CN106676960A - 节能型热升华转印纸 - Google Patents

节能型热升华转印纸 Download PDF

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CN106676960A
CN106676960A CN201611158904.2A CN201611158904A CN106676960A CN 106676960 A CN106676960 A CN 106676960A CN 201611158904 A CN201611158904 A CN 201611158904A CN 106676960 A CN106676960 A CN 106676960A
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戚裕
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Abstract

本发明公开了一种节能型热升华转印纸，包括基材、粘结剂和涂布在基材表面上的涂层，所述涂层在基材表面的涂布量为每平方米4～15克，所述涂层包括蔗糖1‑10份、季戊四醇1‑15份、羧甲基纤维素5‑30份、聚乙二醇脂肪酸酯2‑15份、杀菌剂2‑10份、喷墨介质吸附剂2‑20份、淀粉5‑20份、丙烯酸树脂5‑20份、松浆油脂肪酸2‑15份、聚丙烯酰胺1‑15份、多糖衍生物1‑10份、聚柠檬酸2‑20份、二氧化硅1‑15份、氧化铝1‑15份，二氧化钛1‑15份、高岭土1‑15份、碳酸钙1‑15份、纳米二氧化钛粉末4‑10份、超细氧化锡锑粉末8‑15份，本发明制备工艺简单，制得油墨具有良好的托墨能力、耐腐性、耐磨性、抗氧化性、耐水性和附着能力。

Description

节能型热升华转印纸
技术领域
本发明涉及热升华转印技术领域，具体为一种节能型热升华转印纸。
背景技术
热升华转印是一种无水印染工艺，具有较高的环保效应，对目前国家倡导的高能耗行业节能减排改造工程具有重要价值，目前已成为研究热点。热升华转印的原理是在高温下(通常为220℃以上)，热升华转印介质上的分散染料升华至化纤面料上并直接被面料纤维固定，印染好的化纤面料可以免水洗。可以认为，热升华转印工艺，尤其是数码热升华转印工艺，是一种高度环保并且实用可靠的工艺，有希望替代传统印染工艺。
而喷墨热升华转印纸提升了印刷精致度，更重要的是能够便捷地实现了纺织品的无水印染，喷墨打印机在电脑的控制下可以直接在喷墨热升华转印纸上打印出色彩艳丽、形象逼真的效果而无需制版等工序，再经过简单加热工序即可使被转印物得到精致的印刷效果。然而，由于升华转移印刷过程需要加热到较高的温度，因此高温转移时油墨的连接料必须具备一定的耐热性此外，现有的转印纸墨水的托墨能力比较差，需要涂布的量比较多，目前国内外对于热升华转移印纸及其制备方法较少。
发明内容
本发明的目的在于提供一种节能型热升华转印纸，以解决上述背景技术中提出的问题。
为实现上述目的，本发明提供如下技术方案：一种节能型热升华转印纸，包括基材、粘结剂和涂布在基材表面上的涂层，所述涂层在基材表面的涂布量为每平方米4～15克，所述涂层包括蔗糖1-10份、季戊四醇1-15份、羧甲基纤维素5-30份、聚乙二醇脂肪酸酯2-15份、杀菌剂2-10份、喷墨介质吸附剂2-20份、淀粉5-20份、丙烯酸树脂5-20份、松浆油脂肪酸2-15份、聚丙烯酰胺1-15份、多糖衍生物1-10份、聚柠檬酸2-20份、二氧化硅1-15份、氧化铝1-15份，二氧化钛1-15份、高岭土1-15份、碳酸钙1-15份、纳米二氧化钛粉末4-10份、超细氧化锡锑粉末8-15份、海藻酸钠10-20份、硅藻土粉末5-10份、酚醛树脂4-8份、甲苯2-12份、双咪唑啉季铵盐缓蚀剂4-8份以及噻吩水分散液10-20份。
较佳的，所述多糖衍生物包括：聚葡萄糖、葡聚糖、阿拉伯胶、琼脂、糖元、透明质酸。
较佳的，所述的聚乙二醇脂肪酸酯为聚乙二醇400双硬脂酸酯、聚乙二醇400单硬脂酸酯、聚乙二醇6000单油酸酯、聚乙二醇400单月桂酸酯、聚乙二醇2000双硬脂酸酯中的一种或几种。
较佳的，所述的基材为每平方米90克的热升华原纸，所述涂层的涂布量为每平方米10克。
较佳的，所述粘结剂为水性树脂，采用乙二醛、聚酰胺类树脂、碳酸锆钾、苯乙烯系热塑性弹性体中的任意一种或几种的混合物。
较佳的，所述涂层最佳配比为蔗糖2份、季戊四醇3份、羧甲基纤维素10份、聚乙二醇脂肪酸酯5份、杀菌剂3份、喷墨介质吸附剂6份、淀粉5份、丙烯酸树脂6份、松浆油脂肪酸3份、聚丙烯酰胺4份、多糖衍生物2份、聚柠檬酸3份、二氧化硅2份、氧化铝2份，二氧化钛2份、高岭土2份、碳酸钙5份、纳米二氧化钛粉末5份、超细氧化锡锑粉末8份、海藻酸钠10份、硅藻土粉末5份、酚醛树脂4份、甲苯5份、双咪唑啉季铵盐缓蚀剂4份以及噻吩水分散液10份。
与现有技术相比，本发明的有益效果是：
(1)本发明制备工艺简单，制得热升华转印纸具有良好的托墨能力、耐磨性、抗氧化性、耐水性和附着能力；
(2)本发明中增加有防腐蚀剂，能够使涂层具有良好的防腐蚀性；
(3)本发明中添加有一定比例的纳米二氧化钛粉末和超细氧化锡锑粉末，能够使涂层更加均匀，进一步提高了转印质量。
(4)本发明添加的双咪唑啉季铵盐缓蚀剂以及噻吩水分散液，能够调节涂层的PH，同时还能够防止打印过程中，涂层阻塞喷嘴，影响转印效果。
具体实施方式
下面对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本发明提供一种技术方案：一种节能型热升华转印纸，包括基材、粘结剂和涂布在基材表面上的涂层，所述涂层在基材表面的涂布量为每平方米4～15克，所述涂层包括蔗糖1-10份、季戊四醇1-15份、羧甲基纤维素5-30份、聚乙二醇脂肪酸酯2-15份、杀菌剂2-10份、喷墨介质吸附剂2-20份、淀粉5-20份、丙烯酸树脂5-20份、松浆油脂肪酸2-15份、聚丙烯酰胺1-15份、多糖衍生物1-10份、聚柠檬酸2-20份、二氧化硅1-15份、氧化铝1-15份，二氧化钛1-15份、高岭土1-15份、碳酸钙1-15份、纳米二氧化钛粉末4-10份、超细氧化锡锑粉末8-15份、海藻酸钠10-20份、硅藻土粉末5-10份、酚醛树脂4-8份、甲苯2-12份、双咪唑啉季铵盐缓蚀剂4-8份以及噻吩水分散液10-20份。
实施例一：
于本实施例中，所述涂层最佳配比为蔗糖2份、季戊四醇3份、羧甲基纤维素10份、聚乙二醇脂肪酸酯5份、杀菌剂3份、喷墨介质吸附剂6份、淀粉5份、丙烯酸树脂6份、松浆油脂肪酸3份、聚丙烯酰胺4份、多糖衍生物2份、聚柠檬酸3份、二氧化硅2份、氧化铝2份，二氧化钛2份、高岭土2份、碳酸钙5份、纳米二氧化钛粉末5份、超细氧化锡锑粉末8份、海藻酸钠10份、硅藻土粉末5份、酚醛树脂4份、甲苯5份、双咪唑啉季铵盐缓蚀剂4份以及噻吩水分散液10份。
于本实施例中，所述多糖衍生物包括：聚葡萄糖、葡聚糖、阿拉伯胶、琼脂、糖元、透明质酸。
于本实施例中，所述的聚乙二醇脂肪酸酯为聚乙二醇400双硬脂酸酯、聚乙二醇400单硬脂酸酯、聚乙二醇6000单油酸酯、聚乙二醇400单月桂酸酯、聚乙二醇2000双硬脂酸酯中的一种或几种。
于本实施例中，所述的基材为每平方米90克的热升华原纸，所述涂层的涂布量为每平方米10克。
于本实施例中，所述粘结剂为水性树脂，采用乙二醛、聚酰胺类树脂、碳酸锆钾、苯乙烯系热塑性弹性体中的任意一种或几种的混合物。
实施例二：
于本实施例中，所述涂层最佳配比为蔗糖5份、季戊四醇4份、羧甲基纤维素10份、聚乙二醇脂肪酸酯10份、杀菌剂4份、喷墨介质吸附剂6份、淀粉5份、丙烯酸树脂6份、松浆油脂肪酸3份、聚丙烯酰胺4份、多糖衍生物2份、聚柠檬酸5份、二氧化硅2份、氧化铝2份，二氧化钛2份、高岭土2份、碳酸钙5份、纳米二氧化钛粉末5份、超细氧化锡锑粉末8份、海藻酸钠10份、硅藻土粉末5份、酚醛树脂4份、甲苯5份、双咪唑啉季铵盐缓蚀剂4份以及噻吩水分散液10份。
于本实施例中，所述多糖衍生物包括：聚葡萄糖、葡聚糖、阿拉伯胶、琼脂、糖元、透明质酸。
于本实施例中，所述的聚乙二醇脂肪酸酯为聚乙二醇400双硬脂酸酯、聚乙二醇400单硬脂酸酯、聚乙二醇6000单油酸酯、聚乙二醇400单月桂酸酯、聚乙二醇2000双硬脂酸酯中的一种或几种。
于本实施例中，所述的基材为每平方米90克的热升华原纸，所述涂层的涂布量为每平方米10克。
于本实施例中，所述粘结剂为水性树脂，采用乙二醛、聚酰胺类树脂、碳酸锆钾、苯乙烯系热塑性弹性体中的任意一种或几种的混合物。
实施例三：
于本实施例中，所述涂层最佳配比为蔗糖2份、季戊四醇3份、羧甲基纤维素15份、聚乙二醇脂肪酸酯10份、杀菌剂3份、喷墨介质吸附剂6份、淀粉5份、丙烯酸树脂6份、松浆油脂肪酸3份、聚丙烯酰胺4份、多糖衍生物2份、聚柠檬酸3份、二氧化硅2份、氧化铝2份，二氧化钛2份、高岭土2份、碳酸钙5份、纳米二氧化钛粉末6份、超细氧化锡锑粉末10份、海藻酸钠12份、硅藻土粉末5份、酚醛树脂4份、甲苯5份、双咪唑啉季铵盐缓蚀剂4份以及噻吩水分散液10份。
于本实施例中，所述多糖衍生物包括：聚葡萄糖、葡聚糖、阿拉伯胶、琼脂、糖元、透明质酸。
于本实施例中，所述的聚乙二醇脂肪酸酯为聚乙二醇400双硬脂酸酯、聚乙二醇400单硬脂酸酯、聚乙二醇6000单油酸酯、聚乙二醇400单月桂酸酯、聚乙二醇2000双硬脂酸酯中的一种或几种。
于本实施例中，所述的基材为每平方米90克的热升华原纸，所述涂层的涂布量为每平方米10克。
于本实施例中，所述粘结剂为水性树脂，采用乙二醛、聚酰胺类树脂、碳酸锆钾、苯乙烯系热塑性弹性体中的任意一种或几种的混合物。
实施例四：
于本实施例中，所述涂层最佳配比为蔗糖8份、季戊四醇4份、羧甲基纤维素12份、聚乙二醇脂肪酸酯5份、杀菌剂3份、喷墨介质吸附剂6份、淀粉5份、丙烯酸树脂8份、松浆油脂肪酸5份、聚丙烯酰胺4份、多糖衍生物2份、聚柠檬酸3份、二氧化硅2份、氧化铝2份，二氧化钛2份、高岭土2份、碳酸钙6份、纳米二氧化钛粉末5份、超细氧化锡锑粉末8份、海藻酸钠10份、硅藻土粉末5份、酚醛树脂4份、甲苯5份、双咪唑啉季铵盐缓蚀剂4份以及噻吩水分散液10份。
于本实施例中，所述多糖衍生物包括：聚葡萄糖、葡聚糖、阿拉伯胶、琼脂、糖元、透明质酸。
于本实施例中，所述的聚乙二醇脂肪酸酯为聚乙二醇400双硬脂酸酯、聚乙二醇400单硬脂酸酯、聚乙二醇6000单油酸酯、聚乙二醇400单月桂酸酯、聚乙二醇2000双硬脂酸酯中的一种或几种。
于本实施例中，所述的基材为每平方米90克的热升华原纸，所述涂层的涂布量为每平方米10克。
于本实施例中，所述粘结剂为水性树脂，采用乙二醛、聚酰胺类树脂、碳酸锆钾、苯乙烯系热塑性弹性体中的任意一种或几种的混合物。
本发明制备工艺简单，制得热升华转印纸具有良好的托墨能力、防腐性、耐磨性、抗氧化性、耐水性和附着能力；本发明中添加防腐蚀剂，能使油墨具有良好的防腐蚀性，本发明中添加有一定比例的纳米二氧化钛粉末和超细氧化锡锑粉末，能够使涂层更加均匀，还能提高涂层的抗静电能力，提高了转印质量；本发明添加的双咪唑啉季铵盐缓蚀剂以及噻吩水分散液，能够调节涂层的PH，同时还能够防止打印过程中，涂层阻塞喷嘴，影响转印效果。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。

Claims (6)

1.一种节能型热升华转印纸，其特征在于：包括基材、粘结剂和涂布在基材表面上的涂层，所述涂层在基材表面的涂布量为每平方米4～15克，所述涂层包括蔗糖1-10份、季戊四醇1-15份、羧甲基纤维素5-30份、聚乙二醇脂肪酸酯2-15份、杀菌剂2-10份、喷墨介质吸附剂2-20份、淀粉5-20份、丙烯酸树脂5-20份、松浆油脂肪酸2-15份、聚丙烯酰胺1-15份、多糖衍生物1-10份、聚柠檬酸2-20份、二氧化硅1-15份、氧化铝1-15份，二氧化钛1-15份、高岭土1-15份、碳酸钙1-15份、纳米二氧化钛粉末4-10份、超细氧化锡锑粉末8-15份、海藻酸钠10-20份、硅藻土粉末5-10份、酚醛树脂4-8份、甲苯2-12份、双咪唑啉季铵盐缓蚀剂4-8份以及噻吩水分散液10-20份。
2.根据权利要求1所述的节能型热升华转印纸,其特征在于：所述多糖衍生物包括：聚葡萄糖、葡聚糖、阿拉伯胶、琼脂、糖元、透明质酸。
3.根据权利要求1所述的节能型热升华转印纸,其特征在于：所述的聚乙二醇脂肪酸酯为聚乙二醇400双硬脂酸酯、聚乙二醇400单硬脂酸酯、聚乙二醇6000单油酸酯、聚乙二醇400单月桂酸酯、聚乙二醇2000双硬脂酸酯中的一种或几种。
4.根据权利要求1所述的节能型热升华转印纸,其特征在于：所述的基材为每平方米90克的热升华原纸，所述涂层的涂布量为每平方米10克。
5.根据权利要求1所述的节能型热升华转印纸,其特征在于：所述粘结剂为水性树脂，采用乙二醛、聚酰胺类树脂、碳酸锆钾、苯乙烯系热塑性弹性体中的任意一种或几种的混合物。
6.根据权利要求1所述的节能型热升华转印纸,其特征在于：所述涂层最佳配比为蔗糖2份、季戊四醇3份、羧甲基纤维素10份、聚乙二醇脂肪酸酯5份、杀菌剂3份、喷墨介质吸附剂6份、淀粉5份、丙烯酸树脂6份、松浆油脂肪酸3份、聚丙烯酰胺4份、多糖衍生物2份、聚柠檬酸3份、二氧化硅2份、氧化铝2份，二氧化钛2份、高岭土2份、碳酸钙5份、纳米二氧化钛粉末5份、超细氧化锡锑粉末8份、海藻酸钠10份、硅藻土粉末5份、酚醛树脂4份、甲苯5份、双咪唑啉季铵盐缓蚀剂4份以及噻吩水分散液10份。
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