CN106283921A - Wear-resistant wallpaper and preparation method thereof - Google Patents
Wear-resistant wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN106283921A CN106283921A CN201610805965.7A CN201610805965A CN106283921A CN 106283921 A CN106283921 A CN 106283921A CN 201610805965 A CN201610805965 A CN 201610805965A CN 106283921 A CN106283921 A CN 106283921A
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- CN
- China
- Prior art keywords
- preparation
- fiber
- wear
- wallpaper
- dispensing
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
- D21D1/00—Methods of beating or refining; Beaters of the Hollander type
- D21D1/20—Methods of refining
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/36—Inorganic fibres or flakes
- D21H13/38—Inorganic fibres or flakes siliceous
- D21H13/40—Inorganic fibres or flakes siliceous vitreous, e.g. mineral wool, glass fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention discloses the preparation method of a kind of wear-resistant wallpaper, the method includes: (1) Plant fiber is added water defibrination process prepare oleo stock；(2) modified glass-fiber, phthalocyanine, Polyethylene Glycol, starch, fatty acid and dispersant are prepared dispensing；(3) dispensing is added in described oleo stock, and dilute, then prepare wear-resistant wallpaper through professional equipment molding, drying；Wherein, in parts by weight, dispensing with the weight ratio of oleo stock is: 1:90 100；A length of 65 75 μm of modified glass-fiber.The wear-resistant wallpaper prepared by the method has high tenacity and big tensile strength, it is possible to reach wear-resisting effect.
Description
Technical field
The present invention relates to wallpaper, be specifically related to wear-resistant wallpaper and preparation method thereof.
Background technology
Wallpaper, be a kind of indoor hardware fitting for papering metope, is widely used in house, office, hotel, hotel
Interior decoration etc..Material is not limited to paper, also comprises other materials.Because having, color is various, pattern abundant, luxurious style, peace
The feature that other house decorative materials multiple such as loopful guarantor, easy construction, affordable are incomparable, thus be widely used.
Wallpaper is divided into a lot of class, such as overlay film wallpaper, coating wallpaper, embossing wallpaper etc..Generally produce body paper, then warp with bleached wood pulp
The processed of different operations, as be coated with, prints, emboss or surface being covered and moulded, the most cut, pack after dispatch from the factory.But it is current
Commercially available wallpaper, its mechanical mechanics property such as intensity, toughness is the best, easily abrasion occurs thus affect attractive in appearance and use in using.
Summary of the invention
An object of the present invention is to provide mild condition, the preparation method of wear-resistant wallpaper simple to operate.
It is a further object of the present invention to provide, by what said method was prepared from, there is high tenacity and big tensile strength, energy
Enough reach the wear-resistant wallpaper of abrasion resistant effect.
The preparation method of wear-resistant wallpaper that the present invention provides includes: (1) Plant fiber is added water defibrination process prepare former
Slurry；(2) modified glass-fiber, phthalocyanine, Polyethylene Glycol, starch, fatty acid and dispersant are prepared dispensing；(3) will join
Material adds in described oleo stock, and dilute, then prepares wear-resistant wallpaper through professional equipment molding, drying；Wherein, with weight
Part meter, dispensing with the weight ratio of oleo stock is: 1:90-100；The a length of 65-75 μm of modified glass-fiber.
In the step (1) of above-mentioned preparation method, the concrete kind of Plant fiber can select, from one-tenth in wide scope
Consider in basis, it is preferable that Plant fiber is one kind of multiple in bark, bamboo, bagasse, phragmites communis, Caulis et Folium Oryzae and wheat straw.
In the step (2) of above-mentioned preparation method, the concrete kind of dispersant can select in wide scope, but is
Improve the tensile strength of obtained wallpaper, it is preferable that dispersant is sodium lauryl sulphate, methyl anyl alcohol and cellulose derivative
In one or more.
In the step (2) of above-mentioned preparation method, the concrete amount ratio of each material can select in wide scope, but
For improving the tensile strength of obtained wallpaper further, it is preferable that relative to the modified glass-fiber of 5 weight portions, phthalocyanine is
10-20 weight portion, Polyethylene Glycol be 5-8 weight portion, starch be 5-10 weight portion, fatty acid be that 10-20 weight portion, dispersant are
5-10 weight portion.
In the step (2) of above-mentioned preparation method, modified glass-fiber is to prepare by the following method: first by glass fibre
It is placed in hydrogen peroxide and carries out oxidation processes, be then immersed in titanate coupling agent.
In the above-mentioned method preparing modified glass-fiber, the length of glass fibre can select in wide scope, for
The contact force increasing glass fibre and hydrogen peroxide optimizes oxidation effectiveness, it is preferable that a length of 50-80 μm of glass fibre.
In the above-mentioned method preparing modified glass-fiber, the concentration of hydrogen peroxide can select, from one-tenth in wide scope
Consider in this and effect, it is preferable that the concentration of the amount of the material of hydrogen peroxide is 0.05-0.1mol/L.
In the above-mentioned method preparing modified glass-fiber, the temperature and time of immersion can select in wide scope,
For improving the titanate coupling agent modified effect to glass fibre, it is preferable that the temperature of immersion is 40-70 DEG C, the time of immersion
For 30-50min.
In the step (3) of above-mentioned preparation method, dispensing can select with the concrete amount ratio of water in wide scope, from
Consider on cost and effect, it is preferable that dispensing is 1:800-1:1000 with the volume ratio of water.
Present invention also offers wear-resistant wallpaper, this wallpaper is to be prepared from by above-mentioned method.
By technique scheme, the present invention is processed by the defibrination that first Plant fiber added water and prepares oleo stock, will change simultaneously
Property glass fibre, phthalocyanine, Polyethylene Glycol, starch, fatty acid and dispersant prepare dispensing；Last dispensing adds oleo stock
In, dilute, molding, drying prepare wear-resistant wallpaper.In the process, the process of defibrination enables to obtained wallpaper tool
Having high tenacity, additionally, modified glass fibre peacekeeping unclassified stores interacts, the dispensing prepared can effectively improve obtained wall
The toughness of paper and tensile strength；Last dispensing and the mixing of oleo stock, each storeroom interacts and then makes obtained wallpaper have
Excellent mechanical mechanical property, it is possible to reach wear-resisting effect.The method be a kind of with low cost, mild condition, environmental protection and
Method simple to operate.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
Embodiment 1
(1) defibrination that added water by bamboo processes and prepares oleo stock；
(2) by the modified glass-fiber of a length of for 5 weight portions 65 μm, 12 weight portion phthalocyanines, 5 weight portion Polyethylene Glycol, 6
Weight starch, 12 parts by weight of fatty acid and 5 weight portion sodium lauryl sulphates are mixed to prepare dispensing；
(3) 1 weight portion dispensing is added in 90 weight portion oleo stock, and add 800 weight parts water dilutions, then molding, drying
Prepare wear-resistant wallpaper A1.
Wherein, modified glass-fiber is to prepare by the following method: first the glass fibre of a length of 55 μm is placed in concentration
For the hydrogen peroxide of 0.05mol/L carries out oxidation processes, then it is placed in the titanate coupling agent that temperature is 45 DEG C immersion
35min。
Embodiment 2
(1) by phragmites communis and Caulis et Folium Oryzae, defibrination in water processes and prepares oleo stock；
(2) by the modified glass-fiber of a length of for 5 weight portions 75 μm, 20 weight portion phthalocyanines, 8 weight portion Polyethylene Glycol, 8
Weight starch, 18 parts by weight of fatty acid and 8 weight portion phthalocyanine derivants are mixed to prepare dispensing；
(3) 1 weight portion dispensing is added in 98 weight portion oleo stock, and add 1000 weight parts water dilutions, then molding, drying
Prepare wear-resistant wallpaper A2.
Wherein, modified glass-fiber is to prepare by the following method: first the glass fibre of a length of 80 μm is placed in material
Amount the hydrogen peroxide that concentration is 0.1mol/L in carry out oxidation processes, be then placed in the titanate coupling agent that temperature is 65 DEG C
Soak 45min.
Embodiment 3
(1) phragmites communis defibrination in water is processed prepared oleo stock；
(2) by the modified glass-fiber of a length of for 5 weight portions 70 μm, 15 weight portion phthalocyanines, 6 weight portion Polyethylene Glycol, 7
Weight starch, 15 parts by weight of fatty acid and 7 weight portion methyl anyl alcohols are mixed to prepare dispensing；
(3) 1 weight portion dispensing is added in 95 weight portion oleo stock, and add 900 weight parts water dilutions, then molding, drying
Prepare wear-resistant wallpaper A3.
Wherein, modified glass-fiber is to prepare by the following method: first the glass fibre of a length of 65 μm is placed in material
Amount the hydrogen peroxide that concentration is 0.075mol/L in carry out oxidation processes, be then placed in the titanate coupling agent that temperature is 55 DEG C
Middle immersion 40min.
Comparative example 1
Carry out preparing wallpaper B1 according to the method for embodiment 1, except that, the modified glass fibre added in step (2)
A length of 200 μm of dimension.
Comparative example 2
Carry out preparing wallpaper B2 according to the method for embodiment 2, except that, dispensing and the weight of oleo stock in step (3)
Amount ratio is 1:10.
Detection example 1
The wallpaper preparing above-described embodiment and comparative example carries out the test of toughness, tensile strength, and concrete outcome is shown in Table 1.
Table 1
| A1 | A2 | A3 | B1 | B2 | |
| Toughness/MPa | 82 | 84 | 82 | 60 | 62 |
| Tensile strength/MPa | 112 | 110 | 108 | 58 | 64 |
By above-mentioned detection example, the toughness of the wallpaper prepared by above-described embodiment is big, tensile strength is big.By above-mentioned
The testing result of embodiment is learnt, the wear-resistant wallpaper that the present invention provides has high tenacity and big tensile strength, it is possible to reach
Wear-resisting effect.Additionally, from the preparation process of the present invention it can be seen that the preparation method bar of wear-resistant wallpaper that provides of the present invention
Part is gentle, simple to operate.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this
A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can
The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this
The thought of invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. the preparation method of a wear-resistant wallpaper, it is characterised in that described method includes:
(1) defibrination that Plant fiber added water processes and prepares oleo stock；
(2) modified glass-fiber, phthalocyanine, Polyethylene Glycol, starch, fatty acid and dispersant are prepared dispensing；
(3) described dispensing is added in described oleo stock, and dilute, then prepare wear-resistant through professional equipment molding, drying
Wallpaper；
Wherein, in parts by weight, described dispensing with the weight ratio of described oleo stock is: 1:90-100；Described modified glass-fiber
A length of 65-75 μm.
Preparation method the most according to claim 1, wherein, in step (1), described Plant fiber is bark, bamboo, sweet
One kind of multiple in bagasse, phragmites communis, Caulis et Folium Oryzae and wheat straw.
Preparation method the most according to claim 1, wherein, in step (2), described dispersant is lauryl sulphate acid
One or more in sodium, methyl anyl alcohol and cellulose derivative.
4. according to the preparation method according to any one of claim 1-3, wherein, in step (2), relative to 5 weight portions
Described modified glass-fiber, described phthalocyanine be 10-20 weight portion, described Polyethylene Glycol be 5-8 weight portion, described starch be 5-
10 weight portions, described fatty acid be 10-20 weight portion, described dispersant be 5-10 weight portion.
Preparation method the most according to claim 4, wherein, in step (2), described modified glass-fiber is by following
Method prepares: is first placed in hydrogen peroxide by glass fibre and carries out oxidation processes, is then immersed in titanate coupling agent.
Preparation method the most according to claim 5, wherein, a length of 50-80 μm of described glass fibre.
Preparation method the most according to claim 5, wherein, the concentration of the amount of the material of described hydrogen peroxide is 0.05-
0.1mol/L。
8. according to the preparation method described in claim 5 or 7, wherein, the temperature of described immersion is 40-70 DEG C, the time of immersion
For 30-50min.
Preparation method the most according to claim 8, wherein, in step (3), described dispensing with the volume ratio of described water is
1:800-1:1000。
10. a wear-resistant wallpaper, it is characterised in that described wallpaper passes through the method in claim 1-9 described in any one
It is prepared from.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610805965.7A CN106283921A (en) | 2016-09-07 | 2016-09-07 | Wear-resistant wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610805965.7A CN106283921A (en) | 2016-09-07 | 2016-09-07 | Wear-resistant wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106283921A true CN106283921A (en) | 2017-01-04 |
Family
ID=57710920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610805965.7A Pending CN106283921A (en) | 2016-09-07 | 2016-09-07 | Wear-resistant wallpaper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106283921A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107119501A (en) * | 2017-06-22 | 2017-09-01 | 合肥励仙电力工程有限公司 | High wear-resisting wrapping paper of a kind of structural strength and preparation method thereof |
| CN108505398A (en) * | 2018-05-17 | 2018-09-07 | 安徽银兔装饰材料有限公司 | Environmental protection wall paper and preparation method thereof |
| CN108505399A (en) * | 2018-05-17 | 2018-09-07 | 安徽银兔装饰材料有限公司 | Environmental protection wall paper and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07122236B2 (en) * | 1990-12-13 | 1995-12-25 | 日本製紙株式会社 | Exterior wallpaper backing paper |
| CN103074807A (en) * | 2013-01-28 | 2013-05-01 | 浙江华邦特种纸业有限公司 | Making method of ultrathin low-weight sound-absorbing decoration paper |
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
| CN105219013A (en) * | 2015-11-18 | 2016-01-06 | 上海瀚氏模具成型有限公司 | Damage resistant ABS plastic and preparation method thereof |
| CN105297531A (en) * | 2015-11-16 | 2016-02-03 | 上海畅厘信息科技有限公司 | Paper pulp |
-
2016
- 2016-09-07 CN CN201610805965.7A patent/CN106283921A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07122236B2 (en) * | 1990-12-13 | 1995-12-25 | 日本製紙株式会社 | Exterior wallpaper backing paper |
| CN103074807A (en) * | 2013-01-28 | 2013-05-01 | 浙江华邦特种纸业有限公司 | Making method of ultrathin low-weight sound-absorbing decoration paper |
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
| CN105297531A (en) * | 2015-11-16 | 2016-02-03 | 上海畅厘信息科技有限公司 | Paper pulp |
| CN105219013A (en) * | 2015-11-18 | 2016-01-06 | 上海瀚氏模具成型有限公司 | Damage resistant ABS plastic and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107119501A (en) * | 2017-06-22 | 2017-09-01 | 合肥励仙电力工程有限公司 | High wear-resisting wrapping paper of a kind of structural strength and preparation method thereof |
| CN108505398A (en) * | 2018-05-17 | 2018-09-07 | 安徽银兔装饰材料有限公司 | Environmental protection wall paper and preparation method thereof |
| CN108505399A (en) * | 2018-05-17 | 2018-09-07 | 安徽银兔装饰材料有限公司 | Environmental protection wall paper and preparation method thereof |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170104 |
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| RJ01 | Rejection of invention patent application after publication |