CN105297552B - A kind of preparation method of the water-based crackle wallpaper of protection against the tide - Google Patents
A kind of preparation method of the water-based crackle wallpaper of protection against the tide Download PDFInfo
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- CN105297552B CN105297552B CN201510732262.1A CN201510732262A CN105297552B CN 105297552 B CN105297552 B CN 105297552B CN 201510732262 A CN201510732262 A CN 201510732262A CN 105297552 B CN105297552 B CN 105297552B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 208000037656 Respiratory Sounds Diseases 0.000 title claims abstract description 16
- 238000007639 printing Methods 0.000 claims abstract description 37
- 239000011265 semifinished product Substances 0.000 claims abstract description 34
- 230000003115 biocidal effect Effects 0.000 claims abstract description 33
- 238000001035 drying Methods 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000000758 substrate Substances 0.000 claims abstract description 22
- 230000008569 process Effects 0.000 claims abstract description 18
- 239000002002 slurry Substances 0.000 claims abstract description 16
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims description 48
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000010408 film Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 18
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 16
- 230000002421 anti-septic effect Effects 0.000 claims description 13
- 239000000839 emulsion Substances 0.000 claims description 13
- 239000002562 thickening agent Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 9
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 9
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 9
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 9
- -1 polypropylene Polymers 0.000 claims description 9
- 235000019260 propionic acid Nutrition 0.000 claims description 9
- YOIZTLBZAMFVPK-UHFFFAOYSA-N 2-(3-ethoxy-4-hydroxyphenyl)-2-hydroxyacetic acid Chemical compound CCOC1=CC(C(O)C(O)=O)=CC=C1O YOIZTLBZAMFVPK-UHFFFAOYSA-N 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- 239000003822 epoxy resin Substances 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 8
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 7
- 239000004743 Polypropylene Substances 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000004745 nonwoven fabric Substances 0.000 claims description 7
- 229920001155 polypropylene Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 229920005989 resin Polymers 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000012043 crude product Substances 0.000 claims description 6
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 6
- 239000010445 mica Substances 0.000 claims description 6
- 229910052618 mica group Inorganic materials 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 3
- 238000007650 screen-printing Methods 0.000 claims description 3
- 239000002966 varnish Substances 0.000 claims description 3
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229940106691 bisphenol a Drugs 0.000 claims 1
- 230000001680 brushing effect Effects 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 229920002678 cellulose Polymers 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 238000000643 oven drying Methods 0.000 claims 1
- 150000002924 oxiranes Chemical class 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 8
- 238000007603 infrared drying Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 150000004672 propanoic acids Chemical class 0.000 description 6
- 238000005034 decoration Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004599 antimicrobial Substances 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 108700025474 F 372 Proteins 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/12—Stencil printing; Silk-screen printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/22—Metallic printing; Printing with powdered inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/072—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements
- E04F13/075—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of specially adapted, structured or shaped covering or lining elements for insulation or surface protection, e.g. against noise or impact
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Architecture (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Pest Control & Pesticides (AREA)
- Paper (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of preparation method of the water-based crackle wallpaper of protection against the tide, including substrate layer is chosen, and form the figuratum printing layer of tool on substrate layer by typography, wallpaper semi-finished product are made；Jinsha layer is printed by cylinder overprinting process in the front of wallpaper semi-finished product；Coat antibiotic layer, damp-proof layer and dryness glue-line successively at the back side of wallpaper semi-finished product；Drying in oven is placed in after being completed for printing；By on the wallpaper semi-finished product of water-based crack slurry printing after the drying, Drying and cooling obtains crackle wallpaper under the conditions of 100 DEG C ~ 120 DEG C.The present invention can play good antibacterial effect, while by being optimized to the formula of damp-proof layer, reached more excellent moisture effect by adhering to antibiotic layer in wallpaper；And by the printing of water paste, there is more preferable attractive, decorative sense.
Description
Technical field
The present invention relates to adornment technical field, and in particular to a kind of preparation method of the water-based crackle wallpaper of protection against the tide.
Background technology
Wallpaper, also referred to as wallpaper, wall paper, it is a kind of indoor hardware fitting for being used to paper metope, is widely used in house, does
Public room, the interior decoration etc. of hotel.Material is not limited to paper, also comprising other materials.
Because with color is various, pattern is abundant, luxurious style, safety and environmental protection, easy for construction, affordable etc. it is a variety of its
The characteristics of its house decorative material institute is incomparable, therefore obtained in developed countries and regions such as America and Europe, Japan considerable degree of general
And.
Wallpaper is divided into many classes, such as overlay film wallpaper, coating wallpaper, embossing wallpaper.Generally produced with bleached wood pulp
Modeling is covered on body paper, then the working process through different processes, such as coating, printing, embossing or surface, is dispatched from the factory after last cut, packaging.
With certain intensity, toughness, appearance attractive in appearance and good water repelling property.
Wallpaper is the important component of Modern Interior Decoration material, be indoor wall surface primary decoration finishing material it
One, because wallpaper has good decorative effect, so obtaining more and more extensive application.With the continuous social and economic development
With the continuous improvement of people's level of production, hotel and house emerge in multitude, and fitting-up of the people to interior requires more and more higher,
More focus on the decorative effect of surface of wall.At present, increasing people is directed to the research of wallpaper, but research stays in mostly
In terms of the decorative effect of wallpaper, such as change pattern etc., more focus on surface.And more application is building to wallpaper
After interior decoration, indoor very big area is occupied, if it there can be some functions, such as antibacterial functions, then can be played good
The effect of.And the wallpaper of prior art does not possess antibacterial functions.Prior art more focuses on the fancy design on surface, color
Collocation and entirety decorative effect, the feature of wallpaper is focused on few, especially the antibiotic property to wallpaper, health should
With functional study deficiency, it is impossible to meet requirement of the consumers in general to the wallpaper with antibacterial functions.In order to adapt to special space
The place that the needs of environment, such as hospital, school be crowded and bacterium is easily propagated, the wallpaper as decorative material for internal wall should
Function with antibacterial.Therefore, highly desirable a kind of antibacterial wallpaper of people and preparation method thereof comes out.
The use environment of wallpaper suffers from the limitation of its performance, particularly in the larger place of ambient humidity, to wallpaper
Humidity resistance also have larger requirement, otherwise the service life of wallpaper will substantially reduce.
The content of the invention
It is an object of the invention to provide a kind of preparation method moistureproof and with water-based crackle wallpaper with good antibacterial.
For the above-mentioned purpose, a kind of preparation side of the water-based crackle wallpaper of protection against the tide is provided in one embodiment of the present of invention
Method, comprise the following steps：
1) substrate layer, is chosen, and forms the figuratum printing layer of tool on substrate layer by typography, wallpaper half is made
Finished product；
2) Jinsha layer, is printed by cylinder overprinting process in the front of wallpaper semi-finished product；
3) antibiotic layer, damp-proof layer and dryness glue-line, are coated successively at the back side of wallpaper semi-finished product；Baking is placed in after being completed for printing
Dried in case；
4), water-based crack slurry is printed on wallpaper semi-finished product after the drying, dried under the conditions of 100 DEG C~120 DEG C
Cooling obtains crackle wallpaper；
The raw material components of wherein described antibiotic layer include：50 parts~100 parts of water lustering oil, 5 parts~10 parts of antiseptic；Institute
Stating the raw material components of damp-proof layer includes：50 parts~100 parts of EHMA, 20 parts~50 parts of bisphenol A type epoxy resin,
10 parts~30 parts of polyacrylic resin, 10 parts~30 parts of ethyl acetate, 0.1 part~1 part of antimony oxide, 0.1 part of aluminium hydroxide
~1 part, 1 part~5 parts of 2,2- dihydromethyl propionic acids, 1 part~5 parts of DBSA；
The raw material components of wherein described water-based crack slurry include：45 parts~60 parts of acrylic emulsion；20 parts of aqueous color paste
~30 parts；2 parts~5 parts of propane diols；10 parts~20 parts of deionized water；5 parts~10 parts of ethylenediamine；5 parts~10 parts of thickener.
Preferably, substrate layer is one kind in PVC coated papers, pure paper, non-woven paper, non-woven fabrics, gauze or gauze.
Preferably, substrate layer forms the typography of pattern and includes gravure, convex print, screen printing, ink-jet, printing, brush, paint
Picture or anglicanum.
Preferably, the raw material of Jinsha layer includes
80 parts~150 parts of urethane acrylate, 20 parts~80 parts of filler, 5 parts~50 parts of golden pigment composition, varnish
1 part~5 parts, 0.2 part~5 parts of thickener, 3 parts~5 parts of film forming agent, 1 part~3 parts of ethanol, 1 part~5 parts of mica powder.
Preferably, the feedstock composition preparation method of Jinsha layer is：The raw material of formula ratio is taken, by urethane acrylate
Emulsion adds in agitator, then is ground the mixture of fill composition and emulsion with milling apparatus, and low whipping speed is
Under the conditions of 500~2000r/min, 20~30min of stirring makes it well mixed；Be gradually added again adhesive force auxiliary agent, thickener, into
Film, ethanol and mica powder, continue to be kept stirring for 10~20min, sealed after being sufficiently mixed.
Preferably, the method for preparing raw material of antibiotic layer is
Component by weight is weighed, water lustering oil is placed in homogenizer, in 500r/min~2000r/min
Rotating speed under add antiseptic stirring 10min~30min.
Preferably, the raw material amount of antibiotic layer is 15g/m2~100g/m2；The raw material amount of the damp-proof layer is
100g/m2~300g/m2；The coating thickness of the dryness glue-line is 2mm~5mm.
Preferably, it is attached with diaphragm outside Jinsha layer.
Preferably, antiseptic is Inorganic Ag System Antimicrobial Agents.
Preferably, water lustering oil is water-based matte gloss oil or transparent highlight water-based gloss oil.
Preferably, thickener is that nonionic hydrophobically modified ethoxylated urethanes copolymer or hydrophobic association ethoxy are fine
Dimension element.
Preferably, the preparation method of water-based crack slurry is：By acrylic emulsion be added in reactor stir 5min~
10min, control rotating speed 1000r/min~2000r/min continues to stir after putting into aqueous color paste, propane diols, deionized water, ethylenediamine
5min~10min is mixed, thickener is eventually adding and continues to stir 5min~10min acquisition crude products；Crude product is passed through into 150 mesh~250
Water-based crack slurry is obtained after mesh sieve.
In summary, the present invention has advantages below：
The present invention can play good antibacterial effect by adhering to antibiotic layer in wallpaper, while by damp-proof layer
Formula optimize, reached more excellent moisture effect；And by the printing of water paste, there is more preferable attractive, decorative
Sense.
Embodiment
The preparation of raw material
1st, the preparation of antibiotic layer raw material：
Method one：
A, component：60 parts of water-based matte gloss oil, 6 parts of Inorganic Ag System Antimicrobial Agents；
B, preparation method：Component by weight is weighed, water lustering oil is placed in homogenizer, in 1000r/
Antiseptic stirring 15min is added under min rotating speed；Obtain the antimicrobial mix for forming antibiotic layer.
Method two：
A, component：Transparent 80 parts of highlight water-based gloss oil, 5 parts of Inorganic Ag System Antimicrobial Agents；
B, preparation method：Component by weight is weighed, water lustering oil is placed in homogenizer, in 2000r/
Antiseptic stirring 20min is added under min rotating speed；Obtain the antimicrobial mix for forming antibiotic layer.
2nd, the preparation of Jinsha layer raw material：
A, component：
80 parts~150 parts of urethane acrylate, 20 parts~80 parts of filler, 5 parts~50 parts of golden pigment composition, varnish
1 part~5 parts, 0.2 part~5 parts of thickener, 3 parts~5 parts of film forming agent, 1 part~3 parts of ethanol, 1 part~5 parts of mica powder.
B, preparation method：The raw material of formula ratio is taken, the emulsion of urethane acrylate is added in agitator, then with grinding
The mixture of fill composition and emulsion is ground by equipment, under the conditions of low whipping speed is 500~2000r/min, stirring
20~30min makes it well mixed；Adhesive force auxiliary agent, thickener, film forming agent, ethanol and mica powder are gradually added again, continue to protect
10~20min of stirring is held, is sealed after being sufficiently mixed.
3rd, the preparation of water paste：
Raw material components
50 parts of acrylic emulsion；22 parts of aqueous color paste；
2 parts of propane diols；12 parts of deionized water；6 parts of ethylenediamine；
5 parts of nonionic hydrophobically modified ethoxylated urethanes copolymer.
Wherein propane diols and ethylenediamine as the stabilizer of water paste, be able to can improve the stability of water paste with
And the uniformity.
Acrylic emulsion is added in reactor and stirs 8min, input aqueous color paste, propane diols, deionized water, second two
Control rotating speed 1500r/min to continue to stir 5min after amine, be eventually adding thickener and continue to stir 5min acquisition crude products；Crude product is led to
Water-based crack slurry is obtained after crossing 200 mesh sieves.
Embodiment 1
1) non-woven fabrics, is chosen as substrate layer, and tool is formed on substrate layer by the typography of convex print or gravure
Figuratum printing layer, wallpaper semi-finished product are made.
2) Jinsha layer, is printed by cylinder overprinting process in the front of wallpaper semi-finished product；Cylinder overprinting process parameter is specific
For：Print speed printing speed is 50m/min；Oven temperature forms adhesion effects first to be dried with 130 DEG C, then with 190 DEG C of film forming；On cylinder
Formed with hexagonal loop, the percent opening of hexagonal loop is 40%；The thickness of net of finished product cylinder is 0.3mm；After printing Jinsha layer,
Layer protecting film is laid outside Jinsha layer.
3) antibiotic layer, damp-proof layer and dryness glue-line, are coated successively at the back side of wallpaper semi-finished product；The raw material of antibiotic layer
Measure as 20g/m2；The raw material amount of damp-proof layer is 120g/m2；The coating thickness of dryness glue-line is 3mm.It is placed in after being completed for printing
Drying in oven；Or pass through infrared drying.
4), water-based crack slurry is printed on wallpaper semi-finished product after the drying, after Drying and cooling under the conditions of 100 DEG C
To crackle wallpaper.
The raw material components of antibiotic layer include：80 parts of water lustering oil, 9 parts of antiseptic；
The raw material components of damp-proof layer include：70 parts of EHMA, 20 parts of bisphenol A type epoxy resin, polypropylene
12 parts of acid resin, 10 parts of ethyl acetate, 0.4 part of antimony oxide, 0.2 part of aluminium hydroxide, 2 parts of 2,2- dihydromethyl propionic acids, ten
1 part of dialkyl benzene sulfonic acids.
The raw material components of water paste are
50 parts of acrylic emulsion；22 parts of aqueous color paste；
2 parts of propane diols；12 parts of deionized water；6 parts of ethylenediamine；
5 parts of nonionic hydrophobically modified ethoxylated urethanes copolymer.
Embodiment 2
1), choose pure paper as substrate layer, and formed on substrate layer by the typography of screen printing have it is figuratum
Printing layer, wallpaper semi-finished product are made.
2) Jinsha layer, is printed by cylinder overprinting process in the front of wallpaper semi-finished product；Cylinder overprinting process parameter is specific
For：Print speed printing speed is 50/min；Oven temperature forms adhesion effects first to be dried with 150 DEG C, then with 200 DEG C of film forming；On cylinder
Formed with hexagonal loop, the percent opening of hexagonal loop is 40%；The thickness of net of finished product cylinder is 0.3mm；After printing Jinsha layer,
Layer protecting film is laid outside Jinsha layer.
3) antibiotic layer, damp-proof layer and dryness glue-line, are coated successively at the back side of wallpaper semi-finished product；The raw material of antibiotic layer
Measure as 50g/m2；The raw material amount of damp-proof layer is 200g/m2；The coating thickness of dryness glue-line is 4mm.It is placed in after being completed for printing
Drying in oven；Or pass through infrared drying.
4), water-based crack slurry is printed on wallpaper semi-finished product after the drying, after Drying and cooling under the conditions of 100 DEG C
To crackle wallpaper.
The raw material components of antibiotic layer include：80 parts of water lustering oil, 9 parts of antiseptic；
The raw material components of damp-proof layer include：70 parts of EHMA, 20 parts of bisphenol A type epoxy resin, polypropylene
12 parts of acid resin, 10 parts of ethyl acetate, 0.4 part of antimony oxide, 0.2 part of aluminium hydroxide, 2 parts of 2,2- dihydromethyl propionic acids, ten
1 part of dialkyl benzene sulfonic acids.
Influence of the damp-proof layer raw material components to moisture effect
Embodiment 3
1) non-woven fabrics, is chosen as substrate layer, and tool is formed on substrate layer by the typography of convex print or gravure
Figuratum printing layer, wallpaper semi-finished product are made.
2) Jinsha layer, is printed by cylinder overprinting process in the front of wallpaper semi-finished product；Cylinder overprinting process parameter is specific
For：Print speed printing speed is 50m/min；Oven temperature forms adhesion effects first to be dried with 130 DEG C, then with 190 DEG C of film forming；On cylinder
Formed with hexagonal loop, the percent opening of hexagonal loop is 40%；The thickness of net of finished product cylinder is 0.3mm；After printing Jinsha layer,
Layer protecting film is laid outside Jinsha layer.
3) antibiotic layer, damp-proof layer and dryness glue-line, are coated successively at the back side of wallpaper semi-finished product；The raw material of antibiotic layer
Measure as 20g/m2；The raw material amount of damp-proof layer is 120g/m2；The coating thickness of dryness glue-line is 3mm.It is placed in after being completed for printing
Drying in oven；Or pass through infrared drying.
4), water-based crack slurry is printed on wallpaper semi-finished product after the drying, after Drying and cooling under the conditions of 105 DEG C
To crackle wallpaper.
The raw material components of antibiotic layer include：80 parts of water lustering oil, 9 parts of antiseptic；
The raw material components of damp-proof layer include：70 parts of EHMA, 20 parts of bisphenol A type epoxy resin, polypropylene
12 parts of acid resin, 10 parts of ethyl acetate, 0.4 part of antimony oxide, 2 parts of 2,2- dihydromethyl propionic acids, DBSA 1
Part.
Embodiment 4
1) non-woven fabrics, is chosen as substrate layer, and tool is formed on substrate layer by the typography of convex print or gravure
Figuratum printing layer, wallpaper semi-finished product are made.
2) Jinsha layer, is printed by cylinder overprinting process in the front of wallpaper semi-finished product；Cylinder overprinting process parameter is specific
For：Print speed printing speed is 50m/min；Oven temperature forms adhesion effects first to be dried with 130 DEG C, then with 190 DEG C of film forming；On cylinder
Formed with hexagonal loop, the percent opening of hexagonal loop is 40%；The thickness of net of finished product cylinder is 0.3mm；After printing Jinsha layer,
Layer protecting film is laid outside Jinsha layer.
3) antibiotic layer, damp-proof layer and dryness glue-line, are coated successively at the back side of wallpaper semi-finished product；The raw material of antibiotic layer
Measure as 20g/m2；The raw material amount of damp-proof layer is 120g/m2；The coating thickness of dryness glue-line is 3mm.It is placed in after being completed for printing
Drying in oven；Or pass through infrared drying.
4), water-based crack slurry is printed on wallpaper semi-finished product after the drying, after Drying and cooling under the conditions of 110 DEG C
To crackle wallpaper.
The raw material components of antibiotic layer include：80 parts of water lustering oil, 9 parts of antiseptic；
The raw material components of damp-proof layer include：70 parts of EHMA, 20 parts of bisphenol A type epoxy resin, polypropylene
12 parts of acid resin, 10 parts of ethyl acetate, 0.4 part of antimony oxide, 0.2 part of aluminium hydroxide, 1 part of DBSA.
Embodiment 5
1) non-woven fabrics, is chosen as substrate layer, and tool is formed on substrate layer by the typography of convex print or gravure
Figuratum printing layer, wallpaper semi-finished product are made.
2) Jinsha layer, is printed by cylinder overprinting process in the front of wallpaper semi-finished product；Cylinder overprinting process parameter is specific
For：Print speed printing speed is 50m/min；Oven temperature forms adhesion effects first to be dried with 130 DEG C, then with 190 DEG C of film forming；On cylinder
Formed with hexagonal loop, the percent opening of hexagonal loop is 40%；The thickness of net of finished product cylinder is 0.3mm；After printing Jinsha layer,
Layer protecting film is laid outside Jinsha layer.
3) antibiotic layer, damp-proof layer and dryness glue-line, are coated successively at the back side of wallpaper semi-finished product；The raw material of antibiotic layer
Measure as 20g/m2；The raw material amount of damp-proof layer is 120g/m2；The coating thickness of dryness glue-line is 3mm.It is placed in after being completed for printing
Drying in oven；Or pass through infrared drying.
4), water-based crack slurry is printed on wallpaper semi-finished product after the drying, after Drying and cooling under the conditions of 100 DEG C
To crackle wallpaper.
The raw material components of antibiotic layer include：80 parts of water lustering oil, 9 parts of antiseptic；
The raw material components of damp-proof layer include：70 parts of EHMA, 20 parts of bisphenol A type epoxy resin, polypropylene
12 parts of acid resin, 10 parts of ethyl acetate, 0.4 part of antimony oxide, 0.2 part of aluminium hydroxide, 2 parts of 2,2- dihydromethyl propionic acids.
Embodiment 6
1) non-woven fabrics, is chosen as substrate layer, and tool is formed on substrate layer by the typography of convex print or gravure
Figuratum printing layer, wallpaper semi-finished product are made.
2) Jinsha layer, is printed by cylinder overprinting process in the front of wallpaper semi-finished product；Cylinder overprinting process parameter is specific
For：Print speed printing speed is 50m/min；Oven temperature forms adhesion effects first to be dried with 130 DEG C, then with 190 DEG C of film forming；On cylinder
Formed with hexagonal loop, the percent opening of hexagonal loop is 40%；The thickness of net of finished product cylinder is 0.3mm；After printing Jinsha layer,
Layer protecting film is laid outside Jinsha layer.
3) antibiotic layer, damp-proof layer and dryness glue-line, are coated successively at the back side of wallpaper semi-finished product；The raw material of antibiotic layer
Measure as 20g/m2；The raw material amount of damp-proof layer is 120g/m2；The coating thickness of dryness glue-line is 3mm.It is placed in after being completed for printing
Drying in oven；Or pass through infrared drying.
4), water-based crack slurry is printed on wallpaper semi-finished product after the drying, after Drying and cooling under the conditions of 100 DEG C
To crackle wallpaper.
The raw material components of antibiotic layer include：80 parts of water lustering oil, 9 parts of antiseptic；
The raw material components of damp-proof layer include：70 parts of EHMA, 20 parts of bisphenol A type epoxy resin, polypropylene
12 parts of acid resin, 10 parts of ethyl acetate, 0.4 part of antimony oxide.
Moisture-resistant test
The wallpaper that the methods described of embodiment 3~6 is produced carries out water vapour transit dose measure.
Testing standard：ASTM F372；2
Testing equipment：Automatic multiple-head moisture-inhibiting analyzer
Experimental enviroment：37 DEG C, RH=100%
Result of the test such as table 1：
Table 1：Moisture-vapor transmission (24h) in embodiment 3~6
| Embodiment | Moisture-vapor transmission |
| Embodiment 3 | 0.10g/m2 |
| Embodiment 4 | 0.17g/m2 |
| Embodiment 5 | 0.32g/m2 |
| Embodiment 6 | 0.35g/m2 |
By the comparing result of table 1 it is known that not adding antimony oxide, aluminium hydroxide and 2,2- dihydroxy in embodiment 6
Methylpropanoic acid, its moisture-vapor transmission are higher than embodiment 3~5, illustrate adding DBSA, aluminium hydroxide and 2,2-
The humidity resistance of wallpaper is had a certain upgrade after dihydromethyl propionic acid, wherein to add DBSA in embodiment 3
It is more notable with the lifting after 2,2- dihydromethyl propionic acids to humidity resistance, add the reality of aluminium hydroxide and DBSA
The wallpaper humidity resistance for applying the preparation of example 4 also has and had a distinct increment.In summary, the present invention is adding DBSA, hydrogen
Aluminum oxide and 2,2- dihydromethyl propionic acid can lift the humidity resistance of damp-proof layer, and then improve moisture effect.
Claims (8)
1. a kind of preparation method of the water-based crackle wallpaper of protection against the tide, comprises the following steps：
1）, choose substrate layer, and forms on substrate layer the figuratum printing layer of tool by typography, be made wallpaper partly into
Product；
2）, wallpaper semi-finished product front pass through cylinder overprinting process print Jinsha layer；
3）, coat antibiotic layer, damp-proof layer and dryness glue-line successively at the back side of wallpaper semi-finished product；It is placed in after being completed for printing in baking oven
Drying；
4）, by water-based crack slurry printing wallpaper semi-finished product after the drying, Drying and cooling obtains under the conditions of 100 DEG C ~ 120 DEG C
To crackle wallpaper；
The raw material components of wherein described antibiotic layer include：50 parts ~ 100 parts of water lustering oil, 5 parts ~ 10 parts of antiseptic；The protection against the tide
The raw material components of layer include：50 parts ~ 100 parts of EHMA, 20 parts ~ 50 parts of bisphenol-A type epoxy resin, polypropylene
10 parts ~ 30 parts of acid resin, 10 parts ~ 30 parts of ethyl acetate, 0.1 part ~ 1 part of antimony oxide, 0.1 part ~ 1 part of aluminium hydroxide, 2,2-
1 part ~ 5 parts of dihydromethyl propionic acid, 1 part ~ 5 parts of DBSA；
The raw material components of wherein described water-based crack slurry include：45 parts ~ 60 parts of acrylic emulsion；20 parts ~ 30 parts of aqueous color paste；
2 parts ~ 5 parts of propane diols；10 parts ~ 20 parts of deionized water；5 parts ~ 10 parts of ethylenediamine；5 parts ~ 10 parts of thickener；
The raw material of the Jinsha layer includes
80 parts ~ 150 parts of urethane acrylate, 20 parts ~ 80 parts of filler, 5 parts ~ 50 parts of golden pigment composition, varnish 1 part ~ 5
Part, 0.2 part ~ 5 parts of thickener, 3 parts ~ 5 parts of film forming agent, 1 part ~ 3 parts of ethanol, 1 part ~ 5 parts of mica powder；The raw material group of the Jinsha layer
Compound preparation method is：The raw material of formula ratio is taken, the emulsion of urethane acrylate is added in agitator, then use milling apparatus
The mixture of fill composition and emulsion is ground, under the conditions of low whipping speed is 500 ~ 2000r/min, stirring 20 ~
30min makes it well mixed；Adhesive force auxiliary agent, thickener, film forming agent, ethanol and mica powder are gradually added again, are continued holding and are stirred
10 ~ 20min is mixed, is sealed after being sufficiently mixed.
2. preparation method as claimed in claim 1, it is characterised in that：The substrate layer be PVC coated papers, pure paper, non-woven paper,
One kind in non-woven fabrics, gauze or gauze.
3. preparation method as claimed in claim 1, it is characterised in that：The substrate layer forms the typography of pattern including recessed
Print, convex print, screen printing, ink-jet, printing, brushing, drawing or anglicanum.
4. preparation method as claimed in claim 1, it is characterised in that：The preparation method of the antibiotic layer raw material is：
Component by weight is weighed, water lustering oil is placed in homogenizer, in turning for the r/min of 500r/min ~ 2000
Speed is lower to add antiseptic stirring 10min ~ 30min.
5. preparation method as claimed in claim 1, it is characterised in that：The raw material amount of the antibiotic layer is 15 g/m2~100
g/m2；The raw material amount of the damp-proof layer is 100 g/m2~300 g/m2；The coating thickness of the dryness glue-line be 2mm ~
5mm。
6. preparation method as claimed in claim 1, it is characterised in that：Diaphragm is attached with outside the Jinsha layer.
7. preparation method as claimed in claim 1, it is characterised in that：The thickener is nonionic hydrophobically modified oxirane
Polyurethane copolymer or process of hydrophobic associated ethoxyl cellulose.
8. preparation method as claimed in claim 1, it is characterised in that：The preparation method of the water-based crack slurry is：By third
Olefin(e) acid emulsion is added to stirring 5min ~ 10min in reactor, is controlled after input aqueous color paste, propane diols, deionized water, ethylenediamine
Rotating speed 1000r/min ~ 2000r/min processed continues to stir 5min ~ 10min, is eventually adding thickener and continues to stir 5min ~ 10min
Obtain crude product；By crude product by obtaining water-based crack slurry after the mesh sieve of 150 mesh ~ 250.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510732262.1A CN105297552B (en) | 2015-11-02 | 2015-11-02 | A kind of preparation method of the water-based crackle wallpaper of protection against the tide |
| CN201710954796.8A CN107724176A (en) | 2015-11-02 | 2015-11-02 | A kind of moistureproof water-based crackle wallpaper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510732262.1A CN105297552B (en) | 2015-11-02 | 2015-11-02 | A kind of preparation method of the water-based crackle wallpaper of protection against the tide |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710954796.8A Division CN107724176A (en) | 2015-11-02 | 2015-11-02 | A kind of moistureproof water-based crackle wallpaper |
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| CN105297552B true CN105297552B (en) | 2017-11-14 |
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| CN201510732262.1A Expired - Fee Related CN105297552B (en) | 2015-11-02 | 2015-11-02 | A kind of preparation method of the water-based crackle wallpaper of protection against the tide |
| CN201710954796.8A Pending CN107724176A (en) | 2015-11-02 | 2015-11-02 | A kind of moistureproof water-based crackle wallpaper |
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| CN201710954796.8A Pending CN107724176A (en) | 2015-11-02 | 2015-11-02 | A kind of moistureproof water-based crackle wallpaper |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105803851A (en) * | 2016-03-31 | 2016-07-27 | 自贡市华尔美科技有限公司 | Environment-friendly inflaming retardant wallpaper |
| CN106703311A (en) * | 2016-12-22 | 2017-05-24 | 安徽易有墙纸有限公司 | Heat-resisting waterproof wallpaper and production method thereof |
| CN106835854A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of fire-proof and water-proof wallpaper and preparation method thereof |
| CN106835855A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of corrosion-resistant waterproof wallpaper and preparation method thereof |
| CN106758512A (en) * | 2016-12-22 | 2017-05-31 | 安徽易有墙纸有限公司 | A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof |
| CN108638679A (en) * | 2018-03-12 | 2018-10-12 | 浙江慕容时尚家居有限公司 | A kind of processing technology of nonwoven wallpaper digit printing |
| CN108221495A (en) * | 2018-03-13 | 2018-06-29 | 昆山市聚光装饰材料有限公司 | The preparation method of moisture-proof grains of sand wallpaper |
| CN108544865A (en) * | 2018-03-16 | 2018-09-18 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of signature card printing technology |
| CN108621620A (en) * | 2018-03-16 | 2018-10-09 | 佛山市高明金盾恒业电脑特种印刷有限公司 | A kind of bankbook printing technology |
| CN108517722A (en) * | 2018-05-07 | 2018-09-11 | 合肥市晨雷思建筑材料科技有限公司 | A kind of novel anticracking wallpaper and preparation method thereof |
| CN112323541A (en) * | 2020-08-20 | 2021-02-05 | 安徽紫荆花墙饰材料股份有限公司 | Production method of antibacterial and antibacterial wallpaper |
| CN115821602A (en) * | 2022-12-14 | 2023-03-21 | 上海慕缇家新材料科技有限公司 | Preparation method of painting-free formaldehyde-removing, mildew-proof, antibacterial, stain-resistant and flame-retardant art paint |
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| CN105297552A (en) | 2016-02-03 |
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