CN106221475A - A kind of novel environment friendly water-repellent paint - Google Patents

A kind of novel environment friendly water-repellent paint Download PDF

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Publication number
CN106221475A
CN106221475A CN201610812834.1A CN201610812834A CN106221475A CN 106221475 A CN106221475 A CN 106221475A CN 201610812834 A CN201610812834 A CN 201610812834A CN 106221475 A CN106221475 A CN 106221475A
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agent
prepares
environment friendly
mixture
repellent paint
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张洁
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Guangxi Nanning Zhicui Technology Consulting Co Ltd
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Guangxi Nanning Zhicui Technology Consulting Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/26Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/26Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/283Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing one or more carboxylic moiety in the chain, e.g. acetoacetoxyethyl(meth)acrylate
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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Abstract

The invention discloses a kind of novel environment friendly water-repellent paint, including following raw material: stearyl methacrylate, rosin resin, tributyl citrate, ethyl methacrylate, aqueous acrylic emulsion, polyacrylamide solution, Tissuemat E, white carbon black, montmorillonite, mica powder, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, wetting agent, adhesion promoter, catalyst, initiator, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, thickening agent, coalescents, fire retardant.The coating of the present invention had both had adhesive force and the mechanical property of excellence, had again excellent resistance to water, resistance to ag(e)ing, crack resistance and a thermal adaptability, and the nonhazardous of product own, it is the novel environment friendly water-repellent paint of a kind of excellent combination property.

Description

A kind of novel environment friendly water-repellent paint
[technical field]
The invention belongs to coating technology of preparing neck, be specifically related to a kind of novel environment friendly water-repellent paint.
[background technology]
Water-repellent paint is the material of a kind of liquid or semi liquid state, uses the construction technology such as brush or spraying on building surface, passes through Chemical reaction forms a continuous print, has the thin film of certain elasticity and thickness, so can resist certain water pressure, from And reach the purpose of waterproof and moistureproof.Water-repellent paint is a kind of special coating, and its particularity is that coating surface can be formed One softness, waterproof, the Waterproof structural course of cracking resistance, stop that hydrone permeates externally to basic unit.
Building and structures in use, all can be affected by various natural causes, and build form and Waterproof position is different, and suffered influence factor is the most different.As building roof waterproof layer is exposed in natural environment for a long time, by rain, The erosion of snow, wind, frost, ultraviolet and air pollutants;Building under ground portion is not only chronically in water environment, but also The repeated action of differential settlement to be born;Bridge is then intended to bear the alternate stress effect of frequent traffic load.Therefore, use In the material of buildings waterproof, do not need only have the mechanical property under opposing complex stress effect, also need to be maintained at respectively simultaneously The lasting stability of combination property under the influence of kind natural cause is long-term.Tradition Novel durable waterproof paint is waterproof, easily outside room Cause aging, dry and cracked, deform, the phenomenon such as fracture;And waterproof for kitchen, lavatory etc., tired for complex-shaped place construction Difficulty, and durability is poor, every few years needs to reprocess, and has both added expense, has upset again the orthobiosis of people.
[summary of the invention]
The present invention provides a kind of novel environment friendly water-repellent paint, is used for outside room waterproof with solution tradition Novel durable waterproof paint, holds Easily cause aging, dry and cracked, deform, the problem such as fracture.The coating of the present invention had both had adhesive force and the mechanical property of excellence, had again There is excellent resistance to water, resistance to ag(e)ing, crack resistance and a thermal adaptability, and the nonhazardous of product own, it is a kind of comprehensive The novel environment friendly water-repellent paint of excellent performance.
For solve above technical problem, the present invention by the following technical solutions:
A kind of novel environment friendly water-repellent paint, in units of weight, including following raw material: stearyl methacrylate 102-138 Part, rosin resin 32-59 part, tributyl citrate 21-38 part, ethyl methacrylate 15-26 part, aqueous acrylic emulsion 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, white carbon black 4-8 part, montmorillonite 3-6 part, mica powder 2-5 Part, polyester fiber 3-6 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5 part, degasser 0.4- 0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalyst 0.1-0.3 part, Initiator 0.1-0.2 part, vertical stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part, defoamer 0.4-0.6 Part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3 part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part, fire retardant 1.2- 1.5 part;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 14-22 part, 2, 2-dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9 Part, aluminium hydroxide 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, association Effect agent 0.3-0.5 part;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described novel environment friendly water-repellent paint, comprises the following steps:
S1: by stearyl methacrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, charcoal Black, montmorillonite, mica powder, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, moistening Agent, adhesion promoter, catalyst, initiator mixing, be 120-150W at microwave power, and temperature is 88-95 DEG C, and rotating speed is Stir 2.5-3h under 2400-3000r/min, prepare mixture a;
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares Agent, optical brightener, defoamer, viscosifier, be 140-180W at microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/ Stir 3-5h under min, prepare mixture b;
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares Thick dose, coalescents, fire retardant, be 130-200W at microwave power, temperature is 105-115 DEG C, and rotating speed is 200-400r/min Lower stirring 2-4h, prepares mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31: APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is 300-400r/min 5-8min, prepares mixture A;
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3- Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 400-600r/min at speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8-at being 83-89 DEG C 2.5h, prepares mixture B;
S33: after the mixture B that step S32 prepares is cooled to room temperature, filters precipitate, is 3000-5000r/ at rotating speed Under min, centrifugal drying is to water content≤4%, prepares fire retardant;
S4: mixture c step S3 prepared is melt extruded at 108-115 DEG C by extruder, and passes through crusher Film-making, prepares lamellar body after cooling;
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing;
S6: pelletizing step S5 prepared crosses 120-180 mesh sieve after pulverizing, and prepares novel environment friendly water-repellent paint.
Further, described preservative is Liquid BPF-369.
Further, described antioxidant is antioxidant AT-330.
Further, described light stabilizer is light stabilizer HS-3101.
Further, described UV absorbent is oxybenzoic acid phenyl ester.
Further, described thickening agent is xanthan gum.
Further, described coalescents is Yi Siman coalescents.
The method have the advantages that
(1) coating of the present invention had both had adhesive force and the mechanical property of excellence, have again excellent resistance to water, resistance to ag(e)ing, Crack resistance and thermal adaptability, and the nonhazardous of product own, be the waterproof painting of novel environment friendly of a kind of excellent combination property Material;
(2) the novel environment friendly water-repellent paint of the present invention has weatherability, is widely used in the outdoor gold such as guardrail, Men Ye, aluminium section bar Metal surface application.
[detailed description of the invention]
For ease of being more fully understood that the present invention, being illustrated by following example, these embodiments belong to the protection of the present invention Scope, but it is not intended to protection scope of the present invention.
In an embodiment, described novel environment friendly water-repellent paint, in units of weight, including following raw material: methacrylic acid Stearate 102-138 part, rosin resin 32-59 part, tributyl citrate 21-38 part, ethyl methacrylate 15-26 part, Aqueous acrylic emulsion 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, white carbon black 4-8 part, montmorillonite 3-6 part, mica powder 2-5 part, polyester fiber 3-6 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5 Part, degasser 0.4-0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalysis Agent 0.1-0.3 part, initiator 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part, Defoamer 0.4-0.6 part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3 Part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part, Fire retardant 1.2-1.5 part;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described preservative is Liquid BPF-369;
Described antioxidant is antioxidant AT-330;
Described light stabilizer is light stabilizer HS-3101;
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum;
Described coalescents is Yi Siman coalescents;
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 14-22 part, 2, 2-dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9 Part, aluminium hydroxide 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, association Effect agent 0.3-0.5 part;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described novel environment friendly water-repellent paint, comprises the following steps:
S1: by stearyl methacrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, charcoal Black, montmorillonite, mica powder, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, moistening Agent, adhesion promoter, catalyst, initiator mixing, be 120-150W at microwave power, and temperature is 88-95 DEG C, and rotating speed is Stir 2.5-3h under 2400-3000r/min, prepare mixture a;
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares Agent, optical brightener, defoamer, viscosifier, be 140-180W at microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/ Stir 3-5h under min, prepare mixture b;
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares Thick dose, coalescents, fire retardant, be 130-200W at microwave power, temperature is 105-115 DEG C, and rotating speed is 200-400r/min Lower stirring 2-4h, prepares mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31: APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is 300-400r/min 5-8min, prepares mixture A;
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3- Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 400-600r/min at speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8-at being 83-89 DEG C 2.5h, prepares mixture B;
S33: after the mixture B that step S32 prepares is cooled to room temperature, filters precipitate, is 3000-5000r/ at rotating speed Under min, centrifugal drying is to water content≤4%, prepares fire retardant;
S4: mixture c step S3 prepared is melt extruded at 108-115 DEG C by extruder, and passes through crusher Film-making, prepares lamellar body after cooling;
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing;
S6: pelletizing step S5 prepared crosses 120-180 mesh sieve after pulverizing, and prepares novel environment friendly water-repellent paint.
Embodiment 1
A kind of novel environment friendly water-repellent paint, in units of weight, including following raw material: stearyl methacrylate 120 parts, pine 45 parts of balsam, tributyl citrate 30 parts, ethyl methacrylate 20 parts, aqueous acrylic emulsion 40 parts, polyacrylamide Solution 30 parts, Tissuemat E 30 parts, white carbon black 6 parts, montmorillonite 5 parts, mica powder 4 parts, 5 parts of polyester fiber, boron fibre 4 parts, hydroxypropyl Ylmethyl cellulose 6 parts, bamboo carbon fiber 4 parts, degasser 0.6 part, dispersant 0.7 part, wetting agent 0.3 part, adhesion promoter 0.4 part, catalyst 0.2 part, initiator 0.1 part, hang down stricture of vagina agent 0.5 part, toughener 0.4 part, optical brightener 0.5 part, defoamer 0.5 Part, viscosifier 0.2 part, 1.2 parts of firming agent, preservative 0.2 part, 0.2 part of antioxidant, light stabilizer 0.1 part, UV absorbent 0.2 part, thickening agent 0.5 part, coalescents 0.3 part, fire retardant 1.4 parts;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described preservative is Liquid BPF-369;
Described antioxidant is antioxidant AT-330;
Described light stabilizer is light stabilizer HS-3101;
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum;
Described coalescents is Yi Siman coalescents;
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 18 parts, 2,2-bis- Methyl isophthalic acid, 3-propylidene dimethylacrylate 10 parts, APP 12 parts, tetramethylolmethane 7 parts, 8 parts of carbamide, aluminium hydroxide 4 Part, antimony oxide 8 parts, manganese oxide 4 parts, bentonite 2.5 parts, penetrating agent 0.7 part, synergist 0.4 part;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described novel environment friendly water-repellent paint, comprises the following steps:
S1: by stearyl methacrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, charcoal Black, montmorillonite, mica powder, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, moistening Agent, adhesion promoter, catalyst, initiator mixing, be 135W at microwave power, and temperature is 92 DEG C, and rotating speed is 2800r/min Lower stirring 2.8h, prepares mixture a;
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares Agent, optical brightener, defoamer, viscosifier, be 160W at microwave power, and temperature is 120 DEG C, and rotating speed is stirring 4h under 500r/min, Prepare mixture b;
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares Thick dose, coalescents, fire retardant, be 180W at microwave power, temperature is 110 DEG C, rotating speed be under 300r/min stirring 3h, prepare Mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31: APP, 135 parts of water are added in microwave reactor, stirs 7min, system under speed of agitator is 350r/min Obtain mixture A;
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3- Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 500r/min at speed of agitator, and microwave power is 160W, and temperature is stirring 2.2h at 86 DEG C, prepares mixture B;
S33: by step S32 prepare mixture B be cooled to room temperature after, by precipitate filter, under rotating speed is 4000r/min from It is 4% that the heart is dried to water content, prepares fire retardant;
S4: mixture c step S3 prepared is melt extruded at 112 DEG C by extruder, and by crusher film-making, Lamellar body is prepared after cooling;
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing;
S6: pelletizing step S5 prepared crosses 150 mesh sieve after pulverizing, and prepares novel environment friendly water-repellent paint.
Embodiment 2
A kind of novel environment friendly water-repellent paint, in units of weight, including following raw material: stearyl methacrylate 102 parts, pine 32 parts of balsam, tributyl citrate 21 parts, ethyl methacrylate 15 parts, aqueous acrylic emulsion 32 parts, polyacrylamide Solution 24 parts, Tissuemat E 20 parts, white carbon black 4 parts, montmorillonite 3 parts, mica powder 2 parts, 3 parts of polyester fiber, boron fibre 3 parts, hydroxypropyl Ylmethyl cellulose 4 parts, bamboo carbon fiber 2 parts, degasser 0.4 part, dispersant 0.5 part, wetting agent 0.2-0. part, adhesive force promote Agent 0.3 part, catalyst 0.1 part, initiator 0.1 part, vertical stricture of vagina agent 0.3 part, toughener 0.2 part, optical brightener 0.3 part, defoamer 0.4 Part, viscosifier 0.2 part, 0.8 part of firming agent, preservative 0.2 part, 0.2 part of antioxidant, light stabilizer 0.1 part, UV absorbent 0.2 part, thickening agent 0.3 part, coalescents 0.3 part, fire retardant 1.2 parts;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described preservative is Liquid BPF-369;
Described antioxidant is antioxidant AT-330;
Described light stabilizer is light stabilizer HS-3101;
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum;
Described coalescents is Yi Siman coalescents;
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 14 parts, 2,2-bis- Methyl isophthalic acid, 3-propylidene dimethylacrylate 8 parts, APP 9 parts, tetramethylolmethane 4 parts, 6 parts of carbamide, aluminium hydroxide 2 parts, Antimony oxide 6 parts, manganese oxide 2 parts, bentonite 2 parts, penetrating agent 0.6 part, synergist 0.3 part;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described novel environment friendly water-repellent paint, comprises the following steps:
S1: by stearyl methacrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, charcoal Black, montmorillonite, mica powder, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, moistening Agent, adhesion promoter, catalyst, initiator mixing, be 120W at microwave power, and temperature is 88 DEG C, and rotating speed is 2400r/min Lower stirring 3h, prepares mixture a;
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares Agent, optical brightener, defoamer, viscosifier, be 140W at microwave power, and temperature is 115 DEG C, and rotating speed is stirring 5h under 400r/min, Prepare mixture b;
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares Thick dose, coalescents, fire retardant, be 130W at microwave power, temperature is 105 DEG C, rotating speed be under 200r/min stirring 4h, prepare Mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31: APP, 120 parts of water are added in microwave reactor, stirs 8min, system under speed of agitator is 300r/min Obtain mixture A;
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3- Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 400r/min at speed of agitator, and microwave power is 130W, and temperature is stirring 2.5h at 83 DEG C, prepares mixture B;
S33: by step S32 prepare mixture B be cooled to room temperature after, by precipitate filter, under rotating speed is 3000r/min from It is 3% that the heart is dried to water content, prepares fire retardant;
S4: mixture c step S3 prepared is melt extruded at 108 DEG C by extruder, and by crusher film-making, Lamellar body is prepared after cooling;
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing;
S6: pelletizing step S5 prepared crosses 120 mesh sieve after pulverizing, and prepares novel environment friendly water-repellent paint.
Embodiment 3
A kind of novel environment friendly water-repellent paint, in units of weight, including following raw material: stearyl methacrylate 138 parts, pine 59 parts of balsam, tributyl citrate 38 parts, ethyl methacrylate 26 parts, aqueous acrylic emulsion 48 parts, polyacrylamide Solution 34 parts, Tissuemat E 40 parts, white carbon black 8 parts, montmorillonite 6 parts, mica powder 5 parts, 6 parts of polyester fiber, boron fibre 5 parts, hydroxypropyl Ylmethyl cellulose 8 parts, bamboo carbon fiber 5 parts, degasser 0.8 part, dispersant 0.8 part, wetting agent 0.4 part, adhesion promoter 0.5 part, catalyst 0.3 part, initiator 0.2 part, hang down stricture of vagina agent 0.6 part, toughener 0.5 part, optical brightener 0.7 part, defoamer 0.6 Part, viscosifier 0.3 part, 1.5 parts of firming agent, preservative 0.3 part, 0.3 part of antioxidant, light stabilizer 0.2 part, UV absorbent 0.3 part, thickening agent 0.6 part, coalescents 0.4 part, fire retardant 1.5 parts;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described preservative is Liquid BPF-369;
Described antioxidant is antioxidant AT-330;
Described light stabilizer is light stabilizer HS-3101;
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum;
Described coalescents is Yi Siman coalescents;
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 22 parts, 2,2-bis- Methyl isophthalic acid, 3-propylidene dimethylacrylate 12 parts, APP 15 parts, tetramethylolmethane 10 parts, 9 parts of carbamide, aluminium hydroxide 5 Part, antimony oxide 10 parts, manganese oxide 6 parts, bentonite 3 parts, penetrating agent 0.8 part, synergist 0.5 part;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described novel environment friendly water-repellent paint, comprises the following steps:
S1: by stearyl methacrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, charcoal Black, montmorillonite, mica powder, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, moistening Agent, adhesion promoter, catalyst, initiator mixing, be 150W at microwave power, and temperature is 95 DEG C, and rotating speed is 3000r/min Lower stirring 2.5h, prepares mixture a;
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares Agent, optical brightener, defoamer, viscosifier, be 180W at microwave power, and temperature is 125 DEG C, and rotating speed is stirring 3h under 600r/min, Prepare mixture b;
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares Thick dose, coalescents, fire retardant, be 200W at microwave power, temperature is 115 DEG C, rotating speed be under 400r/min stirring 2h, prepare Mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31: APP, 150 parts of water are added in microwave reactor, stirs 5min, system under speed of agitator is 400r/min Obtain mixture A;
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3- Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 600r/min at speed of agitator, and microwave power is 180W, and temperature is stirring 1.8h at 89 DEG C, prepares mixture B;
S33: by step S32 prepare mixture B be cooled to room temperature after, by precipitate filter, under rotating speed is 5000r/min from It is 2% that the heart is dried to water content, prepares fire retardant;
S4: mixture c step S3 prepared is melt extruded at 1115 DEG C by extruder, and by crusher system Sheet, prepares lamellar body after cooling;
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing;
S6: pelletizing step S5 prepared crosses 180 mesh sieve after pulverizing, and prepares novel environment friendly water-repellent paint.
The performance indications of the novel environment friendly water-repellent paint that detection embodiment 1-3 prepares, result is as shown in the table.
As seen from the above table: the coating of the present invention had both had adhesive force and the mechanical property of excellence, have again excellent water-fast Property, resistance to ag(e)ing, crack resistance and thermal adaptability, and the nonhazardous of product own, be the new of a kind of excellent combination property Type environment-friendly waterproof paint.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanation, technology belonging to the present invention is led For the those of ordinary skill in territory, without departing from the inventive concept of the premise, it is also possible to make some simple deduction or replace, All should be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.

Claims (7)

1. a novel environment friendly water-repellent paint, it is characterised in that in units of weight, including following raw material: methacrylic acid is hard Fat acid ester 102-138 part, rosin resin 32-59 part, tributyl citrate 21-38 part, ethyl methacrylate 15-26 part, water Property acrylic emulsion 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, white carbon black 4-8 part, montmorillonite 3-6 Part, mica powder 2-5 part, polyester fiber 3-6 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5 part, Degasser 0.4-0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalyst 0.1-0.3 part, initiator 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part, disappear Infusion 0.4-0.6 part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3 Part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part, Fire retardant 1.2-1.5 part;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid. (acrylic acid ethylene glycol) ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described fire retardant is in units of weight portion, including following raw material: 3-M2BOL acetas 14-22 part, 2, 2-dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9 Part, aluminium hydroxide 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, association Effect agent 0.3-0.5 part;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described novel environment friendly water-repellent paint, comprises the following steps:
S1: by stearyl methacrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, charcoal Black, montmorillonite, mica powder, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, moistening Agent, adhesion promoter, catalyst, initiator mixing, be 120-150W at microwave power, and temperature is 88-95 DEG C, and rotating speed is Stir 2.5-3h under 2400-3000r/min, prepare mixture a;
S2: add aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down in the mixture a that step S1 prepares Agent, optical brightener, defoamer, viscosifier, be 140-180W at microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/ Stir 3-5h under min, prepare mixture b;
S3: add firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing in the mixture b that step S2 prepares Thick dose, coalescents, fire retardant, be 130-200W at microwave power, temperature is 105-115 DEG C, and rotating speed is 200-400r/min Lower stirring 2-4h, prepares mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31: APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is 300-400r/min 5-8min, prepares mixture A;
S32: to step S31 prepare mixture A in add 3-M2BOL acetas, 2,2-dimethyl-1,3- Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 400-600r/min at speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8-at being 83-89 DEG C 2.5h, prepares mixture B;
S33: after the mixture B that step S32 prepares is cooled to room temperature, filters precipitate, is 3000-5000r/ at rotating speed Under min, centrifugal drying is to water content≤4%, prepares fire retardant;
S4: mixture c step S3 prepared is melt extruded at 108-115 DEG C by extruder, and passes through crusher Film-making, prepares lamellar body after cooling;
S5: lamellar body step S4 prepared uses cutting knife to shear, and prepares pelletizing;
S6: pelletizing step S5 prepared crosses 120-180 mesh sieve after pulverizing, and prepares novel environment friendly water-repellent paint.
Novel environment friendly water-repellent paint the most according to claim 1, it is characterised in that described preservative is Liquid BPF-369.
Novel environment friendly water-repellent paint the most according to claim 1, it is characterised in that described antioxidant is antioxidant AT-330.
Novel environment friendly water-repellent paint the most according to claim 1, it is characterised in that described light stabilizer is light stabilizer HS- 3101。
Novel environment friendly water-repellent paint the most according to claim 1, it is characterised in that described UV absorbent is o-hydroxy Phenyl formate.
Novel environment friendly water-repellent paint the most according to claim 1, it is characterised in that described thickening agent is xanthan gum.
Novel environment friendly water-repellent paint the most according to claim 1, it is characterised in that described coalescents is that Yi Siman film forming helps Agent.
CN201610812834.1A 2016-09-09 2016-09-09 A kind of novel environment friendly water-repellent paint Pending CN106221475A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108047846A (en) * 2017-12-28 2018-05-18 杭州之江园林绿化艺术有限公司 A kind of maintenance tile investment precoat and preparation method thereof
CN108912775A (en) * 2018-06-30 2018-11-30 李晓龙 A kind of novel environment friendly water-repellent paint

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Publication number Priority date Publication date Assignee Title
CN1393485A (en) * 2001-06-29 2003-01-29 大赛璐化学工业株式会社 Flame-retarded polyolefin resin composition
CN104177648A (en) * 2014-08-03 2014-12-03 马晓权 Tire flame retardant
CN104371747A (en) * 2014-09-30 2015-02-25 滁州斯迈特复合材料有限公司 Fire retardant for air-conditioning cabinet
CN104559373A (en) * 2014-12-30 2015-04-29 青建集团股份公司 Waterproof paint for external walls and preparation method of waterproof paint
CN105688360A (en) * 2015-10-29 2016-06-22 陈闽玲 Class-A fire extinguishing agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1393485A (en) * 2001-06-29 2003-01-29 大赛璐化学工业株式会社 Flame-retarded polyolefin resin composition
CN104177648A (en) * 2014-08-03 2014-12-03 马晓权 Tire flame retardant
CN104371747A (en) * 2014-09-30 2015-02-25 滁州斯迈特复合材料有限公司 Fire retardant for air-conditioning cabinet
CN104559373A (en) * 2014-12-30 2015-04-29 青建集团股份公司 Waterproof paint for external walls and preparation method of waterproof paint
CN105688360A (en) * 2015-10-29 2016-06-22 陈闽玲 Class-A fire extinguishing agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108047846A (en) * 2017-12-28 2018-05-18 杭州之江园林绿化艺术有限公司 A kind of maintenance tile investment precoat and preparation method thereof
CN108912775A (en) * 2018-06-30 2018-11-30 李晓龙 A kind of novel environment friendly water-repellent paint

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