CN106398438A - Environment-friendly novel waterproof paint - Google Patents

Environment-friendly novel waterproof paint Download PDF

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Publication number
CN106398438A
CN106398438A CN201610812753.1A CN201610812753A CN106398438A CN 106398438 A CN106398438 A CN 106398438A CN 201610812753 A CN201610812753 A CN 201610812753A CN 106398438 A CN106398438 A CN 106398438A
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agent
environment
mixture
friendly novel
repellent paint
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张洁
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Guangxi Nanning Zhicui Technology Consulting Co Ltd
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Guangxi Nanning Zhicui Technology Consulting Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/14Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
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  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses environment-friendly novel waterproof paint, which is prepared from the following raw materials: hydroxyl-propyl acrylate, rosin resin, tributyl citrate, ethyl methacrylate, waterborne acrylic emulsion, polyacrylamide solution, polyethylene wax, calcium hydroxide, montmorillonite, talcum powder, polyester fiber, boron fiber, hydroxypropyl methyl cellulose, bamboo carbon fiber, a degasifying agent, a dispersing agent, a wetting agent, an adhesion promoter, a catalyst, an initiator, a hammer tone agent, a toughening agent, a brightener, an antifoaming agent, a tackifier, a curing agent, a preservative, an antioxidant, a light stabilizer, an ultraviolet absorbent, a thickening agent, a film forming aid and a flame retardant. Not only does the paint provided by the invention have excellent adhesion and mechanical properties, but also has favorable water resistance, aging resistance, cracking resistance and temperature adaptability; moreover, the product per se has no toxicity and harmfulness, and is environment-friendly novel waterproof paint which is excellent in over-all properties.

Description

A kind of environment-friendly novel water-repellent paint
【Technical field】
The invention belongs to coating preparation technology neck is and in particular to a kind of environment-friendly novel water-repellent paint.
【Background technology】
Water-repellent paint is the material of a kind of liquid or semi liquid state, adopts the construction technology such as brush or spraying on building surface, passes through Chemical reaction forms a thin film that is continuous, having certain elasticity and thickness, so can resist certain water pressure, from And reach the purpose of waterproof and moistureproof.Water-repellent paint is a kind of special coating, and its particularity is that coating surface can be formed One softness, waterproof, the Waterproof structural course of cracking resistance, stop that hydrone permeates externally to basic unit.
Building and structures in use, all can be affected by various natural causes, and build form with Waterproof position is different, and suffered influence factor is also different.As building roof waterproof layer is exposed in natural environment for a long time, by rain, The erosion of snow, wind, frost, ultraviolet and air pollutants;Building under ground portion is not only chronically in water environment, but also The repeated action of differential settlement to be born;And bridge is then intended to bear the alternate stress effect of frequent traffic load.Therefore, use In the material of buildings waterproof, do not need only have the mechanical property under opposing complex stress effect, also need to be maintained at respectively simultaneously The lasting stability of combination property under the influence of kind natural cause is long-term.Traditional Novel durable waterproof paint is used for waterproof outside room, easily Cause aging, dry and cracked, the phenomenon such as deform, fracture;And it is used for the waterproofs such as kitchen, lavatory, tired for complex-shaped place construction Difficulty, and durability is poor, every few years need to reprocess, and both increased expense, have upset the orthobiosiss of people again.
【Content of the invention】
The present invention provides a kind of environment-friendly novel water-repellent paint, to solve traditional Novel durable waterproof paint for waterproof outside room, holds Easily cause aging, dry and cracked, the problems such as deform, fracture.The coating of the present invention had both had excellent adhesive force and mechanical property, had again There are excellent resistance to water, resistance to ag(e)ing, crack resistance and thermal adaptability, and product nonhazardouss itself, it is a kind of comprehensive The environment-friendly novel water-repellent paint of excellent performance.
For solving above technical problem, the present invention employs the following technical solutions:
A kind of environment-friendly novel water-repellent paint, in units of weight, including following raw material:Hydroxypropyl acrylate 104-138 part, Colophonium Resin 33-59 part, tributyl citrate 22-38 part, ethyl methacrylate 15-26 part, aqueous acrylic emulsion 32-48 part, Polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, calcium hydroxide 4-8 part, montmorillonite 3-6 part, Pulvis Talci 2-5 part, Polyester fiber 3-6 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5 part, degasser 0.4-0.8 Part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalyst 0.1-0.3 part, initiation Agent 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part, defoamer 0.4-0.6 part, Viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3 part, light stabilizer 0.1- 0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part, fire retardant 1.2-1.5 Part;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid.(Acrylic acid ethylene glycol)Ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described fire retardant in units of weight portion, including following raw material:3-M2BOL acetass 14-22 part, 2, 2- dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9 Part, aluminium hydroxide 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, association Effect agent 0.3-0.5 part;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described environment-friendly novel water-repellent paint, comprises the following steps:
S1:By Hydroxypropyl acrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, calcium hydroxide, Montmorillonite, Pulvis Talci, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, wetting agent, Adhesion promoter, catalyst, initiator mixing, are 120-150W in microwave power, temperature is 88-95 DEG C, and rotating speed is 2400- 2.5-3h, prepared mixture a is stirred under 3000r/min;
S2:Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1 Agent, optical brightener, defoamer, viscosifier, are 140-180W in microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/ 3-5h, prepared mixture b is stirred under min;
S3:Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2 Thick dose, coalescents, fire retardant, be 130-200W in microwave power, temperature be 105-115 DEG C, rotating speed be 200-400r/min Lower stirring 2-4h, prepared mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31:APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is for 300-400r/min 5-8min, prepared mixture A;
S32:3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31 Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 400-600r/min in speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8- at being 83-89 DEG C 2.5h, prepared mixture B;
S33:The mixture B that step S32 is obtained is cooled to after room temperature, precipitate is filtered, is 3000-5000r/ in rotating speed Under min, centrifugal drying is to water content≤4%, prepared fire retardant;
S4:The mixture c that step S3 is obtained is melt extruded at 108-115 DEG C by extruder, and passes through crusher Film-making, is obtained lamellar body after cooling;
S5:The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing;
S6:The pelletizing that step S5 is obtained crosses 120-180 mesh sieve, prepared environment-friendly novel water-repellent paint after pulverizing.
Further, described preservative is Liquid BPF -369.
Further, described antioxidant is antioxidant AT-330.
Further, described light stabilizer is light stabilizer HS-3101.
Further, described UV absorbent is oxybenzoic acid phenyl ester.
Further, described thickening agent is xanthan gum.
Further, described coalescents are Yi Siman coalescents.
The invention has the advantages that:
(1)The coating of the present invention had both had excellent adhesive force and mechanical property, have again excellent resistance to water, resistance to ag(e)ing, Crack resistance and thermal adaptability, and product nonhazardouss itself, are that a kind of environment-friendly novel waterproof of excellent combination property applies Material;
(2)The environment-friendly novel water-repellent paint of the present invention has weatherability, is widely used in the outdoor gold such as guardrail, Men Ye, aluminium section bar Metal surface application.
【Specific embodiment】
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the protection of the present invention Scope, but do not limit the scope of the invention.
In an embodiment, described environment-friendly novel water-repellent paint, in units of weight, including following raw material:Acrylic acid hydroxypropyl Ester 104-138 part, rosin resin 33-59 part, tributyl citrate 22-38 part, ethyl methacrylate 15-26 part, aqueouss third Olefin(e) acid emulsion 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, calcium hydroxide 4-8 part, montmorillonite 3-6 Part, Pulvis Talci 2-5 part, polyester fiber 3-6 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5 part, Degasser 0.4-0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalyst 0.1-0.3 part, initiator 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part, disappear Infusion 0.4-0.6 part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3 Part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part, Fire retardant 1.2-1.5 part;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid.(Acrylic acid ethylene glycol)Ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described preservative is Liquid BPF -369;
Described antioxidant is antioxidant AT-330;
Described light stabilizer is light stabilizer HS-3101;
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum;
Described coalescents are Yi Siman coalescents;
Described fire retardant in units of weight portion, including following raw material:3-M2BOL acetass 14-22 part, 2, 2- dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9 Part, aluminium hydroxide 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, association Effect agent 0.3-0.5 part;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described environment-friendly novel water-repellent paint, comprises the following steps:
S1:By Hydroxypropyl acrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, calcium hydroxide, Montmorillonite, Pulvis Talci, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, wetting agent, Adhesion promoter, catalyst, initiator mixing, are 120-150W in microwave power, temperature is 88-95 DEG C, and rotating speed is 2400- 2.5-3h, prepared mixture a is stirred under 3000r/min;
S2:Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1 Agent, optical brightener, defoamer, viscosifier, are 140-180W in microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/ 3-5h, prepared mixture b is stirred under min;
S3:Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2 Thick dose, coalescents, fire retardant, be 130-200W in microwave power, temperature be 105-115 DEG C, rotating speed be 200-400r/min Lower stirring 2-4h, prepared mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31:APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is for 300-400r/min 5-8min, prepared mixture A;
S32:3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31 Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 400-600r/min in speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8- at being 83-89 DEG C 2.5h, prepared mixture B;
S33:The mixture B that step S32 is obtained is cooled to after room temperature, precipitate is filtered, is 3000-5000r/ in rotating speed Under min, centrifugal drying is to water content≤4%, prepared fire retardant;
S4:The mixture c that step S3 is obtained is melt extruded at 108-115 DEG C by extruder, and passes through crusher Film-making, is obtained lamellar body after cooling;
S5:The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing;
S6:The pelletizing that step S5 is obtained crosses 120-180 mesh sieve, prepared environment-friendly novel water-repellent paint after pulverizing.
Embodiment 1
A kind of environment-friendly novel water-repellent paint, in units of weight, including following raw material:120 parts of Hydroxypropyl acrylate, rosin resin 45 parts, 30 parts of tributyl citrate, 20 parts of ethyl methacrylate, 40 parts of aqueous acrylic emulsion, polyacrylamide solution 30 Part, 30 parts of Tissuemat E, 6 parts of calcium hydroxide, 5 parts of montmorillonite, 4 parts of Pulvis Talci, 5 parts of polyester fiber, 4 parts of boron fibre, hydroxypropyl 6 parts of methylcellulose, 4 parts of bamboo carbon fiber, 0.6 part of degasser, 0.7 part of dispersant, 0.3 part of wetting agent, adhesion promoter 0.4 Part, 0.2 part of catalyst, 0.1 part of initiator, 0.5 part of stricture of vagina agent of hanging down, 0.4 part of toughener, 0.5 part of optical brightener, 0.5 part of defoamer, increasing 0.2 part of stick, 1.2 parts of firming agent, 0.2 part of preservative, 0.2 part of antioxidant, 0.1 part of light stabilizer, UV absorbent 0.2 Part, 0.5 part of thickening agent, 0.3 part of coalescents, 1.4 parts of fire retardant;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid.(Acrylic acid ethylene glycol)Ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described preservative is Liquid BPF -369;
Described antioxidant is antioxidant AT-330;
Described light stabilizer is light stabilizer HS-3101;
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum;
Described coalescents are Yi Siman coalescents;
Described fire retardant in units of weight portion, including following raw material:18 parts of 3-M2BOL acetass, 2,2- bis- Methyl isophthalic acid, 10 parts of 3- propylidene dimethylacrylate, 12 parts of APP, 7 parts of tetramethylolmethane, 8 parts of carbamide, aluminium hydroxide 4 Part, 8 parts of antimony oxide, 4 parts of manganese oxide, 2.5 parts of bentonite, 0.7 part of penetrating agent, 0.4 part of synergist;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described environment-friendly novel water-repellent paint, comprises the following steps:
S1:By Hydroxypropyl acrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, calcium hydroxide, Montmorillonite, Pulvis Talci, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, wetting agent, Adhesion promoter, catalyst, initiator mixing, are 135W in microwave power, temperature is 92 DEG C, and rotating speed is under 2800r/min Stirring 2.8h, prepared mixture a;
S2:Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1 Agent, optical brightener, defoamer, viscosifier, are 160W in microwave power, and temperature is 120 DEG C, and rotating speed is to stir 4h under 500r/min, Prepared mixture b;
S3:Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2 Thick dose, coalescents, fire retardant, be 180W in microwave power, temperature be 110 DEG C, rotating speed be 300r/min under stir 3h, be obtained Mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31:APP, 135 parts of water are added in microwave reactor, stirs 7min, system under speed of agitator is for 350r/min Obtain mixture A;
S32:3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31 Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 500r/min in speed of agitator, and microwave power is 160W, and temperature stirs 2.2h, prepared mixture B at being 86 DEG C;
S33:By step S32 be obtained mixture B be cooled to after room temperature, precipitate is filtered, under rotating speed is for 4000r/min from Heart drying to water content is 4%, prepared fire retardant;
S4:The mixture c that step S3 is obtained is melt extruded at 112 DEG C by extruder, and passes through crusher film-making, Lamellar body is obtained after cooling;
S5:The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing;
S6:The pelletizing that step S5 is obtained crosses 150 mesh sieve, prepared environment-friendly novel water-repellent paint after pulverizing.
Embodiment 2
A kind of environment-friendly novel water-repellent paint, in units of weight, including following raw material:104 parts of Hydroxypropyl acrylate, rosin resin 33 parts, 22 parts of tributyl citrate, 15 parts of ethyl methacrylate, 32 parts of aqueous acrylic emulsion, polyacrylamide solution 24 Part, 20 parts of Tissuemat E, 4 parts of calcium hydroxide, 3 parts of montmorillonite, 2 parts of Pulvis Talci, 3 parts of polyester fiber, 3 parts of boron fibre, hydroxypropyl 4 parts of methylcellulose, 2 parts of bamboo carbon fiber, 0.4 part of degasser, 0.5 part of dispersant, wetting agent 0.2-0. part, adhesion promoter 0.3 part, 0.1 part of catalyst, 0.1 part of initiator, hang down 0.3 part of stricture of vagina agent, 0.2 part of toughener, 0.3 part of optical brightener, defoamer 0.4 Part, 0.2 part of viscosifier, 0.8 part of firming agent, 0.2 part of preservative, 0.2 part of antioxidant, 0.1 part of light stabilizer, UV absorbent 0.2 part, 0.3 part of thickening agent, 0.3 part of coalescents, 1.2 parts of fire retardant;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid.(Acrylic acid ethylene glycol)Ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described preservative is Liquid BPF -369;
Described antioxidant is antioxidant AT-330;
Described light stabilizer is light stabilizer HS-3101;
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum;
Described coalescents are Yi Siman coalescents;
Described fire retardant in units of weight portion, including following raw material:14 parts of 3-M2BOL acetass, 2,2- bis- Methyl isophthalic acid, 8 parts of 3- propylidene dimethylacrylate, 9 parts of APP, 4 parts of tetramethylolmethane, 6 parts of carbamide, 2 parts of aluminium hydroxide, 6 parts of antimony oxide, 2 parts of manganese oxide, 2 parts of bentonite, 0.6 part of penetrating agent, 0.3 part of synergist;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described environment-friendly novel water-repellent paint, comprises the following steps:
S1:By Hydroxypropyl acrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, calcium hydroxide, Montmorillonite, Pulvis Talci, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, wetting agent, Adhesion promoter, catalyst, initiator mixing, are 120W in microwave power, temperature is 88 DEG C, and rotating speed is under 2400r/min Stirring 3h, prepared mixture a;
S2:Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1 Agent, optical brightener, defoamer, viscosifier, are 140W in microwave power, and temperature is 115 DEG C, and rotating speed is to stir 5h under 400r/min, Prepared mixture b;
S3:Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2 Thick dose, coalescents, fire retardant, be 130W in microwave power, temperature be 105 DEG C, rotating speed be 200r/min under stir 4h, be obtained Mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31:APP, 120 parts of water are added in microwave reactor, stirs 8min, system under speed of agitator is for 300r/min Obtain mixture A;
S32:3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31 Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 400r/min in speed of agitator, and microwave power is 130W, and temperature stirs 2.5h, prepared mixture B at being 83 DEG C;
S33:By step S32 be obtained mixture B be cooled to after room temperature, precipitate is filtered, under rotating speed is for 3000r/min from Heart drying to water content is 3%, prepared fire retardant;
S4:The mixture c that step S3 is obtained is melt extruded at 108 DEG C by extruder, and passes through crusher film-making, Lamellar body is obtained after cooling;
S5:The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing;
S6:The pelletizing that step S5 is obtained crosses 120 mesh sieve, prepared environment-friendly novel water-repellent paint after pulverizing.
Embodiment 3
A kind of environment-friendly novel water-repellent paint, in units of weight, including following raw material:138 parts of Hydroxypropyl acrylate, rosin resin 59 parts, 38 parts of tributyl citrate, 26 parts of ethyl methacrylate, 48 parts of aqueous acrylic emulsion, polyacrylamide solution 34 Part, 40 parts of Tissuemat E, 8 parts of calcium hydroxide, 6 parts of montmorillonite, 5 parts of Pulvis Talci, 6 parts of polyester fiber, 5 parts of boron fibre, hydroxypropyl 8 parts of methylcellulose, 5 parts of bamboo carbon fiber, 0.8 part of degasser, 0.8 part of dispersant, 0.4 part of wetting agent, adhesion promoter 0.5 Part, 0.3 part of catalyst, 0.2 part of initiator, 0.6 part of stricture of vagina agent of hanging down, 0.5 part of toughener, 0.7 part of optical brightener, 0.6 part of defoamer, increasing 0.3 part of stick, 1.5 parts of firming agent, 0.3 part of preservative, 0.3 part of antioxidant, 0.2 part of light stabilizer, UV absorbent 0.3 Part, 0.6 part of thickening agent, 0.4 part of coalescents, 1.5 parts of fire retardant;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid.(Acrylic acid ethylene glycol)Ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described preservative is Liquid BPF -369;
Described antioxidant is antioxidant AT-330;
Described light stabilizer is light stabilizer HS-3101;
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum;
Described coalescents are Yi Siman coalescents;
Described fire retardant in units of weight portion, including following raw material:22 parts of 3-M2BOL acetass, 2,2- bis- Methyl isophthalic acid, 12 parts of 3- propylidene dimethylacrylate, 15 parts of APP, 10 parts of tetramethylolmethane, 9 parts of carbamide, aluminium hydroxide 5 Part, 10 parts of antimony oxide, 6 parts of manganese oxide, 3 parts of bentonite, 0.8 part of penetrating agent, 0.5 part of synergist;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described environment-friendly novel water-repellent paint, comprises the following steps:
S1:By Hydroxypropyl acrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, calcium hydroxide, Montmorillonite, Pulvis Talci, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, wetting agent, Adhesion promoter, catalyst, initiator mixing, are 150W in microwave power, temperature is 95 DEG C, and rotating speed is under 3000r/min Stirring 2.5h, prepared mixture a;
S2:Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1 Agent, optical brightener, defoamer, viscosifier, are 180W in microwave power, and temperature is 125 DEG C, and rotating speed is to stir 3h under 600r/min, Prepared mixture b;
S3:Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2 Thick dose, coalescents, fire retardant, be 200W in microwave power, temperature be 115 DEG C, rotating speed be 400r/min under stir 2h, be obtained Mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31:APP, 150 parts of water are added in microwave reactor, stirs 5min, system under speed of agitator is for 400r/min Obtain mixture A;
S32:3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31 Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 600r/min in speed of agitator, and microwave power is 180W, and temperature stirs 1.8h, prepared mixture B at being 89 DEG C;
S33:By step S32 be obtained mixture B be cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min from Heart drying to water content is 2%, prepared fire retardant;
S4:The mixture c that step S3 is obtained is melt extruded at 1115 DEG C by extruder, and passes through crusher system Piece, is obtained lamellar body after cooling;
S5:The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing;
S6:The pelletizing that step S5 is obtained crosses 180 mesh sieve, prepared environment-friendly novel water-repellent paint after pulverizing.
The performance indications of the environment-friendly novel water-repellent paint that detection embodiment 1-3 is obtained, result is as shown in the table.
As seen from the above table:The coating of the present invention had both had excellent adhesive force and mechanical property, had excellent water-fast again Property, resistance to ag(e)ing, crack resistance and thermal adaptability, and product nonhazardouss itself, are a kind of rings of excellent combination property Protect waterproof coating.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanations, the affiliated technology neck for the present invention For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, The scope of patent protection that the present invention is determined all should be considered as belonging to by the claims submitted to.

Claims (7)

1. a kind of environment-friendly novel water-repellent paint is it is characterised in that in units of weight, including following raw material:Hydroxypropyl acrylate 104-138 part, rosin resin 33-59 part, tributyl citrate 22-38 part, ethyl methacrylate 15-26 part, aqueous acrylamide Yogurt liquid 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, calcium hydroxide 4-8 part, montmorillonite 3-6 Part, Pulvis Talci 2-5 part, polyester fiber 3-6 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5 part, Degasser 0.4-0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalyst 0.1-0.3 part, initiator 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part, disappear Infusion 0.4-0.6 part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3 Part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part, Fire retardant 1.2-1.5 part;
Described degasser is stearic acid;
Described dispersant is dispersant nc;
Described wetting agent is wetting agent CF-10;
Described adhesion promoter is colourless cobalt;
Described catalyst is platinum catalyst;
Described initiator is azo two isopropylformic acid.(Acrylic acid ethylene glycol)Ester;
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down;
Described toughener is MBS terpolymer;
Described optical brightener is optical brightener LD-608;
Described defoamer is defoamer NXZ;
Described viscosifier are propyl trimethoxy silicane;
Described firming agent is epoxylite;
Described fire retardant in units of weight portion, including following raw material:3-M2BOL acetass 14-22 part, 2, 2- dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9 Part, aluminium hydroxide 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, association Effect agent 0.3-0.5 part;
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate;
The preparation method of described environment-friendly novel water-repellent paint, comprises the following steps:
S1:By Hydroxypropyl acrylate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, calcium hydroxide, Montmorillonite, Pulvis Talci, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, wetting agent, Adhesion promoter, catalyst, initiator mixing, are 120-150W in microwave power, temperature is 88-95 DEG C, and rotating speed is 2400- 2.5-3h, prepared mixture a is stirred under 3000r/min;
S2:Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1 Agent, optical brightener, defoamer, viscosifier, are 140-180W in microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/ 3-5h, prepared mixture b is stirred under min;
S3:Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2 Thick dose, coalescents, fire retardant, be 130-200W in microwave power, temperature be 105-115 DEG C, rotating speed be 200-400r/min Lower stirring 2-4h, prepared mixture c;
The preparation method of described fire retardant, comprises the following steps:
S31:APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is for 300-400r/min 5-8min, prepared mixture A;
S32:3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31 Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent, Synergist, is 400-600r/min in speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8- at being 83-89 DEG C 2.5h, prepared mixture B;
S33:The mixture B that step S32 is obtained is cooled to after room temperature, precipitate is filtered, is 3000-5000r/ in rotating speed Under min, centrifugal drying is to water content≤4%, prepared fire retardant;
S4:The mixture c that step S3 is obtained is melt extruded at 108-115 DEG C by extruder, and passes through crusher Film-making, is obtained lamellar body after cooling;
S5:The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing;
S6:The pelletizing that step S5 is obtained crosses 120-180 mesh sieve, prepared environment-friendly novel water-repellent paint after pulverizing.
2. according to claim 1 environment-friendly novel water-repellent paint it is characterised in that described preservative be Liquid BPF -369.
3. according to claim 1 environment-friendly novel water-repellent paint it is characterised in that described antioxidant be antioxidant AT-330.
4. according to claim 1 environment-friendly novel water-repellent paint it is characterised in that described light stabilizer be light stabilizer HS- 3101.
5. according to claim 1 environment-friendly novel water-repellent paint it is characterised in that described UV absorbent be o-hydroxy Phenyl formate.
6. according to claim 1 environment-friendly novel water-repellent paint it is characterised in that described thickening agent be xanthan gum.
7. according to claim 1 environment-friendly novel water-repellent paint it is characterised in that described coalescents help for Yi Siman film forming Agent.
CN201610812753.1A 2016-09-09 2016-09-09 Environment-friendly novel waterproof paint Pending CN106398438A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236433A (en) * 2017-07-26 2017-10-10 合肥梵腾环保科技有限公司 A kind of novel environment friendly building coating and preparation method thereof
CN108912775A (en) * 2018-06-30 2018-11-30 李晓龙 A kind of novel environment friendly water-repellent paint

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1393485A (en) * 2001-06-29 2003-01-29 大赛璐化学工业株式会社 Flame-retarded polyolefin resin composition
CN104177648A (en) * 2014-08-03 2014-12-03 马晓权 Tire flame retardant
CN104371747A (en) * 2014-09-30 2015-02-25 滁州斯迈特复合材料有限公司 Fire retardant for air-conditioning cabinet
CN104559373A (en) * 2014-12-30 2015-04-29 青建集团股份公司 Waterproof paint for external walls and preparation method of waterproof paint
CN105688360A (en) * 2015-10-29 2016-06-22 陈闽玲 Class-A fire extinguishing agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1393485A (en) * 2001-06-29 2003-01-29 大赛璐化学工业株式会社 Flame-retarded polyolefin resin composition
CN104177648A (en) * 2014-08-03 2014-12-03 马晓权 Tire flame retardant
CN104371747A (en) * 2014-09-30 2015-02-25 滁州斯迈特复合材料有限公司 Fire retardant for air-conditioning cabinet
CN104559373A (en) * 2014-12-30 2015-04-29 青建集团股份公司 Waterproof paint for external walls and preparation method of waterproof paint
CN105688360A (en) * 2015-10-29 2016-06-22 陈闽玲 Class-A fire extinguishing agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236433A (en) * 2017-07-26 2017-10-10 合肥梵腾环保科技有限公司 A kind of novel environment friendly building coating and preparation method thereof
CN108912775A (en) * 2018-06-30 2018-11-30 李晓龙 A kind of novel environment friendly water-repellent paint

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Application publication date: 20170215