CN104532688A - Acid and alkali resistant PVC wallpaper base paper and preparation method thereof - Google Patents

Acid and alkali resistant PVC wallpaper base paper and preparation method thereof Download PDF

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Publication number
CN104532688A
CN104532688A CN201410672408.3A CN201410672408A CN104532688A CN 104532688 A CN104532688 A CN 104532688A CN 201410672408 A CN201410672408 A CN 201410672408A CN 104532688 A CN104532688 A CN 104532688A
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China
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parts
acid
pulp
preparation
body paper
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CN201410672408.3A
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Inventor
李华令
肖昌明
向凯
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Anhui Suoya Decorative Materials Co Ltd
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Anhui Suoya Decorative Materials Co Ltd
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Priority to CN201410672408.3A priority Critical patent/CN104532688A/en
Publication of CN104532688A publication Critical patent/CN104532688A/en
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Abstract

The invention relates to a wallpaper base paper, and more specifically relates to an acid and alkali resistant PVC wallpaper base paper and a preparation method thereof. The acid and alkali resistant PVC wallpaper base paper is prepared from following raw materials, by weight, 20 to 30 parts of bamboo pulp, 18 to 25 parts of bleached esparto pulp, 35 to 42 parts of softwood pulp, 1 to 2 parts of softwood pulp plant extract, 1 to 3 parts of urotropine, 3 to 5 parts of sodium alginate, 4 to 6 parts of fluorophlogopite powder, 5 to 8 parts of barium sulfate, 4 to 5 parts of PAE wet strength agent, 1 to 2 parts of a water-based defoamer, 1 to 2 parts of an imidazole cation lubricating agent, 0.5 to 1 part of sodium ethoxylated alkyl sulfate, 12 to 18 parts of an environmental-friendly pigment of 800 to 1250 meshes, 12 to 15 parts of an adhesive, and 3 to 5 parts of an accessory ingredient. The acid and alkali resistant PVC wallpaper base paper possesses excellent gas permeability and toughness, water resistance and corrosion resistance; is high in acid and alkali resistance, and dry and wet strength; is excellent in physical properties; is convenient for later process; is non-toxic; is friendly to the environment; and is capable of providing production of high-quality wallpaper with foundation; and the surface of the acid and alkali resistant PVC wallpaper base paper is compact and flat.

Description

PVC wallpaper body paper of a kind of acid/alkali-corrosion-resistant and preparation method thereof
Technical field
The present invention relates to a kind of hanging raw stock, PVC wallpaper body paper being specifically related to a kind of acid/alkali-corrosion-resistant and preparation method thereof.
Background technology
What wallpaper became many owners gradually as a kind of wall surfacing material is first-selected, the advantages such as its color is various, pattern abundant, environmental protection attractive in appearance, there is the advantage that many traditional wall coverings are incomparable, improve year by year in the utilization rate of China, PVC wallpaper is the common wallpaper of a class, it is mainly with pure paper as base material, and then at substrate surface coating polyvinyl chloride resin sizing material, then postmenstruation, ornamenting processing process obtained finished product.
Body paper directly has influence on operation effect and the service property (quality) in wallpaper later stage as base material, current body paper material ubiquity intensity, poor toughness, surface absorption are uneven, glue not easily applies, water resistant poor heat resistance, grow bacterium and the shortcoming such as to mildew, have a strong impact on the serviceability of finished product, therefore the composition and engineering improving traditional body paper is had very much, improve its adaptability, improve post-production performance, to realize High-efficient Production, obtain quality product.
Summary of the invention
The object of the invention is PVC wallpaper body paper providing a kind of acid/alkali-corrosion-resistant and preparation method thereof, and to achieve these goals, the technical solution used in the present invention is as follows:
PVC wallpaper body paper of a kind of acid/alkali-corrosion-resistant and preparation method thereof, it is characterized in that, this body paper is made up of the raw material of following weight portion: bamboo pulp 20-30, bleaching esparto pulp 18-25, softwood pulp 35-42, eucalyptus leaves plant extraction liquid 1-2, methenamine 1-3, sodium alginate 3-5, fluorophologopite powder 4-6, barium sulfate 5-8, PAE wet strength agent 4-5, water-based defoamer 1-2, Imidazole cation lubricant 1-2, ethoxylated alkyl sulfate 0.5-1,800-1250 order environmental-friendly pigment 12-18, adhesive 12-15, auxiliary agent 3-5;
Auxiliary agent is made up of the raw material of following weight portion: polymine 4-6, neopelex 0.2-0.5, poly-l-lysine (molecular weight 70000-150000) 2-3, sweet mellow wine 1-1.5, oxidized starch 6-8, water-based defoamer 0.1-0.2, atoleine 1-2, water 12-16, preparation method is: first by polymine, neopelex, atoleine drops in 50-60 DEG C of hot water, fully be uniformly mixed and make material dissolve dispersion completely, add sweet mellow wine more subsequently, oxidized starch, be uniformly mixed 30-40min, finally add other leftover materials again, continue insulated and stirred mixing 40-50min, by the rapid draing of gained material after stirring terminates, removing moisture, and be ground into fine powder and get final product.
Described adhesive is aqueous non-toxic adhesive.
PVC wallpaper body paper of described a kind of acid/alkali-corrosion-resistant and preparation method thereof, its preparation method is:
(1) first bamboo pulp, bleaching esparto pulp, softwood pulp mixing are dropped into thin up making beating in beater, beating degree is 28-35 0sR;
(2) by fluorophologopite powder, barium sulfate and Imidazole cation mix lubricant grinding distribution 40-50min, 600-800 mesh sieve is crossed;
(3) step (1), step (2) gained material are mixed with other residual components except pigment, adhesive, auxiliary agent, after being uniformly mixed 1-2h, mixed slurry manufactured paper with pulp through long mesh paper making machine, dry, obtain semi-finished product body paper;
(4) adhesive input is doubled in the water of its weight portion, auxiliary agent, pigment is added after dilution evenly, high-speed stirred makes it mix completely, obtain surface coating liquid, subsequently this surface coating liquid is coated the semi-finished product body paper surface of step (3) gained, then drying, surface pressure polishing decorations, batch after namely obtain body paper and become paper.
Body paper advantage of the present invention is: by softwood pulp, bamboo pulp, straw pulp mixing making beating, the paper of preparation has good gas permeability and toughness, eucalyptus leaves plant extraction liquid in raw material is combined with methenamine can generate photoresistive substance, again with the fluorophologopite powder after surface treatment, the fillers such as barium sulfate together, impart the acid-alkali-corrosive-resisting ability that semi-finished product body paper is excellent, and paper strength obtains lifting, surface is compacted smooth, and auxiliary agent, it is full that pigment and adhesive dilute the surface coating liquid uniform color prepared, keep effective, easy coating, can effectively promote body paper intensity, strengthen water resistant ability, make body paper smooth surface fine and close, postorder process is more efficient.To sum up, hanging raw stock environment-protecting asepsis of the present invention, water-fast corrosion-resistant, good physical properties, is easy to post-production, lays a good foundation for producing high-quality wallpaper finished product.
Detailed description of the invention
Embodiment
The body paper of the present embodiment is obtained by the raw material of following weight portion: bamboo pulp 28, bleaching esparto pulp 25, softwood pulp 40, eucalyptus leaves plant extraction liquid 2, methenamine 3, sodium alginate 4, fluorophologopite powder 5, barium sulfate 7, PAE wet strength agent 4, water-based defoamer 2, Imidazole cation lubricant 1, ethoxylated alkyl sulfate 0.8,1250 order environmental-friendly pigment 15, adhesive 14, auxiliary agent 4.
Auxiliary agent is made up of the raw material of following weight portion: polymine 5, neopelex 0.3, poly-l-lysine (molecular weight 70000-150000) 3, sweet mellow wine 1.2, oxidized starch 8, water-based defoamer 0.1, atoleine 1.5, water 16, preparation method is: first by polymine, neopelex, atoleine drops in 50-60 DEG C of hot water, fully be uniformly mixed and make material dissolve dispersion completely, add sweet mellow wine more subsequently, oxidized starch, be uniformly mixed 40min, finally add other leftover materials again, continue insulated and stirred mixing 45min, by the rapid draing of gained material after stirring terminates, removing moisture, and be ground into fine powder and get final product.
The adhesive adopted to be solid content be 45 ± 1% phenylethylene-maleic anhydride polymer emulsion.
The preparation method of the present embodiment body paper is:
(1) first bamboo pulp, bleaching esparto pulp, softwood pulp mixing are dropped into thin up making beating in beater, beating degree is 30 0sR;
(2) by fluorophologopite powder, barium sulfate and Imidazole cation mix lubricant grinding distribution 50min, 800 mesh sieves are crossed;
(3) step (1), step (2) gained material are mixed with other residual components except pigment, adhesive, auxiliary agent, after being uniformly mixed 1.8h, mixed slurry manufactured paper with pulp through long mesh paper making machine, dry, obtain semi-finished product body paper;
(4) adhesive input is doubled in the water of its weight portion, auxiliary agent, pigment is added after dilution evenly, high-speed stirred makes it mix completely, obtain surface coating liquid, subsequently this surface coating liquid is coated the semi-finished product body paper surface of step (3) gained, then drying, surface pressure polishing decorations, batch after namely obtain body paper and become paper.
Body paper prepared by the present embodiment becomes each performance indications of paper as follows:
Presentation quality: uniform in color, surface smoothing, even tissue; Machine direction tensile strength: 3.3KN/m; Wet strength: 2.5KN/m; Tightness: 0.64g/m 3; Opacity: 95.8%; Air permeability: 2320ml/min; Surface absorption: 52g/m 2(60s); Expansion and contraction 0.2%.

Claims (3)

1. the PVC wallpaper body paper and preparation method thereof of an acid/alkali-corrosion-resistant, it is characterized in that, this body paper is made up of the raw material of following weight portion: bamboo pulp 20-30, bleaching esparto pulp 18-25, softwood pulp 35-42, eucalyptus leaves plant extraction liquid 1-2, methenamine 1-3, sodium alginate 3-5, fluorophologopite powder 4-6, barium sulfate 5-8, PAE wet strength agent 4-5, water-based defoamer 1-2, Imidazole cation lubricant 1-2, ethoxylated alkyl sulfate 0.5-1,800-1250 order environmental-friendly pigment 12-18, adhesive 12-15, auxiliary agent 3-5;
Auxiliary agent is made up of the raw material of following weight portion: polymine 4-6, neopelex 0.2-0.5, poly-l-lysine (molecular weight 70000-150000) 2-3, sweet mellow wine 1-1.5, oxidized starch 6-8, water-based defoamer 0.1-0.2, atoleine 1-2, water 12-16, preparation method is: first by polymine, neopelex, atoleine drops in 50-60 DEG C of hot water, fully be uniformly mixed and make material dissolve dispersion completely, add sweet mellow wine more subsequently, oxidized starch, be uniformly mixed 30-40min, finally add other leftover materials again, continue insulated and stirred mixing 40-50min, by the rapid draing of gained material after stirring terminates, removing moisture, and be ground into fine powder and get final product.
2. the PVC wallpaper body paper and preparation method thereof of a kind of acid/alkali-corrosion-resistant as claimed in claim 1, it is characterized in that, described adhesive is aqueous non-toxic adhesive.
3. the PVC wallpaper body paper and preparation method thereof of a kind of acid/alkali-corrosion-resistant as claimed in claim 1, its preparation method is:
(1) first bamboo pulp, bleaching esparto pulp, softwood pulp mixing are dropped into thin up making beating in beater, beating degree is 28-35 0sR;
(2) by fluorophologopite powder, barium sulfate and Imidazole cation mix lubricant grinding distribution 40-50min, 600-800 mesh sieve is crossed;
(3) step (1), step (2) gained material are mixed with other residual components except pigment, adhesive, auxiliary agent, after being uniformly mixed 1-2h, mixed slurry manufactured paper with pulp through long mesh paper making machine, dry, obtain semi-finished product body paper;
(4) adhesive input is doubled in the water of its weight portion, auxiliary agent, pigment is added after dilution evenly, high-speed stirred makes it mix completely, obtain surface coating liquid, subsequently this surface coating liquid is coated the semi-finished product body paper surface of step (3) gained, then drying, surface pressure polishing decorations, batch after namely obtain body paper and become paper.
CN201410672408.3A 2014-11-22 2014-11-22 Acid and alkali resistant PVC wallpaper base paper and preparation method thereof Pending CN104532688A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104878661A (en) * 2015-05-20 2015-09-02 苏州宏恒化工有限公司 Waterproof and soundproof polyvinyl chloride base wallpaper and preparation method thereof
CN105155336A (en) * 2015-09-11 2015-12-16 姚志宏 Composite body paper resisting corrosion of acid and alkali and manufacturing method thereof
CN106235936A (en) * 2016-07-28 2016-12-21 义乌市义南纸业有限公司 A kind of environmental protection unstressed configuration agent body paper medicated napkin and preparation method thereof
CN107151942A (en) * 2017-06-30 2017-09-12 南宁东印时代广告有限公司 Composite wallpaper

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104005260A (en) * 2013-02-21 2014-08-27 甘木林 Wallpaper base produced with recycled pulp

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104005260A (en) * 2013-02-21 2014-08-27 甘木林 Wallpaper base produced with recycled pulp

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104878661A (en) * 2015-05-20 2015-09-02 苏州宏恒化工有限公司 Waterproof and soundproof polyvinyl chloride base wallpaper and preparation method thereof
CN105155336A (en) * 2015-09-11 2015-12-16 姚志宏 Composite body paper resisting corrosion of acid and alkali and manufacturing method thereof
CN106235936A (en) * 2016-07-28 2016-12-21 义乌市义南纸业有限公司 A kind of environmental protection unstressed configuration agent body paper medicated napkin and preparation method thereof
CN107151942A (en) * 2017-06-30 2017-09-12 南宁东印时代广告有限公司 Composite wallpaper

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