GB1022621A - Producing pigments - Google Patents
Producing pigmentsInfo
- Publication number
- GB1022621A GB1022621A GB623263A GB623263A GB1022621A GB 1022621 A GB1022621 A GB 1022621A GB 623263 A GB623263 A GB 623263A GB 623263 A GB623263 A GB 623263A GB 1022621 A GB1022621 A GB 1022621A
- Authority
- GB
- United Kingdom
- Prior art keywords
- milling
- titanium dioxide
- weight
- stage
- fluid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000049 pigment Substances 0.000 title abstract 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 52
- 238000003801 milling Methods 0.000 abstract 38
- 239000004408 titanium dioxide Substances 0.000 abstract 26
- 239000012530 fluid Substances 0.000 abstract 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 6
- 239000000463 material Substances 0.000 abstract 6
- 229910044991 metal oxide Inorganic materials 0.000 abstract 6
- 150000004706 metal oxides Chemical class 0.000 abstract 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 229910052751 metal Inorganic materials 0.000 abstract 4
- 239000002184 metal Substances 0.000 abstract 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract 2
- 229910052684 Cerium Inorganic materials 0.000 abstract 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000005642 Oleic acid Substances 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 2
- 235000021355 Stearic acid Nutrition 0.000 abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 abstract 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 abstract 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 2
- 239000004411 aluminium Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 2
- 239000011368 organic material Substances 0.000 abstract 2
- 150000002902 organometallic compounds Chemical class 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 2
- 239000010452 phosphate Substances 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 229910052710 silicon Inorganic materials 0.000 abstract 2
- 239000010703 silicon Substances 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- 239000008117 stearic acid Substances 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3692—Combinations of treatments provided for in groups C09C1/3615 - C09C1/3684
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/50—Agglomerated particles
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Paints Or Removers (AREA)
Abstract
A process for producing pigmentary titanium dioxide comprises subjecting titanium dioxide to fluid energy milling in at least two milling stages wherein at least part of the milling fluid introduced into one milling stage is removed before the titanium dioxide is subjected to the next milling stage and wherein (a) the milling fluid is introduced into each milling stage at a pressure of at least 50 p.s.i.g., e.g. 150 to 250 p.s.i.g., or up to 500 p.s.i.g.; (b) the ratio of the weight of milling fluid introduced in each milling stage to the weight of titanium dioxide milled in that stage is between 0.5:1 and 5.0:1; and (c) the ratio of the total weight of milling fluid introduced in all milling stages to the total weight of titanium dioxide milled is at least 1.5: 1, e.g. at least 2.5: 1. The milling fluid is preferably a gas, e.g. air or steam, which does not react with the titanium dioxide. When the milling fluid is steam, the ratio of the weight of milling fluid introduced in each milling stage to the weight of titanium dioxide milled in that stage is from 1.0:1 to 2.0:1; alternatively, where there are at least three milling stages, the ratio of the weight of milling fluid introduced in each stage to the weight of titanium dioxide milled in that stage is from 0.8:1 to 1.2:1. An organic modifying material may be added to the titanium dioxide during one or more of the milling stages. This material may be a polyol, e.g. glycerol, pentaerythritol or trimethylolpropane, a fatty acid, e.g. oleic acid or stearic acid, an amine e.g. triethanolamine or a metal organic compound. The total amount of organic material added is 0.05-5%, e.g. 0.1-2.5%, by weight of the pigment. The titanium dioxide particles before being subjected to the fluid energy milling may be coated with (a) a metal oxide or metal oxides, the metal or metals being aluminium, titanium, zirconium, cerium, tin and/or silicon, the amount of each metal oxide being 0.5-5%, e.g. 0.5 to 3.5% or 0.5-2.6% by weight of the titanium dioxide; (b) silica the amount of which is 0.2-2%, e.g. 0.5-1% or 0.5-0.7%, by weight of the titanium dioxide or (c) a phosphate, with or without other coating materials, the amount of which is 0.05-5%, e.g. 0.5-2.5%, by weight of the titanium dioxide. Examples are described.ALSO:A process for producing pigmentary titanium dioxide comprises subjecting titanium dioxide to fluid energy milling in at least two milling stages wherein at least part of the milling fluid introduced into one milling stage is removed before the titanium dioxide is subjected to the next milling stage and wherein (a) the milling fluid is introduced into each milling stage at a pressure of at least 50 p.s.i.g., e.g. 150-250 p.s.i.g. or up to 500 p.s.i.g., (b) the ratio of the weight of milling fluid introduced in each milling stage to the weight of titanium dioxide milled in that stage is between 0,5 : 1 and 5,0 : 1, and (c) the ratio of the total weight of milling fluid introduced in all milling stages to the total weight of titanium dioxide milled is at least 1,5 : 1, e.g. at least 2,5 : 1. The milling fluid is preferably a gas, e.g. air or steam, which does not react with the titanium dioxide. When the milling fluid is steam, the ratio of the weight of milling fluid introduced in each milling stage to the weight of titanium dioxide milled in that stage is from 1,0 : 1 to 2,0 : 1; alternatively, where there are at least three milling stages, the ratio of the weight of milling fluid introduced in each stage to the weight of titanium dioxide milled in that stage is from 0,8 : 1 to 1,2 : 1. An organic modifying material may be added to the titanium dioxide during one or more of the milling stages. This material may be a polyol e.g. glycerol, pentaerythritol or trimethylolpropane, a fatty acid e.g. oleic acid or stearic acid, an amine e.g. triethanolamine or a metal organic compound. The total amount of organic material added is 0,05-5% e.g. 0,1-2,5% by weight of the pigment. The titanium dioxide particles before being subjected to the fluid energy milling may be coated with (a) a metal oxide or metal oxides, the metal or metals being aluminium, titanium, zirconium, cerium, tin and/or silicon, the amount of each metal oxide being 0,5-5% e.g. 0,5-3,5% or 0,5-2,6%, by weight of the titanium dioxide, (b) silica the amount of which is 0,2-2% e.g. 0,5-1% or 0,5-0,7%, by weight of the titanium dioxide, or (c) a phosphate, with or without other coating materials, the amount of which is 0,05-5% e.g. 0,5-2,5%, by weight of the titanium dioxide. Examples are described.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB623263A GB1022621A (en) | 1963-02-15 | 1963-02-15 | Producing pigments |
| FR963803A FR1387487A (en) | 1963-02-15 | 1964-02-14 | Titanium dioxide grinding process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB623263A GB1022621A (en) | 1963-02-15 | 1963-02-15 | Producing pigments |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1022621A true GB1022621A (en) | 1966-03-16 |
Family
ID=9810804
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB623263A Expired GB1022621A (en) | 1963-02-15 | 1963-02-15 | Producing pigments |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1022621A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3412944A (en) * | 1965-08-03 | 1968-11-26 | Du Pont | Process for producing titanium dioxide pigments |
| US3522078A (en) * | 1967-04-21 | 1970-07-28 | Ppg Industries Inc | Process of treating titanium dioxide |
| US3522079A (en) * | 1966-10-25 | 1970-07-28 | British Titan Products | Precipitation coating process for coating metal oxide particles with a hydrous metal oxide |
| US3529985A (en) * | 1967-12-26 | 1970-09-22 | Nat Lead Co | Titanium dioxide pigment and process for producing same |
| US4405376A (en) | 1980-11-18 | 1983-09-20 | Ishihara Sangyo Kaisha, Ltd. | Titanium dioxide pigment and process for producing same |
| US5147579A (en) * | 1989-07-17 | 1992-09-15 | Tam Ceramics, Inc. | Moisture resistant sodium titanate and potassium titanate |
| US5288320A (en) * | 1991-02-02 | 1994-02-22 | Tioxide Group Services Limited | Oxides and the production thereof |
| DE4312035A1 (en) * | 1993-04-13 | 1994-10-20 | Bayer Ag | Pigments having improved flow properties and use thereof |
| GB2315064A (en) * | 1996-07-05 | 1998-01-21 | Miyoshi Kasei Inc | Dispersion of ultra-violet intercepting agent |
| WO2005108505A1 (en) * | 2004-04-07 | 2005-11-17 | Kronos International, Inc. | Carbon-containing, titanium dioxide-based photocatalyst, and process for producing the same |
| CN1930250B (en) * | 2004-04-07 | 2011-05-18 | 克罗内斯国际公司 | Carbon-containing, titanium dioxide-based photocatalyst, and process for producing the same |
| CN102585559A (en) * | 2011-12-23 | 2012-07-18 | 中国科学院宁波材料技术与工程研究所 | Preparation method for high-light fastness titanium dioxide pigment |
| WO2013041217A1 (en) * | 2011-09-22 | 2013-03-28 | Kronos International, Inc. | Method for the surface modification of titanium dioxide pigment |
-
1963
- 1963-02-15 GB GB623263A patent/GB1022621A/en not_active Expired
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3412944A (en) * | 1965-08-03 | 1968-11-26 | Du Pont | Process for producing titanium dioxide pigments |
| US3522079A (en) * | 1966-10-25 | 1970-07-28 | British Titan Products | Precipitation coating process for coating metal oxide particles with a hydrous metal oxide |
| US3522078A (en) * | 1967-04-21 | 1970-07-28 | Ppg Industries Inc | Process of treating titanium dioxide |
| US3529985A (en) * | 1967-12-26 | 1970-09-22 | Nat Lead Co | Titanium dioxide pigment and process for producing same |
| US4405376A (en) | 1980-11-18 | 1983-09-20 | Ishihara Sangyo Kaisha, Ltd. | Titanium dioxide pigment and process for producing same |
| US5147579A (en) * | 1989-07-17 | 1992-09-15 | Tam Ceramics, Inc. | Moisture resistant sodium titanate and potassium titanate |
| US5288320A (en) * | 1991-02-02 | 1994-02-22 | Tioxide Group Services Limited | Oxides and the production thereof |
| DE4312035A1 (en) * | 1993-04-13 | 1994-10-20 | Bayer Ag | Pigments having improved flow properties and use thereof |
| GB2315064A (en) * | 1996-07-05 | 1998-01-21 | Miyoshi Kasei Inc | Dispersion of ultra-violet intercepting agent |
| US5968529A (en) * | 1996-07-05 | 1999-10-19 | Miyoshi Kasei, Inc. | Dispersion of ultraviolet intercepting moisture-retaining agent and cosmetic article incorporating the dispersion |
| GB2315064B (en) * | 1996-07-05 | 2000-09-27 | Miyoshi Kasei Inc | Dispersion of ultraviolet intercepting agent |
| WO2005108505A1 (en) * | 2004-04-07 | 2005-11-17 | Kronos International, Inc. | Carbon-containing, titanium dioxide-based photocatalyst, and process for producing the same |
| US7524793B2 (en) * | 2004-04-07 | 2009-04-28 | Kronos International Inc | Titanium dioxide photocatalyst containing carbon and method for its production |
| EP2100927A1 (en) * | 2004-04-07 | 2009-09-16 | Kronos International, Inc. | Carbon-containing titanium dioxide photocatalyst and process the production thereof |
| US7615512B2 (en) * | 2004-04-07 | 2009-11-10 | Kronos International Inc | Titanium dioxide photocatalyst containing carbon and method for its production |
| CN1930250B (en) * | 2004-04-07 | 2011-05-18 | 克罗内斯国际公司 | Carbon-containing, titanium dioxide-based photocatalyst, and process for producing the same |
| WO2013041217A1 (en) * | 2011-09-22 | 2013-03-28 | Kronos International, Inc. | Method for the surface modification of titanium dioxide pigment |
| CN102585559A (en) * | 2011-12-23 | 2012-07-18 | 中国科学院宁波材料技术与工程研究所 | Preparation method for high-light fastness titanium dioxide pigment |
| CN102585559B (en) * | 2011-12-23 | 2014-03-26 | 中国科学院宁波材料技术与工程研究所 | Preparation method for high-light fastness titanium dioxide pigment |
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