CN106660039B - 含磺酸聚合物材料作为胺吸附剂 - Google Patents

含磺酸聚合物材料作为胺吸附剂 Download PDF

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CN106660039B
CN106660039B CN201580030189.1A CN201580030189A CN106660039B CN 106660039 B CN106660039 B CN 106660039B CN 201580030189 A CN201580030189 A CN 201580030189A CN 106660039 B CN106660039 B CN 106660039B
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polymeric material
formula
weight
monomers
sulfonic acid
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CN106660039A (zh
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M·S·文德兰德
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B01J20/261—Synthetic macromolecular compounds obtained by reactions only involving carbon to carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/04—Processes using organic exchangers
    • B01J39/05—Processes using organic exchangers in the strongly acidic form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16—Organic material
    • B01J39/18—Macromolecular compounds
    • B01J39/19—Macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/08—Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/16—Organic material
    • B01J39/18—Macromolecular compounds
    • B01J39/20—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/34—Monomers containing two or more unsaturated aliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36—Divinylbenzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/34—Introducing sulfur atoms or sulfur-containing groups
    • C08F8/36—Sulfonation; Sulfation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/202—Polymeric adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/308—Pore size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/311—Porosity, e.g. pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/406—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/58—Ammonia

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201580030189.1A 2014-06-13 2015-05-28 含磺酸聚合物材料作为胺吸附剂 Active CN106660039B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462011694P 2014-06-13 2014-06-13
US62/011,694 2014-06-13
PCT/US2015/032806 WO2015191291A1 (en) 2014-06-13 2015-05-28 Sulfonic acid-containing polymeric materials as amine sorbents

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Publication Number Publication Date
CN106660039A CN106660039A (zh) 2017-05-10
CN106660039B true CN106660039B (zh) 2020-10-27

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Country Link
US (1) US10220370B2 (OSRAM)
EP (1) EP3154690B1 (OSRAM)
JP (1) JP6498220B2 (OSRAM)
KR (1) KR102271166B1 (OSRAM)
CN (1) CN106660039B (OSRAM)
WO (1) WO2015191291A1 (OSRAM)

Families Citing this family (8)

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JP6567052B2 (ja) 2014-11-17 2019-08-28 スリーエム イノベイティブ プロパティズ カンパニー ホルムアルデヒドを捕捉するためのポリマー材料
JP6837010B6 (ja) 2015-05-20 2021-03-31 スリーエム イノベイティブ プロパティズ カンパニー 金属含有ポリマー材料
WO2018089877A1 (en) 2016-11-14 2018-05-17 3M Innovative Properties Company Air filters comprising metal-containing polymeric sorbents
JP6935886B2 (ja) * 2017-03-02 2021-09-15 フィガロ技研株式会社 ガスセンサ及びその製造方法
WO2019140338A1 (en) * 2018-01-12 2019-07-18 University Of South Florida Multifunctional porous materials for water purification and remediation
US11977007B2 (en) * 2019-05-17 2024-05-07 Figaro Engineering Inc. Gas detection device and gas detection method
JP7145818B2 (ja) * 2019-06-24 2022-10-03 富士フイルム株式会社 ポリマー、吸着剤
CN114307986B (zh) * 2021-12-28 2023-05-12 南昌航空大学 一种钯离子吸附剂的制备方法

Citations (1)

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Publication number Priority date Publication date Assignee Title
CN105229055A (zh) * 2013-05-14 2016-01-06 3M创新有限公司 基于可自由基聚合的螺双茚单体的含磺酰基聚合物

Family Cites Families (11)

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Publication number Priority date Publication date Assignee Title
AR017374A1 (es) 1997-10-21 2001-09-05 Dow Chemical Co Interpolimeros substancialmente aleatorios sulfonados, mezclas con los mismos y articulos hechos de los mismos
JP2000273119A (ja) * 1999-03-25 2000-10-03 Lion Corp 芳香族系高分子スルホン化物有機アミン塩の製造方法
JP2003277438A (ja) * 2002-03-27 2003-10-02 Mitsubishi Chemicals Corp スルホン化重合体の製造方法
JP4709518B2 (ja) * 2004-09-29 2011-06-22 株式会社東芝 プロトン伝導膜及び燃料電池
DE102005021335A1 (de) * 2005-05-04 2006-11-09 Röhm Gmbh Verfahren zur Herstellung von Perlpolymerisaten mit einer mittleren Teilchengröße im Bereich von 1 µm bis 40 µm sowie Perlpolymerisat aufweisende Formmassen und Formkörper
KR101182544B1 (ko) * 2010-07-27 2012-09-12 순천향대학교 산학협력단 폐수에 함유된 아민 회수 및 아민 포화 양이온교환수지 재생 방법 및 장치
EP2864770B1 (en) * 2012-06-25 2017-09-27 3M Innovative Properties Company Sensor element, method of making, and method of using the same
CN104781218B (zh) 2012-09-25 2016-10-26 3M创新有限公司 可聚合的螺双茚单体以及由其制备的聚合物
EP2922618A4 (en) * 2012-11-26 2016-08-10 Commw Scient Ind Res Org MIXED MATRIX POLYMER COMPOSITIONS
JP6309084B2 (ja) * 2013-05-14 2018-04-11 スリーエム イノベイティブ プロパティズ カンパニー 堅固でかつねじれたジビニル架橋剤によるスルホニル含有ポリマー材料
EP3083726B1 (en) 2013-12-19 2017-09-27 3M Innovative Properties Company Hydrolyzed divinylbenzene/maleic anhydride polymeric material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105229055A (zh) * 2013-05-14 2016-01-06 3M创新有限公司 基于可自由基聚合的螺双茚单体的含磺酰基聚合物

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Publication number Publication date
CN106660039A (zh) 2017-05-10
EP3154690A1 (en) 2017-04-19
KR20170018349A (ko) 2017-02-17
JP6498220B2 (ja) 2019-04-10
US20170182475A1 (en) 2017-06-29
EP3154690B1 (en) 2019-06-26
KR102271166B1 (ko) 2021-06-30
WO2015191291A1 (en) 2015-12-17
JP2017519077A (ja) 2017-07-13
US10220370B2 (en) 2019-03-05

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