CN106711033A - Substrate etching method - Google Patents

Substrate etching method Download PDF

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Publication number
CN106711033A
CN106711033A CN201510792034.3A CN201510792034A CN106711033A CN 106711033 A CN106711033 A CN 106711033A CN 201510792034 A CN201510792034 A CN 201510792034A CN 106711033 A CN106711033 A CN 106711033A
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substrate
etching method
turning
substrate etching
height
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CN106711033B (en
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朱印伍
吴鑫
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Beijing NMC Co Ltd
Beijing North Microelectronics Co Ltd
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Beijing North Microelectronics Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/3065Plasma etching; Reactive-ion etching

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Drying Of Semiconductors (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

The invention provides a substrate etching method comprising a main etching step and an over etching step. The main etching step further comprises a step S1 and a step S2. When a corner appears in a graph sidewall, the step S1 is ended and the step S2 is simultaneously started. The over etching step comprises a step S3 and a step S4. When the height of the corner reaches the fixed value, the step S3 is ended and the step S4 is simultaneously started. The back blowing air pressure adopted for cooling a substrate in the step S1 and the step S4 is less than the back blowing air pressure adopted for cooling the substrate in the step S2 and the step S3. According to the substrate etching method, the bottom width of the substrate graph can be increased under the condition of having low influence on the height of the substrate graph so as to obtain the substrate graph of which the bottom width and the height meet the requirements.

Description

Substrate etching method
Technical field
The present invention relates to field of semiconductor manufacture, in particular it relates to a kind of substrate etching method.
Background technology
Graphical sapphire substrate (Patterned Sapphire Substrate, abbreviation PSS) conduct A kind of method of the raising GaN base LED component light extraction efficiency for generally using is extensive at present Apply in LED preparation fields.Suitable figure pattern and size are to reduce epitaxial crystal Defect, the necessary condition for improving internal quantum efficiency, preferably substrate figure is pyramidal structure at present, Highly generally 1~2 μm, at intervals of 2~3 μm, bottom width is 2~3 μm, and side wall oblique angle is 31.6°。
ICP (Inductively Coupled Plasma, inductively coupled plasma) technology is A kind of method for preparing sapphire pattern substrate, it is can control plasma density and bombardment Energy, the advantages of be suitable to Automatic Network Matching during glow discharge and extensive use.The method is general With BCl3Or CHF3Or the mixed gas of the two are used as reacting gas, and by controlling work The parameter of pressure, reaction gas flow, magnetic field intensity and Dc bias etc., controls the quarter of technique Erosion speed and uniformity, to cause that the height and bottom width of tpo substrate shape reach requirement.
A kind of existing regulative mode is the side using relatively low etch rate in technical process Formula increases the bottom width of substrate figure.For example, in the case where being reduced during carrying out main etch step Electrode power, this can reduce bombardment of the plasma to pattern side wall, such that it is able to increase cone The bottom broadening of shape structure, and then reach the purpose for increasing bottom width.But, reduce etch rate It is elongated to not only result in the process time, so as to reduce production efficiency, but also can be because in work During skill, the turning excessive height formed in pattern side wall causes the turning in technique knot Cannot be eliminated after beam, as shown in figure 1, being the tpo substrate obtained using relatively low etch rate The scanning electron microscope (SEM) photograph of shape pattern.
Existing another regulative mode is blown using the back of the body higher by technical process Air pressure reduces underlayer temperature, to reduce the volatilization of accessory substance, it is attached to side wall, Such that it is able to increase the bottom width of substrate figure, but photoetching can be increased due to reducing underlayer temperature The etch rate of glue, causes the height reduction of substrate figure, as shown in Fig. 2 being whole In technical process, the ESEM of the substrate figure pattern of pressure acquisition of being blown using the back of the body higher Figure, as shown in Figure 2, although figure bottom width is 2.75 μm, meets and requires, but figure is high Degree is only 1.53 μm, is not reaching to claimed range (such as 1.6~1.7 μm).If conversely, carrying Underlayer temperature high, although the height of substrate figure can be improved, but substrate figure can be caused Bottom width reduces.Therefore, how to obtain bottom width and height is satisfied by the substrate figure of requirement, be Current problem demanding prompt solution.
The content of the invention
It is contemplated that at least solving one of technical problem present in prior art, it is proposed that A kind of substrate etching method, its can on substrate figure height influence it is less in the case of, Increase the bottom width of substrate figure, it is hereby achieved that bottom width and height are satisfied by desired tpo substrate Shape.
A kind of substrate etching method is provided to realize the purpose of the present invention, including main etching step Rapid and over etching step,
The main etch step further includes step S1 and step S2, when pattern side wall goes out During existing turning, terminate the step S1, start simultaneously at the step S2;
The over etching step further includes step S3 and step S4, when the turning When highly reaching fixed value, terminate the step S3, start simultaneously at the step S4;
Wherein, the back of the body for cooling down substrate that the step S1 and the step S4 are used Pressure blow less than the back of the body for cooling down substrate that the step S2 and the step S3 are used Blow and press.
Preferably, the step S1 and the step S4 are blown using first back of the body and press cooling Substrate;The step S2 and the step S3 are blown using second back of the body and press cooling substrate; First back of the body is blown to press and pressure of blowing is carried on the back less than described second.
Preferably, according to during the main etch step is carried out, the etching of mask is fast Rate judges that the moment at turning occurs in pattern side wall.
Preferably, according to during the over etching step is carried out, the height at the turning The reduction speed of degree judges that the height at the turning reaches the moment of fixed value.
Preferably, the span of the fixed value is in 200~400nm.
Preferably, the process time sum of the step S2 and the step S3 is 10~45min.
Preferably, the step S1 corresponding technique moment is the 0th minute~the 20th minute.
Preferably, the step S4 corresponding technique moment terminate for the 30th minute~technique.
Preferably, first back of the body blows the span pressed in 2~5Torr.
Preferably, second back of the body blows the span pressed in 4~8Torr.
The invention has the advantages that:
The substrate etching method that the present invention is provided, its main etch step includes step S1 and step S2, and when turning occurs in the pattern side wall of substrate, end step S1 starts simultaneously at step S2;Over etching step includes step S3 and step S4, and when the height at turning reaches fixed value When, end step S3 starts simultaneously at step S4.Wherein, step S1 and step S4 are adopted The back of the body for cooling down substrate blows pressure less than being used for that step S2 and step S3 is used Cool down the back of the body air blowing pressure of substrate.Due in the whole process time, with the pattern side wall of substrate There is the moment at turning as starting point (now step S2 starts), reached with the height at turning To fixed value as end point (now step S3 complete) this time segment figure bottom width increasing Rate of acceleration highest, therefore, reduce lining by blowing pressure using the back of the body higher in this time period Bottom temperature, and remaining process time (step S1 and step S4) is blown using the relatively low back of the body Press to improve underlayer temperature, the purpose of increase figure bottom width can be reached in shorter time, together When time higher due to shortening mask etching speed, mask after main etch step can be increased Residual thickness, thereby may be ensured that pattern height reaches claimed range, it is final obtain bottom width and Highly it is satisfied by desired figure pattern.
Brief description of the drawings
Fig. 1 is the scanning electron microscope (SEM) photograph of the substrate figure pattern obtained using relatively low etch rate;
Fig. 2 is to blow to press the scanning electron microscope (SEM) photograph of the substrate figure pattern for obtaining using the back of the body higher;
Fig. 3 is the evolution process figure of substrate figure pattern;
Fig. 4 is the bottom width of substrate figure with the change curve of etch period;
Fig. 5 is the bottom width of substrate figure with the change curve for carrying on the back blow pressure power;And
Fig. 6 is the substrate figure obtained using substrate etching method provided in an embodiment of the present invention The scanning electron microscope (SEM) photograph of pattern.
Specific embodiment
To make those skilled in the art more fully understand technical scheme, tie below Accompanying drawing is closed to be described in detail the substrate etching method that the present invention is provided.
The substrate etching method that the present invention is provided is carried out using existing plasma processing device Etching technics, it is preferred that the plasma processing device can set for inductively coupled plasma Standby, it mainly includes reaction chamber, inductance coil, upper radio system and lower radio system.Its In, the bogey for carrying substrate, such as pedestal, machinery are provided with reaction chamber Chuck or electrostatic chuck etc..Upper radio system is used to apply Top electrode work(to inductance coil Rate, plasma is formed to the etching gas in provocative reaction chamber;Lower radio system is used for Apply lower electrode power to substrate, so that plasma etched features on substrate.
And, during technique is performed etching, to substrate lower surface and bogey Gap conveying back of the body blowing (such as helium) between loading end, is used to be carried out by with substrate Heat exchange and cool down substrate, the pressure that the back of the body blowing applies towards substrate lower surface is referred to as the back of the body and blows Air pressure.It is readily appreciated that, the back of the body is blown, and pressure is higher, then underlayer temperature is lower;The pressure conversely, back of the body is blown Lower, then underlayer temperature is higher.Therefore, by adjusting back of the body air blowing pressure, it is possible to achieve to substrate The control of temperature, such that it is able to fast and effeciently adjust the height and bottom width of substrate figure.This hair The substrate etching method of bright offer, comprises the following steps:
Main etch step (Main Etch, ME), for modifying mask pattern, while etching Form the base profile of figure.
Over etching step (Over Etch, OE), (side wall and turns for modifying figure pattern Angle) so that its size and dimension reaches technological requirement.
Wherein, when main etch step is carried out, etching ion is moved towards approximate 45 ° of direction, This causes that the sidewall profile of substrate figure is gradually changed in etching process.Specifically, carving The starting stage of erosion, due to being limited by mask original sidewall, the side wall of substrate figure hang down Straight degree is higher;However, with the increase of etch period, two relative side walls of mask can direction Laterally shrink, cause the width of mask to become narrow gradually, this cause the side wall of substrate figure because The cross-direction shrinkage of mask and there is turning.In main etch step, the chamber pressure of reaction chamber Scope in 2~5mT;The scope of upper electrode power is in 1000~2500W;Lower electrode power Scope is in 100~700W;The range of flow of etching gas is in 60~200sccm;Process time Scope in 15~40min.
Over etching step uses relatively low chamber pressure and substrate bias power higher, is used to improve Physical bombardment energy, so that the turning of substrate side wall is progressively smaller until disappearance, so that substrate Figure pattern reaches technological requirement.In over etching step, the model of the chamber pressure of reaction chamber It is trapped among 1.5~3mT;The scope of upper electrode power is in 1000~2500W;The model of lower electrode power It is trapped among 500~800W;The range of flow of etching gas is in 60~100sccm;Process time Scope is in 10~20min.
Further, above-mentioned main etch step includes step S1 and step S2, when figure side When turning occurs in wall, end step S1 starts simultaneously at step S2.Over etching step includes step Rapid S3 and step S4, when the height at turning reaches fixed value, end step S3, while Start step S4.Wherein, the back of the body for cooling down substrate that step S1 and step S4 are used Pressure of blowing is blown less than the back of the body for cooling down substrate that step S2 and step S3 is used and is pressed. Also, step S1 and step S4 are blown using first back of the body and press cooling substrate;Step S2 and Step S3 is blown using second back of the body and presses cooling substrate.That is, step S1 and step The back of the body of S4 is blown, and pressure is identical, and rapid S2 is identical with the back of the body of step S3 air blowing pressure, and step S1 Blown with the back of the body that step S4 is used and press (the first back of the body air blowing pressure) to be adopted less than rapid S2 and step S3 The back of the body is blown and is pressed (second back of the body is blown and pressed).
Due in the whole process time, when there is turning with the pattern side wall of substrate As starting point (now step S2 starts), fixed value as knot is reached using the height at turning The highest of advancing the speed of spot (now step S3 is completed) this time segment figure bottom width, because This, reduces underlayer temperature by blowing pressure using the back of the body higher within this time period, and its Remaining process time (step S1 and step S4) blows pressure to improve substrate using the relatively low back of the body Temperature, can reach the purpose of increase figure bottom width in shorter time.Furtherly, although The height of substrate figure will certainly be reduced using the back of the body higher pressure of blowing, but, due to using compared with The back of the body high is blown, and this time period of pressure is shorter, and this causes that the reduction degree of pattern height is smaller, from And still can reach technological requirement scope.Simultaneously as within the time period figure bottom width Advance the speed most fast, even if time shorter remaining on can make figure bottom width increase to technological requirement In the range of, it is final to obtain bottom width and be highly satisfied by desired figure pattern.
It should be noted that in the present embodiment, the back of the body of step S1 and step S4 is blown and is pressed Identical, step S2 is identical with the back of the body of step S3 air blowing pressure.But the invention is not limited in This, in actual applications, the back of the body air blowing pressure of step S1 and step S4 can also be according to specific Situation is designed as difference.Likewise, the back of the body air blowing pressure of step S2 and step S3 can also root Difference is designed as according to concrete condition.
Preferably, the process time sum of above-mentioned steps S2 and step S3 is 10~45min. The step S1 corresponding technique moment is the 0th minute~the 20th minute.The corresponding works of step S4 The skill moment terminated for the 30th minute~technique.First back of the body blows the span pressed in 2~5Torr. Second back of the body blows the span pressed in 4~8Torr.
From the foregoing, it will be observed that the substrate etching method that the present invention is provided is using underlayer temperature higher Under the conditions of can promote pattern height increase, figure bottom width reduce;Relatively low underlayer temperature can condition Under figure bottom width can be promoted to increase, pattern height is the characteristics of reduce, by targetedly in figure This time period of highest of advancing the speed of shape bottom width uses back of the body blow pressure power higher, to reduce substrate Temperature, can reach the purpose of increase figure bottom width, simultaneously because shortening in shorter time The mask etching speed time higher, the residual thickness of mask after main etch step can be increased, Thereby may be ensured that pattern height reaches claimed range, it is final to obtain bottom width and be highly satisfied by wanting The figure pattern asked.
As shown in figure 3, being the evolution process figure of substrate figure pattern.The work of main etch step Skill parameter is:The chamber pressure of reaction chamber is 3mT;Upper electrode power is 1600W;Under Electrode power is 500W;The flow of etching gas is 120sccm;Process time is 20min. The technological parameter of over etching step is:The chamber pressure of reaction chamber is 2.5mT;Top electrode work( Rate is 1600W;Lower electrode power is 700W;The flow of etching gas is 70sccm;Work The skill time is 25min.
In main etch step, within the 0th minute~the 15th minute this period, due to turning Angle does not occur also, angle (hereinafter referred to as side wall angle) base between the side wall of figure and base This is constant, therefore, the bottom width substantially constant of figure.Turning was will appear from the 15th minute. Within the 15th minute~the 20th minute this period, turning occurs, and moves gradually downward, So that side wall angle is tapered into, so that the broadening of figure gradually increases.
Over etching step was initially entered from the 20th minute, in this step, due to bottom electrode work( Rate is improved, and this causes that the bombardment of plasma acts on enhancing, and figure base edge inside contracts quickening, So that side wall angle increases, advancing the speed for bottom width is slack-off.Since the 30th minute, Close to 90 °, now advancing the speed for bottom width is basically unchanged side wall angle.By above-mentioned tpo substrate It is with side wall angle that the evolution process of shape pattern can be seen that advancing the speed for figure bottom width Change and change, i.e. side wall angle is bigger, then figure bottom width advance the speed it is slower;Conversely, Side wall angle is smaller, then figure bottom width advance the speed it is faster.
Fig. 4 is the bottom width of substrate figure with the change curve of etch period.Fig. 5 is substrate The bottom width of figure is with the change curve for carrying on the back blow pressure power.From Fig. 4 and Fig. 5, the 15th point The figure bottom width increase speed of this time period of clock~30th minute is most fast, i.e.,:Main etch step The moment that middle turning occurs is the starting point of the quick increase of bottom width, and turning is highly in over etching step The moment for being reduced to 300nm or so is the end point that bottom width quickly increases, by targeted Ground blows pressure to reduce underlayer temperature within the time period using the back of the body higher, can effectively increase Figure bottom width.
Preferably, in main etch step, due to when turning occurs, remaining mask (such as photoresist) thickness substantially constant, in 1.3um or so.Therefore, it can basis entering During row main etch step, the etch rate of mask judge pattern side wall occur turning when Carve, with the starting point that this determination bottom width quickly increases.
Additionally, it is preferred that, in over etching step, due to the end point base that bottom width quickly increases This is constant in turning height reduction to this moment of a fixed value, and the span of the fixed value exists 200~400nm, such as 300nm, therefore, it can be judged according to the reduction speed of turning height The height at the turning reaches the moment of fixed value, with the end point that this determination bottom width quickly increases.
One specific embodiment of the substrate etching method for being provided for the present invention below, the substrate Lithographic method specifically includes following steps:
Main etch step, it further includes step ME1 and step ME2, wherein,
The technological parameter of step ME1 is:The chamber pressure of reaction chamber is 2.5mT;Upper electricity Pole power is 1400W;Lower electrode power is 350W;The flow of etching gas is 80sccm; Process time is 18min;The back of the body blows pressure for 4Torr.
The technological parameter of step ME2 is:The chamber pressure of reaction chamber is 2.5mT;Upper electricity Pole power is 1400W;Lower electrode power is 350W;Etching gas are 80sccm;Technique Time is 7min;The back of the body blows pressure for 6Torr.
Over etching step, it further includes step OE1 and step OE2, wherein,
The technological parameter of step OE1 is:The chamber pressure of reaction chamber is 2.2mT;Upper electricity Pole power is 1400W;Lower electrode power is 500W;The flow of etching gas is 60sccm; Process time is 5min;The back of the body blows pressure for 6Torr.
The technological parameter of step OE2 is:The chamber pressure of reaction chamber is 2.2mT;Upper electricity Pole power is 1400W;Lower electrode power is 500W;Etching gas are 60sccm;Technique Time is 8min;The back of the body blows pressure for 4Torr.
Under the technological parameter of above-mentioned steps ME1, the etch rate of mask is about 70nm/min, for the photoresist (being used as mask) of 2.6um, according to etching speed Rate, can extrapolate when carrying out to the 18th minute the process time, the surplus glue thickness of photoresist 1.3um is can reach, the starting point using back of the body blow pressure power higher is now.In above-mentioned steps Under the technological parameter of OE2, the reduction speed of turning height is about 40nm/min, according to this Speed can be extrapolated out when carrying out to the 30th minute the process time, the reduction of turning height To 300nm or so (such as 325nm), the knot using back of the body blow pressure power higher is now Spot.
Fig. 6 is the substrate figure obtained using substrate etching method provided in an embodiment of the present invention The scanning electron microscope (SEM) photograph of pattern.It will be appreciated from fig. 6 that using substrate etching provided in an embodiment of the present invention The substrate figure that method is obtained, it is highly 1.67um;Bottom width is 2.69um, reaches work The scope of skill requirement.
It is understood that the principle that is intended to be merely illustrative of the present of embodiment of above and The illustrative embodiments of use, but the invention is not limited in this.For in the art For those of ordinary skill, without departing from the spirit and substance in the present invention, can do Go out all variations and modifications, these variations and modifications are also considered as protection scope of the present invention.

Claims (10)

1. a kind of substrate etching method, including main etch step and over etching step, its feature It is,
The main etch step further includes step S1 and step S2, when pattern side wall goes out During existing turning, terminate the step S1, start simultaneously at the step S2;
The over etching step further includes step S3 and step S4, when the turning When highly reaching fixed value, terminate the step S3, start simultaneously at the step S4;
Wherein, the back of the body for cooling down substrate that the step S1 and the step S4 are used Pressure blow less than the back of the body for cooling down substrate that the step S2 and the step S3 are used Blow and press.
2. substrate etching method according to claim 1, it is characterised in that the step The rapid S1 and step S4 is blown using first back of the body and presses cooling substrate;The step S2 and The step S3 is blown using second back of the body and presses cooling substrate;First back of the body air blowing pressure is less than Second back of the body is blown and is pressed.
3. substrate etching method according to claim 1, it is characterised in that according to During carrying out the main etch step, the etch rate of mask judges that turning occurs in pattern side wall The moment at angle.
4. substrate etching method according to claim 1, it is characterised in that according to During carrying out the over etching step, the reduction speed of the height at the turning judges described The height at turning reaches the moment of fixed value.
5. substrate etching method according to claim 1, it is characterised in that described solid The span of definite value is in 200~400nm.
6. substrate etching method according to claim 1, it is characterised in that the step The process time sum of the rapid S2 and step S3 is 10~45min.
7. substrate etching method according to claim 6, it is characterised in that the step The rapid S1 corresponding technique moment is the 0th minute~the 20th minute.
8. substrate etching method according to claim 6, it is characterised in that the step The rapid S4 corresponding technique moment terminated for the 30th minute~technique.
9. substrate etching method according to claim 2, it is characterised in that described One back of the body blows the span pressed in 2~5Torr.
10. substrate etching method according to claim 2, it is characterised in that described Two back ofs the body blow the span pressed in 4~8Torr.
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CN110867503B (en) * 2018-08-28 2021-06-08 北京北方华创微电子装备有限公司 Manufacturing method of patterned substrate, patterned substrate and light emitting diode

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