CN106398437A - Environment-friendly waterproof coating - Google Patents
Environment-friendly waterproof coating Download PDFInfo
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- CN106398437A CN106398437A CN201610812749.5A CN201610812749A CN106398437A CN 106398437 A CN106398437 A CN 106398437A CN 201610812749 A CN201610812749 A CN 201610812749A CN 106398437 A CN106398437 A CN 106398437A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
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Abstract
The invention discloses an environment-friendly waterproof coating which comprises dioctyl phthalate, rosin resin, tributyl citrate, ethyl methacrylate, waterborne acrylic emulsion, polyacrylamide solution, polyethylene wax, barium sulfate, diatomite, titanium dioxide, polyester fiber, boron fiber, hydroxypropyl methyl cellulose, bamboo charcoal fiber, degassing agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator, pattern dropping agent, toughener, sensitizer, defoamer, tackifier, curing agent, preservative, antioxidant, photostabilizer, ultraviolet absorber, thickener, film forming assistant and flame retardant. The environment-friendly waterproof coating has excellent adhesion, mechanical performance, waterproofness, aging resistance, anti-cracking performance and temperature adaptivity and is harmless, nontoxic and excellent in comprehensive performance.
Description
【Technical field】
The invention belongs to coating preparation technology neck is and in particular to a kind of environment-friendly waterproof paint.
【Background technology】
Water-repellent paint is the material of a kind of liquid or semi liquid state, adopts the construction technology such as brush or spraying on building surface, passes through
Chemical reaction forms a thin film that is continuous, having certain elasticity and thickness, so can resist certain water pressure, from
And reach the purpose of waterproof and moistureproof.Water-repellent paint is a kind of special coating, and its particularity is that coating surface can be formed
One softness, waterproof, the Waterproof structural course of cracking resistance, stop that hydrone permeates externally to basic unit.
Building and structures in use, all can be affected by various natural causes, and build form with
Waterproof position is different, and suffered influence factor is also different.As building roof waterproof layer is exposed in natural environment for a long time, by rain,
The erosion of snow, wind, frost, ultraviolet and air pollutants；Building under ground portion is not only chronically in water environment, but also
The repeated action of differential settlement to be born；And bridge is then intended to bear the alternate stress effect of frequent traffic load.Therefore, use
In the material of buildings waterproof, do not need only have the mechanical property under opposing complex stress effect, also need to be maintained at respectively simultaneously
The lasting stability of combination property under the influence of kind natural cause is long-term.Traditional Novel durable waterproof paint is used for waterproof outside room, easily
Cause aging, dry and cracked, the phenomenon such as deform, fracture；And it is used for the waterproofs such as kitchen, lavatory, tired for complex-shaped place construction
Difficulty, and durability is poor, every few years need to reprocess, and both increased expense, have upset the orthobiosiss of people again.
【Content of the invention】
The present invention provides a kind of environment-friendly waterproof paint, to solve traditional Novel durable waterproof paint for waterproof outside room, easily draws
Rise aging, dry and cracked, the problems such as deform, fracture.The coating of the present invention had both had excellent adhesive force and mechanical property, had excellent again
Good resistance to water, resistance to ag(e)ing, crack resistance and thermal adaptability, and product nonhazardouss itself, are a kind of combination properties
Excellent environment-friendly waterproof paint.
For solving above technical problem, the present invention employs the following technical solutions：
A kind of environment-friendly waterproof paint, in units of weight, including following raw material：Dioctyl phthalate 100-140 part, Colophonium
Resin 30-60 part, tributyl citrate 20-40 part, ethyl methacrylate 15-26 part, aqueous acrylic emulsion 32-48 part,
Polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, barium sulfate 4-8 part, kieselguhr 3-6 part, titanium dioxide 2-5 part,
Polyester fiber 3-6 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5 part, degasser 0.4-0.8
Part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalyst 0.1-0.3 part, initiation
Agent 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part, defoamer 0.4-0.6 part,
Viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3 part, light stabilizer 0.1-
0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part, fire retardant 1.2-1.5
Part；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described fire retardant in units of weight portion, including following raw material：3-M2BOL acetass 14-22 part, 2,
2- dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9
Part, aluminium hydroxide 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, association
Effect agent 0.3-0.5 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described environment-friendly waterproof paint, comprises the following steps：
S1：By dioctyl phthalate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, sulphuric acid
Barium, kieselguhr, titanium dioxide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, profit
Humectant, adhesion promoter, catalyst, initiator mixing, are 120-150W in microwave power, temperature is 88-95 DEG C, rotating speed is
2.5-3h, prepared mixture a is stirred under 2400-3000r/min；
S2：Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1
Agent, optical brightener, defoamer, viscosifier, are 140-180W in microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/
3-5h, prepared mixture b is stirred under min；
S3：Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2
Thick dose, coalescents, fire retardant, be 130-200W in microwave power, temperature be 105-115 DEG C, rotating speed be 200-400r/min
Lower stirring 2-4h, prepared mixture c；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is for 300-400r/min
5-8min, prepared mixture A；
S32：3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent,
Synergist, is 400-600r/min in speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8- at being 83-89 DEG C
2.5h, prepared mixture B；
S33：The mixture B that step S32 is obtained is cooled to after room temperature, precipitate is filtered, is 3000-5000r/ in rotating speed
Under min, centrifugal drying is to water content≤4%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 108-115 DEG C by extruder, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 120-180 mesh sieve, prepared environment-friendly waterproof paint after pulverizing.
Further, described preservative is Liquid BPF -369.
Further, described antioxidant is antioxidant AT-330.
Further, described light stabilizer is light stabilizer HS-3101.
Further, described UV absorbent is oxybenzoic acid phenyl ester.
Further, described thickening agent is xanthan gum.
Further, described coalescents are Yi Siman coalescents.
The invention has the advantages that：
（1）The coating of the present invention had both had excellent adhesive force and mechanical property, have again excellent resistance to water, resistance to ag(e)ing,
Crack resistance and thermal adaptability, and product nonhazardouss itself, are a kind of environment-friendly waterproof paints of excellent combination property；
（2）The environment-friendly waterproof paint of the present invention has weatherability, is widely used in the open air such as guardrail, Men Ye, aluminium section bar metal watch
Face application.
【Specific embodiment】
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the protection of the present invention
Scope, but do not limit the scope of the invention.
In an embodiment, described environment-friendly waterproof paint, in units of weight, including following raw material：Phthalic acid two is pungent
Ester 100-140 part, rosin resin 30-60 part, tributyl citrate 20-40 part, ethyl methacrylate 15-26 part, aqueouss third
Olefin(e) acid emulsion 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, barium sulfate 4-8 part, kieselguhr 3-6
Part, titanium dioxide 2-5 part, polyester fiber 3-6 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5
Part, degasser 0.4-0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalysis
Agent 0.1-0.3 part, initiator 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part,
Defoamer 0.4-0.6 part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3
Part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part,
Fire retardant 1.2-1.5 part；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：3-M2BOL acetass 14-22 part, 2,
2- dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9
Part, aluminium hydroxide 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, association
Effect agent 0.3-0.5 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described environment-friendly waterproof paint, comprises the following steps：
S1：By dioctyl phthalate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, sulphuric acid
Barium, kieselguhr, titanium dioxide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, profit
Humectant, adhesion promoter, catalyst, initiator mixing, are 120-150W in microwave power, temperature is 88-95 DEG C, rotating speed is
2.5-3h, prepared mixture a is stirred under 2400-3000r/min；
S2：Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1
Agent, optical brightener, defoamer, viscosifier, are 140-180W in microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/
3-5h, prepared mixture b is stirred under min；
S3：Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2
Thick dose, coalescents, fire retardant, be 130-200W in microwave power, temperature be 105-115 DEG C, rotating speed be 200-400r/min
Lower stirring 2-4h, prepared mixture c；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is for 300-400r/min
5-8min, prepared mixture A；
S32：3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent,
Synergist, is 400-600r/min in speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8- at being 83-89 DEG C
2.5h, prepared mixture B；
S33：The mixture B that step S32 is obtained is cooled to after room temperature, precipitate is filtered, is 3000-5000r/ in rotating speed
Under min, centrifugal drying is to water content≤4%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 108-115 DEG C by extruder, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 120-180 mesh sieve, prepared environment-friendly waterproof paint after pulverizing.
Embodiment 1
A kind of environment-friendly waterproof paint, in units of weight, including following raw material：120 parts of dioctyl phthalate, rosin resin
45 parts, 30 parts of tributyl citrate, 20 parts of ethyl methacrylate, 40 parts of aqueous acrylic emulsion, polyacrylamide solution 30
Part, 30 parts of Tissuemat E, 6 parts of barium sulfate, 5 parts of kieselguhr, 4 parts of titanium dioxide, 5 parts of polyester fiber, 4 parts of boron fibre, hydroxypropyl
6 parts of methylcellulose, 4 parts of bamboo carbon fiber, 0.6 part of degasser, 0.7 part of dispersant, 0.3 part of wetting agent, adhesion promoter 0.4
Part, 0.2 part of catalyst, 0.1 part of initiator, 0.5 part of stricture of vagina agent of hanging down, 0.4 part of toughener, 0.5 part of optical brightener, 0.5 part of defoamer, increasing
0.2 part of stick, 1.2 parts of firming agent, 0.2 part of preservative, 0.2 part of antioxidant, 0.1 part of light stabilizer, UV absorbent 0.2
Part, 0.5 part of thickening agent, 0.3 part of coalescents, 1.4 parts of fire retardant；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：18 parts of 3-M2BOL acetass, 2,2- bis-
Methyl isophthalic acid, 10 parts of 3- propylidene dimethylacrylate, 12 parts of APP, 7 parts of tetramethylolmethane, 8 parts of carbamide, aluminium hydroxide 4
Part, 8 parts of antimony oxide, 4 parts of manganese oxide, 2.5 parts of bentonite, 0.7 part of penetrating agent, 0.4 part of synergist；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described environment-friendly waterproof paint, comprises the following steps：
S1：By dioctyl phthalate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, sulphuric acid
Barium, kieselguhr, titanium dioxide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, profit
Humectant, adhesion promoter, catalyst, initiator mixing, are 135W in microwave power, temperature is 92 DEG C, and rotating speed is 2800r/
2.8h, prepared mixture a is stirred under min；
S2：Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1
Agent, optical brightener, defoamer, viscosifier, are 160W in microwave power, and temperature is 120 DEG C, and rotating speed is to stir 4h under 500r/min,
Prepared mixture b；
S3：Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2
Thick dose, coalescents, fire retardant, be 180W in microwave power, temperature be 110 DEG C, rotating speed be 300r/min under stir 3h, be obtained
Mixture c；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, 135 parts of water are added in microwave reactor, stirs 7min, system under speed of agitator is for 350r/min
Obtain mixture A；
S32：3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent,
Synergist, is 500r/min in speed of agitator, and microwave power is 160W, and temperature stirs 2.2h, prepared mixture B at being 86 DEG C；
S33：By step S32 be obtained mixture B be cooled to after room temperature, precipitate is filtered, under rotating speed is for 4000r/min from
Heart drying to water content is 4%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 112 DEG C by extruder, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 150 mesh sieve, prepared environment-friendly waterproof paint after pulverizing.
Embodiment 2
A kind of environment-friendly waterproof paint, in units of weight, including following raw material：100 parts of dioctyl phthalate, rosin resin
30 parts, 20 parts of tributyl citrate, 15 parts of ethyl methacrylate, 32 parts of aqueous acrylic emulsion, polyacrylamide solution 24
Part, 20 parts of Tissuemat E, 4 parts of barium sulfate, 3 parts of kieselguhr, 2 parts of titanium dioxide, 3 parts of polyester fiber, 3 parts of boron fibre, hydroxypropyl
4 parts of methylcellulose, 2 parts of bamboo carbon fiber, 0.4 part of degasser, 0.5 part of dispersant, wetting agent 0.2-0. part, adhesion promoter
0.3 part, 0.1 part of catalyst, 0.1 part of initiator, hang down 0.3 part of stricture of vagina agent, 0.2 part of toughener, 0.3 part of optical brightener, defoamer 0.4
Part, 0.2 part of viscosifier, 0.8 part of firming agent, 0.2 part of preservative, 0.2 part of antioxidant, 0.1 part of light stabilizer, UV absorbent
0.2 part, 0.3 part of thickening agent, 0.3 part of coalescents, 1.2 parts of fire retardant；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：14 parts of 3-M2BOL acetass, 2,2- bis-
Methyl isophthalic acid, 8 parts of 3- propylidene dimethylacrylate, 9 parts of APP, 4 parts of tetramethylolmethane, 6 parts of carbamide, 2 parts of aluminium hydroxide,
6 parts of antimony oxide, 2 parts of manganese oxide, 2 parts of bentonite, 0.6 part of penetrating agent, 0.3 part of synergist；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described environment-friendly waterproof paint, comprises the following steps：
S1：By dioctyl phthalate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, sulphuric acid
Barium, kieselguhr, titanium dioxide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, profit
Humectant, adhesion promoter, catalyst, initiator mixing, are 120W in microwave power, temperature is 88 DEG C, and rotating speed is 2400r/
3h, prepared mixture a is stirred under min；
S2：Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1
Agent, optical brightener, defoamer, viscosifier, are 140W in microwave power, and temperature is 115 DEG C, and rotating speed is to stir 5h under 400r/min,
Prepared mixture b；
S3：Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2
Thick dose, coalescents, fire retardant, be 130W in microwave power, temperature be 105 DEG C, rotating speed be 200r/min under stir 4h, be obtained
Mixture c；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, 120 parts of water are added in microwave reactor, stirs 8min, system under speed of agitator is for 300r/min
Obtain mixture A；
S32：3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent,
Synergist, is 400r/min in speed of agitator, and microwave power is 130W, and temperature stirs 2.5h, prepared mixture B at being 83 DEG C；
S33：By step S32 be obtained mixture B be cooled to after room temperature, precipitate is filtered, under rotating speed is for 3000r/min from
Heart drying to water content is 3%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 108 DEG C by extruder, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 120 mesh sieve, prepared environment-friendly waterproof paint after pulverizing.
Embodiment 3
A kind of environment-friendly waterproof paint, in units of weight, including following raw material：140 parts of dioctyl phthalate, rosin resin
60 parts, 40 parts of tributyl citrate, 26 parts of ethyl methacrylate, 48 parts of aqueous acrylic emulsion, polyacrylamide solution 34
Part, 40 parts of Tissuemat E, 8 parts of barium sulfate, 6 parts of kieselguhr, 5 parts of titanium dioxide, 6 parts of polyester fiber, 5 parts of boron fibre, hydroxypropyl
8 parts of methylcellulose, 5 parts of bamboo carbon fiber, 0.8 part of degasser, 0.8 part of dispersant, 0.4 part of wetting agent, adhesion promoter 0.5
Part, 0.3 part of catalyst, 0.2 part of initiator, 0.6 part of stricture of vagina agent of hanging down, 0.5 part of toughener, 0.7 part of optical brightener, 0.6 part of defoamer, increasing
0.3 part of stick, 1.5 parts of firming agent, 0.3 part of preservative, 0.3 part of antioxidant, 0.2 part of light stabilizer, UV absorbent 0.3
Part, 0.6 part of thickening agent, 0.4 part of coalescents, 1.5 parts of fire retardant；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester
Described thickening agent is xanthan gum；
Described coalescents are Yi Siman coalescents；
Described fire retardant in units of weight portion, including following raw material：22 parts of 3-M2BOL acetass, 2,2- bis-
Methyl isophthalic acid, 12 parts of 3- propylidene dimethylacrylate, 15 parts of APP, 10 parts of tetramethylolmethane, 9 parts of carbamide, aluminium hydroxide 5
Part, 10 parts of antimony oxide, 6 parts of manganese oxide, 3 parts of bentonite, 0.8 part of penetrating agent, 0.5 part of synergist；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described environment-friendly waterproof paint, comprises the following steps：
S1：By dioctyl phthalate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, sulphuric acid
Barium, kieselguhr, titanium dioxide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, profit
Humectant, adhesion promoter, catalyst, initiator mixing, are 150W in microwave power, temperature is 95 DEG C, and rotating speed is 3000r/
2.5h, prepared mixture a is stirred under min；
S2：Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1
Agent, optical brightener, defoamer, viscosifier, are 180W in microwave power, and temperature is 125 DEG C, and rotating speed is to stir 3h under 600r/min,
Prepared mixture b；
S3：Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2
Thick dose, coalescents, fire retardant, be 200W in microwave power, temperature be 115 DEG C, rotating speed be 400r/min under stir 2h, be obtained
Mixture c；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, 150 parts of water are added in microwave reactor, stirs 5min, system under speed of agitator is for 400r/min
Obtain mixture A；
S32：3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent,
Synergist, is 600r/min in speed of agitator, and microwave power is 180W, and temperature stirs 1.8h, prepared mixture B at being 89 DEG C；
S33：By step S32 be obtained mixture B be cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min from
Heart drying to water content is 2%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 1115 DEG C by extruder, and passes through crusher system
Piece, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 180 mesh sieve, prepared environment-friendly waterproof paint after pulverizing.
The performance indications of the environment-friendly waterproof paint that detection embodiment 1-3 is obtained, result is as shown in the table.
As seen from the above table：The coating of the present invention had both had excellent adhesive force and mechanical property, had excellent water-fast again
Property, resistance to ag(e)ing, crack resistance and thermal adaptability, and product nonhazardouss itself, are a kind of rings of excellent combination property
Protect water-repellent paint.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanations, the affiliated technology neck for the present invention
For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made,
The scope of patent protection that the present invention is determined all should be considered as belonging to by the claims submitted to.
Claims (7)
1. a kind of environment-friendly waterproof paint is it is characterised in that in units of weight, including following raw material：Dioctyl phthalate
100-140 part, rosin resin 30-60 part, tributyl citrate 20-40 part, ethyl methacrylate 15-26 part, aqueous acrylamide
Yogurt liquid 32-48 part, polyacrylamide solution 24-34 part, Tissuemat E 20-40 part, barium sulfate 4-8 part, kieselguhr 3-6 part,
Titanium dioxide 2-5 part, polyester fiber 3-6 part, boron fibre 3-5 part, hydroxypropyl methyl cellulose 4-8 part, bamboo carbon fiber 2-5 part,
Degasser 0.4-0.8 part, dispersant 0.5-0.8 part, wetting agent 0.2-0.4 part, adhesion promoter 0.3-0.5 part, catalyst
0.1-0.3 part, initiator 0.1-0.2 part, hang down stricture of vagina agent 0.3-0.6 part, toughener 0.2-0.5 part, optical brightener 0.3-0.7 part, disappear
Infusion 0.4-0.6 part, viscosifier 0.2-0.3 part, firming agent 0.8-1.5 part, preservative 0.2-0.3 part, antioxidant 0.2-0.3
Part, light stabilizer 0.1-0.2 part, UV absorbent 0.2-0.3 part, thickening agent 0.3-0.6 part, coalescents 0.3-0.4 part,
Fire retardant 1.2-1.5 part；
Described degasser is stearic acid；
Described dispersant is dispersant nc；
Described wetting agent is wetting agent CF-10；
Described adhesion promoter is colourless cobalt；
Described catalyst is platinum catalyst；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is the stricture of vagina agent HM-2 that hangs down；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer NXZ；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is epoxylite；
Described fire retardant in units of weight portion, including following raw material：3-M2BOL acetass 14-22 part, 2,
2- dimethyl-trimethylene dimethylacrylate 8-12 part, APP 9-15 part, tetramethylolmethane 4-10 part, carbamide 6-9
Part, aluminium hydroxide 2-5 part, antimony oxide 6-10 part, manganese oxide 2-6 part, bentonite 2-3 part, penetrating agent 0.6-0.8 part, association
Effect agent 0.3-0.5 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described environment-friendly waterproof paint, comprises the following steps：
S1：By dioctyl phthalate, rosin resin, tributyl citrate, ethyl methacrylate, Tissuemat E, sulphuric acid
Barium, kieselguhr, titanium dioxide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, bamboo carbon fiber, degasser, dispersant, profit
Humectant, adhesion promoter, catalyst, initiator mixing, are 120-150W in microwave power, temperature is 88-95 DEG C, rotating speed is
2.5-3h, prepared mixture a is stirred under 2400-3000r/min；
S2：Aqueous acrylic emulsion, polyacrylamide solution, the stricture of vagina agent, toughness reinforcing of hanging down is added in the mixture a being obtained to step S1
Agent, optical brightener, defoamer, viscosifier, are 140-180W in microwave power, and temperature is 115-125 DEG C, and rotating speed is 400-600r/
3-5h, prepared mixture b is stirred under min；
S3：Firming agent, preservative, antioxidant, light stabilizer, ultraviolet absorber, increasing is added in the mixture b being obtained to step S2
Thick dose, coalescents, fire retardant, be 130-200W in microwave power, temperature be 105-115 DEG C, rotating speed be 200-400r/min
Lower stirring 2-4h, prepared mixture c；
The preparation method of described fire retardant, comprises the following steps：
S31：APP, water 120-150 part are added in microwave reactor, stirs under speed of agitator is for 300-400r/min
5-8min, prepared mixture A；
S32：3-M2BOL acetass, 2,2- dimethyl -1,3- is added in the mixture A being obtained to step S31
Propylidene dimethylacrylate, tetramethylolmethane, carbamide, aluminium hydroxide, antimony oxide, manganese oxide, bentonite, penetrating agent,
Synergist, is 400-600r/min in speed of agitator, and microwave power is 130-180W, and temperature stirs 1.8- at being 83-89 DEG C
2.5h, prepared mixture B；
S33：The mixture B that step S32 is obtained is cooled to after room temperature, precipitate is filtered, is 3000-5000r/ in rotating speed
Under min, centrifugal drying is to water content≤4%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 108-115 DEG C by extruder, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 120-180 mesh sieve, prepared environment-friendly waterproof paint after pulverizing.
2. according to claim 1 environment-friendly waterproof paint it is characterised in that described preservative be Liquid BPF -369.
3. according to claim 1 environment-friendly waterproof paint it is characterised in that described antioxidant be antioxidant AT-330.
4. according to claim 1 environment-friendly waterproof paint it is characterised in that described light stabilizer be light stabilizer HS-3101.
5. according to claim 1 environment-friendly waterproof paint it is characterised in that described UV absorbent be oxybenzoic acid
Phenyl ester.
6. according to claim 1 environment-friendly waterproof paint it is characterised in that described thickening agent be xanthan gum.
7. according to claim 1 environment-friendly waterproof paint it is characterised in that described coalescents be Yi Siman coalescents.
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|---|---|---|---|
| CN201610812749.5A CN106398437A (en) | 2016-09-09 | 2016-09-09 | Environment-friendly waterproof coating |
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| CN201610812749.5A CN106398437A (en) | 2016-09-09 | 2016-09-09 | Environment-friendly waterproof coating |
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| CN108084871A (en) * | 2017-11-26 | 2018-05-29 | 长沙无道工业设计有限公司 | Environment protection oil paint |
| CN109133759A (en) * | 2018-06-29 | 2019-01-04 | 天峨县宏昌农机专业合作社 | A kind of water-repellent paint and preparation method thereof |
| CN109796875A (en) * | 2018-12-28 | 2019-05-24 | 苏州市姑苏新型建材有限公司 | Aqueous non-bituminous uncured water-repellent paint of base of one kind and preparation method thereof |
| CN111945015A (en) * | 2020-07-08 | 2020-11-17 | 江苏海云花新材料有限公司 | Non-weight loss clay refining agent |
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| CN104559373A (en) * | 2014-12-30 | 2015-04-29 | 青建集团股份公司 | Waterproof paint for external walls and preparation method of waterproof paint |
| CN105688360A (en) * | 2015-10-29 | 2016-06-22 | 陈闽玲 | Class-A fire extinguishing agent |
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| CN1393485A (en) * | 2001-06-29 | 2003-01-29 | 大赛璐化学工业株式会社 | Flame-retarded polyolefin resin composition |
| CN104177648A (en) * | 2014-08-03 | 2014-12-03 | 马晓权 | Tire flame retardant |
| CN104371747A (en) * | 2014-09-30 | 2015-02-25 | 滁州斯迈特复合材料有限公司 | Fire retardant for air-conditioning cabinet |
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| CN108084871A (en) * | 2017-11-26 | 2018-05-29 | 长沙无道工业设计有限公司 | Environment protection oil paint |
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| CN109133759A (en) * | 2018-06-29 | 2019-01-04 | 天峨县宏昌农机专业合作社 | A kind of water-repellent paint and preparation method thereof |
| CN109796875A (en) * | 2018-12-28 | 2019-05-24 | 苏州市姑苏新型建材有限公司 | Aqueous non-bituminous uncured water-repellent paint of base of one kind and preparation method thereof |
| CN111945015A (en) * | 2020-07-08 | 2020-11-17 | 江苏海云花新材料有限公司 | Non-weight loss clay refining agent |
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