CN106245419A - Aging resistance wallpaper and preparation method thereof - Google Patents
Aging resistance wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN106245419A CN106245419A CN201610805995.8A CN201610805995A CN106245419A CN 106245419 A CN106245419 A CN 106245419A CN 201610805995 A CN201610805995 A CN 201610805995A CN 106245419 A CN106245419 A CN 106245419A
- Authority
- CN
- China
- Prior art keywords
- preparation
- wallpaper
- dispensing
- aging resistance
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/36—Inorganic fibres or flakes
- D21H13/38—Inorganic fibres or flakes siliceous
- D21H13/40—Inorganic fibres or flakes siliceous vitreous, e.g. mineral wool, glass fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/25—Cellulose
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
Abstract
The invention discloses the preparation method of a kind of aging resistance wallpaper, the method includes: (1) Plant fiber is added water defibrination process prepare oleo stock；(2) modified glass-fiber, cellulose, phthalocyanine blue, starch, polyvinyl alcohol and adhesive are mixed to prepare dispensing；(3) dispensing is added in described oleo stock, and dilute, then molding, drying prepare aging resistance wallpaper；Wherein, in parts by weight, dispensing with the weight ratio of oleo stock is: 1:20 25.The aging resistance wallpaper prepared by the method has high tenacity and big tensile strength, it is possible to reach wear-resisting effect.
Description
Technical field
The present invention relates to wallpaper, be specifically related to aging resistance wallpaper and preparation method thereof.
Background technology
Wallpaper, be a kind of indoor hardware fitting for papering metope, is widely used in house, office, hotel, hotel
Interior decoration etc..Material is not limited to paper, also comprises other materials.Because having, color is various, pattern abundant, luxurious style, peace
The feature that other house decorative materials multiple such as loopful guarantor, easy construction, affordable are incomparable, thus be widely used.
Wallpaper is divided into a lot of class, such as overlay film wallpaper, coating wallpaper, embossing wallpaper etc..Generally produce body paper, then warp with bleached wood pulp
The processed of different operations, as be coated with, prints, emboss or surface being covered and moulded, the most cut, pack after dispatch from the factory.But it is current
Commercially available wallpaper, its mechanical mechanics property such as intensity, toughness is the best, easily abrasion occurs thus affect attractive in appearance and use in using.
Summary of the invention
An object of the present invention is to provide mild condition, the preparation method of aging resistance wallpaper simple to operate.
It is a further object of the present invention to provide, by what said method was prepared from, there is high tenacity and big tensile strength, energy
Enough reach the aging resistance wallpaper of abrasion resistant effect.
The preparation method of aging resistance wallpaper that the present invention provides includes: (1) Plant fiber is added water defibrination process prepare former
Slurry；(2) modified glass-fiber, cellulose, phthalocyanine blue, starch, polyvinyl alcohol and adhesive are mixed to prepare dispensing；(3) will join
Material adds in described oleo stock, and dilute, and then molding, drying prepare aging resistance wallpaper；Wherein, in parts by weight, dispensing
With the weight ratio of oleo stock it is: 1:20-25.
In the step (1) of above-mentioned preparation method, the concrete kind of Plant fiber can select, from one-tenth in wide scope
Consider in basis, it is preferable that Plant fiber is one kind of multiple in bark, bamboo, bagasse, phragmites communis, Caulis et Folium Oryzae and wheat straw.
In the step (2) of above-mentioned preparation method, the concrete kind of adhesive can select in wide scope, but is
Improve the tensile strength of obtained wallpaper, it is preferable that adhesive is in polyvinyl acetate, Vinylidene Chloride and polyisobutylene
Plant or multiple.
In the step (2) of above-mentioned preparation method, the concrete amount ratio of each material can select in wide scope, but
For improving the tensile strength of obtained wallpaper further, it is preferable that relative to the modified glass-fiber of 5 weight portions, cellulose is
10-20 weight portion, phthalocyanine blue be 5-8 weight portion, starch be 5-10 weight portion, polyvinyl alcohol be that 10-20 weight portion, adhesive are
5-10 weight portion.
In the step (2) of above-mentioned preparation method, modified glass-fiber is to prepare by the following method: first by glass fibre
It is placed in potassium permanganate solution and carries out oxidation processes, be then immersed in titanate coupling agent.
In the above-mentioned method preparing modified glass-fiber, the length of glass fibre can select in wide scope, for
The contact force increasing glass fibre and potassium permanganate solution optimizes oxidation effectiveness, it is preferable that a length of 50-80 of glass fibre
μm。
In the above-mentioned method preparing modified glass-fiber, the concentration of potassium permanganate solution can be selected in wide scope
Select, consider from cost and effect, it is preferable that the concentration of the amount of the material of potassium permanganate solution is 0.05-0.1mol/L.
In the above-mentioned method preparing modified glass-fiber, the temperature and time of immersion can select in wide scope,
For improving the titanate coupling agent modified effect to glass fibre, it is preferable that the temperature of immersion is 40-70 DEG C, the time of immersion
For 30-50min.
In the step (3) of above-mentioned preparation method, dispensing can select with the concrete amount ratio of water in wide scope, from
Consider on cost and effect, it is preferable that dispensing is 1:800-1:1000 with the volume ratio of water.
Present invention also offers aging resistance wallpaper, this wallpaper is to be prepared from by above-mentioned method.
By technique scheme, the present invention is processed by the defibrination that first Plant fiber added water and prepares oleo stock, will change simultaneously
Property glass fibre, cellulose, phthalocyanine blue, starch, polyvinyl alcohol and adhesive are mixed to prepare dispensing；Last dispensing adds oleo stock
In, dilute, molding, drying prepare aging resistance wallpaper.In the process, the process of defibrination enables to obtained wallpaper tool
Having high tenacity, additionally, modified glass fibre peacekeeping unclassified stores interacts, the dispensing prepared can effectively improve obtained wall
The toughness of paper and tensile strength；Last dispensing and the mixing of oleo stock, each storeroom interacts and then makes obtained wallpaper have
Excellent mechanical mechanical property, it is possible to reach wear-resisting effect.The method be a kind of with low cost, mild condition, environmental protection and
Method simple to operate.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that described herein specifically
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.
Embodiment 1
(1) defibrination that added water by bamboo processes and prepares oleo stock；
(2) by 5 part by weight modified glass fibre, 12 part by weight of cellulose, 5 weight portion phthalocyanine blues, 6 weight starch, 12
Weight account polyethylene alcohol and 5 weight portion polyvinyl acetate are mixed to prepare dispensing；
(3) 1 weight portion dispensing is added in 20 weight portion oleo stock, and add 800 weight parts water dilutions, then molding, drying
Prepare aging resistance wallpaper A1.
Wherein, modified glass-fiber is to prepare by the following method: first the glass fibre of a length of 55 μm is placed in concentration
For the potassium permanganate solution of 0.05mol/L carries out oxidation processes, then it is placed in the titanate coupling agent that temperature is 45 DEG C leaching
Bubble 35min.
Embodiment 2
(1) by phragmites communis and Caulis et Folium Oryzae, defibrination in water processes and prepares oleo stock；
(2) by 5 part by weight modified glass fibre, 20 part by weight of cellulose, 8 weight portion phthalocyanine blues, 8 weight starch, 18
Weight account polyethylene alcohol and 8 weight portion polyisobutylene are mixed to prepare dispensing；
(3) 1 weight portion dispensing is added in 25 weight portion oleo stock, and add 1000 weight parts water dilutions, then molding, drying
Prepare aging resistance wallpaper A2.
Wherein, modified glass-fiber is to prepare by the following method: first the glass fibre of a length of 80 μm is placed in material
Amount the potassium permanganate solution that concentration is 0.1mol/L in carry out oxidation processes, be then placed in titanate esters that temperature is 65 DEG C even
45min is soaked in connection agent.
Embodiment 3
(1) phragmites communis defibrination in water is processed prepared oleo stock；
(2) by 5 weight modified glass-fibers, 15 part by weight of cellulose, 6 weight portion phthalocyanine blues, 7 weight starch, 15 weights
Amount part polyvinyl alcohol and 7 weight portion Vinylidene Chloride are mixed to prepare dispensing；
(3) 1 weight portion dispensing is added in 22 weight portion oleo stock, and add 900 weight parts water dilutions, then molding, drying
Prepare aging resistance wallpaper A3.
Wherein, modified glass-fiber is to prepare by the following method: first the glass fibre of a length of 65 μm is placed in material
Amount the potassium permanganate solution that concentration is 0.075mol/L in carry out oxidation processes, be then placed in the titanate esters that temperature is 55 DEG C
Coupling agent soaks 40min.
Comparative example 1
Carry out preparing wallpaper B1 according to the method for embodiment 1, except that, step does not adds starch in (2).
Comparative example 2
Carry out preparing wallpaper B2 according to the method for embodiment 2, except that, dispensing and the weight of oleo stock in step (3)
Amount ratio is: 1:70.
Detection example 1
The wallpaper preparing above-described embodiment and comparative example carries out the test of toughness, tensile strength, and concrete outcome is shown in Table 1.
Table 1
| A1 | A2 | A3 | B1 | B2 | |
| Toughness/MPa | 100 | 98 | 102 | 60 | 70 |
| Tensile strength/MPa | 112 | 110 | 108 | 58 | 64 |
By above-mentioned detection example, the toughness of the wallpaper prepared by above-described embodiment is big, tensile strength is big.By above-mentioned
The testing result of embodiment is learnt, the aging resistance wallpaper that the present invention provides has high tenacity and big tensile strength, it is possible to reach
Wear-resisting effect.Additionally, from the preparation process of the present invention it can be seen that the preparation method bar of aging resistance wallpaper that provides of the present invention
Part is gentle, simple to operate.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned embodiment
Detail, in the technology concept of the present invention, technical scheme can be carried out multiple simple variant, this
A little simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technical characteristic described in above-mentioned detailed description of the invention, at not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to various can
The compound mode of energy illustrates the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as it is without prejudice to this
The thought of invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. the preparation method of an aging resistance wallpaper, it is characterised in that described method includes:
(1) defibrination that Plant fiber added water processes and prepares oleo stock；
(2) modified glass-fiber, cellulose, phthalocyanine blue, starch, polyvinyl alcohol and adhesive are mixed to prepare dispensing；
(3) described dispensing is added in described oleo stock, and dilute, then molding, drying prepare aging resistance wallpaper；
Wherein, in parts by weight, described dispensing with the weight ratio of described oleo stock is: 1:20-25.
Preparation method the most according to claim 1, wherein, in step (1), described Plant fiber is bark, bamboo, sweet
One kind of multiple in bagasse, phragmites communis, Caulis et Folium Oryzae and wheat straw.
Preparation method the most according to claim 1, wherein, in step (2), described adhesive be polyvinyl acetate,
One or more in Vinylidene Chloride and polyisobutylene.
4. according to the preparation method according to any one of claim 1-3, wherein, in step (2), relative to 5 weight portions
Described modified glass-fiber, described cellulose be 10-20 weight portion, described phthalocyanine blue be 5-8 weight portion, described starch be 5-10
Weight portion, described polyvinyl alcohol be 10-20 weight portion, described adhesive be 5-10 weight portion.
Preparation method the most according to claim 4, wherein, in step (2), described modified glass-fiber is by following
Method prepares: is first placed in potassium permanganate solution by glass fibre and carries out oxidation processes, is then immersed in titanate coupling agent.
Preparation method the most according to claim 5, wherein, a length of 50-80 μm of described glass fibre.
Preparation method the most according to claim 5, wherein, the concentration of the amount of the material of described potassium permanganate solution is
0.05-0.1mol/L。
8. according to the preparation method described in claim 5 or 7, wherein, the temperature of described immersion is 40-70 DEG C, the time of immersion
For 30-50min.
Preparation method the most according to claim 8, wherein, in step (3), described dispensing with the volume ratio of described water is
1:800-1:1000。
10. an aging resistance wallpaper, it is characterised in that described wallpaper passes through the method in claim 1-9 described in any one
It is prepared from.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610805995.8A CN106245419A (en) | 2016-09-07 | 2016-09-07 | Aging resistance wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610805995.8A CN106245419A (en) | 2016-09-07 | 2016-09-07 | Aging resistance wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106245419A true CN106245419A (en) | 2016-12-21 |
Family
ID=57599283
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610805995.8A Pending CN106245419A (en) | 2016-09-07 | 2016-09-07 | Aging resistance wallpaper and preparation method thereof |
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| Country | Link |
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| CN (1) | CN106245419A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108505398A (en) * | 2018-05-17 | 2018-09-07 | 安徽银兔装饰材料有限公司 | Environmental protection wall paper and preparation method thereof |
| CN108505399A (en) * | 2018-05-17 | 2018-09-07 | 安徽银兔装饰材料有限公司 | Environmental protection wall paper and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
| CN105219013A (en) * | 2015-11-18 | 2016-01-06 | 上海瀚氏模具成型有限公司 | Damage resistant ABS plastic and preparation method thereof |
-
2016
- 2016-09-07 CN CN201610805995.8A patent/CN106245419A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105178110A (en) * | 2015-06-17 | 2015-12-23 | 山东香山装饰工程有限公司 | Wallpaper and preparation method thereof |
| CN105219013A (en) * | 2015-11-18 | 2016-01-06 | 上海瀚氏模具成型有限公司 | Damage resistant ABS plastic and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 沈新元: "《先进高分子材料》", 28 February 2006, 中国纺织出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108505398A (en) * | 2018-05-17 | 2018-09-07 | 安徽银兔装饰材料有限公司 | Environmental protection wall paper and preparation method thereof |
| CN108505399A (en) * | 2018-05-17 | 2018-09-07 | 安徽银兔装饰材料有限公司 | Environmental protection wall paper and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20161221 |