CN106665858A - Green tea goat milk with function of reducing blood pressure and preparation method of green tea goat milk - Google Patents
Green tea goat milk with function of reducing blood pressure and preparation method of green tea goat milk Download PDFInfo
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- CN106665858A CN106665858A CN201611264797.1A CN201611264797A CN106665858A CN 106665858 A CN106665858 A CN 106665858A CN 201611264797 A CN201611264797 A CN 201611264797A CN 106665858 A CN106665858 A CN 106665858A
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING THEREOF
- A23C9/00—Milk preparations; Milk powder or milk powder preparations
- A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
- A23C9/156—Flavoured milk preparations ; Addition of fruits, vegetables, sugars, sugar alcohols or sweeteners
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23F—COFFEE; TEA; THEIR SUBSTITUTES; MANUFACTURE, PREPARATION, OR INFUSION THEREOF
- A23F3/00—Tea; Tea substitutes; Preparations thereof
- A23F3/06—Treating tea before extraction; Preparations produced thereby
- A23F3/14—Tea preparations, e.g. using additives
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Abstract
The invention provides green tea goat milk with a function of reducing blood pressure and a preparation method of the green tea goat milk. Goat milk beverage which is rich in ACE inhibitory peptides is prepared by compound enzymolysis, is low in production cost, not limited by resource and small in environmental pollution, and can be mass-produced, and products are safe. On the basis, ultra-fine green tea powder is prepared by enzymic hydrolysis of cell walls and a low-temperature ultra-fine pulverizing technology, specific surface area is increased, and a large number of effective constituents are released. The ultra-fine green tea powder is added in the goat milk in proportion, and the obtained product not only has various nutrient substances and tea fragrance in green tea, but also has treatment effect of reducing high blood pressure, and has wide application prospect in the food industry. The tea powder is prepared by low-temperature ultra-fine pulverization, the original color, flavor and taste quality of tea leaves can be maintained effectively, after the tea leaves is pulverized into ultra-fine powder, the specific surface area of the tea powder is increased obviously, the effective constituents are released easily, human absorption can be improved, and therefore, nutrition absorptivity of human to the tea leaves is improved. Ultra-fine pulverization is a pure physical process, and pure natural property of processed products is maintained.
Description
Technical field
The present invention relates to functional beverage and preparation method thereof, specially a kind of green tea goat milk with antihypertensive function and
Its preparation method.
Background technology
The health of the hypertension serious harm mankind, triggers various cardiovascular and cerebrovascular diseases and kidney trouble, also easily causes brain finally
Neutralize the morbidity of coronary heart disease.China hyperpietic number up to 3.3 hundred million people, and in rejuvenation trend, 25 years old to 34 years old
The illness rate of hypertension has reached 20.4% in male.Therefore it is extremely urgent to the prophylactic treatment of hypertension.Vasotonia
Can degrade carnosine of releiving of plain invertase (ACE) makes it lose activity, and then influences capillary diastole to cause elevation of the blood pressure.Research
It was found that micromolecule polypeptide --- the ace inhibitory peptide formed after food protein is hydrolyzed, can significantly reduce hypertension, and
Have no toxic side effect.This biologically active peptide, it is this in small enteral with the advantage that molecular weight is small, safe and effective, physiological function is strong
Peptide can be absorbed in the form of complete peptide fragment, will not cause rejection.Therefore food-borne ace inhibitory peptide is in exploitation hypotensive
Food and health products aspect have broad prospects.The method for preparing ace inhibitory peptide at present has four kinds, is respectively directly to extract
Method, chemical synthesis, microbe fermentation method and enzymatic isolation method.Direct extraction method needs to consume a large amount of living resources, chemical synthesis
Inefficiency, Product recycling are difficult, and microbe fermentation method is too high to strain and food source requirement, and enzymatic isolation method mild condition, it is right
Proteinaceous nutrient destruction is small, and course of reaction is easily controllable, but at present more using cow's milk as food source, on the sheep fresh understatement of breast
Road.
Goat milk is of high nutritive value, and its trophic component is given birth in addition to lactose in dry, fat, protein, calcium, phosphorus and dimension
Plain A equal sizes are above cow's milk, close to human milk, are referred to as fine work in breast.Ace inhibitory peptide, convenient sources are prepared from sheep breast
Safety, and ace inhibitory peptide can jointly be absorbed by the body with other nutritional ingredients.
Modern study proves that tealeaves has various effects such as anti-oxidant, anti-mutation, antitumor, the immune, lowering fat and protecting liver of regulation.
Especially unfermentable green tea, contained active component such as Tea Polyphenols, caffeine, amino acid, vitamin equal proportion is higher.Traditional
The method of drinking tea is to use boiling water brewing tea, but boiling water is brewed and whole nutritional ingredient dissolutions of tealeaves can not inhaled for human body
Receive, some insoluble or slightly solubility composition such as vitamin As, E, K and most protein, dietary fiber, carrotene with
And part mineral matter etc. resides in tea grounds.
In sum, goat milk gently moistens, in China's breast source very abundant;Green tea as China one of main teas,
National drink is described as, it is very popular;Therefore ace inhibitory peptide is prepared from sheep breast and green tea combines to be made and is easy to drink, rich in ACE suppressions
The green tea goat milk beverage of peptide processed, not only improves the nutritive value and health-care efficacy of goat milk, can also provide the various battalion in green tea
Material and tea smell are supported, new product appearance feature and peculiar flavour is formed, the growing green of consumer and health is met
Food demand.On the research rich in ace inhibitory peptide green tea goat milk, relevant report is there is no both at home and abroad at present.
The content of the invention
For problems of the prior art, the present invention provides a kind of green tea goat milk and its system with antihypertensive function
Preparation Method, production cost is relatively low, and not by resource constraint, environmental pollution is small, can largely produce and product is safer;It is not only able to
Various nutriments and tea smell in green tea are provided, reduction hypertension therapeutic effect is more had concurrently, are had in food service industry extensive
Application prospect.
The present invention is to be achieved through the following technical solutions:
A kind of green tea goat milk preparation method with antihypertensive function, comprises the following steps,
Step 1, extracting degreasing sheep breast is added dropwise 1mol/L HCl and stirs at 45-80 DEG C, until pH value is 4-7, is contained
There is the sheep breast of casein and lactalbumin;
Step 2, volume fraction is added for 5-10% composite enzyme solutions are entered in the sheep breast containing casein and lactalbumin
Stop after the hydrolysis of row 70-120min, obtain the sheep breast rich in ace inhibitory peptide;
Step 3, by mass fraction for the tannin enzyme solutions of 5-10% are uniformly sprayed at green tea surface, and holding at least 2 is small
Shi Jinhang is digested, wherein, the ratio of tannase liquor capacity and green tea quality is 0.2-3;Then go out enzyme 0.5- at 70-90 DEG C
1h;Finally by ball milling at 1-10 DEG C ultramicro grinding 1-3h, at room temperature cross 2000 mesh sieves, through 45-55 DEG C of drying after, obtain
Ultrafine green tea powder of the tea powder average grain diameter less than 14 μm;
Step 4, at 40-80 DEG C, the sheep breast and ultrafine green tea powder that will be enriched in ace inhibitory peptide are thoroughly mixed uniformly,
Wherein, rich in ace inhibitory peptide sheep breast volume and the ratio of ultrafine green tea powder quality is (10-8):1;Then cooled down through moist heat sterilization
Afterwards, the green tea goat milk with antihypertensive function is obtained.
Preferably, in step 1, degreasing sheep breast is obtained as follows;Distilled water is added to be made into recovery in goat milk powder
Sheep breast, degreasing sheep breast is obtained after restoring sheep breast high speed centrifugation, is placed in 4 DEG C and is saved backup;Wherein, the matter of goat milk powder and distilled water
Amount volume ratio is (0.5-2):9.
Preferably, in step 2, hydrolysising reacting temperature is 45-80 DEG C.
Preferably, 0.1mol/L NaOH are added dropwise in reaction solution in step 2, during hydrolysis and adjust pH value to 6.5-
8.5。
Preferably, in step 2, composite enzyme solution includes that volume ratio is (3-1):1 trypsase and Proteinase K.
Preferably, in step 3, green tea is balanced 30- by described green tea using the spring tea through fried green under constant temperature and humidity
48h。
Further, constant temperature is 22 DEG C, and constant humidity is RH=60%.
Preferably, in step 4, will be enriched in ace inhibitory peptide sheep breast and ultrafine green tea powder be thoroughly mixed it is uniform after according to
It is secondary to add white sugar and flavoring essence, then cooled down through moist heat sterilization.
Preferably, in step 4, during moist heat sterilization, at 121 DEG C, sterilize 10-30min.
A kind of green tea goat milk with antihypertensive function, is prepared by method of the present invention;It includes containing ACE
The sheep breast and ultrafine green tea powder of peptide for inhibiting, the ratio of sheep breast volume and ultrafine green tea powder quality containing ace inhibitory peptide is (10-8):
1。
Compared with prior art, the present invention has following beneficial technique effect:
The present invention prepares the goat milk beverage rich in ace inhibitory peptide using conbined enzymolysis, and the method production cost is relatively low, no
By resource constraint, environmental pollution is small, can largely produce and product is safer.On this basis, combined using enzymatic shell-broken low
Warm superfine communication technique prepares ultrafine green tea powder, increases specific surface area, largely discharges active ingredient.In sheep breast by a certain percentage
Addition ultrafine green tea powder, products obtained therefrom not only provides the various nutriments and tea smell in green tea, more has reduction hypertension concurrently
Therapeutic effect, has wide application prospect in food service industry.Wherein, the broken tea powder for preparing of low-temperature submicron powder can not only effectively keep tea
The original color, smell and taste quality of leaf, and after tealeaves ultramicro grinding, tea powder specific surface area substantially increases, and active ingredient is easy to release,
Body absorption can be promoted, and then improve nutrition absorption rate of the human body to tealeaves.Ultramicro grinding is pure physical process, in processing not
Chemical reagent is added, the pure natural property of converted products is kept.Carry out enzymatic shell-broken pretreatment before crushing, reaction condition is gentle,
Effective content of tea is hardly suffered a loss in process in leaching, the yield of active ingredient is high, products therefrom purity, stability, work
Property is higher and environmentally safe.
Brief description of the drawings
Fig. 1 is the scanning electron microscope (SEM) photograph SEM of ultrafine green tea powder described in present example.
Fig. 2 is ultrafine green tea powder nutrient composition content described in present example.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail, it is described be explanation of the invention and
It is not to limit.
A kind of a kind of green tea goat milk with antihypertensive function of the present invention and preparation method thereof, there is provided feature green tea sheep
The preparation method of milk drink, being rich in prepared green tea goat milk has ace inhibitory peptide.The present invention is with ultrafine green tea powder and is rich in
The sheep breast of ace inhibitory peptide is raw material, is sufficiently mixed at 40-80 DEG C, adds white sugar and flavoring essence, and high-temperature heat sterilization is cold
But green tea goat milk beverage is obtained afterwards.
Specifically, the sheep breast is degreasing sheep breast, commercially available goat milk powder is pressed 1:9 (w/v) add distilled water, in 6000rpm
Rotating speed under be centrifuged 15min obtain final product degreasing sheep breast.The ace inhibitory peptide is prepared by combined-enzyme method, with feta albumen and breast
Albumin is substrate, and the complex enzyme mixed using trypsase and Proteinase K carries out enzymolysis preparation.The degreasing sheep breast is at 45 DEG C
Under, be added dropwise 1mol/L HCl, stirring intensity 1200rpm, to pH value be 4.6 when stop stirring.0.1mol/L NaOH regulations are added dropwise
PH value is 8.4, and the volume ratio of trypsase and Proteinase K is 1 in complex enzyme:1, addition is 8% (v/v), is entered at 45 DEG C
Row hydrolysis, stops after 90min, obtains the sheep breast rich in ace inhibitory peptide, is suppressed using determined by ultraviolet spectrophotometry ACE
Rate is 80%, IC50It is 0.8523mg/mL (IC to be worth50It is the required peptide concentration when the activity inhibited of ACE is to 50%).
A certain proportion of ultrafine green tea powder is added in sheep breast enzymolysis liquid, preferably using 9:1 (v/w), the ultrafine green tea powder is with city
Spring tea (fried green) is sold for raw material, 48h is balanced under constant temperature and humidity (22 DEG C, RH=60%), with 10% (w/v) tannin enzyme solutions broken wall
Treatment at least 2 hours, high temperature goes out after enzyme.2h is ground at 4 DEG C by ball-milling medium of zirconium oxide, tea powder average grain diameter is less than 14 μ
M, as shown in figure 1, making multiple nutritional components such as protein, polyphenol, amino acid, vitamin C etc. in tealeaves fully discharge such as Fig. 2 institutes
Show.Saved backup after the 45 DEG C of dryings of gained super fine tea powder.
Green tea goat milk prepared by the present invention is rich in ace inhibitory peptide, and small molecular protein ace inhibitory peptide can be with complete in small intestine
The form of whole peptide fragment is absorbed, and will not cause rejection, without any side effects.Described green tea is broken by low-temperature submicron powder
Afterwards, its nutritional ingredient can not only be effectively maintained, and the composition such as vitamin A, E, K of its slightly solubility can be in sheep breasts
Fully dissolving, and then expand absorption of the human body to nutriment.Green tea goat milk beverage preparation process is simple, raw material sources enrich,
Tea smell contained by the existing green tea of product, and with multiple effects such as reduction hypertension, enhance immunities.
Embodiment 1
A kind of green tea goat milk preparation method rich in ace inhibitory peptide, comprises the following steps:
First:A certain amount of commercially available goat milk powder is weighed, proportionally 0.5:9 (w/v) add distilled water to be made into recovery sheep breast,
High speed centrifugation 15min obtains degreasing sheep breast under 6000rpm rotating speeds, is placed in 4 DEG C and saves backup.
Second:100mL degreasings sheep breast is taken, 1mol/L HCl are added dropwise at 45 DEG C, stirred with the magnetic force of stirring intensity 1200rpm
Mix device and be stirred and stop when pH=4, obtain the sheep breast containing casein and lactalbumin.
3rd:Composite enzyme solution (trypsase and Proteinase K, 1 are prepared according to a certain percentage:1, v/v), addition is
5% (v/v), be hydrolyzed reaction at 45 DEG C, 0.1mol/L NaOH is added dropwise in reaction solution and adjusts to pH=6.5,70min
After stop.The sheep breast rich in ace inhibitory peptide is obtained, determined by ultraviolet spectrophotometry ACE inhibiting rates can be used.
4th:With commercially available spring tea (fried green) as raw material, 30h is balanced under constant temperature and humidity (22 DEG C, RH=60%).Take quantitatively green
Tea prepares mass fraction 5% (w/v) tannin enzyme solutions on pallet, by 0.7% enzyme addition, is uniformly sprayed with laryngeal spray
Green tea surface is sprinkled upon, and holding is digested at least 2 hours.70 DEG C of high temperature go out enzyme.Surpass at 1 DEG C by ball-milling medium of zirconium oxide
Crushing of Ultrafine 1h, crosses 2000 mesh sieves at room temperature, and the 45 DEG C of dryings of gained super fine tea powder obtain ultra micro of the tea powder average grain diameter less than 14 μm
Green tea powder is standby.
5th:Will be enriched in the newborn and dry ultrafine green tea powder of sheep of ace inhibitory peptide according to a certain percentage 10:1 (v/w),
30min is thoroughly mixed at 40 DEG C.
6th:White sugar and flavoring essence are sequentially added, moist heat sterilization (121 DEG C, 10min) obtains green tea sheep after cooling
Milk beverage.Green tea goat milk beverage smell delicate fragrance prepared by the present invention, mouthfeel is sweet, and color and luster is salubrious, has antihypertensive function concurrently.
Embodiment 2
A kind of green tea goat milk preparation method rich in ace inhibitory peptide, comprises the following steps:
First:A certain amount of commercially available goat milk powder is weighed, proportionally 1:9 (w/v) add distilled water to be made into recovery sheep breast,
High speed centrifugation 30min obtains degreasing sheep breast under 6000rpm rotating speeds, is placed in 4 DEG C and saves backup.
Second:100mL degreasings sheep breast is taken, 1mol/L HCl are added dropwise at 50 DEG C, stirred with the magnetic force of stirring intensity 1200rpm
Mix device and be stirred and stop when pH=5.5, obtain the sheep breast containing casein and lactalbumin.
3rd:Composite enzyme solution (trypsase and Proteinase K, 2 are prepared according to a certain percentage:1, v/v), addition is
8% (v/v), be hydrolyzed reaction at 50 DEG C, 0.1mol/L NaOH is added dropwise in reaction solution and adjusts to pH=7, after 90min
Stop.The sheep breast rich in ace inhibitory peptide is obtained, determined by ultraviolet spectrophotometry ACE inhibiting rates can be used.
4th:With commercially available spring tea (fried green) as raw material, 38h is balanced under constant temperature and humidity (22 DEG C, RH=60%).Take quantitatively green
Tea prepares mass fraction 8% (w/v) tannin enzyme solutions on pallet, by 3% enzyme addition, is uniformly sprayed with laryngeal spray
Digested within least 2 hours on green tea surface, and holding.80 DEG C of high temperature go out enzyme.The ultra micro at 4 DEG C with zirconium oxide as ball-milling medium
2h is crushed, 2000 mesh sieves are crossed at room temperature, the 50 DEG C of dryings of gained super fine tea powder obtain ultra micro of the tea powder average grain diameter less than 14 μm green
Tea powder is standby.
5th:Will be enriched in the newborn and dry ultrafine green tea powder of sheep of ace inhibitory peptide according to a certain percentage 9:1 (v/w), 60
30min is thoroughly mixed at DEG C.
6th:White sugar and flavoring essence are sequentially added, moist heat sterilization (121 DEG C, 15min) obtains green tea sheep after cooling
Milk beverage.Green tea goat milk beverage smell delicate fragrance prepared by the present invention, mouthfeel is sweet, and color and luster is salubrious, has antihypertensive function concurrently.
Embodiment 3
A kind of green tea goat milk preparation method rich in ace inhibitory peptide, comprises the following steps:
First:A certain amount of commercially available goat milk powder is weighed, proportionally 2:9 (w/v) add distilled water to be made into recovery sheep breast,
High speed centrifugation 40min obtains degreasing sheep breast under 6000rpm rotating speeds, is placed in 4 DEG C and saves backup.
Second:100mL degreasings sheep breast is taken, 1mol/L HCl are added dropwise at 80 DEG C, stirred with the magnetic force of stirring intensity 1200rpm
Mix device and be stirred and stop when pH=7.Obtain the sheep breast containing casein and lactalbumin.
3rd:Composite enzyme solution (trypsase and Proteinase K, 3 are prepared according to a certain percentage:1, v/v), addition is
10% (v/v), be hydrolyzed reaction at 80 DEG C, 0.1mol/L NaOH is added dropwise in reaction solution and adjusts to pH=8.5,
Stop after 120min.The sheep breast rich in ace inhibitory peptide is obtained, determined by ultraviolet spectrophotometry ACE inhibiting rates can be used.
4th:With commercially available spring tea (fried green) as raw material, 48h is balanced under constant temperature and humidity (22 DEG C, RH=60%).Take quantitatively green
Tea prepares mass fraction 10% (w/v) tannin enzyme solutions on pallet, by 0.2% enzyme addition, is uniformly sprayed with laryngeal spray
Green tea surface is sprinkled upon, and holding is digested at least 2 hours.90 DEG C of high temperature go out enzyme.It is ball-milling medium at 10 DEG C with zirconium oxide
Ultramicro grinding 3h, crosses 2000 mesh sieves at room temperature, and the 55 DEG C of dryings of gained super fine tea powder obtain tea powder average grain diameter super less than 14 μm
Micro- green tea powder is standby.
5th:Will be enriched in the newborn and dry ultrafine green tea powder of sheep of ace inhibitory peptide according to a certain percentage 8:1 (v/w), 80
30min is thoroughly mixed at DEG C.
6th:White sugar and flavoring essence are sequentially added, moist heat sterilization (121 DEG C, 30min) obtains green tea sheep after cooling
Milk beverage.Green tea goat milk beverage smell delicate fragrance prepared by the present invention, mouthfeel is sweet, and color and luster is salubrious, has antihypertensive function concurrently.
The scope of the present invention is not limited by the specific embodiments described, and the embodiment is only used as illustrating of the invention each
The single example of aspect, the scope of the invention also method and component including functional equivalent.Those skilled in the art without departing from
On the premise of claim limits scope, various modifications and variations, the modifications and variations done still can be made to the present invention
Still fall within protection scope of the present invention.
Claims (10)
1. a kind of green tea goat milk preparation method with antihypertensive function, it is characterised in that comprise the following steps,
Step 1, extracting degreasing sheep breast is added dropwise 1mol/L HCl and stirs at 45-80 DEG C, until pH value is 4-7, obtains containing junket
The sheep breast of albumen and lactalbumin;
Step 2, volume fraction is added for 5-10% composite enzyme solutions carry out 70- in the sheep breast containing casein and lactalbumin
Stop after the hydrolysis of 120min, obtain the sheep breast rich in ace inhibitory peptide;
Step 3, by mass fraction for the tannin enzyme solutions of 5-10% are uniformly sprayed at green tea surface, and holding is entered at least 2 hours
Row enzymolysis, wherein, the ratio of tannase liquor capacity and green tea quality is 0.2-3;Then go out enzyme 0.5-1h at 70-90 DEG C;Most
Afterwards by ball milling ultramicro grinding 1-3h at 1-10 DEG C, 2000 mesh sieves are crossed at room temperature, through 45-55 DEG C of drying after, obtain tea powder
Ultrafine green tea powder of the average grain diameter less than 14 μm;
Step 4, at 40-80 DEG C, the sheep breast and ultrafine green tea powder that will be enriched in ace inhibitory peptide are thoroughly mixed uniformly, wherein,
The ratio of sheep breast volume and ultrafine green tea powder quality rich in ace inhibitory peptide is (10-8):1;Then after being cooled down through moist heat sterilization, obtain
To the green tea goat milk with antihypertensive function.
2. a kind of green tea goat milk preparation method with antihypertensive function according to claim 1, it is characterised in that step
In 1, degreasing sheep breast is obtained as follows;Add distilled water to be made into recovery sheep breast in goat milk powder, sheep breast will be restored at a high speed
Degreasing sheep breast is obtained after centrifugation, 4 DEG C is placed in and is saved backup;Wherein, the mass volume ratio of goat milk powder and distilled water is (0.5-2):
9。
3. a kind of green tea goat milk preparation method with antihypertensive function according to claim 1, it is characterised in that step
In 2, hydrolysising reacting temperature is 45-80 DEG C.
4. a kind of green tea goat milk preparation method with antihypertensive function according to claim 1, it is characterised in that step
0.1mol/L NaOH are added dropwise in reaction solution in 2, during hydrolysis and adjust pH value to 6.5-8.5.
5. a kind of green tea goat milk preparation method with antihypertensive function according to claim 1, it is characterised in that step
In 2, composite enzyme solution includes that volume ratio is (3-1):1 trypsase and Proteinase K.
6. a kind of green tea goat milk preparation method with antihypertensive function according to claim 1, it is characterised in that step
In 3, green tea is balanced 30-48h by described green tea using the spring tea through fried green under constant temperature and humidity.
7. a kind of green tea goat milk preparation method with antihypertensive function according to claim 6, it is characterised in that constant temperature
It it is 22 DEG C, constant humidity is RH=60%.
8. a kind of green tea goat milk preparation method with antihypertensive function according to claim 1, it is characterised in that step
In 4, will be enriched in ace inhibitory peptide sheep breast and ultrafine green tea powder be thoroughly mixed it is uniform after sequentially add white sugar and edible perfume
Essence, then cooled down through moist heat sterilization.
9. a kind of green tea goat milk preparation method with antihypertensive function according to claim 1, it is characterised in that step
In 4, during moist heat sterilization, at 121 DEG C, sterilize 10-30min.
10. a kind of green tea goat milk with antihypertensive function, it is characterised in that the side as described in claim 1-9 any one
Method is prepared;It includes sheep breast and ultrafine green tea powder containing ace inhibitory peptide, the sheep breast volume containing ace inhibitory peptide and super
The ratio of micro- green tea powder quality is (10-8):1.
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Cited By (10)
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CN107484828A (en) * | 2017-09-30 | 2017-12-19 | 美可高特羊乳有限公司 | A kind of sheep breast composition with antihypertensive effect and preparation method thereof |
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