CN106823362A - A kind of carbon nano fluorescent water bullet - Google Patents
A kind of carbon nano fluorescent water bullet Download PDFInfo
- Publication number
- CN106823362A CN106823362A CN201710032836.3A CN201710032836A CN106823362A CN 106823362 A CN106823362 A CN 106823362A CN 201710032836 A CN201710032836 A CN 201710032836A CN 106823362 A CN106823362 A CN 106823362A
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- China
- Prior art keywords
- water
- water bullet
- liquid
- quantum dot
- bullet
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 117
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 23
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000007788 liquid Substances 0.000 claims abstract description 39
- 239000012153 distilled water Substances 0.000 claims abstract description 15
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 14
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims abstract description 11
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229940041616 menthol Drugs 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 4
- 239000000243 solution Substances 0.000 claims description 25
- 238000004043 dyeing Methods 0.000 claims description 15
- 238000004140 cleaning Methods 0.000 claims description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 8
- 238000007654 immersion Methods 0.000 claims description 7
- 239000011259 mixed solution Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000003643 water by type Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000003517 fume Substances 0.000 claims description 4
- 235000015205 orange juice Nutrition 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- 239000006228 supernatant Substances 0.000 claims description 3
- 229920002521 macromolecule Polymers 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 4
- 238000009877 rendering Methods 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 241001062009 Indigofera Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 229940031098 ethanolamine Drugs 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F9/00—Games not otherwise provided for
- A63F9/02—Shooting or hurling games
- A63F9/0278—Projectiles
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H33/00—Other toys
- A63H33/18—Throwing or slinging toys, e.g. flying disc toys
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F2250/00—Miscellaneous game characteristics
- A63F2250/04—Miscellaneous game characteristics containing a liquid
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F2250/00—Miscellaneous game characteristics
- A63F2250/42—Miscellaneous game characteristics with a light-sensitive substance, e.g. photoluminescent
- A63F2250/423—Miscellaneous game characteristics with a light-sensitive substance, e.g. photoluminescent fluorescent
Landscapes
- Engineering & Computer Science (AREA)
- Multimedia (AREA)
- Cosmetics (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Toys (AREA)
Abstract
The invention provides a kind of carbon nano fluorescent water bullet, including water shell case and water bullet liquid, the water shell case is made up of ydroscopic high-molecular resin material, and the water bullet liquid component and its quality proportioning are：Fluorescent carbon quantum dot 0.5 10%, triethanolamine 0.1 0.35%, menthol 0.15 0.5%, essence 0.05 0.15%, distilled water surplus.The water bullet liquid can respectively be obtained monochromatic red, yellow, green, blue fluorescence water bullet liquid, can also mix two kinds or two kinds of water bullet liquid by different proportion, obtain middle color fluorescence water bullet liquid.The water bullet that water bullet liquid of the present invention is made, can send from red and increased the range of application and interest of water bullet to blue colorful visible fluorescence in dark surrounds and under the irradiation of visible ray light sources with different wavelengths, good for night CS or stage set rendering effect.
Description
Technical field
Product is rendered the present invention relates to night CS (true man CS confrontation) and stage set, more particularly to a kind of peashooter water
Bullet, particularly belongs to a kind of carbon nano fluorescent water bullet.
Background technology
It is well known that the composition of peashooter water bullet is water-absorbing resin, and it is a kind of functional high molecule material, can largely absorb water
Point and swelling can maintain the synthetic resin that moisture does not outflow.Existing toy water bullet liquid is water bullet liquid with running water, only
For being shot under daylight or other general light sources, do not possess the function of transmitting fluorescence.With the development of science and technology, people
For spiritual quality requirements raising, modern night CS (true man CS confrontation) and stage arrangement it is more and more diversified, it is traditional
Commercially available water bullet can not meet the demand that modern night CS or stage are rendered.
The content of the invention
The invention aims to provide a kind of carbon nano fluorescent water bullet, the water bullet is in compared with dark surrounds and visible ray
Under light sources with different wavelengths irradiation, can send red to blue colorful visible fluorescence, range of application and the interest of raising water bullet can be
Night CS (true man CS confrontation) provides a kind of new product.
A kind of carbon nano fluorescent water bullet that the present invention is provided, including water shell case and water bullet liquid, the water shell case are macromolecule
Absorbing resin material is made, and the water bullet liquid component and its percent mass proportioning are：Fluorescent carbon quantum dot 0.5-10%, three ethanol
Amine 0.1-0.35%, menthol 0.15-0.5%, essence 0.05-0.15%, distilled water surplus.
Described fluorescent carbon quantum dot is prepared as follows obtaining：5g-10g orange juice is weighed, is added to and is filled 5-
In the reactor of 20mL secondary waters, it is uniformly mixed, 200-2000 μ L 2- (2- amino ethoxies) is then added into solution
In, it is sufficiently stirred for being well mixed solution, finally reactor is placed in Muffle furnace, in 2-7 hour is reacted at 200 DEG C, obtain
To the solid of brownish black, as fluorescent carbon quantum dot.The carbon quantum dot sends blue-fluorescence under 330-365nm light irradiations,
Green fluorescence is sent under 435-488nm light irradiations, red fluorescence is sent under 510-543nm light irradiations.
Or：Weigh 4-16g phosphorus pentoxides to be added in beaker, then by the dense acetic acid of 2-8mL and 200-6000 μ L bis-
Secondary water is sequentially added in beaker, 5-15min is reacted in fume hood and obtains black solid, as fluorescent carbon quantum dot.The carbon amounts
Son point sends green fluorescence under 330-365nm light irradiations, and red fluorescence is sent under 510-543nm light irradiations.
Or：2-10g sucrose is weighed, is added it in 4-20mL distilled water, be uniformly mixed, then by 20-
The 100mL concentrated sulfuric acids are added in solution, solution is maintained at 4-6h is stirred at 60 DEG C, and solution colour is from the colourless red that is changed into until palm fibre
Black, that is, react complete, is finally adjusted to neutrality pH value of solution with NaOH, and be centrifuged under conditions of 6000 turns/min
Oily precipitation in bottom is dissolved in secondary water by 10-15min, abandoning supernatant, that is, obtain fluorescent carbon quantum dot.The carbon quantum dot exists
Yellow fluorescence is sent under 330-365nm light irradiations.
The fluorescent carbon quantum dot has particle diameter small, and good water solubility, chemical inertness is high, and resistance to photobleaching, hypotoxicity is suitable for
As water bullet liquid fluorescent dye.
Described essence is camomile essence, and menthol is freshener, and triethanolamine is pH adjusting agent.
The preparation method of carbon nano fluorescent water bullet：Fluorescent carbon quantum dot, triethanolamine is weighed according to the above ratio to add
To in distilled water, it is well mixed, then by menthol and essence addition solution, is sufficiently stirred for being well mixed solution, obtains final product
To water bullet liquid；
Dyeing, dyeing at least 2h in cleaning dry water shell case immersion water bullet liquid, the taking-up from dyeing liquor then will be by
The water bullet of dyeing is placed under cleaning ambient, is dried at room temperature 3-5 minutes, obtains purpose product.
Carbon nano fluorescent water bullet beneficial effect of the present invention：
Water bullet of the present invention can send red colorful to indigo plant in compared with dark surrounds and under the irradiation of visible ray light sources with different wavelengths
Visible fluorescence, improves the range of application and interest of water bullet；Meanwhile, the water bullet that the water bullet liquid is made can be with light of stage
Change send the fluorescence of different colours, satisfaction renders the demand of different stage sets.And there is refrigerant radiating, arousing brain, raising spirit
Effect.
The present invention prepare the raw materials used wide material sources of water bullet, it is cheap, have no toxic side effect, and manufacture craft is simple.This
Invent as night CS confrontation provides a kind of new product.
Specific embodiment
A kind of preparation of carbon Nanometer blue fluorescence water bullet of embodiment 1
Formula：Fluorescent carbon quantum dot 1g, triethanolamine 0.2g, menthol 0.15ml, camomile essence 0.15ml distilled water
99.7ml。
Above-mentioned carbon quantum dot is synthesized by following method：4.2g orange juice is weighed, is added to and is filled 10mL secondary waters
In reactor, it is uniformly mixed, then by 1356 μ L 2- (2- amino ethoxies) addition solution, is sufficiently stirred for making solution
It is well mixed, finally reactor is placed in Muffle furnace, in 5 hours are reacted at 200 DEG C, the solid of brownish black is obtained, as
Required carbon quantum dot.The carbon quantum dot sends blue-fluorescence under 365nm light irradiations, and green is sent under 488nm light irradiations
Fluorescence, red fluorescence is sent under 543nm light irradiations.
It is prepared by water bullet liquid：Carbon quantum dot, triethanolamine are weighed according to the above ratio, add them into 99.7mL distilled water
In, it is uniformly mixed, during 0.15mL menthols, 0.15ml camomile essence then sequentially added into solution, it is sufficiently stirred for making molten
Liquid is well mixed, and obtains final product carbon Nanometer blue fluorescence water bullet liquid；
Dyeing：2.5h is dyeed in the dry water shell case immersion blue-fluorescence water bullet liquid of cleaning, taken out from dyeing liquor, so
The water bullet that will be colored afterwards is placed under cleaning ambient, is dried 3 minutes at room temperature, obtains blue-fluorescence water bullet.
A kind of preparation of the nano red fluorescence water bullet of the carbon of embodiment 2
Formula：Fluorescent carbon quantum dot 4g, triethanolamine 0.4g, menthol 0.2ml, camomile essence 0.2ml distilled water
99.6ml；
Above-mentioned carbon quantum dot is synthesized by following method：5.3g orange juice is weighed, is added to and is filled 15mL secondary waters
In reactor, it is uniformly mixed, then by 1605 μ L 2- (2- amino ethoxies) addition solution, is sufficiently stirred for making solution
It is well mixed, finally reactor is placed in Muffle furnace, in 6 hours are reacted at 200 DEG C, the solid of brownish black is obtained, as
Required carbon quantum dot, carbon quantum dot sends red fluorescence under 543nm light irradiations.
It is prepared by water bullet liquid：Carbon quantum dot, triethanolamine are weighed according to the above ratio, add them into 99.6mL distilled water
In, it is uniformly mixed, during 0.2mL menthols, 0.2ml camomile essence then sequentially added into solution, it is sufficiently stirred for making solution
It is well mixed, you can to obtain the nano red fluorescence water bullet liquid of carbon.
Dyeing：2.5h is dyeed in the dry water shell case immersion red fluorescence water bullet liquid of cleaning, taken out from dyeing liquor, so
The water bullet that will be colored afterwards is placed under cleaning ambient, is dried 3 minutes at room temperature, obtains red fluorescence water bullet.
A kind of preparation of carbon nano green fluorescence water bullet of embodiment 3
Formula：Fluorescent carbon quantum dot 2.3g, triethanolamine 0.15g, menthol 0.15ml, camomile essence 0.15ml, distillation
Water 99.7ml；
Above-mentioned carbon quantum dot is synthesized by following method：Weigh 2.6g phosphorus pentoxides to be added in beaker, then will
The dense acetic acid of 1mL and 80 μ L secondary waters are sequentially added in beaker, 5min is reacted in fume hood and obtains black solid, as required
Carbon quantum dot, the carbon quantum dot sends green fluorescence under 365nm light irradiations, and red fluorescence is sent under 543nm light irradiations.
It is prepared by water bullet liquid：Carbon quantum dot, NaOH and ethanol are weighed according to the above ratio, add them into 99.7mL steamings
In distilled water, it is uniformly mixed, during 0.15mL menthols, 0.15ml camomile essence then sequentially added into solution, is sufficiently stirred for
It is well mixed solution, you can to obtain carbon nano green fluorescence water bullet liquid.
Dyeing：2.5h is dyeed in the dry water shell case immersion green fluorescence water bullet liquid of cleaning, taken out from dyeing liquor, so
The water bullet that will be colored afterwards is placed under cleaning ambient, is dried 3 minutes at room temperature, obtains green fluorescence water bullet.
A kind of preparation of the carbon of embodiment 4 nanometer yellow fluorescence water bullet
Formula：Fluorescent carbon quantum dot 3.2g, triethanolamine 0.15g, menthol 0.15ml, camomile essence 0.15ml, distillation
Water 99.7ml；
Above-mentioned carbon quantum dot is synthesized by following method：2g sucrose is weighed, is added it in 4mL distilled water, stirred
It is well mixed, then by 40mL concentrated sulfuric acids addition solution, solution is maintained at 60 DEG C and stirs 4h, solution colour is by without discoloration
It is that red arrives neutrality until brownish black, i.e. reaction completely, are finally adjusted pH value of solution with NaOH, and 6000 turns/min's
Under the conditions of be centrifuged 10min, oily precipitation in bottom is dissolved in secondary water by abandoning supernatant, that is, obtain required carbon quantum dot, the carbon
Quantum dot sends yellow fluorescence under 365nm light irradiations.
It is prepared by water bullet liquid：Carbon quantum dot 3.2g, triethanolamine 0.15g are weighed by above-mentioned, 99.7mL steamings are added them into
In distilled water, it is uniformly mixed, during 0.15mL menthols, 0.15ml camomile essence then sequentially added into solution, is sufficiently stirred for
It is well mixed solution, you can to obtain carbon nanometer yellow fluorescence water bullet liquid；
Dyeing：2.5h is dyeed in the dry water shell case immersion yellow fluorescence water bullet liquid of cleaning, taken out from dyeing liquor, so
The water bullet that will be colored afterwards is placed under cleaning ambient, is dried 3 minutes at room temperature, obtains yellow fluorescence water bullet.
A kind of preparation of the nano red fluorescence water bullet of the carbon of embodiment 5
Formula：Fluorescent carbon quantum dot 6.2g, triethanolamine 0.15g, menthol 0.15ml, camomile essence 0.15ml, distillation
Water 99.7ml；
Above-mentioned carbon quantum dot is synthesized by following method：Weigh 4.6g phosphorus pentoxides to be added in beaker, then will
The dense acetic acid of 2mL and 160 μ L secondary waters are sequentially added in beaker, 7min is reacted in fume hood and obtains black solid, as required
Carbon quantum dot, the carbon quantum dot sends red fluorescence under 543nm light irradiations.
It is prepared by water bullet liquid：Carbon quantum dot, triethanolamine are weighed according to the above ratio, in adding them into 90mL distilled water,
It is uniformly mixed, during 0.15mL menthols, 0.15ml camomiles essence and 2mL Metadelphenes then sequentially added into solution, fully
Stirring is well mixed solution, you can obtain the nano red fluorescence water bullet liquid of carbon.
Dyeing：2.5h is dyeed in the dry water shell case immersion red fluorescence water bullet liquid of cleaning, taken out from dyeing liquor, so
The water bullet that will be colored afterwards is placed under cleaning ambient, is dried 3 minutes at room temperature, obtains red fluorescence water bullet.
Water bullet liquid prepared by above-described embodiment 1,2,3,4 or 5, is long placed in and will not produce precipitation, nontoxic and smell is pure and fresh.
By in embodiment two or more mix in different ratio, can obtain various middle colors.These water bullet liquid and it
The water bullet that is made the fluorescence of different colours can be sent under Compound eye, improvement of visual effect very well, and increased night
Between CS it is interesting and change is felt and good for stage set rendering effect.
The above, is only the preferable embodiment in part of the invention, and any formal limit is not done to the present invention
System.
Claims (4)
1. a kind of carbon nano fluorescent water bullet, it is characterised in that including water shell case and water bullet liquid, the water shell case is macromolecule water uptake
Resin material is made, and the water bullet liquid component and its quality proportioning are：Fluorescent carbon quantum dot 0.5-10%, triethanolamine 0.1-
0.35%, menthol 0.15-0.5%, essence 0.05-0.15%, distilled water surplus.
2. a kind of carbon nano fluorescent water bullet as claimed in claim 1, it is characterised in that described fluorescent carbon quantum dot is by as follows
Method is prepared：5g-10g orange juice is weighed, is added in the reactor for filling 5-20mL secondary waters, be uniformly mixed,
Then by 200-2000 μ L 2- (2- amino ethoxies) addition solution, it is sufficiently stirred for being well mixed solution, finally will reaction
Kettle is placed in Muffle furnace, in 2-7 hour is reacted at 200 DEG C, obtains the solid of brownish black, as fluorescent carbon quantum dot；
Or：Weigh 4-16g phosphorus pentoxides to be added in beaker, then by the dense acetic acid of 2-8mL and 200-6000 μ L secondary waters
Sequentially add in beaker, reaction 5-15min obtains black solid, as fluorescent carbon quantum dot in fume hood；
Or：2-10g sucrose is weighed, is added it in 4-20mL distilled water, be uniformly mixed, it is then that 20-100mL is dense
Sulfuric acid is added in solution, solution is maintained at 4-6h is stirred at 60 DEG C, and solution colour is changed into red until brownish black from colourless, i.e.,
Reaction is complete, is finally adjusted to neutrality pH value of solution with NaOH, and 10-15min is centrifuged under conditions of 6000 turns/min,
Abandoning supernatant, secondary water is dissolved in by bottom oily precipitation, that is, obtain fluorescent carbon quantum dot.
3. a kind of carbon nano fluorescent water bullet as claimed in claim 1, it is characterised in that described essence is camomile essence.
4. a kind of preparation method of carbon nano fluorescent water bullet：Water bullet liquid component and its quality proportioning as described in claim 1 or 2,
Weigh fluorescent carbon quantum dot, triethanolamine to be added in distilled water, be well mixed, then add menthol and essence molten
In liquid, it is sufficiently stirred for being well mixed solution, that is, obtains water bullet liquid；Clean dye in dry water shell case immersion water bullet liquid to
Few 2h, takes out from dyeing liquor, and the water bullet that then will be colored is placed under cleaning ambient, dries at room temperature 3-5 minutes, obtains mesh
Product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710032836.3A CN106823362B (en) | 2017-01-18 | 2017-01-18 | Carbon nano fluorescent water bomb |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710032836.3A CN106823362B (en) | 2017-01-18 | 2017-01-18 | Carbon nano fluorescent water bomb |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106823362A true CN106823362A (en) | 2017-06-13 |
| CN106823362B CN106823362B (en) | 2020-06-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710032836.3A Expired - Fee Related CN106823362B (en) | 2017-01-18 | 2017-01-18 | Carbon nano fluorescent water bomb |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090208684A1 (en) * | 2005-06-30 | 2009-08-20 | Michael Dunleavy | Self-Reparing Structure |
| US20110088511A1 (en) * | 2010-08-28 | 2011-04-21 | Ghanavi Jalaledin | Method for producing rod-shaped and branched metallic nano-structures by polyol compounds |
| CN103525414A (en) * | 2013-10-21 | 2014-01-22 | 北京理工大学 | Carbon quantum dot magnetic and fluorescent difunctional nano material and preparation method thereof |
| CN104031642A (en) * | 2014-06-24 | 2014-09-10 | 山西大学 | Fluorescence carbon quantum dots, and preparation method and application thereof |
| CN104479674A (en) * | 2014-11-28 | 2015-04-01 | 湖南科技大学 | Method of preparing near-infrared carbon quantum dots by taking Coomassie brilliant blue as carbon source |
-
2017
- 2017-01-18 CN CN201710032836.3A patent/CN106823362B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090208684A1 (en) * | 2005-06-30 | 2009-08-20 | Michael Dunleavy | Self-Reparing Structure |
| US20110088511A1 (en) * | 2010-08-28 | 2011-04-21 | Ghanavi Jalaledin | Method for producing rod-shaped and branched metallic nano-structures by polyol compounds |
| CN103525414A (en) * | 2013-10-21 | 2014-01-22 | 北京理工大学 | Carbon quantum dot magnetic and fluorescent difunctional nano material and preparation method thereof |
| CN104031642A (en) * | 2014-06-24 | 2014-09-10 | 山西大学 | Fluorescence carbon quantum dots, and preparation method and application thereof |
| CN104479674A (en) * | 2014-11-28 | 2015-04-01 | 湖南科技大学 | Method of preparing near-infrared carbon quantum dots by taking Coomassie brilliant blue as carbon source |
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| CN106823362B (en) | 2020-06-12 |
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