CN108796815A - A kind of non-woven fabrics for wall cloth - Google Patents
A kind of non-woven fabrics for wall cloth Download PDFInfo
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- CN108796815A CN108796815A CN201810650075.2A CN201810650075A CN108796815A CN 108796815 A CN108796815 A CN 108796815A CN 201810650075 A CN201810650075 A CN 201810650075A CN 108796815 A CN108796815 A CN 108796815A
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- talcum powder
- woven fabrics
- wall cloth
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/413—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties containing granules other than absorbent substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
Abstract
The invention discloses a kind of non-woven fabrics for wall cloth, raw material includes by weight：32-47 parts of Kynoar, 22-33 parts of acrylic resin, 6-14 parts of Wholly aromatic polyester, 15-21 parts of asbestos, 2.5-9 parts of anti-blushing agent, 2-6 parts of carboxymethyl cellulose, 1.5-4 parts of nano silver particles, 1.5-3.5 parts of terylene chemical fibre, 0.5-2.8 parts of nano-meter flame retardants.The present invention has excellent humidity resistance.
Description
Technical field
The present invention relates to non-woven fabrics, and in particular to a kind of non-woven fabrics for wall cloth.
Background technology
Since the base material of wall cloth skin-material is mostly natural materials, either jacquard weave wall cloth, yarn wall cloth or non-woven fabrics
Wall cloth, embossment wall cloth, by the surface of specially treated, quality is all relatively soft comfortable, and texture more naturally, color also more
Soft, great artistic effect is shown, a kind of feeling of warmth of people is given.Wall cloth not only has the environmental protection characteristic as wallpaper, but also
Update is also very easy, and with stronger sound-absorbing, sound insulation value, can also prevent fires, anti-mould and anti-moth, also unusual scrubbing resistance.
The humidity resistance of existing non-woven fabrics wall cloth is not high, cannot meet the needs of market.
Invention content
Technical problems based on background technology, the present invention propose a kind of non-woven fabrics for wall cloth.The present invention has
There is excellent humidity resistance.
A kind of non-woven fabrics for wall cloth proposed by the present invention, raw material include by weight：Kynoar 32-47
Part, 22-33 parts of acrylic resin, 6-14 parts of Wholly aromatic polyester, 15-21 parts of asbestos, 2.5-9 parts of anti-blushing agent, carboxymethyl cellulose
2-6 parts plain, 1.5-4 parts of nano silver particles, 1.5-3.5 parts of terylene chemical fibre, 0.5-2.8 parts of nano-meter flame retardants.
Preferably, the anti-blushing agent is prepared as follows：Polymethylacrylic acid is added into micron order talcum powder
Nano zirconium dioxide, heating is added in ethylene oxidic ester, temperature reaction, and insulation reaction obtains talcum powder-zirconia composite；
The starch of gelatinization is added into talcum powder-zirconia composite, is uniformly dispersed, it is dry, sieving is smashed, anti-blushing agent is obtained.
Preferably, the anti-blushing agent is prepared as follows：Polymethylacrylic acid is added into micron order talcum powder
Ethylene oxidic ester reacts 1-3h at 50-70 DEG C, and nano zirconium dioxide is added, is warming up to 80-95 DEG C, insulation reaction 1.5-2.5h,
Obtain talcum powder-zirconia composite；The starch of gelatinization is added into talcum powder-zirconia composite, is uniformly dispersed,
Dry 20-40min at 70-85 DEG C, smashed 300-400 mesh sieve, and obtained anti-blushing agent.
Preferably, the starch of the gelatinization is the starch being gelatinized at 80-90 DEG C.
Preferably, the weight ratio of the micron order talcum powder and nano zirconium dioxide is 1：1.5-2.4.
Preferably, the weight ratio of the talcum powder-zirconia composite and starch is 1：1.2-2.5.
Preferably, the granularity of the micron order talcum powder is 5-20um.
The present invention can be prepared conventionally.
The present invention raw material include：Kynoar, acrylic resin, Wholly aromatic polyester, asbestos, anti-blushing agent, carboxylic first
Base cellulose, nano silver particles, terylene chemical fibre, nano-meter flame retardants, in preferred embodiment, in the preparation process of anti-blushing agent, first
Poly (glycidyl methacrylate) is grafted on talcum powder in the micron-scale, then nano zirconium dioxide is fixed on and has been grafted poly- first
On the talcum powder particle of base glycidyl acrylate, the secondary structure of raspberry shape is formed, obtained talcum powder-zirconium dioxide is multiple
Closing object not only has excellent hydrophobic surface, and due to the presence of raspberry shape secondary structure, it is made to show that good machinery is steady
It is qualitative, under the influence of by the factors such as external force friction and oiliness pollution, its hydrophobic performance can be maintained, is had persistent anti-
Damp performance；Then talcum powder-zirconia composite is modified using gelatinized starch, stirring action keeps starch molecule uniform
Ground is dispersed between talcum powder-zirconia composite aggregation, dried to weaken talcum powder-zirconia composite
Particle buildup effect caused by journey ultimately improves point of the talcum powder-zirconia composite in resin and other components
Property is dissipated, the humidity resistance of the present invention is optimized.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
A kind of non-woven fabrics for wall cloth, raw material include by weight：32 parts of Kynoar, acrylic resin 33
Part, 6 parts of Wholly aromatic polyester, 21 parts of asbestos, 2.5 parts of anti-blushing agent, 6 parts of carboxymethyl cellulose, 1.5 parts of nano silver particles, terylene
3.5 parts of chemical fibre, 0.5 part of nano-meter flame retardants.
Embodiment 2
A kind of non-woven fabrics for wall cloth, raw material include by weight：47 parts of Kynoar, acrylic resin 22
Part, 14 parts of Wholly aromatic polyester, 15 parts of asbestos, 9 parts of anti-blushing agent, 2 parts of carboxymethyl cellulose, 4 parts of nano silver particles, terylene chemical fibre
1.5 parts, 2.8 parts of nano-meter flame retardants；
Wherein, the anti-blushing agent is prepared as follows：Polymethylacrylic acid contracting is added into micron order talcum powder
Nano zirconium dioxide, heating is added in water glyceride, temperature reaction, and insulation reaction obtains talcum powder-zirconia composite；To
The starch of gelatinization is added in talcum powder-zirconia composite, is uniformly dispersed, it is dry, sieving is smashed, anti-blushing agent is obtained.
Embodiment 3
A kind of non-woven fabrics for wall cloth, raw material include by weight：40 parts of Kynoar, acrylic resin 27
Part, 10 parts of Wholly aromatic polyester, 18 parts of asbestos, 5 parts of anti-blushing agent, 4 parts of carboxymethyl cellulose, 3 parts of nano silver particles, terylene chemical fibre
2 parts, 1.5 parts of nano-meter flame retardants；
Wherein, the anti-blushing agent is prepared as follows：Polymethylacrylic acid contracting is added into micron order talcum powder
Water glyceride reacts 2h at 60 DEG C, and nano zirconium dioxide is added, is warming up to 85 DEG C, insulation reaction 2h obtains talcum powder-dioxy
Change zirconium composite；The starch of gelatinization is added into talcum powder-zirconia composite, is uniformly dispersed, dry 30min at 80 DEG C,
350 mesh sieve was smashed, anti-blushing agent is obtained；
The starch of the gelatinization is the starch being gelatinized at 85 DEG C；
The weight ratio of the micron order talcum powder and nano zirconium dioxide is 1：2；
The weight ratio of the talcum powder-zirconia composite and starch is 1：2；
The granularity of the micron order talcum powder is 10um.
Embodiment 4
A kind of non-woven fabrics for wall cloth, raw material include by weight：35 parts of Kynoar, acrylic resin 24
Part, 8 parts of Wholly aromatic polyester, 17 parts of asbestos, 3.5 parts of anti-blushing agent, 3 parts of carboxymethyl cellulose, 2 parts of nano silver particles, terylene
Fine 1.8 parts, 1 part of nano-meter flame retardants；
Wherein, the anti-blushing agent is prepared as follows：Polymethylacrylic acid contracting is added into micron order talcum powder
Water glyceride reacts 3h at 50 DEG C, and nano zirconium dioxide is added, is warming up to 80 DEG C, insulation reaction 2.5h obtains talcum powder-two
Zirconia composite；The starch of gelatinization is added into talcum powder-zirconia composite, is uniformly dispersed, it is dry at 70 DEG C
40min smashed 300 mesh sieve, and obtained anti-blushing agent；
The starch of the gelatinization is the starch being gelatinized at 90 DEG C；
The weight ratio of the micron order talcum powder and nano zirconium dioxide is 1：1.5；
The weight ratio of the talcum powder-zirconia composite and starch is 1：2.5；
The granularity of the micron order talcum powder is 5um.
Embodiment 5
A kind of non-woven fabrics for wall cloth, raw material include by weight：45 parts of Kynoar, acrylic resin 30
Part, 12 parts of Wholly aromatic polyester, 20 parts of asbestos, 7 parts of anti-blushing agent, 5 parts of carboxymethyl cellulose, 3.5 parts of nano silver particles, terylene
Fine 3 parts, 2 parts of nano-meter flame retardants；
Wherein, the anti-blushing agent is prepared as follows：Polymethylacrylic acid contracting is added into micron order talcum powder
Water glyceride reacts 1h at 70 DEG C, and nano zirconium dioxide is added, is warming up to 95 DEG C, insulation reaction 1.5h obtains talcum powder-two
Zirconia composite；The starch of gelatinization is added into talcum powder-zirconia composite, is uniformly dispersed, it is dry at 85 DEG C
20min smashed 400 mesh sieve, and obtained anti-blushing agent；
The starch of the gelatinization is the starch being gelatinized at 80 DEG C；
The weight ratio of the micron order talcum powder and nano zirconium dioxide is 1：2.4；
The weight ratio of the talcum powder-zirconia composite and starch is 1：1.2；
The granularity of the micron order talcum powder is 20um.
Comparative example 1
A kind of non-woven fabrics for wall cloth, raw material include by weight：45 parts of Kynoar, acrylic resin 30
Part, 12 parts of Wholly aromatic polyester, 20 parts of asbestos, 7 parts of anti-blushing agent, 5 parts of carboxymethyl cellulose, 3.5 parts of nano silver particles, terylene
Fine 3 parts, 2 parts of nano-meter flame retardants.
Test example 1
It is embodiment 5 is obtained respectively non-woven fabrics, the non-woven fabrics for obtaining embodiment 5 after 20min is ultrasonically treated, right
Non-woven fabrics that ratio 1 obtains and non-woven fabrics on the market carry out humidity resistance test, are denoted as test group and control group 1- successively
3；Test result is as follows table：
As can be seen from the above table, anti-blushing agent prepared by ad hoc approach is added, the humidity resistance of the present invention can be effectively improved,
And the non-woven fabrics for obtaining embodiment 5, after 20min is ultrasonically treated, regain is still very low, it is seen that the present invention has excellent
Different and persistent humidity resistance, and the humidity resistance of the present invention is much better than non-woven fabrics on the market.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of non-woven fabrics for wall cloth, which is characterized in that its raw material includes by weight：32-47 parts of Kynoar, third
22-33 parts of olefin(e) acid resin, 6-14 parts of Wholly aromatic polyester, 15-21 parts of asbestos, 2.5-9 parts of anti-blushing agent, carboxymethyl cellulose 2-6
Part, 1.5-4 parts of nano silver particles, 1.5-3.5 parts of terylene chemical fibre, 0.5-2.8 parts of nano-meter flame retardants.
2. being used for the non-woven fabrics of wall cloth according to claim 1, which is characterized in that the anti-blushing agent is made as follows
It is standby：Poly (glycidyl methacrylate) is added into micron order talcum powder, nano zirconium dioxide is added in temperature reaction, heats up,
Insulation reaction obtains talcum powder-zirconia composite；The starch of gelatinization is added into talcum powder-zirconia composite, point
Uniform, drying is dissipated, smashing sieving obtains anti-blushing agent.
3. being used for the non-woven fabrics of wall cloth according to claim 2, which is characterized in that the anti-blushing agent is made as follows
It is standby：Poly (glycidyl methacrylate) is added into micron order talcum powder, 1-3h is reacted at 50-70 DEG C, nano-silica is added
Change zirconium, is warming up to 80-95 DEG C, insulation reaction 1.5-2.5h obtains talcum powder-zirconia composite；To talcum powder-titanium dioxide
The starch of gelatinization is added in zirconium composite, is uniformly dispersed, dry 20-40min at 70-85 DEG C smashed 300-400 mesh sieve, and obtained
To anti-blushing agent.
4. according to the non-woven fabrics for being used for wall cloth described in Claims 2 or 3, which is characterized in that the starch of the gelatinization is in 80-90
The starch being gelatinized at DEG C.
5. according to the non-woven fabrics for being used for wall cloth described in Claims 2 or 3, which is characterized in that the micron order talcum powder and nanometer
The weight ratio of zirconium dioxide is 1：1.5-2.4.
6. according to the non-woven fabrics for being used for wall cloth described in Claims 2 or 3, which is characterized in that the talcum powder-zirconium dioxide is compound
The weight ratio of object and starch is 1：1.2-2.5.
7. according to the non-woven fabrics for being used for wall cloth described in Claims 2 or 3, which is characterized in that the granularity of the micron order talcum powder
For 5-20um.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810650075.2A CN108796815A (en) | 2018-06-22 | 2018-06-22 | A kind of non-woven fabrics for wall cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810650075.2A CN108796815A (en) | 2018-06-22 | 2018-06-22 | A kind of non-woven fabrics for wall cloth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108796815A true CN108796815A (en) | 2018-11-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810650075.2A Pending CN108796815A (en) | 2018-06-22 | 2018-06-22 | A kind of non-woven fabrics for wall cloth |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112609327A (en) * | 2020-12-04 | 2021-04-06 | 江阴市华思诚无纺布有限公司 | Antibacterial non-woven fabric for transplantable roof greening and production method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241793A (en) * | 2010-05-14 | 2011-11-16 | 威海东方润德新材料有限公司 | Cationic crosslinking enhanced surface sizing agent |
| CN104846697A (en) * | 2015-04-24 | 2015-08-19 | 杭州百事特实业股份有限公司 | Cation cross-linked styrene-acrylic surface sizing agent and preparation method thereof |
| CN104988796A (en) * | 2015-05-29 | 2015-10-21 | 常州博润新材料科技有限公司 | Enhanced multifunctional surface sizing assistant for papermaking and preparation method thereof |
| CN105442335A (en) * | 2015-11-25 | 2016-03-30 | 安徽索亚装饰材料有限公司 | High-toughness wallpaper containing modified acrylic resin emulsion coating |
| CN108085997A (en) * | 2017-12-05 | 2018-05-29 | 苏州固泰新材股份有限公司 | A kind of weather-proof antifouling wallpaper and preparation method thereof |
-
2018
- 2018-06-22 CN CN201810650075.2A patent/CN108796815A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102241793A (en) * | 2010-05-14 | 2011-11-16 | 威海东方润德新材料有限公司 | Cationic crosslinking enhanced surface sizing agent |
| CN104846697A (en) * | 2015-04-24 | 2015-08-19 | 杭州百事特实业股份有限公司 | Cation cross-linked styrene-acrylic surface sizing agent and preparation method thereof |
| CN104988796A (en) * | 2015-05-29 | 2015-10-21 | 常州博润新材料科技有限公司 | Enhanced multifunctional surface sizing assistant for papermaking and preparation method thereof |
| CN105442335A (en) * | 2015-11-25 | 2016-03-30 | 安徽索亚装饰材料有限公司 | High-toughness wallpaper containing modified acrylic resin emulsion coating |
| CN108085997A (en) * | 2017-12-05 | 2018-05-29 | 苏州固泰新材股份有限公司 | A kind of weather-proof antifouling wallpaper and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112609327A (en) * | 2020-12-04 | 2021-04-06 | 江阴市华思诚无纺布有限公司 | Antibacterial non-woven fabric for transplantable roof greening and production method thereof |
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