CN102585559B - Preparation method for high-light fastness titanium dioxide pigment - Google Patents
Preparation method for high-light fastness titanium dioxide pigment Download PDFInfo
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Abstract
The invention discloses a preparation method for a high-light fastness titanium dioxide pigment. The preparation method comprises the following steps of: preparing aqueous suspension of a titanium dioxide initial product; depositing a layer of dense silicon dioxide cladding layer on a titanium dioxide pigment; depositing an aluminum phosphate compound on the silicon dioxide-coated titanium dioxide pigment; depositing aluminum hydroxide by using a parallel-flow method; after the aluminum hydroxide is coated, stirring and aging; and filtering, washing, drying, and performing fluid energy milling and organic treatment to obtain the high-light fastness titanium dioxide pigment. The method provided by the invention has the advantages of high controllability, reproducibility, high operability and the like, facilitates industrial production and has a good application prospect. The titanium dioxide pigment prepared by the method has the advantages of high light fastness, high light resistance, high non-transparency, high color-change resistance and the like, and can be used in decoration paper, laminated paper and coating and plastic products which have high requirements on the light resistance.
Description
Technical field
The present invention relates to field prepared by TiO 2 pigment, relate in particular to a kind of preparation method of TiO 2 pigment of high-light-fastness.
Background technology
TiO 2 pigment is widely used in a plurality of fields such as papermaking, ink, coating, plastics, and papermaking is one of its most important Application Areas, in papermaking, decorative paper is to use maximum a kind of of titanium dioxide, and in decorative paper, average usage quantity can reach 27%, and in white in finish paper, usage quantity can reach 45%.Decorative paper is the integral part of the coated material of ornamental thermosetting resin, is placed on below the overlay paper in product structure, mainly works the covering effect that the decoration function of floral designs is provided and prevents the infiltration of bottom glue.Decorative paper is specially adapted in ornamenting, laminating material floor and the inside fitting of furniture surface, this kind of paper requires the titanium dioxide using not only to have higher opacifying power, water dispersible, also should there is good photostabilization, to guarantee the still nondiscoloration of decorative paper life-time service, but due to titanium dioxide particularly rutile titanium dioxide there is photocatalytic activity, in use, can make the organic composition catalyzed degradation contacting with it, the serious various performance and used lifes that reduce decorative paper, this just requires used titanium dioxide through special surface treatment.
Publication number is that the Chinese patent application of CN 101360793A discloses a kind of used for decorative paper TiO 2 pigment, and described pigment has top coat, and this coating comprises aluminum phosphate, aluminum oxide, silicon oxide and titanium oxide.Silicon oxide exists with loose precipitation forms, and specific surface area (BET) is 15m at least
2/ g.The preparation method of this TiO 2 pigment, first aluminium and phosphorus component join in tio_2 suspension, add subsequently the titanium component of alkaline silicon components and acid-reaction and optionally add other pH value regulating component, wherein pH value is adjusted to the value in 4～9 scope.
Publication number is that the Chinese patent application of CN 101389714A discloses a kind of used for decorative paper TiO 2 pigment, on titanium dioxide granule, there is aluminum phosphate, aluminum oxide and hollow body coating, this pigment has good opacity, although this technical scheme has improved the opaqueness of TiO 2 pigment, not obvious to the sunproof raising of TiO 2 pigment.
Granted publication number discloses a kind of used for decorative paper TiO 2 pigment for the Chinese patent of CN 1296439C, it is feature that this preparation process be take the compound that precipitates successively phosphorus, titanium, aluminium and magnesium at titanium dioxide surface, thereby obtain, has high shoe lid ability and high delay and the pigment simultaneously with high change ash stability.
Publication number is that the Chinese patent application of CN 1806018A discloses a kind of used for decorative paper TiO 2 pigment preparation method, this preparation method comprises: in tio_2 suspension, at least add aluminium and phosphorus component, in this process, its pH value drops to below 10, subsequently by adding acidic components that the pH value of suspension is dropped to below 9.Although this technical scheme has improved retention and the opacity of TiO 2 pigment, the photostabilization of TiO 2 pigment need to improve.
US Patent No. 12192790 discloses a kind of manufacture method of decorative paper titanium white, it is at the coated fine and close aluminum phosphate compound of titanium dioxide surface, and the anti-grey sex change that pyroprocessing improves TiO 2 pigment after coating, although this technical scheme has improved anti-grey sex change by pyroprocessing, but pyroprocessing has increased energy consumption, cause the production cost of TiO 2 pigment to increase.
Summary of the invention
The invention provides a kind of preparation method of high-light fastness titanium dioxide pigment, in titanium dioxide surface successively coated fine and close silicon-dioxide, aluminum phosphate compound and aluminium hydroxide, photostabilization, light permanency, opacity and the anti-look sex change that can improve TiO 2 pigment.
A preparation method for high-light fastness titanium dioxide pigment, comprises the following steps:
(1) prepare the aqeous suspension of titanium dioxide first product;
(2) in aqeous suspension, add sodium silicate aqueous solution, 30 ℃～90 ℃ and pH value be under 7～10 conditions at the surperficial coated silica of titanium dioxide, obtain the titanium dioxide of coated silica;
(3) adding the aqueous solution of the water-soluble cpds of phosphorus or the water-soluble cpds of phosphorus and the aluminum saline solution of part amount, is under 7～10 conditions, on the titanium dioxide at coated silica, to be coated aluminum phosphate compound at 30 ℃～90 ℃ with pH value;
(4) add the aluminum saline solution of surplus, keeping pH value is 4～10, at 30 ℃～90 ℃ cladded aluminium hydroxides;
(5) adding after aluminum saline solution pH value is 5～8 or adjust pH to 5～8, after filtration, washing, dry, comminution by gas stream and organic process, obtains high-light fastness titanium dioxide pigment.
In order to obtain the better invention effect of the present invention, below as of the present invention preferably:
In step (1), the aqeous suspension of preparing titanium dioxide first product comprises the following steps:
(a) with distilled water or deionized water, titanium dioxide first product is made into slurry;
(b) in the slurry of step (a), add dispersion agent adjust pH to 7～11, after sand milling, filter, obtain the aqeous suspension of titanium dioxide first product.
In step (a), described titanium dioxide first product can be the rutile titanium dioxide of producing by chlorination process, can be also rutile-type or anatase titanium dioxide by Production By Sulfuric Acid Process, all can select commercially available prod.Further preferably, described titanium dioxide first product is selected the titanium dioxide substantially with rutile-type structure.Concentration to titanium dioxide first product in slurry does not have special requirement, and preferred, the concentration that contains titanium dioxide first product in slurry is 100g/L～500g/L.
In step (b), described dispersion agent is one or both in water glass, Sodium hexametaphosphate 99, can adopt the mode of the aqueous solution to add; The mass ratio of described dispersion agent and titanium dioxide first product more preferably 0.1～0.5: 100.Above-mentioned dispersion agent adds, on the one hand due to volume effect, make titanium dioxide first product be dispersed in uniformly in slurry system, on the other hand, owing to existing steric effect, between solid particulate because of electrostatic repulsion away from, be difficult for occurring agglomeration, make system even, suspension property increases, thereby makes to have better effect in carrying out follow-up sand milling step.
Step (2) to step (4) is coated under steady temperature, in step (2) to step (4), do not need to change temperature, process controllability is good, and required Heating temperature is not high, than prior art, can reduce the loss of heat, thereby reduce production costs.Type of heating is not had to too much requirement, in whole process, can adopt heating means well known by persons skilled in the art to maintain the temperature of slurry, as water vapour heating, hot resistance heating etc.Further preferred described steady temperature is the temperature value in 40 ℃～70 ℃.
In step (2), the concentration of described sodium silicate aqueous solution mesosilicic acid sodium is 30g/L～200g/L; The add-on of described sodium silicate aqueous solution is 0.5%～4% of titanium dioxide first product add-on, and the add-on of described sodium silicate aqueous solution is with SiO
2quality meter, titanium dioxide first product add-on is with TiO
2quality meter.The too short throw out autohemagglutination that is easy to make generation of joining day of sodium silicate aqueous solution, rather than be formed uniformly coated with silica layer, and the long production efficiency that can reduce of the joining day of sodium silicate aqueous solution, increase energy consumption simultaneously, therefore, the best continuously and smoothly of described sodium silicate aqueous solution adds and the joining day continues 1h～5h, more preferably 1h～3h, under this optimum condition, make to be coated preferably fine and close silicon-dioxide on the surface of titanium dioxide.
In step (2), pH value is 8～9, and keeps pH constant.Slower in the interval silicic acid gel speed of this pH, be more conducive to form fine and close continuous silicon dioxide layer, by controlling the pH value of slurry, at the fine and close continuous silicon dioxide layer of titanium dioxide granule Surface Creation.
In step (3), the water-soluble cpds of described phosphorus can be selected a kind of in alkali metal phosphate, ammonium phosphate, polyphosphate, phosphoric acid etc., is specially Sodium phosphate dibasic, phosphoric acid or Sodium hexametaphosphate 99; The add-on of the aqueous solution of the water-soluble cpds of described phosphorus or the water-soluble cpds of phosphorus is 1.0%～5.0% of titanium dioxide first product add-on, and the add-on of the aqueous solution of the water-soluble cpds of described phosphorus or the water-soluble cpds of phosphorus is with P
2o
5quality meter, titanium dioxide first product add-on is with TiO
2quality meter; In the aqueous solution of the water-soluble cpds of described phosphorus, the concentration of the water-soluble cpds of phosphorus is 100g/L～500g/L; PH value is 7～9.5.Thereby at the titanium dioxide surface of coated silica, be coated better the aluminum phosphate compound of one deck densification, can significantly improve the photostabilization of TiO 2 pigment, can improve opaqueness simultaneously.
The aqueous solution of the water-soluble cpds of phosphorus or the water-soluble cpds of phosphorus can add separately in succession with the aluminum saline solution of part amount, also can add simultaneously.
In step (3) and step (4), described aluminum saline solution is aluminum sulfate aqueous solution, the sodium metaaluminate aqueous solution, aluminum nitrate aqueous solution, aluminum chloride aqueous solution or the aluminum acetate aqueous solution; In described aluminum saline solution, the concentration of aluminium salt is 10g/L～200g/L; Total add-on of described aluminum saline solution is 1.0%～8.0% of titanium dioxide first product add-on, and the add-on of described aluminum saline solution is with Al
2o
3quality meter, titanium dioxide first product add-on is with TiO
2quality meter.
In step (4), pH value is 7～9.5, and when pH remains on 7～9.5, precipitation easily forms the boehmite-type aluminium hydroxide of sheet, is more conducive to improve the dispersiveness of TiO 2 pigment.
In step (5), add after aluminum saline solution, can select to stir slaking 10min～30min, in whipping process, can make slurry slaking, make slurry system more stable, thereby be more conducive to follow-up processing.Add acid solution or alkaline solution, behind adjust pH to 5～8, can select to stir slaking 15min～60min again, stir slaking and make after placing for some time, each material in slurry system tends towards stability, then is further processed.
In step (5), described dry temperature is 100 ℃～300 ℃; Described organic process is for adopting amine, alcohol, organosilicon or carboxylic acid to process.
In the present invention, the control of pH value adopts and adds acid solution well known to those skilled in the art or alkaline solution to realize, and the mode that adds of acid solution or alkaline solution can be that the mode adding separately can be also the mode simultaneously adding with raw material stream; Described acid solution can be selected hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid or nitric acid etc.; Described alkaline solution can be selected aqueous sodium hydroxide solution, potassium hydroxide aqueous solution, ammonia soln or aqueous sodium carbonate etc.
Compared with prior art, tool of the present invention has the following advantages:
The preparation method of high-light fastness titanium dioxide pigment of the present invention, has that controllability is good, a favorable reproducibility, the advantage such as workable, is easy to suitability for industrialized production, has good application prospect.
High-light fastness titanium dioxide pigment prepared by preparation method of the present invention has novel titanium dioxide surface coating structure, and coated successively at titanium dioxide surface, the first layer is fine and close silicon-dioxide, to significantly improve the photostabilization of TiO 2 particles; The second layer is coated fine and close aluminum phosphate compound, is improving the sunproof opaqueness that simultaneously improves; The 3rd layer of cladded aluminium hydroxide, the dispersiveness of raising TiO 2 pigment.High-light fastness titanium dioxide pigment prepared by the present invention has the advantages such as high-light-fastness, high light-fast, high opacity and the sex change of high resistance look.High-light fastness titanium dioxide pigment prepared by the present invention can be used in decorative paper, laminated paper and the coating that light permanency is had higher requirements and plastics.
Accompanying drawing explanation
Fig. 1 is the electron microscope photo scanning that embodiment 1 titanium dioxide surface has been coated the first layer silicon-dioxide;
Fig. 2 is the electron microscope photo scanning that embodiment 1 titanium dioxide surface has been coated the first layer silicon-dioxide and second layer aluminum phosphate compound;
Fig. 3 is the electron microscope photo scanning that embodiment 1 titanium dioxide surface has been coated the first layer silicon-dioxide, second layer aluminum phosphate compound and the 3rd layer of aluminium hydroxide.
Embodiment
Embodiment 1
With deionized water by 1000g titanium dioxide first product (by the anatase titanium dioxide of Production By Sulfuric Acid Process, Ningbo Xinfu Titanium Dioxide Co., Ltd.), be mixed with the slurry that the concentration containing titanium dioxide first product is 320g/L, adding Sodium hexametaphosphate 99 mass concentration is the sodium hexametaphosphate solution 0.05L of 70g/L, add and contain the aqueous sodium hydroxide solution adjusting pH to 8 that sodium hydroxide mass percent is 20%, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product.
The aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 40 ℃, and until cladded aluminium hydroxide finishes all to keep this temperature.Start to wrap fine and close silicon-dioxide, drip relative titanium dioxide first product add-on (with TiO
2quality meter) (add-on of sodium silicate aqueous solution is with SiO for 1.0% the sodium silicate silicate sodium silicate aqueous solution that is 100g/L
2quality meter), simultaneously and stream to add mass percent be that 15% sulfuric acid keeps pH=8, sodium silicate aqueous solution continuously and smoothly adds and the joining day continues 3h, after reinforced end, stirs slaking 20min.
Drip relative titanium dioxide first product add-on (with TiO
2quality meter) 3.0% phosphoric acid is (with P
2o
5quality meter), the joining day of phosphoric acid is 1.5h, and also stream adds the sodium metaaluminate aqueous solution that the sodium metaaluminate concentration of part amount is 100g/L simultaneously, keeps pH=8.When phosphoric acid adds, stir slaking 30min.
The sodium metaaluminate aqueous solution mass percent that adds surplus is that 15% sulfuric acid stream join in reaction paste, keeps pH=8.Total add-on of the sodium metaaluminate aqueous solution is (with Al
2o
3quality meter) be that relative titanium dioxide first product add-on is (with TiO
2quality meter) 4.0%.
After the sodium metaaluminate aqueous solution adds, stir slaking 20min.With mass percent, it is 15% sulphur acid for adjusting pH to 7, stir slaking 40min, filter, with deionized water wash, in DZF-6053 type vacuum drying oven after 200 ℃ of dry 10h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP) (TMP), obtain the about 1kg of high-light fastness titanium dioxide pigment.
Embodiment 2
With deionized water by 1000g titanium dioxide first product (by the rutile titanium dioxide of Production By Sulfuric Acid Process, Ningbo Xinfu Titanium Dioxide Co., Ltd.), be mixed with and contain the slurry that titanium dioxide first product concentration is 280g/L, adding water glass mass concentration is the sodium silicate aqueous solution 0.03L of 100g/L, add and contain the aqueous sodium hydroxide solution adjusting pH to 9 that sodium hydroxide mass percent is 10%, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product.
The aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 55 ℃, and until cladded aluminium hydroxide finishes all to keep this temperature.Start to wrap fine and close silicon-dioxide, drip relative titanium dioxide first product add-on (with TiO
2quality meter) 2.0% the sodium silicate silicate sodium silicate aqueous solution that is 200g/L is (with SiO
2quality meter), also stream adds the hydrochloric acid of 2mol/L to keep pH=9 simultaneously, and sodium silicate aqueous solution continuously and smoothly adds and the joining day continues 2h, after reinforced end, and stirring slaking 20min.
Drip relative titanium dioxide first product add-on (with TiO
2quality meter) 1.0% phosphoric acid is (with P
2o
5quality meter), add relative titanium dioxide first product add-on (with TiO
2quality meter) approximately 0.5% sodium metaaluminate concentration is 200g/L the sodium metaaluminate aqueous solution is adjusted pH to 9.5, stirs slaking 30min.
Add relative titanium dioxide first product add-on (with TiO
2quality meter) the 5.0% sodium metaaluminate concentration sodium metaaluminate aqueous solution that is 200g/L (with Al
2o
3quality meter), with the hydrochloric acid of 2mol/L stream, keep pH=9.5 simultaneously.
After the sodium metaaluminate aqueous solution adds, stir slaking 20min.Salt acid for adjusting pH to 7 with 2mol/L, stir slaking 40min, filter, use deionized water wash, in DZF-6053 type vacuum drying oven, after 120 ℃ of dry 20h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP) (TMP), obtain the about 1kg of TiO 2 pigment.
Embodiment 3
With deionized water by 1000g titanium dioxide first product (by the anatase titanium dioxide of Production By Sulfuric Acid Process, Ningbo Xinfu Titanium Dioxide Co., Ltd.), be mixed with and contain the slurry that titanium dioxide first product concentration is 300g/L, adding water glass mass concentration is the sodium silicate aqueous solution 0.03L of 100g/L, add and contain the aqueous sodium hydroxide solution adjusting pH to 10 that sodium hydroxide mass percent is 10%, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product.
The aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 70 ℃, and until cladded aluminium hydroxide finishes all to keep this temperature.To adding mass percent in coating tank, be that 10% sulfuric acid is adjusted pH=8.5, start to wrap fine and close silicon-dioxide, drip relative titanium dioxide first product add-on (with TiO
2quality meter) 1.8% the sodium silicate silicate sodium silicate aqueous solution that is 50g/L is (with SiO
2quality meter), simultaneously and stream to add mass percent be that 10% sulfuric acid keeps pH=8.5, sodium silicate aqueous solution continuously and smoothly adds and the joining day continues 4h, after reinforced end, stirs slaking 20min.
Drip relative titanium dioxide first product add-on (with TiO
2quality meter) 2.5% the Sodium phosphate dibasic concentration Sodium phosphate dibasic aqueous solution that is 3mol/L is (with P
2o
5quality meter), then add relative titanium dioxide first product add-on (with TiO
2quality meter) 1.5% the Tai-Ace S 150 concentration aluminum sulfate aqueous solution that is 150g/L is (with Al
2o
3quality meter), stir slaking 10min; The aqueous sodium hydroxide solution that slowly to add containing sodium hydroxide mass percent be 15% is adjusted pH to 7, stirs slaking 30min.
Add relative titanium dioxide first product add-on (with TiO
2quality meter) 4.0% the Tai-Ace S 150 concentration aluminum sulfate aqueous solution that is 150g/L is (with Al
2o
3quality meter), with being that 15% aqueous sodium hydroxide solution stream join in reaction paste containing sodium hydroxide mass percent, keep pH=7.
Add after aluminum sulfate aqueous solution, stir slaking 30min, pH=7, filter, with deionized water wash, in DZF-6053 type vacuum drying oven after 300 ℃ of dry 12h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP) (TMP), obtain the about 1kg of high-light fastness titanium dioxide pigment.
Embodiment 4
With deionized water by 1000g titanium dioxide first product (rutile titanium dioxide of producing by chlorination process), be mixed with and contain the slurry that titanium dioxide first product concentration is 320g/L, adding Sodium hexametaphosphate 99 mass concentration is the sodium hexametaphosphate solution 0.05L of 70g/L, add and contain the aqueous sodium hydroxide solution adjusting pH to 8.5 that sodium hydroxide mass percent is 30%, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product.
The aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 60 ℃, and until cladded aluminium hydroxide finishes all to keep this temperature.Start to wrap fine and close silicon-dioxide, drip relative titanium dioxide first product add-on (with TiO
2quality meter) 1.5% the sodium silicate silicate sodium silicate aqueous solution that is 150g/L is (with SiO
2quality meter), also stream adds the hydrochloric acid of 4mol/L to keep pH=8.5 simultaneously, and sodium silicate aqueous solution continuously and smoothly adds and the joining day continues 3h, after reinforced end, and stirring slaking 20min.
Add relative titanium dioxide first product (with TiO
2quality meter) 3.0% the hexa metaphosphoric acid na concn sodium hexametaphosphate solution that is 100g/L is (with P
2o
5quality meter), add relative titanium dioxide first product add-on (with TiO
2quality meter) approximately 0.5% sodium metaaluminate concentration is 100g/L the sodium metaaluminate aqueous solution is adjusted pH to 8.5.
Add relative titanium dioxide first product amount (with TiO
2quality meter) 4% the sodium metaaluminate concentration sodium metaaluminate aqueous solution that is 100g/L is (with Al
2o
3quality meter), also stream adds the hydrochloric acid of 4mol/L to keep pH=8.5 simultaneously.
After the sodium metaaluminate aqueous solution adds, stir slaking 20min.Salt acid for adjusting pH to 7 with 4mol/L, stir slaking 30min, filter, with deionized water wash, in DZF-6053 type vacuum drying oven after 150 ℃ of dry 15h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP) (TMP), obtain the about 1kg of high-light fastness titanium dioxide pigment.
Comparative example 1
With deionized water by 1000g titanium dioxide first product (by the rutile titanium dioxide of Production By Sulfuric Acid Process, Ningbo Xinfu Titanium Dioxide Co., Ltd.), be mixed with and contain the slurry that titanium dioxide first product concentration is 320g/L, adding Sodium hexametaphosphate 99 mass concentration is the sodium hexametaphosphate solution 0.05L of 70g/L, adding mass percent is that 5% aqueous sodium hydroxide solution regulates pH to 10, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product.
The aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 60 ℃, and all keep this temperature before coating finishes.Add relative titanium dioxide first product add-on (with TiO
2quality meter) 3.0% Sodium hexametaphosphate 99 is (with P
2o
5quality meter), then add relative titanium dioxide first product add-on (with TiO
2quality meter) approximately 0.5% sodium metaaluminate concentration is 150g/L the sodium metaaluminate aqueous solution is adjusted pH to 8.5, stirs slaking 20min.
Add relative titanium dioxide first product add-on (with TiO
2quality meter) 4% the sodium metaaluminate concentration sodium metaaluminate aqueous solution that is 150g/L is (with Al
2o
3quality meter), also stream adds the hydrochloric acid of 1mol/L to keep pH=8.5 simultaneously.
After sodium metaaluminate aqueous solution solution adds, stir slaking 20min.Salt acid for adjusting pH to 7 with 1mol/L, stir slaking 30min, filter, use deionized water wash, in DZF-6053 type vacuum drying oven, after 150 ℃ of dry 15h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP) (TMP), obtain approximately 1 kilogram of TiO 2 pigment.
Comparative example 2
With deionized water by 1000g titanium dioxide first product (by the rutile titanium dioxide of Production By Sulfuric Acid Process, Ningbo Xinfu Titanium Dioxide Co., Ltd.), be mixed with and contain the slurry that titanium dioxide first product concentration is 320g/L, adding Sodium hexametaphosphate 99 mass concentration is the sodium hexametaphosphate solution 0.05L of 70g/L, adding mass percent is that 5% aqueous sodium hydroxide solution regulates pH to 10, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product.
The aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 60 ℃, and all keep this temperature before coating finishes.The salt acid for adjusting pH to 8.5 that adds 1mol/L to coating tank.Start to wrap fine and close silicon-dioxide, drip relative titanium dioxide first product add-on (with TiO
2quality meter) 1.5% the sodium silicate silicate sodium silicate aqueous solution that is 100g/L is (with SiO
2quality meter), while stream add the maintenance pH=8.5 of hydrochloric acid 1mol/L, and sodium silicate aqueous solution continuously and smoothly adds and the joining day continues 3h, stirs slaking 20min.
Add relative titanium dioxide first product add-on (with TiO
2quality meter) 4% the sodium metaaluminate concentration sodium metaaluminate aqueous solution that is 100g/L is (with Al
2o
3quality meter), also stream adds the hydrochloric acid of 1mol/L to keep pH=8.5 simultaneously.
After the sodium metaaluminate aqueous solution adds, stir slaking 20min.Salt acid for adjusting pH to 7 with 1mol/L, stir slaking 30min filter, with deionized water wash, in DZF-6053 type vacuum drying oven after 150 ℃ of dry 15h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP) (TMP), obtain TiO 2 pigment 1kg.
Testing method
The TiO 2 pigment of the high-light fastness titanium dioxide pigment of embodiment 1～4 preparation and comparative example 1～2 preparation is added respectively to the decorative paper based on melamine resin, and measure subsequently their optical property and photostabilization in the laminated cardboard of compacting.
A) prepare laminated cardboard (laboratory scale)
The pigment suspension that is 36% containing TiO 2 pigment mass percent by a certain amount of TiO 2 pigment and tap water preparation.Pigment suspension is added in paper pulp, make decorative paper, in decorative paper, the weight per unit area of TiO 2 pigment is (100 ± 3) gram/m, and in decorative paper, titanium dioxide weight percentage is (40 ± 1) %.
The preparation of laminated cardboard comprises dipping and is pressed into laminated cardboard.Decorative paper is immersed in melamine resin solution, and in drying by circulating air case 25 seconds of precoagulated at 130 ℃.Then flood for the second time, then at 130 ℃, be dried 110 seconds in drying by circulating air case.The remaining water content of this decorative paper is 4% to 6% of decorative paper gross weight.The core paper of the decorative paper of condensation and resin impregnating and black bottom paper are stacked successively, then be pressed into pertinax through laminating machine.
TiO 2 pigment is selected the high-light fastness titanium dioxide pigment of embodiment 1～4 preparation and the TiO 2 pigment of comparative example 1～2 preparation successively, thereby prepares different pertinaxs.
B) measure
In order to evaluate the photostabilization of TiO 2 pigment.Corresponding pertinax sample is placed in Xenon weather-ometer (SNT-800 type, Shanghai Yi Xiang testing installation company limited) and is irradiated, and this light source is nitrogen Jupiter, and the temperature in this instrument sample room is 45 ± 3 ℃, and relative humidity is (65 ± 5) %.Measure afterwards the changes delta E of colour CIELAB, weigh the photostabilization of pertinax by the size of Δ E, Δ E is less, and photostabilization is better.
The Δ E data results that different pertinax test prepared by the TiO 2 pigment of the high-light fastness titanium dioxide pigment of embodiment 1～4 preparation and comparative example 1～2 preparation obtains is as shown in table 1.
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example 1 | Comparative example 2 | |
| ΔE | 0.39 | 0.31 | 0.41 | 0.32 | 0.63 | 0.76 |
From the data results of table 1, the high-light fastness titanium dioxide pigment that the inventive method makes has high-light-fastness.
Claims (4)
1. a preparation method for high-light fastness titanium dioxide pigment, comprises the following steps:
(1) with deionized water by 1000g titanium dioxide first product, be mixed with the slurry that the concentration containing titanium dioxide first product is 320g/L, adding Sodium hexametaphosphate 99 mass concentration is the sodium hexametaphosphate solution 0.05L of 70g/L, add and contain the aqueous sodium hydroxide solution adjusting pH to 8 that sodium hydroxide mass percent is 20%, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product;
(2) aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 40 ℃, and until cladded aluminium hydroxide finishes all to keep this temperature, start to wrap fine and close silicon-dioxide, the sodium silicate aqueous solution that the sodium silicate silicate that drips relative titanium dioxide first product add-on 1.0% is 100g/L, simultaneously and stream to add mass percent be that 15% sulfuric acid keeps pH=8, sodium silicate aqueous solution continuously and smoothly adds and the joining day continues 3h, after reinforced end, stir slaking 20min;
(3) drip the phosphoric acid of relative titanium dioxide first product add-on 3.0%, the joining day of phosphoric acid is 1.5h, and also stream adds the sodium metaaluminate aqueous solution that the sodium metaaluminate concentration of part amount is 100g/L simultaneously, keeps pH=8; When phosphoric acid adds, stir slaking 30min;
(4) adding the sodium metaaluminate aqueous solution mass percent of surplus is that 15% sulfuric acid stream join in reaction paste, keeps pH=8, and total add-on of the sodium metaaluminate aqueous solution is 4.0% of relative titanium dioxide first product add-on;
(5) after the sodium metaaluminate aqueous solution adds, stir slaking 20min, with mass percent, it is 15% sulphur acid for adjusting pH to 7, stir slaking 40min, filter, with deionized water wash, in DZF-6053 type vacuum drying oven after 200 ℃ of dry 10h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP), obtain high-light fastness titanium dioxide pigment 1kg;
In step (1), described titanium dioxide first product is the anatase titanium dioxide by Production By Sulfuric Acid Process;
In step (2)～(4), described titanium dioxide first product add-on is with TiO
2quality meter;
In step (2), the add-on of described sodium silicate aqueous solution is with SiO
2quality meter;
In step (3), the add-on of described phosphoric acid is with P
2o
5quality meter;
In step (4), the add-on of the described sodium metaaluminate aqueous solution is with Al
2o
3quality meter.
2. a preparation method for high-light fastness titanium dioxide pigment, is characterized in that, comprises the following steps:
(1) with deionized water by 1000g titanium dioxide first product, be mixed with and contain the slurry that titanium dioxide first product concentration is 280g/L, adding water glass mass concentration is the sodium silicate aqueous solution 0.03L of 100g/L, add and contain the aqueous sodium hydroxide solution adjusting pH to 9 that sodium hydroxide mass percent is 10%, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product;
(2) aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 55 ℃, and until cladded aluminium hydroxide finishes all to keep this temperature; Start to wrap fine and close silicon-dioxide, the sodium silicate aqueous solution that the sodium silicate silicate that drips relative titanium dioxide first product add-on 2.0% is 200g/L, also stream adds the hydrochloric acid of 2mol/L to keep pH=9 simultaneously, sodium silicate aqueous solution continuously and smoothly adds and the joining day continues 2h, after reinforced end, stir slaking 20min;
(3) drip the phosphoric acid of relative titanium dioxide first product add-on 1.0%, the sodium metaaluminate aqueous solution that the sodium metaaluminate concentration that adds relative titanium dioxide first product add-on 0.5% is 200g/L is adjusted pH to 9.5, stirs slaking 30min;
(4) add the sodium metaaluminate aqueous solution that 5.0% sodium metaaluminate concentration of relative titanium dioxide first product add-on is 200g/L, with hydrochloric acid the stream of 2mol/L, keep pH=9.5 simultaneously;
(5), after the sodium metaaluminate aqueous solution adds, stir slaking 20min; Salt acid for adjusting pH to 7 with 2mol/L, stir slaking 40min, filter, use deionized water wash, in DZF-6053 type vacuum drying oven, after 120 ℃ of dry 20h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP), obtain TiO 2 pigment 1kg;
In step (1), described titanium dioxide first product is the rutile titanium dioxide by Production By Sulfuric Acid Process;
In step (2)～(4), described titanium dioxide first product add-on is with TiO
2quality meter;
In step (2), the add-on of described sodium silicate aqueous solution is with SiO
2quality meter;
In step (3), the add-on of described phosphoric acid is with P
2o
5quality meter;
In step (4), the add-on of the described sodium metaaluminate aqueous solution is with Al
2o
3quality meter.
3. a preparation method for high-light fastness titanium dioxide pigment, is characterized in that, comprises the following steps:
(1) with deionized water by 1000g titanium dioxide first product, be mixed with and contain the slurry that titanium dioxide first product concentration is 300g/L, adding water glass mass concentration is the sodium silicate aqueous solution 0.03L of 100g/L, add and contain the aqueous sodium hydroxide solution adjusting pH to 10 that sodium hydroxide mass percent is 10%, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product;
(2) aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 70 ℃, and until cladded aluminium hydroxide finishes all to keep this temperature; To adding mass percent in coating tank, be that 10% sulfuric acid is adjusted pH=8.5, start to wrap fine and close silicon-dioxide, the sodium silicate aqueous solution that the sodium silicate silicate that drips relative titanium dioxide first product add-on 1.8% is 50g/L, simultaneously and stream to add mass percent be that 10% sulfuric acid keeps pH=8.5, sodium silicate aqueous solution continuously and smoothly adds and the joining day continues 4h, after reinforced end, stir slaking 20min;
(3) drip the Sodium phosphate dibasic aqueous solution that the Sodium phosphate dibasic concentration of relative titanium dioxide first product add-on 2.5% is 3mol/L, then the aluminum sulfate aqueous solution that the Tai-Ace S 150 concentration that adds relative titanium dioxide first product add-on 1.5% is 150g/L, stirs slaking 10min; The aqueous sodium hydroxide solution that slowly to add containing sodium hydroxide mass percent be 15% is adjusted pH to 7, stirs slaking 30min;
(4) add the aluminum sulfate aqueous solution that the Tai-Ace S 150 concentration of relative titanium dioxide first product add-on 4.0% is 150g/L, with being that 15% aqueous sodium hydroxide solution stream join in reaction paste containing sodium hydroxide mass percent, keep pH=7;
(5) add after aluminum sulfate aqueous solution, stir slaking 30min, pH=7, filters, with deionized water wash, in DZF-6053 type vacuum drying oven after 300 ℃ of dry 12h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP), obtain high-light fastness titanium dioxide pigment 1kg;
In step (1), described titanium dioxide first product is the anatase titanium dioxide by Production By Sulfuric Acid Process;
In step (2)～(4), described titanium dioxide first product add-on is with TiO
2quality meter;
In step (2), the add-on of described sodium silicate aqueous solution is with SiO
2quality meter;
In step (3), the add-on of the described Sodium phosphate dibasic aqueous solution is with P
2o
5quality meter;
In step (3) and (4), the add-on of described aluminum sulfate aqueous solution is with Al
2o
3quality meter.
4. a preparation method for high-light fastness titanium dioxide pigment, is characterized in that, comprises the following steps:
(1) with deionized water by 1000g titanium dioxide first product, be mixed with and contain the slurry that titanium dioxide first product concentration is 320g/L, adding Sodium hexametaphosphate 99 mass concentration is the sodium hexametaphosphate solution 0.05L of 70g/L, add and contain the aqueous sodium hydroxide solution adjusting pH to 8.5 that sodium hydroxide mass percent is 30%, then slurry is passed into sand milling in sand mill, slurry after sand milling, by screen cloth filtering coarse particles, obtains the aqeous suspension of titanium dioxide first product;
(2) aqeous suspension of titanium dioxide first product is joined in coating tank, stir simultaneously and be warming up to 60 ℃, and until cladded aluminium hydroxide finishes all to keep this temperature; Start to wrap fine and close silicon-dioxide, the sodium silicate aqueous solution that the sodium silicate silicate that drips relative titanium dioxide first product add-on 1.5% is 150g/L, also stream adds the hydrochloric acid of 4mol/L to keep pH=8.5 simultaneously, sodium silicate aqueous solution continuously and smoothly adds and the joining day continues 3h, after reinforced end, stir slaking 20min;
(3) add the sodium hexametaphosphate solution that the hexa metaphosphoric acid na concn of relative titanium dioxide first product 3.0% is 100g/L, the sodium metaaluminate aqueous solution that the sodium metaaluminate concentration that adds relative titanium dioxide first product add-on 0.5% is 100g/L is adjusted pH to 8.5;
(4) add the sodium metaaluminate aqueous solution that the sodium metaaluminate concentration of relative titanium dioxide first product amount 4% is 100g/L, simultaneously and stream add the hydrochloric acid of 4mol/L to keep pH=8.5;
(5), after the sodium metaaluminate aqueous solution adds, stir slaking 20min; Salt acid for adjusting pH to 7 with 4mol/L, stir slaking 30min, filter, use deionized water wash, in DZF-6053 type vacuum drying oven, after 150 ℃ of dry 15h, in comminution by gas stream, add after organic coated dose of 3g of TriMethylolPropane(TMP), obtain high-light fastness titanium dioxide pigment 1kg;
In step (1), the rutile titanium dioxide of described titanium dioxide first product for producing by chlorination process;
In step (2)～(4), described titanium dioxide first product add-on is with TiO
2quality meter;
In step (2), the add-on of described sodium silicate aqueous solution is with SiO
2quality meter;
In step (3), the add-on of described sodium hexametaphosphate solution is with P
2o
5quality meter;
In step (4), the add-on of the described sodium metaaluminate aqueous solution is with Al
2o
3quality meter.
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3146119A (en) * | 1961-07-03 | 1964-08-25 | Pittsburgh Plate Glass Co | Pigment treatment |
| GB1022621A (en) * | 1963-02-15 | 1966-03-16 | British Titan Products | Producing pigments |
| US4134776A (en) * | 1977-12-27 | 1979-01-16 | The Mearl Corporation | Exterior grade titanium dioxide coated mica |
| EP0654508B1 (en) * | 1993-11-24 | 1999-05-12 | Kerr-Mcgee Chemical Llc | Method of producing agglomerated titanium dioxide |
| JP2004091507A (en) * | 2002-08-29 | 2004-03-25 | Nippon Sheet Glass Co Ltd | Gel-like composition and product using the same |
| CN1671801A (en) * | 2002-08-08 | 2005-09-21 | 克罗内斯国际公司 | Method for surface treatment of a titanium dioxide pigment |
| CN1806018A (en) * | 2003-07-18 | 2006-07-19 | 克罗内斯国际公司 | Method for treating the surface of a titanium dioxide pigment |
| CN101360793A (en) * | 2006-01-30 | 2009-02-04 | 克罗内斯国际公司 | Titanium dioxide pigment featuring great opacity, and method for the production thereof |
| CN101367548A (en) * | 2008-09-12 | 2009-02-18 | 江苏工业学院 | Method of preparing hydrophobic nano-titanium dioxide powder |
| CN101389714A (en) * | 2006-03-16 | 2009-03-18 | 克罗内斯国际公司 | Titanium dioxide pigment coated with hollow bodies, and production method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760051A (en) * | 2008-11-07 | 2010-06-30 | 南通芯迎设计服务有限公司 | Preparation method of titanium dioxide power with silicon being coated on surface |
-
2011
- 2011-12-23 CN CN201110437804.4A patent/CN102585559B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3146119A (en) * | 1961-07-03 | 1964-08-25 | Pittsburgh Plate Glass Co | Pigment treatment |
| GB1022621A (en) * | 1963-02-15 | 1966-03-16 | British Titan Products | Producing pigments |
| US4134776A (en) * | 1977-12-27 | 1979-01-16 | The Mearl Corporation | Exterior grade titanium dioxide coated mica |
| EP0654508B1 (en) * | 1993-11-24 | 1999-05-12 | Kerr-Mcgee Chemical Llc | Method of producing agglomerated titanium dioxide |
| CN1671801A (en) * | 2002-08-08 | 2005-09-21 | 克罗内斯国际公司 | Method for surface treatment of a titanium dioxide pigment |
| JP2004091507A (en) * | 2002-08-29 | 2004-03-25 | Nippon Sheet Glass Co Ltd | Gel-like composition and product using the same |
| CN1806018A (en) * | 2003-07-18 | 2006-07-19 | 克罗内斯国际公司 | Method for treating the surface of a titanium dioxide pigment |
| CN101360793A (en) * | 2006-01-30 | 2009-02-04 | 克罗内斯国际公司 | Titanium dioxide pigment featuring great opacity, and method for the production thereof |
| CN101389714A (en) * | 2006-03-16 | 2009-03-18 | 克罗内斯国际公司 | Titanium dioxide pigment coated with hollow bodies, and production method |
| CN101367548A (en) * | 2008-09-12 | 2009-02-18 | 江苏工业学院 | Method of preparing hydrophobic nano-titanium dioxide powder |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109705630A (en) * | 2018-12-21 | 2019-05-03 | 中信钛业股份有限公司 | A kind of preparation method of high fast light laminated paper titanium dioxide pigment |
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