CN108085997A - A kind of weather-proof antifouling wallpaper and preparation method thereof - Google Patents
A kind of weather-proof antifouling wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN108085997A CN108085997A CN201711265048.5A CN201711265048A CN108085997A CN 108085997 A CN108085997 A CN 108085997A CN 201711265048 A CN201711265048 A CN 201711265048A CN 108085997 A CN108085997 A CN 108085997A
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- Prior art keywords
- pvdf
- pvc
- preparation
- weather
- wallpaper
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0011—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using non-woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
- D06N3/065—PVC together with other resins except polyurethanes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
- D21H23/50—Spraying or projecting
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1692—Weather resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/06—Building materials
- D06N2211/063—Wall coverings
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention belongs to building material technical fields, and in particular to weather-proof antifouling wallpaper and preparation method thereof.The PVDF coatings that the weather-proof antifouling wall paper includes non-woven fabrics base material, is covered in the PVC/PVDF composite layers of substrate surface and is sprayed on composite layer.The preparation method is prepared including PVC/PVDF composite materials, on base material prepared by film and PVDF coatings.Weather-proof antifouling wallpaper provided by the invention passes through surface PVDF coatings, not only solve the automatically cleaning problem of wallpaper, and greatly improve the weatherability of wallpaper, it can ensure that long-time service is non-discolouring, it insures a like-new appearance indefinitely, further using PVC and PVDF composite materials, be conducive to the attachment of PVDF coatings and the improvement of itself weatherability.
Description
Technical field
The invention belongs to building material technical fields, and in particular to weather-proof antifouling wallpaper and preparation method thereof.
Background technology
Wallpaper also known as wallpaper, because it is various with color, pattern enriches, safety and environmental protection, easy construction, and affordable etc. is excellent
Gesture is widely used in house ornamentation, and common wallpaper is generally using materials such as pure paper, non-woven fabrics as base material, in its surface coated with resins slurry
Material, be plasticized through high temperature, print be embossed etc. processes be made.
Most common coating paste is mainly made of polyvinyl chloride resin and filler currently on the market, although this coating material
Have many advantages, such as attractive and durable, but its weatherability is poor, is irradiated by natural light and heat, will soon stale, largely effecting on makes
Aesthetics, it is therefore desirable to frequent replacement, it is inconvenient；And its resistance to soiling is poor, easily contaminated, again can not after pollution
It is cleaned by simple wiping, for the above reasons, the use of wallpaper receives very big limitation.
The content of the invention
It is easy to change to solve current wallpaper the present invention provides a kind of weather-proof antifouling wallpaper and preparation method thereof, it is easily dirty
Dye, the problem of being not easy to clean.
In order to solve the above-mentioned technical problem, the technical scheme is that：The weather-proof antifouling wallpaper, including nonwoven fabric base
Material, PVC (polyvinyl chloride)/PVDF (Kynoar) composite layers for being covered in substrate surface and it is sprayed on composite layer
On PVDF coatings.
Optionally, the thickness of the PVDF coatings is 1 micron.
The present invention also provides the preparation methods of above-mentioned weather-proof antifouling wallpaper, specifically comprise the following steps：
1) prepared by PVC/PVDF composite materials：The raw material of PVC/PVDF composite materials is mixed, heating water bath stirring is prepared
Obtain PVC/PVDF composite material solution；
2) film on base material：The PVC/PVDF composite materials solution of step 1) configuration is coated in the non-woven fabrics base material table
Face is simultaneously dried, and forms PVC/PVDF composite layers；
3) prepared by PVDF coatings：PVDF coating is configured, the PVDF coating is sprayed to the PVC/PVDF of step 2) formation
On composite layer.
Optionally, the raw material of the PVC/PVDF composite materials is made of following composition by weight：
6-8 parts of PVDF
4-6 parts of PVC
100 parts of solution.
Optionally, the solution is dimethylformamide and the mixed solution of acetone, and the volume ratio of the two is 7:3.
Optionally, the PVDF coating includes PVDF resins, polysiloxanes compound, acrylic resin, non-ionic table
Face activating agent, perfluorovinylether copolymer and solvent.
Optionally, the PVDF coating each component is as follows by weight ratio：
Optionally, the polysiloxanes compound is made of polysiloxanes, silicate and solvent, and the weight ratio of three is 1:
(6-10):(0.8-1.5)。
Optionally, the solvent is butanone or isophorone.
Optionally, the step 1) bath temperature is 80 DEG C, and the step 2) drying temperature is 120 DEG C.
Weather-proof antifouling wallpaper provided by the invention not only solves the automatically cleaning problem of wallpaper by surface PVDF coatings,
And greatly improve the weatherability of wallpaper, it is ensured that long-time service is non-discolouring, insures a like-new appearance indefinitely, further using PVC and
PVDF composite materials are conducive to the attachment of PVDF coatings and the improvement of itself weatherability.
Specific embodiment
In order to make it easy to understand, the weather-proof antifouling wallpaper illustrated with reference to embodiment, it should be appreciated that these embodiments are only used for
Illustrate the present invention rather than limit the scope of the invention.
Agents useful for same or raw material of the present invention are commercial goods when not specified.
Embodiment 1
The preparation method of the weather-proof antifouling wallpaper, it is specific as follows：
1) prepared by PVC/PVDF composite materials：The raw material of PVC/PVDF composite materials is mixed, 80 DEG C of heating stirrings of water-bath,
It prepares and obtains PVC/PVDF composite material solution；
2) film on base material：The PVC/PVDF composite materials solution of step 1) configuration is coated in the non-woven fabrics base material table
Face is simultaneously dried at 120 DEG C, forms PVC/PVDF composite layers；
3) prepared by PVDF coatings：PVDF coating is configured, the PVDF coating is sprayed to the PVC/PVDF of step 2) formation
On composite layer, cure
The raw material of the PVC/PVDF composite materials is made of following composition by weight：
6 parts of PVDF
6 parts of PVC
100 parts of solution.
Wherein described solution is dimethylformamide and the mixed solution of acetone, and the volume ratio of the two is 7:3.
The PVDF coating each component is as follows by weight ratio：
The polysiloxanes compound is made of polysiloxanes, silicate and butanone, and the weight ratio of three is 1:6:1.5.
The weather-proof antifouling wallpaper is prepared, it is compound including non-woven fabrics base material, the PVC/PVDF for being covered in substrate surface
Material layer and the PVDF coatings being sprayed on composite layer, the thickness of the PVDF coatings is 1 micron.
Embodiment 2
The preparation method of the weather-proof antifouling wallpaper, it is specific as follows：
4) prepared by PVC/PVDF composite materials：The raw material of PVC/PVDF composite materials is mixed, 80 DEG C of heating stirrings of water-bath,
It prepares and obtains PVC/PVDF composite material solution；
5) film on base material：The PVC/PVDF composite materials solution of step 1) configuration is coated in the non-woven fabrics base material table
Face is simultaneously dried at 120 DEG C, forms PVC/PVDF composite layers；
6) prepared by PVDF coatings：PVDF coating is configured, the PVDF coating is sprayed to the PVC/PVDF of step 2) formation
On composite layer, cure
The raw material of the PVC/PVDF composite materials is made of following composition by weight：
8 parts of PVDF
4 parts of PVC
100 parts of solution.
Wherein described solution is dimethylformamide and the mixed solution of acetone, and the volume ratio of the two is 7:3.
The PVDF coating each component is as follows by weight ratio：
The polysiloxanes compound is made of polysiloxanes, silicate and butanone, and the weight ratio of three is 1:10:0.8.
The weather-proof antifouling wallpaper is prepared, it is compound including non-woven fabrics base material, the PVC/PVDF for being covered in substrate surface
Material layer and the PVDF coatings being sprayed on composite layer, the thickness of the PVDF coatings is 1 micron.
3 contrast test of embodiment
The PVC wallpaper of comparative example non-woven fabrics base material purchased in market, wherein
It is as shown in table 1 to carry out water contact angle, pollution resistance, color inhibition and double 85 senile experiments, experimental data：
Table 1
Above-mentioned experimental data explanation, technical solution provided by the invention compared with prior art, self-cleaning, cleaning,
Color inhibition and anti-aging aspect are with the obvious advantage.
Finally it should be noted that：The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations.Although
The present invention is described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that：It still may be used
Either which part or all technical characteristic are equal with modifying to the technical solution recorded in previous embodiment
It replaces, and these modifications or substitutions, the essence of appropriate technical solution is not made to depart from the model of various embodiments of the present invention technical solution
It encloses.
Claims (10)
1. a kind of weather-proof antifouling wallpaper, which is characterized in that compound including non-woven fabrics base material, the PVC/PVDF for being covered in substrate surface
Material layer and the PVDF coatings being sprayed on composite layer.
2. weather-proof antifouling wallpaper according to claim 1, which is characterized in that the thickness of the PVDF coatings is 1 micron.
3. the preparation method of the weather-proof antifouling wallpaper of claim 1 or 2, which is characterized in that include the following steps：
1) prepared by PVC/PVDF composite materials：The raw material of PVC/PVDF composite materials is mixed, heating water bath stirring is prepared and obtained
PVC/PVDF composite material solution；
2) film on base material：By the PVC/PVDF composite materials solution of step 1) configuration coated in the non-woven fabrics base material surface simultaneously
Drying forms PVC/PVDF composite layers；
3) prepared by PVDF coatings：PVDF coating is configured, the PVC/PVDF that the PVDF coating is sprayed to step 2) formation is compound
In material layer.
4. preparation method according to claim 3, which is characterized in that the raw material of the PVC/PVDF composite materials by weighing as follows
Measure component composition：
6-8 parts of PVDF
4-6 parts of PVC
100 parts of solution.
5. preparation method according to claim 4, which is characterized in that the solution is the mixing of dimethylformamide and acetone
Solution, the volume ratio of the two is 7:3.
6. preparation method according to claim 3, which is characterized in that the PVDF coating includes PVDF resins, polysiloxanes
Compound, acrylic resin, nonionic surface active agent, perfluorovinylether copolymer and solvent.
7. preparation method according to claim 6, which is characterized in that the PVDF coating each component is by weight ratio such as
Under：
8. preparation method according to claim 7, which is characterized in that the polysiloxanes compound is by polysiloxanes, silicic acid
Salt and solvent composition, the weight ratio of three is 1:(6-10):(0.8-1.5).
9. according to the preparation method of claim 7 or 8, which is characterized in that the solvent is butanone or isophorone.
10. preparation method according to claim 3, which is characterized in that the step 1) bath temperature is 80 DEG C, the step
2) drying temperature is 120 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711265048.5A CN108085997A (en) | 2017-12-05 | 2017-12-05 | A kind of weather-proof antifouling wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711265048.5A CN108085997A (en) | 2017-12-05 | 2017-12-05 | A kind of weather-proof antifouling wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108085997A true CN108085997A (en) | 2018-05-29 |
Family
ID=62173676
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711265048.5A Pending CN108085997A (en) | 2017-12-05 | 2017-12-05 | A kind of weather-proof antifouling wallpaper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108085997A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108796815A (en) * | 2018-06-22 | 2018-11-13 | 合肥洁诺医疗用品有限公司 | A kind of non-woven fabrics for wall cloth |
| CN115891350A (en) * | 2022-11-30 | 2023-04-04 | 湖南华大戴纳智造科技有限公司 | Inflatable PVC membrane exhaust pipe |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59125980A (en) * | 1983-01-07 | 1984-07-20 | 呉羽化学工業株式会社 | Creped wall paper |
| CN105400285A (en) * | 2015-12-29 | 2016-03-16 | 广东天龙油墨集团股份有限公司 | High-weatherability water-borne printing ink for PVC wallpaper and preparation method thereof |
| CN105482720A (en) * | 2015-12-23 | 2016-04-13 | 青岛宏宇环保空调设备有限公司 | Waterproof wallpaper adhesive |
| CN106592895A (en) * | 2016-11-24 | 2017-04-26 | 浙江歌瑞新材料有限公司 | Weather-proof adhesive sticker type polyvinyl chloride wallpaper |
| CN106677453A (en) * | 2016-11-24 | 2017-05-17 | 浙江歌瑞新材料有限公司 | Weather-proof polyvinyl chloride wallpaper and preparation process thereof |
| CN106758512A (en) * | 2016-12-22 | 2017-05-31 | 安徽易有墙纸有限公司 | A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof |
-
2017
- 2017-12-05 CN CN201711265048.5A patent/CN108085997A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59125980A (en) * | 1983-01-07 | 1984-07-20 | 呉羽化学工業株式会社 | Creped wall paper |
| CN105482720A (en) * | 2015-12-23 | 2016-04-13 | 青岛宏宇环保空调设备有限公司 | Waterproof wallpaper adhesive |
| CN105400285A (en) * | 2015-12-29 | 2016-03-16 | 广东天龙油墨集团股份有限公司 | High-weatherability water-borne printing ink for PVC wallpaper and preparation method thereof |
| CN106592895A (en) * | 2016-11-24 | 2017-04-26 | 浙江歌瑞新材料有限公司 | Weather-proof adhesive sticker type polyvinyl chloride wallpaper |
| CN106677453A (en) * | 2016-11-24 | 2017-05-17 | 浙江歌瑞新材料有限公司 | Weather-proof polyvinyl chloride wallpaper and preparation process thereof |
| CN106758512A (en) * | 2016-12-22 | 2017-05-31 | 安徽易有墙纸有限公司 | A kind of use for laboratory acid and alkali-resistance wallpaper and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108796815A (en) * | 2018-06-22 | 2018-11-13 | 合肥洁诺医疗用品有限公司 | A kind of non-woven fabrics for wall cloth |
| CN115891350A (en) * | 2022-11-30 | 2023-04-04 | 湖南华大戴纳智造科技有限公司 | Inflatable PVC membrane exhaust pipe |
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Application publication date: 20180529 |
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