according to mass ratio:The ratio of 2-4 is mixed.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, in step (1), the condition of immersion includes:Temperature is 40-50 DEG C, time 20-30min.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, in step (2), mixed condition includes:Temperature is 30-50 DEG C, time 40-60min.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, in step (3), mixed condition includes:Temperature is 50-60 DEG C, time 1-2h.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, coupling agent are one or more in coupling agent KH550, coupling agent KH560 and coupling agent KH570;And/or
Thickener is one or more in methylcellulose, hydroxypropyl methyl cellulose and sodium carboxymethylcellulose.
In a kind of preferred embodiment of the present invention, in order to further increase the anti-microbial property of environmental protection wall paper obtained
And flame retardant property, the weight average molecular weight of methacrylate is 7000-9000, and the weight average molecular weight of polyethylene glycol is 5000-
7000;And/or
The average grain diameter of nano zine oxide is 30-50nm.
The present invention also provides a kind of environmental protection wall paper, the environmental protection wall paper is made by above-mentioned preparation method.
The present invention will be described in detail by way of examples below.In following embodiment, the weight of methacrylate is equal
Molecular weight is 7000-9000, and the weight average molecular weight of polyethylene glycol is 5000-7000, and the average grain diameter of nano zine oxide is 30-
50nm。
Embodiment 1
100g plant fibers are placed in 400g aqueous acetic acids (volumetric concentration 30%), is ground, obtains after immersion
To plant fiber powder;By 100g plant fibers powder, 10g HMMM resins, 2g epoxy resin, 5g first
First is obtained after base acrylate, 50g butyl glycol ethers and 2g coupling agents KH550 mixing (temperature is 40 DEG C, time 20min)
Mixing material;100g wood pulps, 10g mica powders, 5g diatomite, 3g lignocelluloses, 30g polyethylene glycol, 2g is nano oxidized
It is obtained after zinc, 2g dibutyl tin laurates, 3g methylcellulose and 200g water mixing (temperature is 30 DEG C, time 40min)
Second mixing material;(it is 1 according to mass ratio after first mixing material and the second mixing material are mixed:2 are mixed, mixing
Condition include:Temperature is 50 DEG C, time 1h), environmental protection wall paper A1 is obtained through hot press molding.The resistance of environmental protection wall paper A1 obtained
Combustion grade is B1, and degerming rate is 70%.
Embodiment 2
100g plant fibers are placed in 500g aqueous acetic acids (volumetric concentration 50%), is ground, obtains after immersion
To plant fiber powder;By 100g plant fibers powder, 30g HMMM resins, 15g epoxy resin, 15g
The is obtained after methacrylate, 90g butyl glycol ethers and 8g coupling agents KH560 mixing (temperature is 50 DEG C, time 30min)
One mixing material;By 100g wood pulps, 20g mica powders, 15g diatomite, 10g lignocelluloses, 80g polyethylene glycol, 7g nanometers
(temperature is 50 DEG C, and the time is for zinc oxide, 10g dibutyl tin laurates, 9g hydroxypropyl methyl celluloses and the mixing of 400g water
The second mixing material is obtained after 60min);(it is 1 according to mass ratio after first mixing material and the second mixing material are mixed:4 into
Row mixing, mixed condition include:Temperature is 60 DEG C, time 2h), environmental protection wall paper A2 is obtained through hot press molding.Ring obtained
The flame retardant rating for protecting wallpaper A2 is B1, and degerming rate is 73%.
Embodiment 3
100g plant fibers are placed in 450g aqueous acetic acids (volumetric concentration 40%), is ground, obtains after immersion
To plant fiber powder;By 100g plant fibers powder, 20g HMMM resins, 7g epoxy resin, 10g
The is obtained after methacrylate, 70g butyl glycol ethers and 6g coupling agents KH570 mixing (temperature is 45 DEG C, time 25min)
One mixing material;By 100g wood pulps, 15g mica powders, 10g diatomite, 7g lignocelluloses, 50g polyethylene glycol, 5g nano oxygens
Change zinc, 6g dibutyl tin laurates, 6g sodium carboxymethylcelluloses and 300g water mixing (temperature is 40 DEG C, time 50min)
After obtain the second mixing material;(it is 1 according to mass ratio after first mixing material and the second mixing material are mixed:3 are mixed
It closes, mixed condition includes:Temperature is 55 DEG C, time 1.5h), environmental protection wall paper A3 is obtained through hot press molding.Environmental protection obtained
The flame retardant rating of wallpaper A3 is B1, and degerming rate is 76%.
Comparative example 1
It is carried out according to the method for embodiment 3, unlike, plant fiber powder is not contained in raw material, obtains environmental protection wall paper
The flame retardant rating of D1, environmental protection wall paper D1 obtained are B2, and degerming rate is 62%.
Comparative example 2
It is carried out according to the method for embodiment 3, unlike, mica powder and diatomite are not contained in raw material, obtain environmental protection wall
The flame retardant rating of paper D2, environmental protection wall paper D2 obtained are B2, and degerming rate is 60%.
The preferred embodiment of the present invention has been described above in detail, still, during present invention is not limited to the embodiments described above
Detail can carry out a variety of simple variants to technical scheme of the present invention within the scope of the technical concept of the present invention, this
A little simple variants all belong to the scope of protection of the present invention.
It is further to note that specific technical features described in the above specific embodiments, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy no longer separately illustrates.
In addition, various embodiments of the present invention can be combined randomly, as long as it is without prejudice to originally
The thought of invention, it should also be regarded as the disclosure of the present invention.
Claims (10)
1. a kind of preparation method of environmental protection wall paper, which is characterized in that the preparation method includes:
(1) plant fiber is placed in aqueous acetic acid, is ground after immersion, obtain plant fiber powder;
(2) by plant fiber powder, HMMM resin, epoxy resin, methacrylate, ethylene glycol fourth
The first mixing material is obtained after ether and coupling agent mixing;
(3) by wood pulp, mica powder, diatomite, lignocellulose, polyethylene glycol, nano zine oxide, di lauric dibutyl
The second mixing material is obtained after tin, thickener and water mixing;
(4) after mixing the first mixing material and the second mixing material, environmental protection wall paper is obtained through hot press molding.
2. preparation method according to claim 1, wherein relative to the plant fiber of 100 parts by weight, the acetic acid is water-soluble
The dosage of liquid is 400-500 parts by weight;And/or
The volumetric concentration of aqueous acetic acid is 30-50%.
3. preparation method according to claim 1, wherein relative to the plant fiber powder of 100 parts by weight, the pregnancy
The dosage of oxygen methyl melamine resin is 10-30 parts by weight, and the dosage of the epoxy resin is 2-15 parts by weight, the first
The dosage of base acrylate is 5-15 parts by weight, and the dosage of the butyl glycol ether is 50-90 parts by weight, the use of the coupling agent
Amount is 2-8 parts by weight;
Relative to the wood pulp of 100 parts by weight, the dosage of the mica powder is 10-20 parts by weight, and the diatomaceous dosage is 5-
The dosage of 15 parts by weight, the lignocellulose is 3-10 parts by weight, and the dosage of the polyethylene glycol is 30-80 parts by weight,
The dosage of the nano zine oxide is 2-7 parts by weight, and the dosage of the dibutyl tin laurate is 2-10 parts by weight, the increasing
Thick dose of dosage is 3-9 parts by weight, and the dosage of the water is 200-400 parts by weight.
4. preparation method according to claim 1, wherein the first mixing material and the second mixing material are according to mass ratio
1:The ratio of 2-4 is mixed.
5. preparation method according to claim 1, wherein in step (1), the condition of immersion includes:Temperature is 40-50
DEG C, time 20-30min.
6. preparation method according to claim 1, wherein in step (2), mixed condition includes:Temperature is 30-50
DEG C, time 40-60min.
7. preparation method according to claim 1, wherein in step (3), mixed condition includes:Temperature is 50-60
DEG C, time 1-2h.
8. preparation method according to claim 1, wherein coupling agent is selected from coupling agent KH550, coupling agent KH560 and idol
Join one or more in agent KH570;And/or
Thickener is one or more in methylcellulose, hydroxypropyl methyl cellulose and sodium carboxymethylcellulose.
9. preparation method according to claim 1, wherein the weight average molecular weight of methacrylate is 7000-9000, is gathered
The weight average molecular weight of ethylene glycol is 5000-7000;And/or
The average grain diameter of nano zine oxide is 30-50nm.
10. a kind of environmental protection wall paper, which is characterized in that the environmental protection wall paper is by the preparation described in any one of claim 1-9
Method is made.
Priority Applications (1)
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CN201810471854.6A CN108505399A (en) | 2018-05-17 | 2018-05-17 | Environmental protection wall paper and preparation method thereof |
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CN201810471854.6A CN108505399A (en) | 2018-05-17 | 2018-05-17 | Environmental protection wall paper and preparation method thereof |
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CN201810471854.6A Withdrawn CN108505399A (en) | 2018-05-17 | 2018-05-17 | Environmental protection wall paper and preparation method thereof |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105862518A (en) * | 2016-04-22 | 2016-08-17 | 滁州市莎朗新材料科技有限公司 | Permanently antibacterial negative-ion melt-blown non-woven fabric wallpaper base paper and making method thereof |
CN106245419A (en) * | 2016-09-07 | 2016-12-21 | 安徽金生金世电子科技有限公司 | Aging resistance wallpaper and preparation method thereof |
CN106283921A (en) * | 2016-09-07 | 2017-01-04 | 安徽金生金世电子科技有限公司 | Wear-resistant wallpaper and preparation method thereof |
CN106867327A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of resistant oil resistant wallpaper and preparation method thereof |
CN107245911A (en) * | 2017-08-02 | 2017-10-13 | 合肥市大卓电力有限责任公司 | A kind of preparation method of novel environment friendly wallpaper |
-
2018
- 2018-05-17 CN CN201810471854.6A patent/CN108505399A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105862518A (en) * | 2016-04-22 | 2016-08-17 | 滁州市莎朗新材料科技有限公司 | Permanently antibacterial negative-ion melt-blown non-woven fabric wallpaper base paper and making method thereof |
CN106245419A (en) * | 2016-09-07 | 2016-12-21 | 安徽金生金世电子科技有限公司 | Aging resistance wallpaper and preparation method thereof |
CN106283921A (en) * | 2016-09-07 | 2017-01-04 | 安徽金生金世电子科技有限公司 | Wear-resistant wallpaper and preparation method thereof |
CN106867327A (en) * | 2016-12-22 | 2017-06-20 | 安徽易有墙纸有限公司 | A kind of resistant oil resistant wallpaper and preparation method thereof |
CN107245911A (en) * | 2017-08-02 | 2017-10-13 | 合肥市大卓电力有限责任公司 | A kind of preparation method of novel environment friendly wallpaper |
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