CN106823362B - Carbon nano fluorescent water bomb - Google Patents
Carbon nano fluorescent water bomb Download PDFInfo
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- CN106823362B CN106823362B CN201710032836.3A CN201710032836A CN106823362B CN 106823362 B CN106823362 B CN 106823362B CN 201710032836 A CN201710032836 A CN 201710032836A CN 106823362 B CN106823362 B CN 106823362B
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- water
- bomb
- water bomb
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- fluorescent
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 126
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 22
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000007788 liquid Substances 0.000 claims abstract description 43
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000012153 distilled water Substances 0.000 claims abstract description 18
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims abstract description 16
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229940041616 menthol Drugs 0.000 claims abstract description 16
- 239000002250 absorbent Substances 0.000 claims abstract description 4
- 229920005989 resin Polymers 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims abstract description 3
- 238000003756 stirring Methods 0.000 claims description 24
- 238000004043 dyeing Methods 0.000 claims description 20
- 238000005303 weighing Methods 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 14
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 12
- 240000003538 Chamaemelum nobile Species 0.000 claims description 12
- 235000007866 Chamaemelum nobile Nutrition 0.000 claims description 12
- 235000007232 Matricaria chamomilla Nutrition 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 229930006000 Sucrose Natural products 0.000 claims description 6
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 6
- 239000005720 sucrose Substances 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 5
- 239000003517 fume Substances 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 4
- 230000007935 neutral effect Effects 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 3
- 239000006228 supernatant Substances 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 2
- 238000009877 rendering Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 description 9
- 235000015205 orange juice Nutrition 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 108010043121 Green Fluorescent Proteins Proteins 0.000 description 4
- -1 2-aminoethoxy Chemical group 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 229920001002 functional polymer Polymers 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000003340 mental effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F9/00—Games not otherwise provided for
- A63F9/02—Shooting or hurling games
- A63F9/0278—Projectiles
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H33/00—Other toys
- A63H33/18—Throwing or slinging toys, e.g. flying disc toys
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F2250/00—Miscellaneous game characteristics
- A63F2250/04—Miscellaneous game characteristics containing a liquid
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F2250/00—Miscellaneous game characteristics
- A63F2250/42—Miscellaneous game characteristics with a light-sensitive substance, e.g. photoluminescent
- A63F2250/423—Miscellaneous game characteristics with a light-sensitive substance, e.g. photoluminescent fluorescent
Abstract
The invention provides a carbon nano fluorescent water bomb which comprises a water bomb shell and water bomb liquid, wherein the water bomb shell is made of a high-molecular water-absorbent resin material, and the water bomb liquid comprises the following components in parts by mass: 0.5-10% of fluorescent carbon quantum dots, 0.1-0.35% of triethanolamine, 0.15-0.5% of menthol, 0.05-0.15% of essence and the balance of distilled water. The water elastic liquid can be respectively prepared into single-color red, yellow, green and blue fluorescent water elastic liquid, or two or more water elastic liquids can be mixed according to different proportions to obtain the intermediate-color fluorescent water elastic liquid. The water bomb made of the water bomb liquid can emit colorful visible fluorescence from red to blue in a dark environment and under the irradiation of light sources with different wavelengths of visible light, so that the application range and the interestingness of the water bomb are increased, and the water bomb has a good rendering effect when being used for CS or stage scenes at night.
Description
Technical Field
The invention relates to products for rendering CS (real person CS confrontation) and stage scenes at night, in particular to a water bomb for a toy gun, and specifically belongs to a carbon nano fluorescent water bomb.
Background
As is well known, the water bullet of a toy gun is made of water-absorbent resin, which is a functional polymer material and is a synthetic resin capable of absorbing a large amount of water and swelling and keeping the water from flowing out. The existing toy water bullet liquid uses tap water as the water bullet liquid, is only used for shooting under sunlight or other common light sources, and does not have the function of emitting fluorescence. With the development of science and technology, the requirements of people on mental quality are improved, the modern nighttime CS (real person CS confrontation) and stage arrangement are more and more diversified, and the traditional commercially available water bomb cannot meet the requirements of the modern nighttime CS or stage rendering.
Disclosure of Invention
The invention aims to provide a carbon nano fluorescent water bomb which can emit red to blue colorful visible fluorescence under the irradiation of light sources with different wavelengths of visible light in a dark environment, improve the application range and the interestingness of the water bomb and provide a new product for CS (real CS countermeasure) at night.
The invention provides a carbon nano fluorescent water bomb which comprises a water bomb shell and water bomb liquid, wherein the water bomb shell is made of a high-molecular water-absorbent resin material, and the water bomb liquid comprises the following components in percentage by mass: 0.5-10% of fluorescent carbon quantum dots, 0.1-0.35% of triethanolamine, 0.15-0.5% of menthol, 0.05-0.15% of essence and the balance of distilled water.
The fluorescent carbon quantum dot is prepared by the following method: weighing 5g to 10g of orange juice, adding the orange juice into a reaction kettle containing 5mL to 20mL of secondary water, stirring and mixing uniformly, then adding 200. mu.L of 2- (2-aminoethoxy) into the solution, fully stirring to uniformly mix the solution, and finally placing the reaction kettle in a muffle furnace to react for 2 hours to 7 hours at 200 ℃ to obtain brownish black solid, namely the fluorescent carbon quantum dots. The carbon quantum dot emits blue fluorescence under the irradiation of 330-365nm light, green fluorescence under the irradiation of 435-488nm light and red fluorescence under the irradiation of 510-543nm light.
Or: weighing 4-16g of phosphorus pentoxide, adding the phosphorus pentoxide into a beaker, sequentially adding 2-8mL of concentrated acetic acid and 6000 muL of secondary water into the beaker, and reacting in a fume hood for 5-15min to obtain a black solid, namely the fluorescent carbon quantum dot. The carbon quantum dot emits green fluorescence under the irradiation of 330-365nm light and emits red fluorescence under the irradiation of 510-543nm light.
Or: weighing 2-10g of sucrose, adding the sucrose into 4-20mL of distilled water, stirring and mixing uniformly, then adding 20-100mL of concentrated sulfuric acid into the solution, keeping the solution at 60 ℃, stirring for 4-6h, changing the color of the solution from colorless to red until brownish black, namely completely reacting, finally adjusting the pH of the solution to be neutral by using sodium hydroxide, centrifuging for 10-15min under the condition of 6000 r/min, discarding the supernatant, and dissolving the oily precipitate at the bottom in secondary water to obtain the fluorescent carbon quantum dot. The carbon quantum dot emits yellow fluorescence under the irradiation of light with 330-365 nm.
The fluorescent carbon quantum dot has the advantages of small particle size, good water solubility, high chemical inertness, photobleaching resistance and low toxicity, and is very suitable for being used as a water elastic liquid fluorescent dye.
The essence is chamomile essence, the menthol is a freshener, and the triethanolamine is a pH regulator.
The preparation method of the carbon nano fluorescent water bomb comprises the following steps: weighing the fluorescent carbon quantum dots and the triethanolamine according to the proportion, adding the fluorescent carbon quantum dots and the triethanolamine into distilled water, uniformly mixing, then adding the menthol crystal and the essence into the solution, and fully stirring to uniformly mix the solution to obtain the water bullet liquid;
and (3) dyeing, namely soaking the clean and dry water bomb shell into water bomb liquid for dyeing for at least 2h, taking out the water bomb shell from the dyeing liquid, then placing the dyed water bomb in a clean environment, and drying at room temperature for 3-5 minutes to obtain the target product.
The carbon nano fluorescent water bomb has the beneficial effects that:
the water bomb can emit red to blue colorful visible fluorescence under the irradiation of light sources with different wavelengths of visible light in a dark environment, so that the application range and the interestingness of the water bomb are improved; meanwhile, the water bomb made of the water bomb liquid can emit fluorescence of different colors along with the change of stage lighting, and the requirements of rendering different stage scenes are met. And has effects of refreshing, cooling, refreshing, and refreshing.
The water bullet prepared by the method has the advantages of wide source of raw materials, low price, no toxic or side effect and simple preparation process. The invention provides a new product for nighttime CS confrontation.
Detailed Description
Example 1 preparation of a carbon nano blue fluorescent water bomb
The formula is as follows: 1g of fluorescent carbon quantum dots, 0.2g of triethanolamine, 0.15ml of menthol and 99.7ml of distilled water of 0.15ml of chamomile essence.
The carbon quantum dots are synthesized by the following method: weighing 4.2g of orange juice, adding the orange juice into a reaction kettle containing 10mL of secondary water, stirring and mixing uniformly, then adding 1356 mu L of 2- (2-aminoethoxy) into the solution, fully stirring to mix the solution uniformly, finally placing the reaction kettle into a muffle furnace, and reacting for 5 hours at 200 ℃ to obtain brownish black solid, namely the required carbon quantum dots. The carbon quantum dot emits blue fluorescence under 365nm light irradiation, green fluorescence under 488nm light irradiation, and red fluorescence under 543nm light irradiation.
Preparing water elastic liquid: weighing the carbon quantum dots and the triethanolamine according to the proportion, adding the carbon quantum dots and the triethanolamine into 99.7mL of distilled water, stirring and mixing uniformly, then sequentially adding 0.15mL of menthol and 0.15mL of chamomile essence into the solution, and fully stirring to uniformly mix the solution to obtain the carbon nano blue fluorescent water elastic liquid;
dyeing: and (3) immersing the clean and dry water bomb shell into blue fluorescent water bomb liquid for dyeing for 2.5h, taking out the water bomb shell from the dyeing liquid, then placing the dyed water bomb in a clean environment, and drying at room temperature for 3 minutes to obtain the blue fluorescent water bomb.
Example 2 preparation of a carbon nano red fluorescent water bomb
The formula is as follows: 4g of fluorescent carbon quantum dots, 0.4g of triethanolamine, 0.2ml of menthol and 99.6ml of distilled water of 0.2ml of chamomile essence;
the carbon quantum dots are synthesized by the following method: weighing 5.3g of orange juice, adding the orange juice into a reaction kettle containing 15mL of secondary water, stirring and mixing uniformly, then adding 1605 muL of 2- (2-aminoethoxy) into the solution, fully stirring to uniformly mix the solution, finally placing the reaction kettle into a muffle furnace, and reacting for 6 hours at 200 ℃ to obtain brownish black solid, namely the required carbon quantum dot, wherein the carbon quantum dot emits red fluorescence under 543nm light irradiation.
Preparing water elastic liquid: weighing the carbon quantum dots and the triethanolamine according to the proportion, adding the carbon quantum dots and the triethanolamine into 99.6mL of distilled water, stirring and mixing uniformly, then sequentially adding 0.2mL of menthol and 0.2mL of chamomile essence into the solution, and fully stirring to uniformly mix the solution, thus obtaining the carbon nano red fluorescent water bullet liquid.
Dyeing: and (3) immersing the clean and dry water bomb shell into red fluorescent water bomb liquid for dyeing for 2.5h, taking out the water bomb shell from the dyeing liquid, then placing the dyed water bomb in a clean environment, and drying at room temperature for 3 minutes to obtain the red fluorescent water bomb.
Example 3 preparation of a carbon nano green fluorescent water bomb
The formula is as follows: 2.3g of fluorescent carbon quantum dots, 0.15g of triethanolamine, 0.15ml of menthol, 0.15ml of chamomile essence and 99.7ml of distilled water;
the carbon quantum dots are synthesized by the following method: 2.6g of phosphorus pentoxide is weighed and added into a beaker, then 1mL of concentrated acetic acid and 80 mu L of secondary water are sequentially added into the beaker, and the mixture reacts in a fume hood for 5min to obtain a black solid, namely the required carbon quantum dot, which emits green fluorescence under 365nm light irradiation and red fluorescence under 543nm light irradiation.
Preparing water elastic liquid: weighing the carbon quantum dots, the sodium hydroxide and the ethanol according to the proportion, adding the carbon quantum dots, the sodium hydroxide and the ethanol into 99.7mL of distilled water, stirring and mixing uniformly, then sequentially adding 0.15mL of menthol and 0.15mL of chamomile essence into the solution, and fully stirring to uniformly mix the solution, thus obtaining the carbon nano green fluorescent water bullet liquid.
Dyeing: and (3) immersing the clean and dry water bomb shell into green fluorescent water bomb liquid for dyeing for 2.5h, taking out the water bomb shell from the dyeing liquid, then placing the dyed water bomb in a clean environment, and drying at room temperature for 3 minutes to obtain the green fluorescent water bomb.
Example 4 preparation of a carbon nano-yellow fluorescent water bomb
The formula is as follows: 3.2g of fluorescent carbon quantum dots, 0.15g of triethanolamine, 0.15ml of menthol, 0.15ml of chamomile essence and 99.7ml of distilled water;
the carbon quantum dots are synthesized by the following method: weighing 2g of sucrose, adding the sucrose into 4mL of distilled water, stirring and mixing uniformly, then adding 40mL of concentrated sulfuric acid into the solution, keeping the solution at 60 ℃ and stirring for 4h, wherein the color of the solution is changed from colorless to red until brownish black, namely, the reaction is complete, finally adjusting the pH of the solution to be neutral by using sodium hydroxide, centrifuging for 10min under the condition of 6000 r/min, discarding the supernatant, and dissolving the oily precipitate at the bottom into secondary water to obtain the required carbon quantum dot which emits yellow fluorescence under the radiation of 365nm light.
Preparing water elastic liquid: weighing 3.2g of carbon quantum dots and 0.15g of triethanolamine according to the above, adding the carbon quantum dots and the triethanolamine into 99.7mL of distilled water, stirring and mixing uniformly, then sequentially adding 0.15mL of menthol and 0.15mL of chamomile essence into the solution, and fully stirring to uniformly mix the solution, thus obtaining the carbon nano yellow fluorescent water elastic liquid;
dyeing: and (3) immersing the clean and dry water bomb shell into yellow fluorescent water bomb liquid for dyeing for 2.5h, taking out the water bomb shell from the dyeing liquid, then placing the dyed water bomb in a clean environment, and drying at room temperature for 3 minutes to obtain the yellow fluorescent water bomb.
Example 5 preparation of a carbon nano red fluorescent hydro-elastic
The formula is as follows: 6.2g of fluorescent carbon quantum dots, 0.15g of triethanolamine, 0.15ml of menthol, 0.15ml of chamomile essence and 99.7ml of distilled water;
the carbon quantum dots are synthesized by the following method: weighing 4.6g of phosphorus pentoxide, adding the phosphorus pentoxide into a beaker, sequentially adding 2mL of concentrated acetic acid and 160 mu L of secondary water into the beaker, and reacting in a fume hood for 7min to obtain a black solid, namely the required carbon quantum dot, wherein the carbon quantum dot emits red fluorescence under the irradiation of 543nm light.
Preparing water elastic liquid: weighing the carbon quantum dots and the triethanolamine according to the proportion, adding the carbon quantum dots and the triethanolamine into 90mL of distilled water, stirring and mixing uniformly, then sequentially adding 0.15mL of menthol, 0.15mL of chamomile essence and 2mL of deet into the solution, and fully stirring to uniformly mix the solution, thus obtaining the carbon nano red fluorescent water bullet liquid.
Dyeing: and (3) immersing the clean and dry water bomb shell into red fluorescent water bomb liquid for dyeing for 2.5h, taking out the water bomb shell from the dyeing liquid, then placing the dyed water bomb in a clean environment, and drying at room temperature for 3 minutes to obtain the red fluorescent water bomb.
The aqueous bullet solutions prepared in examples 1, 2, 3, 4, or 5 above did not precipitate after long-term storage, were non-toxic and harmless, and had a fresh odor. Various intermediate colors can be obtained by mixing two or more of the embodiments in different proportions. The water bomb liquid and the water bombs made of the water bomb liquid can emit fluorescence of different colors under different wavelengths of illumination, the visual effect is good, the interest and the change of the CS at night are increased, and the stage scene rendering effect is good.
The foregoing is only a partial description of the preferred embodiments of the present invention, and is not intended to limit the invention in any way.
Claims (4)
1. The carbon nano fluorescent water bomb is characterized by comprising a water bomb shell and water bomb liquid, wherein the water bomb shell is made of a high-molecular water-absorbent resin material, and the water bomb liquid comprises the following components in parts by mass: 0.5-10% of fluorescent carbon quantum dots, 0.1-0.35% of triethanolamine, 0.15-0.5% of menthol, 0.05-0.15% of essence and the balance of distilled water.
2. The carbon nanofluorescent water bomb according to claim 1, wherein the fluorescent carbon quantum dots are prepared by the following method: weighing 4-16g of phosphorus pentoxide, adding the phosphorus pentoxide into a beaker, sequentially adding 2-8mL of concentrated acetic acid and 6000 muL of secondary water into the beaker, and reacting in a fume hood for 5-15min to obtain black solids, namely the fluorescent carbon quantum dots;
or: weighing 2-10g of sucrose, adding the sucrose into 4-20mL of distilled water, stirring and mixing uniformly, then adding 20-100mL of concentrated sulfuric acid into the solution, keeping the solution at 60 ℃, stirring for 4-6h, changing the color of the solution from colorless to red until brownish black, namely completely reacting, finally adjusting the pH of the solution to be neutral by using sodium hydroxide, centrifuging for 10-15min under the condition of 6000 r/min, discarding the supernatant, and dissolving the oily precipitate at the bottom in secondary water to obtain the fluorescent carbon quantum dot.
3. The carbon nanofluorescent water bomb according to claim 1, wherein the essence is chamomile essence.
4. A preparation method of a carbon nano fluorescent water bomb comprises the following steps: weighing fluorescent carbon quantum dots and triethanolamine according to the components and the mass ratio thereof in the claim 1 or 2, adding the fluorescent carbon quantum dots and the triethanolamine into distilled water, uniformly mixing, then adding menthol and essence into the solution, and fully stirring to uniformly mix the solution, thus obtaining the hydro-elastic liquid; soaking the clean and dry water bomb shell into water bomb liquid for dyeing for at least 2h, taking out the water bomb shell from the dyeing liquid, then placing the dyed water bomb in a clean environment, and drying for 3-5 minutes at room temperature to obtain the target product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710032836.3A CN106823362B (en) | 2017-01-18 | 2017-01-18 | Carbon nano fluorescent water bomb |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710032836.3A CN106823362B (en) | 2017-01-18 | 2017-01-18 | Carbon nano fluorescent water bomb |
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| Publication Number | Publication Date |
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| CN106823362A CN106823362A (en) | 2017-06-13 |
| CN106823362B true CN106823362B (en) | 2020-06-12 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525414A (en) * | 2013-10-21 | 2014-01-22 | 北京理工大学 | Carbon quantum dot magnetic and fluorescent difunctional nano material and preparation method thereof |
| CN104031642A (en) * | 2014-06-24 | 2014-09-10 | 山西大学 | Fluorescence carbon quantum dots, and preparation method and application thereof |
| CN104479674A (en) * | 2014-11-28 | 2015-04-01 | 湖南科技大学 | Method of preparing near-infrared carbon quantum dots by taking Coomassie brilliant blue as carbon source |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| GB0513498D0 (en) * | 2005-06-30 | 2006-03-29 | Bae Systems Plc | Fibre materials |
| US20110088511A1 (en) * | 2010-08-28 | 2011-04-21 | Ghanavi Jalaledin | Method for producing rod-shaped and branched metallic nano-structures by polyol compounds |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103525414A (en) * | 2013-10-21 | 2014-01-22 | 北京理工大学 | Carbon quantum dot magnetic and fluorescent difunctional nano material and preparation method thereof |
| CN104031642A (en) * | 2014-06-24 | 2014-09-10 | 山西大学 | Fluorescence carbon quantum dots, and preparation method and application thereof |
| CN104479674A (en) * | 2014-11-28 | 2015-04-01 | 湖南科技大学 | Method of preparing near-infrared carbon quantum dots by taking Coomassie brilliant blue as carbon source |
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