CN106833232A - Environmentally friendly diatom ooze coating and preparation method thereof - Google Patents
Environmentally friendly diatom ooze coating and preparation method thereof Download PDFInfo
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- CN106833232A CN106833232A CN201710079940.8A CN201710079940A CN106833232A CN 106833232 A CN106833232 A CN 106833232A CN 201710079940 A CN201710079940 A CN 201710079940A CN 106833232 A CN106833232 A CN 106833232A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of environmentally friendly diatom ooze coating, including following percentage component：Modification infusorial earth 15% 25%, sodium alginate 0.3% 0.8%, modified starch 10% 22%, emulsion 15% 23%, Nano titanium dioxide 6% 13%, talcum powder 5% 12%, dispersant 0.5% 2.5%, balance of water.Also disclose the preparation method of environmentally friendly diatom ooze coating.The environmentally friendly diatom ooze coating that the present invention is provided is using sodium alginate is come film forming ability enhancing toughness, anti-riot anticracking and improves glossiness, and use modified starch pollution-free as thickener health, Formaldehyde decomposition rate is up to 90% and discharges negative aeroion simultaneously, environment protection health nonhazardous, it is highly suitable for the place that study, infant room, kindergarten and nursing homes etc. want absolute altitude to environmental protection, it is applied widely.
Description
Technical field
The present invention relates to decorative paint technical field, more particularly to a kind of environmentally friendly diatom ooze coating and preparation method thereof.
Background technology
Diatom ooze is the green inner wall decoration wall material with diatomite as main raw material(s), and diatomite is used as a kind of natural material
Material, without harmful chemical, except with non-ignitable, sound insulation, waterproof, it is lightweight and heat-insulated the features such as in addition to, also dehumidify, remove
It is smelly, absorb formaldehyde, decomposing formaldehyde and the effect such as purify the air of a room, with reference to construction technology, can also be formed come in every shape, texture it is strong
Decorative effect, be excellent environment-friendly type indoor and outdoor decoration material.It is only ornamental very well due to diatom ooze health environment-friendly,
Also there is feature, be the house decorative material of new generation for substituting wallpaper and emulsion paint, the scope of application is very extensive.Can be useful in
Following place：Family's (parlor, bedroom, study, infant room, smallpox etc. metope), apartment, kindergarten, nursing homes, hospital, treatment
Support institute, club, theme club, high-grade restaurant, Resort Hotel, office building, style dining room etc..Current diatom ooze product is more
It is powdered trowelling product, constructs complex.
Interiro wall latex paint has that easy construction, color selection are abundant, surface is smooth, it is easy to maintain the features such as.But it is breathed freely
Easy swelling and cracking when property difference causes wall internal wetted under high humidity environment.
Using diatomite as major function filler, the liquid diatom ooze coating product of similar emulsion paint is made, is keeping work(
While energy property, make its easy construction, overcome the shortcomings of trowelling product.Diatom ooze has many in itself without any pollution
Function is planted, is that the traditional decoration material such as emulsion paint and wallpaper is incomparable.
The content of the invention
It is an object of the invention to provide a kind of mould proof release negative aeroion of energy damping, purifying formaldehyde rate environmentally friendly diatom high
Slime paint is solving the deficiencies in the prior art.
The present invention is achieved through the following technical solutions goal of the invention：
Environmentally friendly diatom ooze coating, including following percentage component：Modification infusorial earth 15%-25%, sodium alginate
0.3%-0.8%, modified starch 10%-22%, emulsion 15%-23%, Nano titanium dioxide 6%-13%, talcum powder 5%-
12%, dispersant 0.5%-2.5%, balance of water.
Further, including following percentage component：Modification infusorial earth 25%, sodium alginate 0.5%, modified starch
15%, emulsion 20%, Nano titanium dioxide 10%, talcum powder 8%, dispersant 1.5% and purified water 20%, sodium alginate tool
There is the ability of gel and film forming, enhancing toughness, anti-riot anticracking can be played a part of, improve glossiness and feel.
Further, the dioxide-containing silica in the diatomite is 88%-95%, and average grain diameter is 0.05mm, energy
Enough retain the microcellular structure of diatomite itself, play a part of abundant damping and absorb decomposing formaldehyde.
Further, the emulsion is one or more of pure-acrylic emulsion, silicone acrylic emulsion or acrylate and vinyl acetate emulsion, thus, makes silicon
Algae slime paint has good film forming, not dry linting after upper wall.
Further, the talcum powder is food grade talc powder, and mesh number is 1250 mesh, 1500 mesh or 2000 mesh, thus, energy
The covering power of coating is enough improved, improves denseness, durability, permeability, scrub resistance, stain resistance and the gloss retention of coating
Deng.
Further, the modified starch is in modified wheat starch, modified corn starch or modified potato starch
Kind, modified starch be on the basis of the inherent characteristic that native starch has, introduced on starch molecule new functional group or
Change starch molecule size and starch granular property, thickening, healthy nonhazardous are played a part of instead of traditional thickener.
Further, the dispersant is one or more in polyacrylate, polycarboxylate or polyphosphate.
It is a further object of the present invention to provide the preparation method of above-mentioned environmentally friendly diatom ooze coating, comprise the following steps：By sea
Mosanom, dispersant and water mixing after add agitator tank in, low whipping speed be 500-800r/min rotating speeds under stir 3-5min,
Modification infusorial earth, Nano titanium dioxide and talcum powder are added in stirring 25-30min under the rotating speed of 2500-3000r/min,
Modified starch and emulsion are subsequently adding in 10-15min is stirred under the rotating speed of 1200-1500r/min, environmental protection is obtained after stirring
Diatom ooze coating.
Its advantage is the environmentally friendly diatom ooze coating that the present invention is provided compared with prior art：Using sodium alginate come into
Film can strengthen toughness, anti-riot anticracking and improve glossiness, and use modified starch pollution-free as thickener health, while passing through
Adjustment and control preparation process each technological parameter, make product excellent, Formaldehyde decomposition rate up to 90% and discharge air bear
Ion, environment protection health nonhazardous.
Specific embodiment
Design of the invention is described in further detail with reference to specific embodiment.
Embodiment 1
Environmentally friendly diatom ooze coating, including following percentage component：Modification infusorial earth 25%, sodium alginate 0.5% is modified
Cornstarch 15%, pure-acrylic emulsion 20%, Nano titanium dioxide 10%, 1250 mesh talcum powder 8%, polyacrylate 1.5%
With purified water 20%.
Added after sodium alginate, polyacrylate and purified water are mixed in agitator tank, low whipping speed is 600r/min
5min is stirred under rotating speed, modification infusorial earth, Nano titanium dioxide and 1250 mesh talcum powder is added in the rotating speed of 2500r/min
Lower stirring 30min, is subsequently adding modified starch and emulsion in 13min is stirred under the rotating speed of 1200r/min, is obtained after stirring
Environmentally friendly diatom ooze coating.
Embodiment 2
Environmentally friendly diatom ooze coating, including following percentage component：Modification infusorial earth 20%, sodium alginate 0.6% is modified
Wheaten starch 20%, silicone acrylic emulsion 15%, Nano titanium dioxide 10%, 1500 mesh talcum powder 10%, polycarboxylate 2% is remaining
It is water to measure.Dioxide-containing silica in diatomite is 70%-80%, and average grain diameter is 0.05mm.
Added after sodium alginate, polycarboxylate and purified water are mixed in agitator tank, low whipping speed turns for 500r/min
The lower stirring 5min of speed, adds modification infusorial earth, Nano titanium dioxide and 1500 mesh talcum powder under the rotating speed of 3000r/min
Stirring 25min, is subsequently adding modified wheat starch and silicone acrylic emulsion in 15min is stirred under the rotating speed of 1500r/min, stirs
Environmental protection diatom ooze coating is obtained afterwards.
Embodiment 3
Modification infusorial earth 18%, sodium alginate 0.5%, be modified potato starch 22%, acrylate and vinyl acetate emulsion 23%, nanoscale dioxy
Change titanium 11%, 2000 mesh talcum powder 8%, polyphosphate 2.5%, balance of water.
Added after sodium alginate, polyphosphate and water are mixed in agitator tank, low whipping speed is 800r/min rotating speeds
Lower stirring 3min, adds modification infusorial earth, Nano titanium dioxide and 2000 mesh talcum powder and is stirred under the rotating speed of 2500r/min
26min is mixed, modified potato starch and acrylate and vinyl acetate emulsion is subsequently adding in stirring 13min under the rotating speed of 1400r/min, after stirring
Environmental protection diatom ooze coating is obtained.
Embodiment 4
Modification infusorial earth 15%, sodium alginate 0.8%, modified corn starch 22%, emulsion 23%, Nano titanium dioxide
12%, 1500 mesh talcum powder 12%, polycarboxylate 2%, balance of water.
Added after sodium alginate, polycarboxylate and water are mixed in agitator tank, low whipping speed is under 600r/min rotating speeds
Stirring 5min, adds modification infusorial earth, Nano titanium dioxide and 1500 mesh talcum powder in stirring under the rotating speed of 2800r/min
25min, is subsequently adding modified corn starch and acrylate and vinyl acetate emulsion in 13min is stirred under the rotating speed of 1400r/min, is made after stirring
Obtain environmentally friendly diatom ooze coating.
Following performance will be carried out as obtained in embodiment 1-4 in 4 groups of environmentally friendly diatom ooze coating feeding national building materials centers
Test, successively with reference to JC/T2082-2011《Humidity conditioning function interior architecture ornament materials》, JC/T1074-2008《Indoor air cleaning
Change material function coating material purifying property》, JC/T2177-2013《Silicon bath mud decoration wall material》Marked with JC/T2110-2012 etc.
Standard is tested following performance, and result of the test is shown in Table 1：
Table 1
The obtained environmental protection diatom ooze coating of the present invention has good humidity, purifying formaldehyde rate as can be seen from Table 1
Up to 90%, while having fungicidal properties, negative aeroion can be largely discharged in addition reaches air-anion concentration
1448Ison/cm3, the release concentration of negative aeroion when being significantly larger than out blank cabin.
Above-described is only some embodiments of the present invention.For the person of ordinary skill of the art, not
On the premise of departing from the invention design, various modifications and improvements can be made, these belong to protection model of the invention
Enclose.
Claims (8)
1. environmentally friendly diatom ooze coating, it is characterised in that the component including following percentage：Modification infusorial earth 15%-25%, marine alga
Sour sodium 0.3%-0.8%, modified starch 10%-22%, emulsion 15%-23%, Nano titanium dioxide 6%-13%, talcum powder
5%-12%, dispersant 0.5%-2.5%, balance of water.
2. environmentally friendly diatom ooze coating according to claim 1, it is characterised in that the component including following percentage：It is modified
Diatomite 25%, sodium alginate 0.5%, modified starch 15%, emulsion 20%, Nano titanium dioxide 10%, talcum powder 8%,
Dispersant 1.5% and purified water 20%.
3. environmentally friendly diatom ooze coating according to claim 1, it is characterised in that the silica in the diatomite contains
It is 88%-95% to measure, and average grain diameter is 0.05mm.
4. environmentally friendly diatom ooze coating according to claim 1, it is characterised in that the emulsion is pure-acrylic emulsion, the breast of silicon third
One or more of liquid or acrylate and vinyl acetate emulsion.
5. environmentally friendly diatom ooze coating according to claim 1, it is characterised in that the talcum powder is food grade talc powder,
Mesh number is 1250 mesh, 1500 mesh or 2000 mesh.
6. environmentally friendly diatom ooze coating according to claim 1, it is characterised in that the modified starch is that modified wheat forms sediment
One kind in powder, modified corn starch or modified potato starch.
7. environmentally friendly diatom ooze coating according to claim 1, it is characterised in that the dispersant is polyacrylate, poly-
One or more in carboxylate or polyphosphate.
8. the preparation method of the environmentally friendly diatom ooze coating according to claim any one of 1-7, it is characterised in that including following
Step：By sodium alginate, dispersant and water mixing after add agitator tank in, low whipping speed be 500-800r/min rotating speeds under stir
3-5min is mixed, modification infusorial earth, Nano titanium dioxide and talcum powder is added in stirring under the rotating speed of 2500-3000r/min
25-30min, is subsequently adding modified starch and emulsion in 10-15min is stirred under the rotating speed of 1200-1500r/min, stirs
Environmental protection diatom ooze coating is obtained afterwards.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710079940.8A CN106833232A (en) | 2017-02-15 | 2017-02-15 | Environmentally friendly diatom ooze coating and preparation method thereof |
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| CN201710079940.8A CN106833232A (en) | 2017-02-15 | 2017-02-15 | Environmentally friendly diatom ooze coating and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108191303A (en) * | 2018-02-10 | 2018-06-22 | 吴刚 | It is a kind of except the preparation method of the fungi-proofing diatom ooze of formaldehyde type |
| CN108329761A (en) * | 2018-01-26 | 2018-07-27 | 德马科起重机械有限公司 | One kind removing formaldehyde diatom ooze indoor decorative paint |
| CN109321067A (en) * | 2018-10-19 | 2019-02-12 | 华夏创美(北京）科技有限公司 | A kind of preparation for removing decomposing formaldehyde |
| CN109722099A (en) * | 2018-12-28 | 2019-05-07 | 徐州众恒淀粉科技有限公司 | A kind of preparation method of the environmentally friendly diatom ooze coating compound by converted starch |
| CN112759954A (en) * | 2021-03-02 | 2021-05-07 | 深圳市海龟梦新能源科技环保材料有限公司 | Environment-friendly diatom ooze exterior wall coating and preparation method thereof |
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| CN103865335A (en) * | 2014-04-01 | 2014-06-18 | 天津银塔实业有限公司 | Wall paint and preparation method thereof |
| CN105131739A (en) * | 2015-09-01 | 2015-12-09 | 天长市银狐漆业有限公司 | Environment-friendly humidifying diatom ooze coating |
| CN105131774A (en) * | 2015-09-06 | 2015-12-09 | 天长市银狐漆业有限公司 | Multifunctional inner wall paint |
| CN105176216A (en) * | 2015-10-13 | 2015-12-23 | 北京大津硅藻新材料股份有限公司 | Diatom ooze coating and preparation method thereof |
| CN105368164A (en) * | 2015-12-21 | 2016-03-02 | 上海鎏彩建材科技股份有限公司 | Plant ecological interior wall coating and preparation method thereof |
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| CN103865335A (en) * | 2014-04-01 | 2014-06-18 | 天津银塔实业有限公司 | Wall paint and preparation method thereof |
| CN105131739A (en) * | 2015-09-01 | 2015-12-09 | 天长市银狐漆业有限公司 | Environment-friendly humidifying diatom ooze coating |
| CN105131774A (en) * | 2015-09-06 | 2015-12-09 | 天长市银狐漆业有限公司 | Multifunctional inner wall paint |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329761A (en) * | 2018-01-26 | 2018-07-27 | 德马科起重机械有限公司 | One kind removing formaldehyde diatom ooze indoor decorative paint |
| CN108191303A (en) * | 2018-02-10 | 2018-06-22 | 吴刚 | It is a kind of except the preparation method of the fungi-proofing diatom ooze of formaldehyde type |
| CN109321067A (en) * | 2018-10-19 | 2019-02-12 | 华夏创美(北京）科技有限公司 | A kind of preparation for removing decomposing formaldehyde |
| CN109722099A (en) * | 2018-12-28 | 2019-05-07 | 徐州众恒淀粉科技有限公司 | A kind of preparation method of the environmentally friendly diatom ooze coating compound by converted starch |
| CN112759954A (en) * | 2021-03-02 | 2021-05-07 | 深圳市海龟梦新能源科技环保材料有限公司 | Environment-friendly diatom ooze exterior wall coating and preparation method thereof |
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Application publication date: 20170613 |