CN105297552A - Preparation method of damp-proof water-based crack wallpaper - Google Patents
Preparation method of damp-proof water-based crack wallpaper Download PDFInfo
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- CN105297552A CN105297552A CN201510732262.1A CN201510732262A CN105297552A CN 105297552 A CN105297552 A CN 105297552A CN 201510732262 A CN201510732262 A CN 201510732262A CN 105297552 A CN105297552 A CN 105297552A
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- water
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 238000007639 printing Methods 0.000 claims abstract description 37
- 238000001035 drying Methods 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000002002 slurry Substances 0.000 claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 11
- 238000000576 coating method Methods 0.000 claims abstract description 11
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims description 47
- 230000003115 biocidal effect Effects 0.000 claims description 31
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 24
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 24
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 20
- 239000000758 substrate Substances 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 19
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 18
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 16
- 239000011265 semifinished product Substances 0.000 claims description 16
- 208000037656 Respiratory Sounds Diseases 0.000 claims description 13
- 230000002421 anti-septic effect Effects 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 13
- 239000002562 thickening agent Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 10
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 10
- 235000019260 propionic acid Nutrition 0.000 claims description 10
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 10
- YOIZTLBZAMFVPK-UHFFFAOYSA-N 2-(3-ethoxy-4-hydroxyphenyl)-2-hydroxyacetic acid Chemical compound CCOC1=CC(C(O)C(O)=O)=CC=C1O YOIZTLBZAMFVPK-UHFFFAOYSA-N 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 8
- 239000003822 epoxy resin Substances 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000004745 nonwoven fabric Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000012043 crude product Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000010408 film Substances 0.000 claims description 3
- 238000003801 milling Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000006072 paste Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 238000007650 screen-printing Methods 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 239000002966 varnish Substances 0.000 claims description 3
- 235000021419 vinegar Nutrition 0.000 claims description 3
- 239000000052 vinegar Substances 0.000 claims description 3
- 230000001680 brushing effect Effects 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- -1 ethoxyl Chemical group 0.000 claims description 2
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 15
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 3
- 241000430525 Aurinia saxatilis Species 0.000 abstract 1
- 239000003292 glue Substances 0.000 abstract 1
- 238000005457 optimization Methods 0.000 abstract 1
- 230000008447 perception Effects 0.000 abstract 1
- 238000007603 infrared drying Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- 239000004599 antimicrobial Substances 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/12—Stencil printing; Silk-screen printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/22—Metallic printing; Printing with powdered inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/072—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements
- E04F13/075—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements for insulation or surface protection, e.g. against noise or impact
Abstract
The invention discloses a preparation method of a damp-proof water-based crack wallpaper. The method comprises the following steps: selecting a base material layer, and forming a printed layer with a pattern on the base material layer through a printing technology to prepare a semi-finished wallpaper product; printing a gold dust layer on the front surface of the semi-finished wallpaper product through a cylinder overprint technology; sequentially coating the back surface of the semi-finished wallpaper product with an antibacterial layer, a damp-proof layer and dry glue layer; drying in a drying oven after printing is ended; and printing water-based crack slurry on the dried semi-finished wallpaper product, and drying and cooling at 100-120 DEG C, so as to obtain the crack wallpaper. The antibacterial layer is attached to the wallpaper, so that a good antibacterial effect can be put into a play; meanwhile, optimization is carried out on the formula of a damp-proof layer to reach an optimal damp-proof effect; and the damp-proof water-based crack wallpaper has a relatively good beautiful decorative perception through printing of the water-based slurry.
Description
Technical field
The present invention relates to adornment technical field, be specifically related to a kind of preparation method of moistureproof water-based crackle wallpaper.
Background technology
Wallpaper, also referred to as wallpaper, wall paper, being a kind of indoor hardware fitting for papering metope, being widely used in the interior decoration etc. in house, office, hotel, hotel.Material is not limited to paper, also comprises other materials.
Because have the advantages that other house decorative materials multiple such as color is various, pattern enriches, luxurious style, safety and environmental protection, easy construction, affordable are incomparable, therefore obtain the universal of certain degree at the developed countries and regions such as American-European, Japanese.
Wallpaper is divided into a lot of class, as overlay film wallpaper, coating wallpaper, embossing wallpaper etc.Usually produce body paper with bleached wood pulp, then through the processing process of different operation, cover as coating, printing, embossing or surface and mould, dispatch from the factory after cutting, packing.There is certain intensity, toughness, appearance attractive in appearance and good water repelling property.
Wallpaper is the important component part of Modern Interior Decoration material, is one of indoor wall surface primary decoration finishing material, because wallpaper has good decorative effect, so obtain applying more and more widely.Along with improving constantly of socioeconomic development and people's level of production, hotel and house emerge in multitude, and people require more and more higher to the fitting-up of indoor, more focus on the decorative effect of surface of wall.At present, increasing people is devoted to the research of wallpaper, but research stays in the decorative effect aspect of wallpaper mostly, as changed the aspects such as pattern, more focuses on surface.And after wallpaper more applies and be Indoor environment finishing, occupy indoor very large area, if it can have some function, as antibacterial functions, then can play good effect.And the wallpaper of prior art does not all possess antibacterial functions.Prior art more focuses on the fancy design on surface, the collocation of color and the decorative effect of entirety, few to the functional emphasis of wallpaper, especially to the antibiotic property of wallpaper, the research of health application function is not enough, can not meet consumers in general to the requirement of wallpaper with antibacterial functions.In order to adapt to the needs of special space environment, the place that as crowded in hospital, school etc. and bacterium is easily propagated, the wallpaper as decorative material for internal wall should have antibacterial function.Therefore, people urgently wish that a kind of antibacterial wallpaper and preparation method thereof is come out.
The environment for use of wallpaper is often subject to the restriction of its performance, particularly in the place that ambient humidity is larger, also have larger requirement to the humidity resistance of wallpaper, otherwise greatly will reduce the service life of wallpaper.
Summary of the invention
The object of this invention is to provide and a kind ofly there is good antibacterial protection against the tide and with the preparation method of water-based crackle wallpaper.
For reaching above-mentioned purpose, providing a kind of preparation method of moistureproof water-based crackle wallpaper in one embodiment of the present of invention, comprising the following steps:
1), choose substrate layer, and on substrate layer, form the figuratum printed layers of tool by typography, obtained wallpaper semi-finished product;
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process;
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; Be completed for printing and be placed on drying in oven;
4), by water-based crack slurry printing wallpaper semi-finished product after the drying, under 100 DEG C ~ 120 DEG C conditions, Drying and cooling obtains crackle wallpaper;
The raw material components of wherein said antibiotic layer comprises: water lustering oil 50 parts ~ 100 parts, antiseptic 5 parts ~ 10 parts; The raw material components of described damp-proof layer comprises: EHMA 50 parts ~ 100 parts, bisphenol A type epoxy resin 20 parts ~ 50 parts, polyacrylic resin 10 parts ~ 30 parts, ethyl acetate 10 parts ~ 30 parts, antimonous oxide 0.1 part ~ 1 part, 0.1 part ~ 1 part, aluminium hydroxide, 2,2-dihydromethyl propionic acid 1 part ~ 5 parts, DBSA 1 part ~ 5 parts;
The raw material components of wherein said water-based crack slurry comprises: acrylic emulsion 45 parts ~ 60 parts; Aqueous color paste 20 parts ~ 30 parts; Propylene glycol 2 parts ~ 5 parts; Deionized water 10 parts ~ 20 parts; Ethylenediamine 5 parts ~ 10 parts; Thickener 5 parts ~ 10 parts.
Preferably, substrate layer is the one in PVC coated paper, pure paper, non-woven paper, nonwoven fabric, gauze or gauze.
Preferably, the typography of substrate layer formation pattern comprises gravure, convex print, screen printing, ink-jet, printing, brushing, drawing or anglicanum.
Preferably, the raw material of Jinsha layer comprises
Urethane acrylate 80 parts ~ 150 parts, filler 20 parts ~ 80 parts, golden pigment composition 5 parts ~ 50 parts, varnish 1 part ~ 5 parts, thickener 0.2 part ~ 5 parts, film forming agent 3 parts ~ 5 parts, ethanol 1 part ~ 3 parts, mica powder 1 part ~ 5 parts.
Preferably, the feedstock composition preparation method of Jinsha layer is: the raw material getting formula ratio, the emulsion of urethane acrylate is added in agitator, grind with the mixture of milling apparatus by fill composition and emulsion again, low whipping speed is under 500 ~ 2000r/min condition, stirs 20 ~ 30min and makes it mix; Progressively add adhesive force auxiliary agent, thickener, film forming agent, ethanol and mica powder again, continue to keep stirring 10 ~ 20min, fully sealing after mixing.
Preferably, the method for preparing raw material of antibiotic layer is
Take component by weight, water lustering oil is placed in homogenizer, under the rotating speed of 500r/min ~ 2000r/min, add antiseptic stir 10min ~ 30min.
Preferably, the raw material amount of antibiotic layer is 15g/m
2~ 100g/m
2; The raw material amount of described damp-proof layer is 100g/m
2~ 300g/m
2; The coating thickness of described dryness glue-line is 2mm ~ 5mm.
Preferably, diaphragm is attached with outside Jinsha layer.
Preferably, antiseptic is Inorganic Ag System Antimicrobial Agents.
Preferably, water lustering oil is water-based matte gloss oil or transparent highlight water-based gloss oil.
Preferably, thickener is nonionic hydrophobically modified ethoxylated urethanes copolymer or process of hydrophobic associated ethoxyl cellulose.
Preferably, the preparation method of water-based crack slurry is: joined in reactor by acrylic emulsion and stir 5min ~ 10min, control rotating speed 1000r/min ~ 2000r/min after dropping into aqueous color paste, propylene glycol, deionized water, ethylenediamine to continue to stir 5min ~ 10min, finally add thickener continuation stirring 5min ~ 10min and obtain crude product; By vinegar bottle by obtaining water-based crack slurry after 150 order ~ 250 mesh sieves.
In sum, the present invention has the following advantages:
The present invention, by adhering to antibiotic layer in wallpaper, can playing good antibacterial effect, simultaneously by being optimized the formula of damp-proof layer, reaching more excellent moisture effect; And by the printing of water paste, there is better attractive, decorative sense.
Detailed description of the invention
The preparation of raw material
1, the preparation of antibiotic layer raw material:
Method one:
A, component: water-based matte gloss oil 60 parts, Inorganic Ag System Antimicrobial Agents 6 parts;
B, preparation method: take component by weight, water lustering oil is placed in homogenizer, add antiseptic and stir 15min under the rotating speed of 1000r/min; Obtain the antimicrobial mix for the formation of antibiotic layer.
Method two:
A, component: transparent highlight water-based gloss oil 80 parts, Inorganic Ag System Antimicrobial Agents 5 parts;
B, preparation method: take component by weight, water lustering oil is placed in homogenizer, add antiseptic and stir 20min under the rotating speed of 2000r/min; Obtain the antimicrobial mix for the formation of antibiotic layer.
2, the preparation of Jinsha layer raw material:
A, component:
Urethane acrylate 80 parts ~ 150 parts, filler 20 parts ~ 80 parts, golden pigment composition 5 parts ~ 50 parts, varnish 1 part ~ 5 parts, thickener 0.2 part ~ 5 parts, film forming agent 3 parts ~ 5 parts, ethanol 1 part ~ 3 parts, mica powder 1 part ~ 5 parts.
B, preparation method: the raw material getting formula ratio, the emulsion of urethane acrylate is added in agitator, grind with the mixture of milling apparatus by fill composition and emulsion, low whipping speed is under 500 ~ 2000r/min condition again, stirs 20 ~ 30min and makes it mix; Progressively add adhesive force auxiliary agent, thickener, film forming agent, ethanol and mica powder again, continue to keep stirring 10 ~ 20min, fully sealing after mixing.
3, the preparation of water paste:
Raw material components
Acrylic emulsion 50 parts; Aqueous color paste 22 parts;
Propylene glycol 2 parts; Deionized water 12 parts; Ethylenediamine 6 parts;
Nonionic hydrophobically modified ethoxylated urethanes copolymer 5 parts.
Wherein propylene glycol and ethylenediamine as the stabilizing agent of water paste, can improve stability and the uniformity of water paste.
Acrylic emulsion is joined in reactor and stirs 8min, control rotating speed 1500r/min after dropping into aqueous color paste, propylene glycol, deionized water, ethylenediamine and continue to stir 5min, finally add thickener continuation stirring 5min and obtain crude product; By vinegar bottle by obtaining water-based crack slurry after 200 mesh sieves.
Embodiment 1
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
4), by water-based crack slurry printing wallpaper semi-finished product after the drying, under 100 DEG C of conditions, crackle wallpaper is obtained after Drying and cooling.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, 0.2 part, aluminium hydroxide, 2,2-dihydromethyl propionic acid 2 parts, DBSA 1 part.
The raw material components of water paste is
Acrylic emulsion 50 parts; Aqueous color paste 22 parts;
Propylene glycol 2 parts; Deionized water 12 parts; Ethylenediamine 6 parts;
Nonionic hydrophobically modified ethoxylated urethanes copolymer 5 parts.
Embodiment 2
1), choose pure paper as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of screen printing, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50/min; Oven temperature is first with 150 DEG C of oven dry, then forms adhesion effect by 200 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 50g/m
2; The raw material amount of damp-proof layer is 200g/m
2; The coating thickness of dryness glue-line is 4mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
4), by water-based crack slurry printing wallpaper semi-finished product after the drying, under 100 DEG C of conditions, crackle wallpaper is obtained after Drying and cooling.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, 0.2 part, aluminium hydroxide, 2,2-dihydromethyl propionic acid 2 parts, DBSA 1 part.
Damp-proof layer raw material components is on the impact of moisture effect
Embodiment 3
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
4), by water-based crack slurry printing wallpaper semi-finished product after the drying, under 105 DEG C of conditions, crackle wallpaper is obtained after Drying and cooling.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, 2,2-dihydromethyl propionic acid 2 parts, DBSA 1 part.
Embodiment 4
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
4), by water-based crack slurry printing wallpaper semi-finished product after the drying, under 110 DEG C of conditions, crackle wallpaper is obtained after Drying and cooling.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, 0.2 part, aluminium hydroxide, DBSA 1 part.
Embodiment 5
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
4), by water-based crack slurry printing wallpaper semi-finished product after the drying, under 100 DEG C of conditions, crackle wallpaper is obtained after Drying and cooling.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part, 0.2 part, aluminium hydroxide, 2,2-dihydromethyl propionic acid 2 parts.
Embodiment 6
1), choose nonwoven fabric as substrate layer, and on substrate layer, form the figuratum printed layers of tool by the typography of convex print or gravure, obtained wallpaper semi-finished product.
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process; Cylinder overprinting process parameter is specially: print speed printing speed is 50m/min; Oven temperature is first with 130 DEG C of oven dry, then forms adhesion effect by 190 DEG C of film forming; Cylinder is formed with hexagonal loop, and the percent opening of hexagonal loop is 40%; The net thickness of finished product cylinder is 0.3mm; After printing Jinsha layer, outside Jinsha layer, lay layer protecting film.
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; The raw material amount of antibiotic layer is 20g/m
2; The raw material amount of damp-proof layer is 120g/m
2; The coating thickness of dryness glue-line is 3mm.Be completed for printing and be placed on drying in oven; Or pass through infrared drying.
4), by water-based crack slurry printing wallpaper semi-finished product after the drying, under 100 DEG C of conditions, crackle wallpaper is obtained after Drying and cooling.
The raw material components of antibiotic layer comprises: water lustering oil 80 parts, antiseptic 9 parts;
The raw material components of damp-proof layer comprises: EHMA 70 parts, bisphenol A type epoxy resin 20 parts, polyacrylic resin 12 parts, ethyl acetate 10 parts, antimonous oxide 0.4 part.
Moisture-resistant test
The wallpaper that the described method of embodiment 3 ~ 6 is produced is carried out water vapour transit dose mensuration.
Test standard: ASTMF372; 2
Testing equipment: automatic multiple-head moisture-inhibiting analyzer
Experimental enviroment: 37 DEG C, RH=100%
Result of the test is as table 1:
Table 1: the moisture-vapor transmission (24h) in embodiment 3 ~ 6
| Embodiment | Moisture-vapor transmission |
| Embodiment 3 | 0.10g/m 2 |
| Embodiment 4 | 0.17g/m 2 |
| Embodiment 5 | 0.32g/m 2 |
| Embodiment 6 | 0.35g/m 2 |
Can be learnt by the comparing result of table 1, antimonous oxide, aluminium hydroxide and 2 is not added in embodiment 6,2-dihydromethyl propionic acid, its moisture-vapor transmission is higher than embodiment 3 ~ 5, illustrate and adding DBSA, aluminium hydroxide and 2, after 2-dihydromethyl propionic acid, the humidity resistance of wallpaper is had a certain upgrade, wherein to add DBSA and 2 in embodiment 3, comparatively remarkable to the lifting of humidity resistance after 2-dihydromethyl propionic acid, the wallpaper humidity resistance prepared of the embodiment 4 adding aluminium hydroxide and DBSA also tool has a distinct increment.In sum, the present invention can promote the humidity resistance of damp-proof layer adding DBSA, aluminium hydroxide and 2,2-dihydromethyl propionic acid, and then improves moisture effect.
Claims (10)
1. a preparation method for moistureproof water-based crackle wallpaper, comprises the following steps:
1), choose substrate layer, and on substrate layer, form the figuratum printed layers of tool by typography, obtained wallpaper semi-finished product;
2), Jinsha layer is printed in the half-finished front of wallpaper by cylinder overprinting process;
3), antibiotic layer, damp-proof layer and dryness glue-line is applied successively at the half-finished back side of wallpaper; Be completed for printing and be placed on drying in oven;
4), by water-based crack slurry printing wallpaper semi-finished product after the drying, under 100 DEG C ~ 120 DEG C conditions, Drying and cooling obtains crackle wallpaper;
The raw material components of wherein said antibiotic layer comprises: water lustering oil 50 parts ~ 100 parts, antiseptic 5 parts ~ 10 parts; The raw material components of described damp-proof layer comprises: EHMA 50 parts ~ 100 parts, bisphenol A type epoxy resin 20 parts ~ 50 parts, polyacrylic resin 10 parts ~ 30 parts, ethyl acetate 10 parts ~ 30 parts, antimonous oxide 0.1 part ~ 1 part, 0.1 part ~ 1 part, aluminium hydroxide, 2,2-dihydromethyl propionic acid 1 part ~ 5 parts, DBSA 1 part ~ 5 parts;
The raw material components of wherein said water-based crack slurry comprises: acrylic emulsion 45 parts ~ 60 parts; Aqueous color paste 20 parts ~ 30 parts; Propylene glycol 2 parts ~ 5 parts; Deionized water 10 parts ~ 20 parts; Ethylenediamine 5 parts ~ 10 parts; Thickener 5 parts ~ 10 parts.
2. preparation method as claimed in claim 1, is characterized in that: described substrate layer is the one in PVC coated paper, pure paper, non-woven paper, nonwoven fabric, gauze or gauze.
3. preparation method as claimed in claim 1, is characterized in that: the typography that described substrate layer forms pattern comprises gravure, convex print, screen printing, ink-jet, printing, brushing, drawing or anglicanum.
4. preparation method as claimed in claim 1, is characterized in that: the raw material of described Jinsha layer comprises
Urethane acrylate 80 parts ~ 150 parts, filler 20 parts ~ 80 parts, golden pigment composition 5 parts ~ 50 parts, varnish 1 part ~ 5 parts, thickener 0.2 part ~ 5 parts, film forming agent 3 parts ~ 5 parts, ethanol 1 part ~ 3 parts, mica powder 1 part ~ 5 parts.
5. preparation method as claimed in claim 4, it is characterized in that: the feedstock composition preparation method of described Jinsha layer is: the raw material getting formula ratio, the emulsion of urethane acrylate is added in agitator, grind with the mixture of milling apparatus by fill composition and emulsion again, low whipping speed is under 500 ~ 2000r/min condition, stirs 20 ~ 30min and makes it mix; Progressively add adhesive force auxiliary agent, thickener, film forming agent, ethanol and mica powder again, continue to keep stirring 10 ~ 20min, fully sealing after mixing.
6. preparation method as claimed in claim 1, is characterized in that: the preparation method of described antibiotic layer raw material is:
Take component by weight, water lustering oil is placed in homogenizer, under the rotating speed of 500r/min ~ 2000r/min, add antiseptic stir 10min ~ 30min.
7. preparation method as claimed in claim 1, is characterized in that: the raw material amount of described antibiotic layer is 15g/m
2~ 100g/m
2; The raw material amount of described damp-proof layer is 100g/m
2~ 300g/m
2; The coating thickness of described dryness glue-line is 2mm ~ 5mm.
8. preparation method as claimed in claim 1, is characterized in that: be attached with diaphragm outside described Jinsha layer.
9. preparation method as claimed in claim 1, is characterized in that: described thickener is nonionic hydrophobically modified ethoxylated urethanes copolymer or process of hydrophobic associated ethoxyl cellulose.
10. preparation method as claimed in claim 1, it is characterized in that: the preparation method of described water-based crack slurry is: joined in reactor by acrylic emulsion and stir 5min ~ 10min, control rotating speed 1000r/min ~ 2000r/min after dropping into aqueous color paste, propylene glycol, deionized water, ethylenediamine to continue to stir 5min ~ 10min, finally add thickener continuation stirring 5min ~ 10min and obtain crude product; Vinegar bottle is obtained water-based crack slurry by after 150 order ~ 250 mesh sieves.
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| CN201510732262.1A CN105297552B (en) | 2015-11-02 | 2015-11-02 | A kind of preparation method of the water-based crackle wallpaper of protection against the tide |
| CN201710954796.8A CN107724176A (en) | 2015-11-02 | 2015-11-02 | A kind of moistureproof water-based crackle wallpaper |
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| CN201710954796.8A Division CN107724176A (en) | 2015-11-02 | 2015-11-02 | A kind of moistureproof water-based crackle wallpaper |
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| CN201710954796.8A Pending CN107724176A (en) | 2015-11-02 | 2015-11-02 | A kind of moistureproof water-based crackle wallpaper |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105803851A (en) * | 2016-03-31 | 2016-07-27 | 自贡市华尔美科技有限公司 | Environment-friendly inflaming retardant wallpaper |
| CN106703311A (en) * | 2016-12-22 | 2017-05-24 | 安徽易有墙纸有限公司 | Heat-resisting waterproof wallpaper and production method thereof |
| CN106758512A (en) * | 2016-12-22 | 2017-05-31 | 安徽易有墙纸有限公司 | A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof |
| CN106835855A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of corrosion-resistant waterproof wallpaper and preparation method thereof |
| CN106835854A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of fire-proof and water-proof wallpaper and preparation method thereof |
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| CN105803851A (en) * | 2016-03-31 | 2016-07-27 | 自贡市华尔美科技有限公司 | Environment-friendly inflaming retardant wallpaper |
| CN106703311A (en) * | 2016-12-22 | 2017-05-24 | 安徽易有墙纸有限公司 | Heat-resisting waterproof wallpaper and production method thereof |
| CN106758512A (en) * | 2016-12-22 | 2017-05-31 | 安徽易有墙纸有限公司 | A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof |
| CN106835855A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of corrosion-resistant waterproof wallpaper and preparation method thereof |
| CN106835854A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of fire-proof and water-proof wallpaper and preparation method thereof |
| CN108544865A (en) * | 2018-03-16 | 2018-09-18 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of signature card printing technology |
| CN108621620A (en) * | 2018-03-16 | 2018-10-09 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of bankbook printing technology |
| CN112323541A (en) * | 2020-08-20 | 2021-02-05 | 安徽紫荆花墙饰材料股份有限公司 | Production method of antibacterial and antibacterial wallpaper |
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| CN105297552B (en) | 2017-11-14 |
| CN107724176A (en) | 2018-02-23 |
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