CN106758512A - A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof - Google Patents
A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN106758512A CN106758512A CN201611201639.1A CN201611201639A CN106758512A CN 106758512 A CN106758512 A CN 106758512A CN 201611201639 A CN201611201639 A CN 201611201639A CN 106758512 A CN106758512 A CN 106758512A
- Authority
- CN
- China
- Prior art keywords
- parts
- acid
- alkali
- resistance
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C09D127/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
- D06N3/183—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials the layers are one next to the other
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/46—Non-macromolecular organic compounds
- D21H19/48—Diolefins, e.g. butadiene; Aromatic vinyl monomers, e.g. styrene; Polymerisable unsaturated acids or derivatives thereof, e.g. acrylic acid
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/52—Cellulose; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of use for laboratory acid and alkali-resistance wallpaper, including substrate layer, waterproof layer and acid and alkali-resistance coating, wherein：The raw material of acid and alkali-resistance coating includes aqueous polyacrylamide acid resin, acrylic emulsion, modified additive, paraffin, beeswax, methyl methacrylate, butyl acrylate, acrylic acid, hydroxypropyl acrylate, maleic anhydride, divinylbenzene, styrene, dibenzoyl peroxide, azodiisobutyronitrile, the pyrrolidones of N methyl 2, triethylamine, isopropanol, titanium dioxide, zinc oxide, nano silicon, composite iron-titanium powder, mica, wollastonite in powder, kaolin, talcum powder, hydroxyethyl cellulose, dispersant, silane coupler KH 560, curing agent, dimethylbenzene, defoamer and levelling agent.The present invention also proposes a kind of preparation method of above-mentioned use for laboratory acid and alkali-resistance wallpaper.The use for laboratory wallpaper for preparing has excellent acid-proof alkaline.
Description
Technical field
The present invention relates to wallpaper field, more particularly to a kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof.
Background technology
Wallpaper because have that color is various, pattern abundant, luxurious style, safety and environmental protection, easy construction, affordable etc. it is many
The characteristics of other house decorative materials of kind institute is incomparable, increasingly popularizes in daily life, what laboratory used
Wallpaper requires very high, the demand when acid-proof alkaline of wallpaper cannot meet actually used in the prior art to its resistance to acids and bases,
Demand when therefore needing a kind of use for laboratory acid and alkali-resistance wallpaper of design badly to meet actually used.
The content of the invention
To solve technical problem present in background technology, the present invention proposes a kind of use for laboratory acid and alkali-resistance wallpaper and its system
Preparation Method, the wallpaper for preparing has excellent acid-proof alkaline.
A kind of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention, including substrate layer, waterproof layer and acid and alkali-resistance coating, base material
The periphery of layer is coated with waterproof layer, and the waterproof layer is coated with acid and alkali-resistance coating away from the periphery of substrate layer, wherein：
Substrate layer is any one in wood pulp paper, non-woven paper, cloth；
The raw material of waterproof layer includes by weight：Polyurethane 80-120 parts, alkyd resin 50-90 parts, vinyl chloride-vinyl acetate resin 5-15
Part, organic solvent 4-9 parts, 2-6 parts of aerosil flatting silica, 1-4 parts of polytetrafluoroethylene (PTFE) wax powder, polyamide wax anti-settling agent 5-
9 parts, 3-9 parts of brokenly bubble polysiloxane solution, polyether-modified 4-8 parts of poly- two radical siloxane, OIT 1-4 parts, ethoxy it is fine
Dimension 2-5 parts of element, waterproof reinforced dose 4-6 parts, 3-9 parts of 2- amino-2-methyl propyl alcohol, 2,2,4- trimethyl -1,3- pentanediols Dan Yi
Butyrate 4-8 parts, 1-5 parts, castor oil 2-5 parts of organotin drier；
The raw material of acid and alkali-resistance coating includes by weight：30-40 parts of aqueous polyacrylamide acid resin, acrylic emulsion 40-80
Part, modified additive 15-25 parts, paraffin 3-5 parts, beeswax 4-6 parts, methyl methacrylate 4-6 parts, butyl acrylate 2-5 parts, third
Olefin(e) acid 1-4 parts, hydroxypropyl acrylate 2-6 parts, maleic anhydride 3-6 parts, divinylbenzene 1-4 parts, styrene 2-5 parts, peroxidating
Dibenzoyl 2-5 parts, azodiisobutyronitrile 3-5 parts, METHYLPYRROLIDONE 1-4 parts, triethylamine 2-5 parts, isopropanol 1-4
Part, titanium dioxide 3-6 parts, zinc oxide 5-15 parts, nano silicon 2-5 parts, composite iron-titanium powder 2-12 parts, mica 4-12 parts, silicon
Limestone flour 6-18 parts, kaolin 4-9 parts, talcum powder 3-9 parts, hydroxyethyl cellulose 1-6 parts, dispersant 2-8 parts, silane coupler
KH-560 2-6 parts, curing agent 3-6 parts, dimethylbenzene 2-8 parts, defoamer 1-4 parts, levelling agent 1-4 parts.
Preferably, in the raw material of waterproof layer, waterproof reinforced dose is prepared by following technique：Polyvinylpyrrolidone is molten
Solution and n-amyl alcohol are well mixed, ultrasonic 40-50min, are subsequently adding the mixing of absolute ethyl alcohol, deionized water and sodium citrate solution equal
It is even, it is subsequently added into ammoniacal liquor and is well mixed, it is subsequently adding tetraethyl orthosilicate, ultrasonic disperse 1-3min, then in 75-85 DEG C of oil bath
Pot in react 16-20h, be washed with deionized 1-3 time simultaneously centrifugation, centrifugal rotational speed is 3800-4200r/min, then in
2-4h is dried in 45-55 DEG C of baking oven and finally obtains waterproof reinforcing material.
Preferably, in the raw material of waterproof layer, in the waterproof reinforced dose of preparation technology for pressing, polyvinylpyrrolidone, citric acid
The weight ratio of sodium solution and tetraethyl orthosilicate is 2-5：1-3：2-4.
Preferably, in the raw material of acid and alkali-resistance coating, the raw material of modified additive includes by weight：Aluminium powder 20-40 parts, nanometer
Carborundum 5-15 parts, tetraethyl orthosilicate 5-15 parts, VTES 2-6 parts, ammoniacal liquor 3-6 parts, alkyd butyric acid fiber
Plain solution 1-4 parts, absolute ethyl alcohol 2-5 parts.
Preferably, in the raw material of acid and alkali-resistance coating, modified additive is prepared by following technique：By aluminium powder, nano silicon carbide
Silicon and absolute ethyl alcohol are well mixed, and 1-3h is stirred under nitrogen protection, then heat to 30-70 DEG C, add tetraethyl orthosilicate, second
Alkenyl triethoxysilane and ammoniacal liquor, stir 5-7h, and vacuum filter, with absolute ethanol washing 2-4 times, is subsequently adding alkyd butyric acid
After cellulose solution mixing, stirring 20-40min obtains modified additive.
A kind of preparation method of use for laboratory acid and alkali-resistance wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained
Finished product；
S2, the front of wallpaper semi-finished product by the feedstock composition of waterproof layer using cylinder overprinting process print waterproof layer,
After primary drying, the feedstock composition of acid and alkali-resistance coating is printed on waterproof using cylinder overprinting process and is gone up layer by layer, formed acidproof
Alkali coating, after being completed for printing, carries out redrying, is cooled to room temperature and obtains use for laboratory acid and alkali-resistance wallpaper.
Preferably, in S2, cylinder overprinting process parameter is：Print speed printing speed is 5-15m/min；Oven temperature is first to use
100-120 DEG C of drying, then form adhesion effect with 160-180 DEG C of film forming；It is formed with hexagonal loop on cylinder, hexagonal loop is opened
Porosity is 30-45%；The thickness of net of finished product cylinder is 0.1-0.3mm.
Preferably, in S2, the temperature of primary drying is 70-90 DEG C, and the time of primary drying is 4-6h；The temperature of redrying
It is 55-65 DEG C to spend, and the time of redrying is 1-3h.
A kind of use for laboratory acid and alkali-resistance wallpaper of the invention, including substrate layer, waterproof layer and acid and alkali-resistance coating, substrate layer
Periphery is coated with waterproof layer, and the waterproof layer is coated with acid and alkali-resistance coating away from the periphery of substrate layer, wherein：Substrate layer is wood pulp
Any one in paper, non-woven paper, cloth；The raw material of waterproof layer includes polyurethane, alkyd resin, vinyl chloride-vinyl acetate resin, organic solvent, gas
Aerosil flatting silica, polytetrafluoroethylene (PTFE) wax powder, polyamide wax anti-settling agent, brokenly bubble polysiloxane solution, polyether-modified poly- two
Radical siloxane, OIT, hydroxyethyl cellulose, waterproof reinforced dose, 2- amino-2-methyls propyl alcohol, 2,2,4- trimethyl -1,
3- pentanediol mono isobutyrates, organotin drier and castor oil, wherein waterproof reinforced dose added by by polyvinyl pyrrole
Alkanone dissolves and n-amyl alcohol is well mixed, ultrasound, is subsequently adding the mixing of absolute ethyl alcohol, deionized water and sodium citrate solution equal
It is even, be subsequently added into ammoniacal liquor and be well mixed, be subsequently adding tetraethyl orthosilicate, then ultrasonic disperse reacts in oil bath pan, spend from
Sub- water washing and centrifugation, then drying finally obtains waterproof reinforcing material in baking oven, in applying to the preparation of waterproof layer,
Effectively increase the water resistance of waterproof layer.The raw material of acid and alkali-resistance coating includes aqueous polyacrylamide acid resin, acrylic emulsion, changes
Property auxiliary agent, paraffin, beeswax, methyl methacrylate, butyl acrylate, acrylic acid, hydroxypropyl acrylate, maleic anhydride, diethyl
Alkenyl benzene, styrene, dibenzoyl peroxide, azodiisobutyronitrile, METHYLPYRROLIDONE, triethylamine, isopropanol, titanium
White powder, zinc oxide, nano silicon, composite iron-titanium powder, mica, wollastonite in powder, kaolin, talcum powder, hydroxyethyl cellulose,
Dispersant, silane coupler KH-560, curing agent, dimethylbenzene, defoamer and levelling agent, with aqueous polyacrylamide acid resin, propylene
Yogurt liquid, modified additive, paraffin, beeswax, methyl methacrylate, butyl acrylate, acrylic acid, hydroxypropyl acrylate and Malaysia
Acid anhydrides is base-material, with divinylbenzene, styrene, dibenzoyl peroxide, azodiisobutyronitrile, METHYLPYRROLIDONE,
Triethylamine, isopropanol, dispersant, silane coupler KH-560, curing agent, dimethylbenzene, defoamer and levelling agent are auxiliary agent, with titanium
White powder, zinc oxide, nano silicon, composite iron-titanium powder, mica, wollastonite in powder, kaolin, talcum powder and hydroxyethyl cellulose
It is filler, by the cooperation of base-material, filler and auxiliary agent, reasonable control proportioning, the acid and alkali-resistance coating for obtaining has excellent acidproof
Alkaline energy, wherein modified additive is well mixed by by aluminium powder, nanometer silicon carbide and absolute ethyl alcohol, stirs under nitrogen protection,
Then heat up, add tetraethyl orthosilicate, VTES and ammoniacal liquor, stirring, vacuum filter is washed with absolute ethyl alcohol
Wash, after being subsequently adding the mixing of alkyd cellulose butyrate solution, stirring obtain it is modified help, in applying to the preparation of acid and alkali-resistance coating,
Further increase acid-proof alkaline.The wallpaper that the present invention is obtained has excellent acid-proof alkaline.
Brief description of the drawings
Fig. 1 is a kind of structural representation of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention.
Specific embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
Bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent etc. are in this hair
In bright protection domain.
Embodiment 1
As shown in figure 1, Fig. 1 is a kind of structural representation of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention.
Reference picture 1, a kind of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and acidproof
Alkali coating 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with acid and alkali-resistance and applies away from the periphery of substrate layer 1
Layer 3, wherein：
Substrate layer 1 is wood pulp paper；
The raw material of waterproof layer 2 includes by weight：It is 100 parts of polyurethane, 70 parts of alkyd resin, 10 parts of vinyl chloride-vinyl acetate resin, organic
6.5 parts of solvent, 4 parts of aerosil flatting silica, 2.5 parts of polytetrafluoroethylene (PTFE) wax powder, 7 parts of polyamide wax anti-settling agent, brokenly bubble are gathered
6 parts of siloxane solution, polyether-modified 6 parts of poly- two radical siloxane, 2.5 parts of OIT, 3.5 parts of hydroxyethyl cellulose, waterproof
5 parts of reinforcing agent, 6 parts of 2- amino-2-methyls propyl alcohol, 2,2,4- trimethyl -1,6 parts of 3- pentanediol mono isobutyrates, organotin are urged
Dry 3 parts of agent, 3.5 parts of castor oil；
The raw material of acid and alkali-resistance coating 3 includes by weight：35 parts of aqueous polyacrylamide acid resin, 60 parts of acrylic emulsion, change
20 parts of auxiliary agent of property, 4 parts of paraffin, 5 parts of beeswax, 5 parts of methyl methacrylate, 3.5 parts of butyl acrylate, 2.5 parts of acrylic acid, propylene
4 parts of sour hydroxypropyl acrylate, 4.5 parts of maleic anhydride, 2.5 parts of divinylbenzene, 3.5 parts of styrene, 3.5 parts of dibenzoyl peroxide, idol
4 parts of nitrogen bis-isobutyronitrile, 2.5 parts of METHYLPYRROLIDONE, 3.5 parts of triethylamine, 2.5 parts of isopropanol, 4.5 parts of titanium dioxide, oxidation
10 parts of zinc, 3.5 parts of nano silicon, 7 parts of composite iron-titanium powder, 8 parts of mica, 12 parts of wollastonite in powder, 6.5 parts of kaolin, talcum
6 parts of powder, 3.5 parts of hydroxyethyl cellulose, 5 parts of dispersant, 4 parts of silane coupler KH-560,4.5 parts of curing agent, 5 parts of dimethylbenzene,
2.5 parts of defoamer, 2.5 parts of levelling agent.
Embodiment 2
As shown in figure 1, Fig. 1 is a kind of structural representation of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention.
Reference picture 1, a kind of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and acidproof
Alkali coating 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with acid and alkali-resistance and applies away from the periphery of substrate layer 1
Layer 3, wherein：
Substrate layer 1 is non-woven paper；
The raw material of waterproof layer 2 includes by weight：80 parts of polyurethane, 90 parts of alkyd resin, 5 parts of vinyl chloride-vinyl acetate resin, You Jirong
9 parts of agent, 2 parts of aerosil flatting silica, 4 parts of polytetrafluoroethylene (PTFE) wax powder, 5 parts of polyamide wax anti-settling agent, brokenly bubble polysiloxanes
9 parts of solution, polyether-modified 4 parts of poly- two radical siloxane, 4 parts of OIT, 2 parts of hydroxyethyl cellulose, waterproof reinforced dose 6 parts,
3 parts of 2- amino-2-methyls propyl alcohol, 2,2,4- trimethyl -1,8 parts of 3- pentanediol mono isobutyrates, 1 part of organotin drier, castor
5 parts of sesame oil；
The raw material of acid and alkali-resistance coating 3 includes by weight：30 parts of aqueous polyacrylamide acid resin, 80 parts of acrylic emulsion, change
15 parts of auxiliary agent of property, 5 parts of paraffin, 4 parts of beeswax, 6 parts of methyl methacrylate, 2 parts of butyl acrylate, 4 parts of acrylic acid, acrylic acid hydroxyl
2 parts of propyl ester, 6 parts of maleic anhydride, 1 part of divinylbenzene, 5 parts of styrene, 2 parts of dibenzoyl peroxide, azodiisobutyronitrile 5
Part, 1 part of METHYLPYRROLIDONE, 5 parts of triethylamine, 1 part of isopropanol, 6 parts of titanium dioxide, 5 parts of zinc oxide, nano silicon 5
Part, 2 parts of composite iron-titanium powder, 12 parts of mica, 6 parts of wollastonite in powder, 9 parts of kaolin, 3 parts of talcum powder, hydroxyethyl cellulose 6 part, point
2 parts of powder, 6 parts of silane coupler KH-560,3 parts of curing agent, 8 parts of dimethylbenzene, 1 part of defoamer, 4 parts of levelling agent.
In the raw material of waterproof layer 2, waterproof reinforced dose is prepared by following technique：By weight by 2 parts of polyvinyl pyrroles
Alkanone dissolves and n-amyl alcohol is well mixed, and ultrasonic 50min is subsequently adding absolute ethyl alcohol, deionized water and 1 part of sodium citrate solution
It is well mixed, it is subsequently added into ammoniacal liquor and is well mixed, it is subsequently adding 4 parts of tetraethyl orthosilicates, ultrasonic disperse 1min, then in 85 DEG C
16h is reacted in oil bath pan, 3 times and centrifugation is washed with deionized, centrifugal rotational speed is 3800r/min, then in 55 DEG C of bakings
2h is dried in case and finally obtains waterproof reinforcing material.
In the raw material of acid and alkali-resistance coating 3, modified additive is prepared by following technique：By weight by 20 parts of aluminium powders, 15
Part nanometer silicon carbide and 2 parts of absolute ethyl alcohols are well mixed, and 3h is stirred under nitrogen protection, then heat to 30 DEG C, add 15 parts
Tetraethyl orthosilicate, 2 parts of VTESs and 6 parts of ammoniacal liquor, stir 5h, vacuum filter, with absolute ethanol washing 4 times,
After being subsequently adding 1 part of alkyd cellulose butyrate solution mixing, stirring 40min obtains modified additive.
Embodiment 3
As shown in figure 1, Fig. 1 is a kind of structural representation of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention.
Reference picture 1, a kind of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and acidproof
Alkali coating 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with acid and alkali-resistance and applies away from the periphery of substrate layer 1
Layer 3, wherein：
Substrate layer 1 is cloth；
The raw material of waterproof layer 2 includes by weight：It is 120 parts of polyurethane, 50 parts of alkyd resin, 15 parts of vinyl chloride-vinyl acetate resin, organic
4 parts of solvent, 6 parts of aerosil flatting silica, 1 part of polytetrafluoroethylene (PTFE) wax powder, 9 parts of polyamide wax anti-settling agent, the poly- silica of brokenly bubble
3 parts of alkane solution, polyether-modified 8 parts of poly- two radical siloxane, 1 part of OIT, 5 parts, waterproof reinforced dose 4 of hydroxyethyl cellulose
Part, 9 parts of 2- amino-2-methyls propyl alcohol, 2,2,4- trimethyl -1,4 parts of 3- pentanediol mono isobutyrates, 5 parts of organotin drier,
2 parts of castor oil；
The raw material of acid and alkali-resistance coating 3 includes by weight：40 parts of aqueous polyacrylamide acid resin, 40 parts of acrylic emulsion, change
25 parts of auxiliary agent of property, 3 parts of paraffin, 6 parts of beeswax, 4 parts of methyl methacrylate, 5 parts of butyl acrylate, 1 part of acrylic acid, acrylic acid hydroxyl
6 parts of propyl ester, 3 parts of maleic anhydride, 4 parts of divinylbenzene, 2 parts of styrene, 5 parts of dibenzoyl peroxide, azodiisobutyronitrile 3
Part, 4 parts of METHYLPYRROLIDONE, 2 parts of triethylamine, 4 parts of isopropanol, 3 parts of titanium dioxide, 15 parts of zinc oxide, nano silicon
2 parts, 12 parts of composite iron-titanium powder, 4 parts of mica, 18 parts of wollastonite in powder, 4 parts of kaolin, 9 parts of talcum powder, 1 part of hydroxyethyl cellulose,
8 parts of dispersant, 2 parts of silane coupler KH-560,6 parts of curing agent, 2 parts of dimethylbenzene, 4 parts of defoamer, 1 part of levelling agent.
A kind of preparation method of use for laboratory acid and alkali-resistance wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained
Finished product；
S2, the front of wallpaper semi-finished product by the feedstock composition of waterproof layer using cylinder overprinting process print waterproof layer,
After primary drying, the temperature of primary drying is 90 DEG C, and the time of primary drying is 4h, and the feedstock composition of acid and alkali-resistance coating is adopted
Waterproof is printed on cylinder overprinting process to go up layer by layer, forms acid and alkali-resistance coating, after being completed for printing, carry out redrying, it is secondary dry
Dry temperature is 65 DEG C, and the time of redrying is 1h, is cooled to room temperature and obtains use for laboratory acid and alkali-resistance wallpaper, wherein, cylinder
Overprinting process parameter is：Print speed printing speed is 15m/min；Oven temperature is first to be dried with 100 DEG C, then is formed with 180 DEG C of film forming
Adhesion effect；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 30%；The thickness of net of finished product cylinder is 0.3mm.
Embodiment 4
As shown in figure 1, Fig. 1 is a kind of structural representation of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention.
Reference picture 1, a kind of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and acidproof
Alkali coating 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with acid and alkali-resistance and applies away from the periphery of substrate layer 1
Layer 3, wherein：
Substrate layer 1 is wood pulp paper；
The raw material of waterproof layer 2 includes by weight：85 parts of polyurethane, 85 parts of alkyd resin, 8 parts of vinyl chloride-vinyl acetate resin, You Jirong
8 parts of agent, 3 parts of aerosil flatting silica, 3 parts of polytetrafluoroethylene (PTFE) wax powder, 6 parts of polyamide wax anti-settling agent, brokenly bubble polysiloxanes
8 parts of solution, polyether-modified 5 parts of poly- two radical siloxane, 3 parts of OIT, 3 parts, waterproof reinforced dose 5.5 of hydroxyethyl cellulose
Part, 4 parts of 2- amino-2-methyls propyl alcohol, 2,2,4- trimethyl -1,7 parts of 3- pentanediol mono isobutyrates, 2 parts of organotin drier,
4 parts of castor oil；
The raw material of acid and alkali-resistance coating 3 includes by weight：32 parts of aqueous polyacrylamide acid resin, 75 parts of acrylic emulsion, change
18 parts of auxiliary agent of property, 4.5 parts of paraffin, 4.5 parts of beeswax, 5.5 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, third
3 parts of olefin(e) acid hydroxypropyl acrylate, 8 parts of maleic anhydride, 2 parts of divinylbenzene, 4 parts of styrene, 3 parts of dibenzoyl peroxide, azo two are different
4.5 parts of butyronitrile, 2 parts of METHYLPYRROLIDONE, 4 parts of triethylamine, 2 parts of isopropanol, 5 parts of titanium dioxide, part, nanometer two of zinc oxide 8
4 parts of silica, 4 parts of composite iron-titanium powder, 11 parts of mica, 7 parts of wollastonite in powder, 8 parts of kaolin, 4 parts of talcum powder, hydroxyethyl cellulose
5 parts, 3 parts of dispersant, 5 parts of silane coupler KH-560,4 parts of curing agent, 7 parts of dimethylbenzene, 2 parts of defoamer, 3 parts of levelling agent.
In the raw material of waterproof layer 2, waterproof reinforced dose is prepared by following technique：By weight by 3 parts of polyvinyl pyrroles
Alkanone dissolves and n-amyl alcohol is well mixed, and ultrasonic 48min is subsequently adding absolute ethyl alcohol, deionized water and 1.5 parts of sodium citrates molten
Liquid is well mixed, and is subsequently added into ammoniacal liquor and is well mixed, and is subsequently adding 3.5 parts of tetraethyl orthosilicates, ultrasonic disperse 1.5min, then
React 17h in 82 DEG C of oil bath pans, 3 times and centrifugation be washed with deionized, centrifugal rotational speed is 3900r/min, then in
2.5h is dried in 52 DEG C of baking ovens finally obtain waterproof reinforcing material.
In the raw material of acid and alkali-resistance coating 3, modified additive is prepared by following technique：By weight by 25 parts of aluminium powders, 12
Part nanometer silicon carbide and 3 parts of absolute ethyl alcohols are well mixed, and 2.5h is stirred under nitrogen protection, then heat to 35 DEG C, add 12
Part tetraethyl orthosilicate, 3 parts of VTESs and 5 parts of ammoniacal liquor, stir 5.5h, vacuum filter, with absolute ethanol washing 4
Secondary, after being subsequently adding 2 parts of alkyd cellulose butyrate solution mixing, stirring 35min obtains modified additive.
A kind of preparation method of use for laboratory acid and alkali-resistance wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained
Finished product；
S2, the front of wallpaper semi-finished product by the feedstock composition of waterproof layer using cylinder overprinting process print waterproof layer,
After primary drying, the temperature of primary drying is 75 DEG C, and the time of primary drying is 5.5h, by the feedstock composition of acid and alkali-resistance coating
Waterproof is printed on using cylinder overprinting process to go up layer by layer, forms acid and alkali-resistance coating, after being completed for printing, carry out redrying, it is secondary
Dry temperature is 58 DEG C, and the time of redrying is 2.5h, is cooled to room temperature and obtains use for laboratory acid and alkali-resistance wallpaper, wherein,
Cylinder overprinting process parameter is：Print speed printing speed is 8m/min；Oven temperature first to be dried with 115 DEG C, then with 165 DEG C of film forming shapes
Into adhesion effect；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 40%；The thickness of net of finished product cylinder is
0.15mm。
Embodiment 5
As shown in figure 1, Fig. 1 is a kind of structural representation of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention.
Reference picture 1, a kind of use for laboratory acid and alkali-resistance wallpaper proposed by the present invention, including substrate layer 1, waterproof layer 2 and acidproof
Alkali coating 3, the periphery of substrate layer 1 is coated with waterproof layer 2, and the waterproof layer 2 is coated with acid and alkali-resistance and applies away from the periphery of substrate layer 1
Layer 3, wherein：
Substrate layer 1 is non-woven paper；
The raw material of waterproof layer 2 includes by weight：It is 115 parts of polyurethane, 55 parts of alkyd resin, 12 parts of vinyl chloride-vinyl acetate resin, organic
5 parts of solvent, 5 parts of aerosil flatting silica, 2 parts of polytetrafluoroethylene (PTFE) wax powder, 8 parts of polyamide wax anti-settling agent, the poly- silica of brokenly bubble
4 parts of alkane solution, polyether-modified 7 parts of poly- two radical siloxane, 2 parts of OIT, 4 parts, waterproof reinforced dose 4.5 of hydroxyethyl cellulose
Part, 8 parts of 2- amino-2-methyls propyl alcohol, 2,2,4- trimethyl -1,5 parts of 3- pentanediol mono isobutyrates, 4 parts of organotin drier,
3 parts of castor oil；
The raw material of acid and alkali-resistance coating 3 includes by weight：38 parts of aqueous polyacrylamide acid resin, 45 parts of acrylic emulsion, change
22 parts of auxiliary agent of property, 3.5 parts of paraffin, 5.5 parts of beeswax, 4.5 parts of methyl methacrylate, 4 parts of butyl acrylate, 2 parts of acrylic acid, third
5 parts of olefin(e) acid hydroxypropyl acrylate, 4 parts of maleic anhydride, 3 parts of divinylbenzene, 3 parts of styrene, 4 parts of dibenzoyl peroxide, azo two are different
3.5 parts of butyronitrile, 3 parts of METHYLPYRROLIDONE, 3 parts of triethylamine, 3 parts of isopropanol, 4 parts of titanium dioxide, zinc oxide 12 part, nanometer
3 parts of silica, 10 parts of composite iron-titanium powder, 5 parts of mica, 17 parts of wollastonite in powder, 5 parts of kaolin, 8 parts of talcum powder, ethoxy are fine
2 parts of dimension element, 7 parts of dispersant, 3 parts of silane coupler KH-560,5 parts of curing agent, 3 parts of dimethylbenzene, 3 parts of defoamer, levelling agent 2
Part.
In the raw material of waterproof layer 2, waterproof reinforced dose is prepared by following technique：By weight by 4 parts of polyvinyl pyrroles
Alkanone dissolves and n-amyl alcohol is well mixed, and ultrasonic 42min is subsequently adding absolute ethyl alcohol, deionized water and 2.5 parts of sodium citrates molten
Liquid is well mixed, and is subsequently added into ammoniacal liquor and is well mixed, and is subsequently adding 2.5 parts of tetraethyl orthosilicates, ultrasonic disperse 2.5min, then
React 19h in 78 DEG C of oil bath pans, 1 time and centrifugation be washed with deionized, centrifugal rotational speed is 4100r/min, then in
3.5h is dried in 48 DEG C of baking ovens finally obtain waterproof reinforcing material.
In the raw material of acid and alkali-resistance coating 3, modified additive is prepared by following technique：By weight by 35 parts of aluminium powders, 8 parts
Nanometer silicon carbide and 4 parts of absolute ethyl alcohols are well mixed, and 1.5h is stirred under nitrogen protection, then heat to 65 DEG C, are adding 8 parts just
Silester, 5 parts of VTESs and 4 parts of ammoniacal liquor, stir 6.5h, vacuum filter, with absolute ethanol washing 2 times,
After being subsequently adding 3 parts of alkyd cellulose butyrate solution mixing, stirring 25min obtains modified additive.
A kind of preparation method of use for laboratory acid and alkali-resistance wallpaper of the invention, comprises the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper half is obtained
Finished product；
S2, the front of wallpaper semi-finished product by the feedstock composition of waterproof layer using cylinder overprinting process print waterproof layer,
After primary drying, the temperature of primary drying is 85 DEG C, and the time of primary drying is 4.5h, by the feedstock composition of acid and alkali-resistance coating
Waterproof is printed on using cylinder overprinting process to go up layer by layer, forms acid and alkali-resistance coating, after being completed for printing, carry out redrying, it is secondary
Dry temperature is 62 DEG C, and the time of redrying is 1.5h, is cooled to room temperature and obtains use for laboratory acid and alkali-resistance wallpaper, wherein,
Cylinder overprinting process parameter is：Print speed printing speed is 12m/min；Oven temperature first to be dried with 105 DEG C, then with 175 DEG C of film forming
Form adhesion effect；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 35%；The thickness of net of finished product cylinder is
0.25mm。
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (8)
1. a kind of use for laboratory acid and alkali-resistance wallpaper, including substrate layer (1), waterproof layer (2) and acid and alkali-resistance coating (3), substrate layer (1)
Periphery be coated with waterproof layer (2), the waterproof layer (2) is coated with acid and alkali-resistance coating (3) away from the periphery of substrate layer (1), its
It is characterised by, wherein：
Substrate layer (1) is wood pulp paper, any one in non-woven paper, cloth；
The raw material of waterproof layer (2) includes by weight：Polyurethane 80-120 parts, alkyd resin 50-90 parts, vinyl chloride-vinyl acetate resin 5-15
Part, organic solvent 4-9 parts, 2-6 parts of aerosil flatting silica, 1-4 parts of polytetrafluoroethylene (PTFE) wax powder, polyamide wax anti-settling agent 5-
9 parts, 3-9 parts of brokenly bubble polysiloxane solution, polyether-modified 4-8 parts of poly- two radical siloxane, OIT 1-4 parts, ethoxy it is fine
Dimension 2-5 parts of element, waterproof reinforced dose 4-6 parts, 3-9 parts of 2- amino-2-methyl propyl alcohol, 2,2,4- trimethyl -1,3- pentanediols Dan Yi
Butyrate 4-8 parts, 1-5 parts, castor oil 2-5 parts of organotin drier；
The raw material of acid and alkali-resistance coating (3) includes by weight：30-40 parts of aqueous polyacrylamide acid resin, acrylic emulsion 40-80
Part, modified additive 15-25 parts, paraffin 3-5 parts, beeswax 4-6 parts, methyl methacrylate 4-6 parts, butyl acrylate 2-5 parts, third
Olefin(e) acid 1-4 parts, hydroxypropyl acrylate 2-6 parts, maleic anhydride 3-6 parts, divinylbenzene 1-4 parts, styrene 2-5 parts, peroxidating
Dibenzoyl 2-5 parts, azodiisobutyronitrile 3-5 parts, METHYLPYRROLIDONE 1-4 parts, triethylamine 2-5 parts, isopropanol 1-4
Part, titanium dioxide 3-6 parts, zinc oxide 5-15 parts, nano silicon 2-5 parts, composite iron-titanium powder 2-12 parts, mica 4-12 parts, silicon
Limestone flour 6-18 parts, kaolin 4-9 parts, talcum powder 3-9 parts, hydroxyethyl cellulose 1-6 parts, dispersant 2-8 parts, silane coupler
KH-560 2-6 parts, curing agent 3-6 parts, dimethylbenzene 2-8 parts, defoamer 1-4 parts, levelling agent 1-4 parts.
2. use for laboratory acid and alkali-resistance wallpaper according to claim 1, it is characterised in that in the raw material of waterproof layer (2), waterproof
Reinforcing agent is prepared by following technique：Polyvinylpyrrolidone dissolving and n-amyl alcohol are well mixed, ultrasonic 40-50min, so
Add absolute ethyl alcohol, deionized water and sodium citrate solution well mixed afterwards, be subsequently added into ammoniacal liquor and be well mixed, be subsequently adding just
Tetraethyl orthosilicate, ultrasonic disperse 1-3min, then reacts 16-20h in 75-85 DEG C of oil bath pan, is washed with deionized 1-3 times
And centrifugation, centrifugal rotational speed is 3800-4200r/min, 2-4h is then dried in 45-55 DEG C of baking oven and finally obtains waterproof increasing
Strong material.
3. use for laboratory acid and alkali-resistance wallpaper according to claim 1 and 2, it is characterised in that in the raw material of waterproof layer (2),
In the waterproof reinforced dose of preparation technology for pressing, the weight ratio of polyvinylpyrrolidone, sodium citrate solution and tetraethyl orthosilicate is
2-5：1-3：2-4.
4. the use for laboratory acid and alkali-resistance wallpaper according to claim any one of 1-3, it is characterised in that acid and alkali-resistance coating (3)
Raw material in, the raw material of modified additive includes by weight：Aluminium powder 20-40 parts, nanometer silicon carbide 5-15 parts, tetraethyl orthosilicate 5-
15 parts, VTES 2-6 parts, ammoniacal liquor 3-6 parts, 1-4 parts, absolute ethyl alcohol 2-5 parts of alkyd cellulose butyrate solution.
5. the use for laboratory acid and alkali-resistance wallpaper according to claim any one of 1-4, it is characterised in that acid and alkali-resistance coating (3)
Raw material in, modified additive is prepared by following technique：Aluminium powder, nanometer silicon carbide and absolute ethyl alcohol are well mixed, in nitrogen
1-3h is stirred under gas shielded, 30-70 DEG C is then heated to, tetraethyl orthosilicate, VTES and ammoniacal liquor is added, stirred
Mix 5-7h, vacuum filter, with absolute ethanol washing 2-4 times, after being subsequently adding the mixing of alkyd cellulose butyrate solution, stirs 20-
40min obtains modified additive.
6. the preparation method of a kind of use for laboratory acid and alkali-resistance wallpaper according to claim any one of 1-5, it is characterised in that
Comprise the following steps：
S1, the figuratum printing layer of tool is formed on substrate layer by typography in base material layer surface, wallpaper semi-finished product are obtained；
S2, the front of wallpaper semi-finished product by the feedstock composition of waterproof layer using cylinder overprinting process print waterproof layer, once
After drying, the feedstock composition of acid and alkali-resistance coating is printed on waterproof using cylinder overprinting process and is gone up layer by layer, formed acid and alkali-resistance and apply
Layer, after being completed for printing, carries out redrying, is cooled to room temperature and obtains use for laboratory acid and alkali-resistance wallpaper.
7. the preparation method of use for laboratory acid and alkali-resistance wallpaper according to claim 6, it is characterised in that in S2, cylinder set
Print technological parameter is：Print speed printing speed is 5-15m/min；Oven temperature is first to be dried with 100-120 DEG C, then with 160-180 DEG C
Film forming forms adhesion effect；Hexagonal loop is formed with cylinder, the percent opening of hexagonal loop is 30-45%；The net of finished product cylinder
Thickness is 0.1-0.3mm.
8. the preparation method of the use for laboratory acid and alkali-resistance wallpaper according to claim 6 or 7, it is characterised in that in S2, once
Dry temperature is 70-90 DEG C, and the time of primary drying is 4-6h；The temperature of redrying be 55-65 DEG C, redrying when
Between be 1-3h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611201639.1A CN106758512A (en) | 2016-12-22 | 2016-12-22 | A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611201639.1A CN106758512A (en) | 2016-12-22 | 2016-12-22 | A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106758512A true CN106758512A (en) | 2017-05-31 |
Family
ID=58897621
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611201639.1A Withdrawn CN106758512A (en) | 2016-12-22 | 2016-12-22 | A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106758512A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107700251A (en) * | 2017-10-19 | 2018-02-16 | 无为县荣华鬃刷制品有限公司 | A kind of anti-aging acidproof basic dye for the printing and dyeing of pig hair |
| CN107761458A (en) * | 2017-11-17 | 2018-03-06 | 安徽银兔装饰材料有限公司 | Antibacterial foaming paper pulp and preparation method thereof |
| CN108085997A (en) * | 2017-12-05 | 2018-05-29 | 苏州固泰新材股份有限公司 | A kind of weather-proof antifouling wallpaper and preparation method thereof |
| CN109321986A (en) * | 2018-08-23 | 2019-02-12 | 广东工业大学 | A kind of waterproof haze composite material and preparation method and application |
| CN109735227A (en) * | 2019-01-22 | 2019-05-10 | 黄山市七七七电子有限公司 | A kind of environment-friendly type compression joint type silicon chip corrosion barrier protection materials and its production technology |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602257A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Waterproof coating material resistant to acid rain scouring |
| CN204401365U (en) * | 2014-12-12 | 2015-06-17 | 广东玉兰装饰材料有限公司 | A kind of Jinsha wallpaper |
| CN105297552A (en) * | 2015-11-02 | 2016-02-03 | 自贡市华尔美科技有限公司 | Preparation method of damp-proof water-based crack wallpaper |
| JP2016138342A (en) * | 2015-01-27 | 2016-08-04 | 王子ホールディングス株式会社 | Backing sheet for wallpaper |
| CN106085230A (en) * | 2016-07-31 | 2016-11-09 | 孝感市亦泓家居创意设计有限公司 | A kind of indoor decoration flame-proof antibiotic acid and alkali-resistance wall paper wallpaper coating |
| CN106084931A (en) * | 2016-06-07 | 2016-11-09 | 蚌埠市禹会区贵宾装饰材料商行 | A kind of modified metal flash coating material of photo frame acid and alkali-resistance |
| CN106241819A (en) * | 2016-07-15 | 2016-12-21 | 中国科学院宁波材料技术与工程研究所 | A kind of SiO2nano wire strengthens silicon dioxide silica aerogel composite material and preparation method thereof |
-
2016
- 2016-12-22 CN CN201611201639.1A patent/CN106758512A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103602257A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Waterproof coating material resistant to acid rain scouring |
| CN204401365U (en) * | 2014-12-12 | 2015-06-17 | 广东玉兰装饰材料有限公司 | A kind of Jinsha wallpaper |
| JP2016138342A (en) * | 2015-01-27 | 2016-08-04 | 王子ホールディングス株式会社 | Backing sheet for wallpaper |
| CN105297552A (en) * | 2015-11-02 | 2016-02-03 | 自贡市华尔美科技有限公司 | Preparation method of damp-proof water-based crack wallpaper |
| CN106084931A (en) * | 2016-06-07 | 2016-11-09 | 蚌埠市禹会区贵宾装饰材料商行 | A kind of modified metal flash coating material of photo frame acid and alkali-resistance |
| CN106241819A (en) * | 2016-07-15 | 2016-12-21 | 中国科学院宁波材料技术与工程研究所 | A kind of SiO2nano wire strengthens silicon dioxide silica aerogel composite material and preparation method thereof |
| CN106085230A (en) * | 2016-07-31 | 2016-11-09 | 孝感市亦泓家居创意设计有限公司 | A kind of indoor decoration flame-proof antibiotic acid and alkali-resistance wall paper wallpaper coating |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107700251A (en) * | 2017-10-19 | 2018-02-16 | 无为县荣华鬃刷制品有限公司 | A kind of anti-aging acidproof basic dye for the printing and dyeing of pig hair |
| CN107761458A (en) * | 2017-11-17 | 2018-03-06 | 安徽银兔装饰材料有限公司 | Antibacterial foaming paper pulp and preparation method thereof |
| CN108085997A (en) * | 2017-12-05 | 2018-05-29 | 苏州固泰新材股份有限公司 | A kind of weather-proof antifouling wallpaper and preparation method thereof |
| CN109321986A (en) * | 2018-08-23 | 2019-02-12 | 广东工业大学 | A kind of waterproof haze composite material and preparation method and application |
| CN109735227A (en) * | 2019-01-22 | 2019-05-10 | 黄山市七七七电子有限公司 | A kind of environment-friendly type compression joint type silicon chip corrosion barrier protection materials and its production technology |
| CN109735227B (en) * | 2019-01-22 | 2021-04-09 | 黄山市七七七电子有限公司 | Environment-friendly crimping type silicon chip corrosion shielding protection material and production process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106758512A (en) | A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof | |
| CN106867327A (en) | A kind of resistant oil resistant wallpaper and preparation method thereof | |
| CN110284372A (en) | A kind of laser transfer paper and its production technology | |
| CN106867372A (en) | A kind of high-hardness water-proof wallpaper | |
| CN106867378A (en) | A kind of tack oil resistant wallpaper high and preparation method thereof | |
| CN103741481B (en) | A kind of blotting founds dry painting canvas | |
| CN107201159A (en) | A kind of cracking resistance, anti-dropout coating and preparation method | |
| CN108774460A (en) | A kind of fragrant slow release automatic cleaning coating and its preparation method and application based on strawberry type microcapsules | |
| CN107386007B (en) | A kind of anti-pollution wallpaper and preparation method thereof | |
| CN106811130A (en) | The elastic aqueous colorful building coating and preparation method of a kind of reflective insulation | |
| CN110016269A (en) | A kind of reflection heat-insulating type texture paint and preparation method thereof | |
| CN106147488B (en) | High-temperature resistant water transfers coating composition and preparation method thereof | |
| CN111377672A (en) | Method for manufacturing external decorative plate | |
| CN101186771B (en) | Method for preparing modified acrylic resin finish | |
| CN107033711A (en) | A kind of true mineral varnish of waterproof and preparation method | |
| CN103820998B (en) | PVC synthetic leather surface conditioning agent, PVC synthetic leather and preparation method thereof | |
| KR100682540B1 (en) | Releaser composition for wet mat construction of color concrete and its applying method | |
| CN106977661A (en) | A kind of special styrene-acrylic emulsion of wallpaper and its preparation method and application | |
| CN112063296A (en) | High-hardness fireproof hydrophobic stone-like ceramic coating, and preparation process and application thereof | |
| CN106956541A (en) | A kind of manufacture craft of waterproof pulp handicraft | |
| CN109593418A (en) | Polyacrylate aqueous latex paint and preparation method thereof | |
| CN102335718B (en) | Processing method for foam model in lost foam forging | |
| CN107088512A (en) | A kind of spraying coating process of nano-silicon inorganic coating | |
| CN109957271A (en) | Fast light, water soluble acrylic acid esters resin coating that film forming is fast and preparation method thereof | |
| CN106049169A (en) | Water-resistant and heat-resistant stiff and smooth PVC wallpaper base paper and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170531 |
|
| WW01 | Invention patent application withdrawn after publication |