CN107629606A - A kind of high resistance chromium nickel electrothermal alloy - Google Patents

A kind of high resistance chromium nickel electrothermal alloy Download PDF

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Publication number
CN107629606A
CN107629606A CN201711102576.9A CN201711102576A CN107629606A CN 107629606 A CN107629606 A CN 107629606A CN 201711102576 A CN201711102576 A CN 201711102576A CN 107629606 A CN107629606 A CN 107629606A
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parts
weight
main body
treatment liquid
coating treatment
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CN201711102576.9A
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Chinese (zh)
Inventor
陈俊达
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Changshu Meili Alloy Material Co Ltd
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Changshu Meili Alloy Material Co Ltd
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Priority to CN201711102576.9A priority Critical patent/CN107629606A/en
Publication of CN107629606A publication Critical patent/CN107629606A/en
Priority to PCT/CN2018/112963 priority patent/WO2019091315A1/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates

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  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Food-Manufacturing Devices (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of high resistance chromium nickel electrothermal alloy, it includes nichrome main body, and the nichrome main body passes through aluminum coated steel, and the aluminum coated steel comprises the following steps：1）1~2 parts by weight fatty alcohol polyoxyethylene ether sulfate, 5.8 parts by weight of lemon acid, 2.6 parts by weight diethylene glycol phenyl ethers, 4.3 parts by weight bipentaerythrites are put into 52 parts by weight of deionized water successively, stirred；2）Put into 1.3 parts by weight ammonium titanium fluorides, 2.4 parts by weight of polypropylene acid sodium, 3.5 parts by weight triethanolamine oleates, 1.7 parts by weight hexamethylenetetramines successively again, continue to stir, to being sufficiently mixed uniformly, coating treatment liquid is made；3）Nichrome main body is inserted in coating treatment liquid and impregnated, is dried after taking-up.High resistance chromium nickel electrothermal alloy of the present invention, its nichrome body surfaces are covered with protecting film, and performance is good, and surface smoothness is good.

Description

A kind of high resistance chromium nickel electrothermal alloy
Technical field
The present invention relates to a kind of high resistance chromium nickel electrothermal alloy.
Background technology
Existing high resistance chromium nickel electrothermal alloy, it is the abrasion-resistant of its nichrome main body, anti-oxidant, corrosion-resistant, antirust, weather-proof Performance has much room for improvement, and surface smoothness is also not ideal enough.
The content of the invention
It is an object of the invention to provide a kind of high resistance chromium nickel electrothermal alloy, and its nichrome main body is by overlay film Reason, nichrome body surfaces are covered with protecting film, have excellent abrasion-resistant, anti-oxidant, corrosion-resistant, antirust, weather resistance, and Surface smoothness is good.
To achieve the above object, the technical scheme is that designing a kind of high resistance chromium nickel electrothermal alloy, it includes nickel Evanohm main body, the nichrome main body pass through aluminum coated steel, and the aluminum coated steel comprises the following steps：
1）By 1~2 parts by weight fatty alcohol polyoxyethylene ether sulfate, 5.8 parts by weight of lemon acid, 2.6 parts by weight diethylene glycol benzene Base ether, 4.3 parts by weight bipentaerythrites are put into 52 parts by weight of deionized water successively, are stirred；
2）Put into 1.3 parts by weight ammonium titanium fluorides, 2.4 parts by weight of polypropylene acid sodium, 3.5 parts by weight triethanolamine oleates successively again Soap, 1.7 parts by weight hexamethylenetetramines, continue to stir, and to being sufficiently mixed uniformly, coating treatment liquid is made；
3）Nichrome main body is inserted in coating treatment liquid and impregnated, is dried after taking-up.
Preferably, a kind of high resistance chromium nickel electrothermal alloy, it includes nichrome main body, and the nichrome main body is by covering Film process, the aluminum coated steel comprise the following steps：
1）By 1.2 parts by weight fatty alcohol polyoxyethylene ether sulfates, 5.8 parts by weight of lemon acid, 2.6 parts by weight diethylene glycol phenyl Ether, 4.3 parts by weight bipentaerythrites are put into 52 parts by weight of deionized water successively, are stirred；
2）Put into 1.3 parts by weight ammonium titanium fluorides, 2.4 parts by weight of polypropylene acid sodium, 3.5 parts by weight triethanolamine oleates successively again Soap, 1.7 parts by weight hexamethylenetetramines, continue to stir, and to being sufficiently mixed uniformly, coating treatment liquid is made；
3）Nichrome main body is inserted in coating treatment liquid and impregnated, is dried after taking-up.
The advantages of the present invention are：A kind of high resistance chromium nickel electrothermal alloy, its nichrome main body are provided By aluminum coated steel, nichrome body surfaces are covered with protecting film, have excellent abrasion-resistant, anti-oxidant, corrosion-resistant, antirust, Weather resistance, and surface smoothness is good.
The performance and purposes of " coating treatment liquid " determined by its component and proportioning, and in " coating treatment liquid " not It can be influenced each other with component, component and its proportioning can determine the final performance of " coating treatment liquid ", such as fruit component and its proportioning not It is mutually coordinated, beneficial effect caused by single component, it can be cut down by other components and even eliminate, when serious, different groups Split-phase mutually contradicts, and does not have whole synthesis effect, produces negative interaction and substandard products.The present invention by a large amount of creative works, repeatedly Checking, obtains the optimal component and proportioning of " coating treatment liquid " so that multiple components combine, mutually coordinated and produce Positive comprehensive effect.
Embodiment
With reference to embodiment, the embodiment of the present invention is further described.Following examples are only used for more Add and clearly demonstrate technical scheme, and can not be limited the scope of the invention with this.
The technical scheme that the present invention is embodied is：
Embodiment 1
A kind of high resistance chromium nickel electrothermal alloy, it includes nichrome main body, and the nichrome main body passes through aluminum coated steel, described Aluminum coated steel comprises the following steps：
1）By 1 parts by weight fatty alcohol polyoxyethylene ether sulfate, 5.8 parts by weight of lemon acid, 2.6 parts by weight diethylene glycol phenyl Ether, 4.3 parts by weight bipentaerythrites are put into 52 parts by weight of deionized water successively, are stirred；
2）Put into 1.3 parts by weight ammonium titanium fluorides, 2.4 parts by weight of polypropylene acid sodium, 3.5 parts by weight triethanolamine oleates successively again Soap, 1.7 parts by weight hexamethylenetetramines, continue to stir, and to being sufficiently mixed uniformly, coating treatment liquid is made；
3）Nichrome main body is inserted in coating treatment liquid and impregnated, is dried after taking-up.
Embodiment 2
A kind of high resistance chromium nickel electrothermal alloy, it includes nichrome main body, and the nichrome main body passes through aluminum coated steel, described Aluminum coated steel comprises the following steps：
1）By 2 parts by weight fatty alcohol polyoxyethylene ether sulfates, 5.8 parts by weight of lemon acid, 2.6 parts by weight diethylene glycol phenyl Ether, 4.3 parts by weight bipentaerythrites are put into 52 parts by weight of deionized water successively, are stirred；
2）Put into 1.3 parts by weight ammonium titanium fluorides, 2.4 parts by weight of polypropylene acid sodium, 3.5 parts by weight triethanolamine oleates successively again Soap, 1.7 parts by weight hexamethylenetetramines, continue to stir, and to being sufficiently mixed uniformly, coating treatment liquid is made；
3）Nichrome main body is inserted in coating treatment liquid and impregnated, is dried after taking-up.
Embodiment 3
A kind of high resistance chromium nickel electrothermal alloy, it includes nichrome main body, and the nichrome main body passes through aluminum coated steel, described Aluminum coated steel comprises the following steps：
1）By 1.2 parts by weight fatty alcohol polyoxyethylene ether sulfates, 5.8 parts by weight of lemon acid, 2.6 parts by weight diethylene glycol phenyl Ether, 4.3 parts by weight bipentaerythrites are put into 52 parts by weight of deionized water successively, are stirred；
2）Put into 1.3 parts by weight ammonium titanium fluorides, 2.4 parts by weight of polypropylene acid sodium, 3.5 parts by weight triethanolamine oleates successively again Soap, 1.7 parts by weight hexamethylenetetramines, continue to stir, and to being sufficiently mixed uniformly, coating treatment liquid is made；
3）Nichrome main body is inserted in coating treatment liquid and impregnated, is dried after taking-up.
Surface through nichrome main body in the various embodiments described above is covered with protecting film, have excellent abrasion-resistant, it is anti-oxidant, Corrosion-resistant, antirust, weather resistance, and surface smoothness is good.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, without departing from the technical principles of the invention, some improvements and modifications can also be made, these improvements and modifications Also it should be regarded as protection scope of the present invention.

Claims (2)

1. a kind of high resistance chromium nickel electrothermal alloy, it is characterised in that it includes nichrome main body, and the nichrome main body is passed through Aluminum coated steel, the aluminum coated steel comprise the following steps：
1）By 1~2 parts by weight fatty alcohol polyoxyethylene ether sulfate, 5.8 parts by weight of lemon acid, 2.6 parts by weight diethylene glycol benzene Base ether, 4.3 parts by weight bipentaerythrites are put into 52 parts by weight of deionized water successively, are stirred；
2）Put into 1.3 parts by weight ammonium titanium fluorides, 2.4 parts by weight of polypropylene acid sodium, 3.5 parts by weight triethanolamine oleates successively again Soap, 1.7 parts by weight hexamethylenetetramines, continue to stir, and to being sufficiently mixed uniformly, coating treatment liquid is made；
3）Nichrome main body is inserted in coating treatment liquid and impregnated, is dried after taking-up.
2. high resistance chromium nickel electrothermal alloy according to claim 1, it is characterised in that it includes nichrome main body, should Nichrome main body passes through aluminum coated steel, and the aluminum coated steel comprises the following steps：
1）By 1.2 parts by weight fatty alcohol polyoxyethylene ether sulfates, 5.8 parts by weight of lemon acid, 2.6 parts by weight diethylene glycol phenyl Ether, 4.3 parts by weight bipentaerythrites are put into 52 parts by weight of deionized water successively, are stirred；
2）Put into 1.3 parts by weight ammonium titanium fluorides, 2.4 parts by weight of polypropylene acid sodium, 3.5 parts by weight triethanolamine oleates successively again Soap, 1.7 parts by weight hexamethylenetetramines, continue to stir, and to being sufficiently mixed uniformly, coating treatment liquid is made；
3）Nichrome main body is inserted in coating treatment liquid and impregnated, is dried after taking-up.
CN201711102576.9A 2017-11-10 2017-11-10 A kind of high resistance chromium nickel electrothermal alloy Pending CN107629606A (en)

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CN201711102576.9A CN107629606A (en) 2017-11-10 2017-11-10 A kind of high resistance chromium nickel electrothermal alloy
PCT/CN2018/112963 WO2019091315A1 (en) 2017-11-10 2018-10-31 Electrothermal chromium-nickel alloy with high resistance

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019091315A1 (en) * 2017-11-10 2019-05-16 常熟市梅李合金材料有限公司 Electrothermal chromium-nickel alloy with high resistance

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105420716A (en) * 2015-12-09 2016-03-23 常熟市常宝电动过跨平车厂 Special flatcar for railway containers
CN106280630A (en) * 2016-08-25 2017-01-04 常熟市梅李合金材料有限公司 Heating high-resistance electrothermic alloy silk

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Publication number Priority date Publication date Assignee Title
CN105986300A (en) * 2015-03-03 2016-10-05 天津友鹏永悦工贸有限公司 Fixing frame for coating bicycle frames
CN106282986A (en) * 2016-08-25 2017-01-04 常熟市梅李合金材料有限公司 Heating nickel chromium triangle flat filament
CN106332326A (en) * 2016-08-25 2017-01-11 常熟市梅李合金材料有限公司 Nickel-chromium wire for electric heating element
CN106958023A (en) * 2017-04-06 2017-07-18 天长市润达金属防锈助剂有限公司 A kind of high osmosis modified metal antirust agent eliminated rust for workpiece
CN107629606A (en) * 2017-11-10 2018-01-26 常熟市梅李合金材料有限公司 A kind of high resistance chromium nickel electrothermal alloy

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105420716A (en) * 2015-12-09 2016-03-23 常熟市常宝电动过跨平车厂 Special flatcar for railway containers
CN106280630A (en) * 2016-08-25 2017-01-04 常熟市梅李合金材料有限公司 Heating high-resistance electrothermic alloy silk

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019091315A1 (en) * 2017-11-10 2019-05-16 常熟市梅李合金材料有限公司 Electrothermal chromium-nickel alloy with high resistance

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