CN106631494A - Special paste foliar fertilizer additive containing wood-vinegar base insecticidal synergist and applied to pears - Google Patents
Special paste foliar fertilizer additive containing wood-vinegar base insecticidal synergist and applied to pears Download PDFInfo
- Publication number
- CN106631494A CN106631494A CN201611250950.5A CN201611250950A CN106631494A CN 106631494 A CN106631494 A CN 106631494A CN 201611250950 A CN201611250950 A CN 201611250950A CN 106631494 A CN106631494 A CN 106631494A
- Authority
- CN
- China
- Prior art keywords
- wood vinegar
- added
- stirring
- synergist
- benzaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a special paste foliar fertilizer additive containing a wood-vinegar base insecticidal synergist and applied to pears. First, crude pure wood vinegar is refined and mixed with lignin to enhance the viscosity of the wood vinegar, and then benzaldehyde L-cysteine Schiff base formed from the reaction of benzaldehyde and L-cysteine is added to the wood vinegar. The insecticidal synergist has a good inhibitory effect on phenol oxidase in pest bodies and has a good insecticidal effect; at the same time, as the wood vinegar can delay the infection period of pests, and the special smell of the wood vinegar can expel the pests and can reduce the growth and reproduction capacity of the pests, the harm of pests to crops is reduced; after being added to paste foliar fertilizer, the product can enhance the fertilizer effect, has the insecticidal effect, is safe and non-toxic actually, is used for increasing yield of the pears and controlling the pest and disease damage and can realize the effect of combination of a pesticide and fertilizer, thereby having good application prospect.
Description
Technical field
The present invention relates to technical field of fertilizers, more particularly to a kind of special paste of pear tree of addition wood vinegar alkali insecticidal synergist
Foliage fertilizer additives.
Background technology
Foliage fertilizer is that nutrient is applied to crops blade surface, and one kind of base function is played by the absorption of blade
Fertilizer type, the pore of blade surface is the passage that foliage fertilizer enters blade, with absorb it is fast, act on strong, low-consuming, efficiency high
The characteristics of, the deficiency of root fertilising can be supplemented, in process of crop growth, crop has shown some nutrient deficiencies
Disease, due to needing the regular hour using soil application, nutrient could be absorbed by crops, it is impossible to alleviates the nutritional deficiency disease of crop in time
Shape, at this moment using foliage dressing, then can make nutrient run through blade and enter plant, solve the problems, such as nutritional deficiency；And for example, some
Fruit tree and other deep some nutrient uptakes of root system crop are fewer, if being difficult to be applied to root using traditional fertilizing method
It is absorption site, its fertilizer efficiency can not be given full play to, and foliage-spray can then obtain preferable effect.Pear tree production is for consumption
Person provide high-quality fruit, it is relatively stringent to nutrient, pear tree growth growing process in from extraneous absorbed nitrogen, phosphorus, potassium,
The mineral nutritions such as calcium, magnesium and rare earth, by the specific metabolic process of tree body different parts, affect Growth status, yield and quality.
《Impact of the foliage application to ' early golden pastry ' pear fruit organic acid content》Spray on fruit tree growth season blade face in one text
1% carbamide, 0.2% potassium dihydrogen phosphate, 1% potassium sulfate, 0.1% calcium chloride, 1% magnesium sulfate, 0.05% rare-earth compound foliage fertilizer are applied, is carried
High fruit mass and fruit longitudinal and transverse demeter, increase fruit, improve fruit quality.Foliage fertilizer adopts liquid formulations in article,
Its nutrient content is low, easy crystallization is separated out, and is easily lost on blade face is imposed on, and causes the waste of fertilizer, and paste-form fertilizer is to be situated between
Form between solid fertilizer and liquid fertilizer, with its mobility increase of the increase of water content, overcomes solid fertilizer easy
Moisture absorption caking, dissolving is slow when using and liquid fertilizer nutrient content is low, the shortcoming that easy crystallization is separated out.Life of the present invention for pear tree
Long demand, researches and develops a kind of foliar fertilizer additive, in being added to Paste Foliage Fertilizer, makes foliage fertilizer collection nutrition, regulation, safety and environmental protection
In one, improve can Crop utilization rate, absorption speeds, adjust Growth of Pear Trees development, improve fruit quality.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of pears of addition wood vinegar alkali insecticidal synergist
Set special paste foliage fertilizer additives.
The present invention is achieved by the following technical solutions：
A kind of special paste foliage fertilizer additives of pear tree of addition wood vinegar alkali insecticidal synergist, are prepared by the raw material of following weight portion
Make：Basic element of cell division 6-7, methanol 31-34, agriculture breast 6021.2-1.3, anhydrous calcium chloride 0.3-0.31, anhydrous magnesium chloride
0.139-0.14, appropriate deionized water, isopropanol 0.15-0.18, Surfactin 0.8-1, carbamide 29-32, potassium humate 15-
17th, dipotassium hydrogen phosphate 9-11, appropriate ammonium sulfate, white sugar 2-3, thick pure wood vinegar 15-16, lignin 0.2-0.3, benzaldehyde 1-
1.1st, L-Cysteine 1.2-1.3, concentration are salicylic acid solution 0.6-0.7, the appropriate dehydrated alcohol of 5wt%.
The special paste foliage fertilizer additives of pear tree of a kind of addition wood vinegar alkali insecticidal synergist, by step in detail below
Make：
（1）The basic element of cell division is added in methanol, stirs stand-by to after being completely dissolved；Anhydrous calcium chloride is mixed with anhydrous magnesium chloride
Close, add in the deionized water that total amount 200-220 times is measured while stirring so as to be completely dissolved, form self-control hard water, be heated to
25-30 DEG C, agriculture breast 602 is added while stirring with 120-150 rev/min of speed, continue to be added after stirring the 30-40 seconds after adding
In stating solution, isopropanol is continuously added, ultrasonic disperse 30-40 minutes, obtain basic element of cell division emulsion；
（2）Potassium humate is put into into ball milling in ball mill, is then mixed with dipotassium hydrogen phosphate after 80 mesh sieves excessively and is put in reactor,
Carbamide is added while stirring with 300-400 rev/min of speed, addition moderate amount of sulfuric acid ammonium regulation system pH value is 8.5-9, is added
White sugar, room temperature condition chelatropic reaction 20-30 minutes under stirring, obtains chelating humic acid synergist；
（3）Thick pure wood vinegar is put in Rotary Evaporators, is distilled at 0.01-0.015MPa, 63-67 DEG C to dripless and is flowed out
Till, obtain mixing with lignin after exquisite wood vinegar, it is stand-by after stirring；Benzaldehyde is mixed with L-Cysteine, plus
Enter the dehydrated alcohol that total amount 5-6 times is measured, be heated to stopped reaction after 120-125 DEG C of backflow 1.5-2 hour, product is taken out
Filter, with dehydrated alcohol sucking filtration 2-3 time, drying, obtains benzaldehyde L-Cysteine Schiff's base at 30-40 DEG C, is then added
In entering above-mentioned mixed liquor, stir under room temperature to being completely dissolved, the salicylic acid solution for adding concentration to be 5wt% obtains modified wood vinegar and kills
Worm synergist；
（4）By step（1）（2）（3）The product mixing for obtaining, adds remaining residual components, is stirred with 500-600 rev/min of speed
Mix to be uniformly dispersed and obtain final product.
It is an advantage of the invention that：The present invention adds suitable emulsifying agent and makes with good dispersion with the basic element of cell division
Basic element of cell division emulsion, promotes the differentiation and growth of cell, compounds the addition of Surfactin, and good surface activity is lived
Property, the membrane permeability of blade surface, the increase of pore perforate degree can be significantly improved, synergism can promote blade to nutrient
Absorption and photosynthetic enhancing；Also with carbamide as chelate, potassium humate and potassium dihydrogen phosphate provide part to the present invention
Ion, white sugar prepares chelating humic acid synergist, it is possible to increase the absorbance of fertilizer, activity as system stabilizers,
Fruit individual characters can also be improved, make blade plumpness dark green, color and luster health enhances the resistances against diseases of pear tree, reduces pest and disease damage
Generation；Product of the present invention is added in Paste Foliage Fertilizer, and dispersive property is good, can arbitrarily increase and decrease the addition control cream of moisture
The mobility of shape fertilizer such that it is able to improve the engagement capacity of foliage fertilizer and blade face, improves the absorption efficiency of foliage fertilizer.
The present invention first by thick pure wood vinegar carry out it is refined after mix with lignin, the viscosity of enhancing wood vinegar, then by benzene
Formaldehyde is reacted in the benzaldehyde L-Cysteine Schiff aqueous slkali wood vinegar for generating with L-Cysteine, and phenol in insect body is aoxidized
Enzyme is inhibited, obtains with good insecticidal effect, simultaneously because wood vinegar itself can postpone insect infect the phase, its
Special odor can pest repelling, and growth and the fertility of insect can be reduced, so as to mitigate harm of the insect to crop；This
Invention product is added in Paste Foliage Fertilizer, can not only strengthen fertilizer efficiency, while there is insecticidal effect, and actual safety non-toxic,
The preventing and treating of volume increase and pest and disease damage for pear tree, can reach the effect of combination of pesticide and fertilizer, have a good application prospect.
Specific embodiment
A kind of special paste foliage fertilizer additives of pear tree of addition wood vinegar alkali insecticidal synergist, by following weight portion（Kilogram）
Raw material make：The basic element of cell division 6, methanol 31, agriculture breast 6021.2, anhydrous calcium chloride 0.3, anhydrous magnesium chloride 0.139, go
Ion appropriate amount of water, isopropanol 0.15, Surfactin 0.8, carbamide 29, potassium humate 15, dipotassium hydrogen phosphate 9, appropriate ammonium sulfate,
White sugar 2, thick pure wood vinegar 15, lignin 0.2, benzaldehyde 1, L-Cysteine 1.2, concentration for 5wt% salicylic acid solution 0.6,
Appropriate dehydrated alcohol.
The special paste foliage fertilizer additives of pear tree of a kind of addition wood vinegar alkali insecticidal synergist, by step in detail below
Make：
（1）The basic element of cell division is added in methanol, stirs stand-by to after being completely dissolved；Anhydrous calcium chloride is mixed with anhydrous magnesium chloride
Close, during the deionized water of 200 times of amounts of total amount is added while stirring so as to be completely dissolved, form self-control hard water, be heated to 25 DEG C,
Agriculture breast 602 is added while stirring with 120 revs/min of speed, continues to be added in above-mentioned solution after stirring 30 seconds after adding, continue to add
Enter isopropanol, ultrasonic disperse 30 minutes obtains basic element of cell division emulsion；
（2）Potassium humate is put into into ball milling in ball mill, is then mixed with dipotassium hydrogen phosphate after 80 mesh sieves excessively and is put in reactor,
Carbamide is added while stirring with 300 revs/min of speed, addition moderate amount of sulfuric acid ammonium regulation system pH value is 8.5, adds white sugar,
Room temperature condition chelatropic reaction 20 minutes under stirring, obtain chelating humic acid synergist；
（3）Thick pure wood vinegar is put in Rotary Evaporators, is distilled at 0.01MPa, 63 DEG C to dripless flowing out, obtained
Mix with lignin after exquisite wood vinegar, it is stand-by after stirring；Benzaldehyde is mixed with L-Cysteine, 5 times of total amount is added
The dehydrated alcohol of amount, be heated to 120 DEG C backflow 1.5 hours after stopped reaction, by product sucking filtration, with dehydrated alcohol sucking filtration 2
It is secondary, dry at 30 DEG C, benzaldehyde L-Cysteine Schiff's base is obtained, in being then added into above-mentioned mixed liquor, stir under room temperature
Mix to being completely dissolved, the salicylic acid solution for adding concentration to be 5wt% obtains modified wood vinegar insecticidal synergist；
（4）By step（1）（2）（3）The product mixing for obtaining, adds remaining residual components, with 500 revs/min of speed stirring point
Dissipate and uniformly obtain final product.
After the present embodiment product is applied, comprehensive nutrition, good absorbing, instant effect, fertilizer efficiency is lasting, the equal output increased of pear tree
19.2%, pest and disease damage incidence rate drops to 4.5% by 9%.
Claims (2)
1. it is a kind of addition wood vinegar alkali insecticidal synergist the special paste foliage fertilizer additives of pear tree, it is characterised in that by following heavy
The raw material of amount part is made：Basic element of cell division 6-7, methanol 31-34, agriculture breast 6021.2-1.3, anhydrous calcium chloride 0.3-0.31,
Anhydrous magnesium chloride 0.139-0.14, appropriate deionized water, isopropanol 0.15-0.18, Surfactin 0.8-1, carbamide 29-32,
Potassium humate 15-17, dipotassium hydrogen phosphate 9-11, appropriate ammonium sulfate, white sugar 2-3, thick pure wood vinegar 15-16, lignin 0.2-
0.3rd, benzaldehyde 1-1.1, L-Cysteine 1.2-1.3, concentration are salicylic acid solution 0.6-0.7, the appropriate dehydrated alcohol of 5wt%.
2. according to claim 1 it is a kind of addition wood vinegar alkali insecticidal synergist the special paste foliage fertilizer additives of pear tree, its
It is characterised by, is made up of step in detail below：
（1）The basic element of cell division is added in methanol, stirs stand-by to after being completely dissolved；Anhydrous calcium chloride is mixed with anhydrous magnesium chloride
Close, add in the deionized water that total amount 200-220 times is measured while stirring so as to be completely dissolved, form self-control hard water, be heated to
25-30 DEG C, agriculture breast 602 is added while stirring with 120-150 rev/min of speed, continue to be added after stirring the 30-40 seconds after adding
In stating solution, isopropanol is continuously added, ultrasonic disperse 30-40 minutes, obtain basic element of cell division emulsion；
（2）Potassium humate is put into into ball milling in ball mill, is then mixed with dipotassium hydrogen phosphate after 80 mesh sieves excessively and is put in reactor,
Carbamide is added while stirring with 300-400 rev/min of speed, addition moderate amount of sulfuric acid ammonium regulation system pH value is 8.5-9, is added
White sugar, room temperature condition chelatropic reaction 20-30 minutes under stirring, obtains chelating humic acid synergist；
（3）Thick pure wood vinegar is put in Rotary Evaporators, is distilled at 0.01-0.015MPa, 63-67 DEG C to dripless and is flowed out
Till, obtain mixing with lignin after exquisite wood vinegar, it is stand-by after stirring；Benzaldehyde is mixed with L-Cysteine, plus
Enter the dehydrated alcohol that total amount 5-6 times is measured, be heated to stopped reaction after 120-125 DEG C of backflow 1.5-2 hour, product is taken out
Filter, with dehydrated alcohol sucking filtration 2-3 time, drying, obtains benzaldehyde L-Cysteine Schiff's base at 30-40 DEG C, is then added
In entering above-mentioned mixed liquor, stir under room temperature to being completely dissolved, the salicylic acid solution for adding concentration to be 5wt% obtains modified wood vinegar and kills
Worm synergist；
（4）By step（1）（2）（3）The product mixing for obtaining, adds remaining residual components, is stirred with 500-600 rev/min of speed
Mix to be uniformly dispersed and obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611250950.5A CN106631494A (en) | 2016-12-30 | 2016-12-30 | Special paste foliar fertilizer additive containing wood-vinegar base insecticidal synergist and applied to pears |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611250950.5A CN106631494A (en) | 2016-12-30 | 2016-12-30 | Special paste foliar fertilizer additive containing wood-vinegar base insecticidal synergist and applied to pears |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106631494A true CN106631494A (en) | 2017-05-10 |
Family
ID=58836473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611250950.5A Withdrawn CN106631494A (en) | 2016-12-30 | 2016-12-30 | Special paste foliar fertilizer additive containing wood-vinegar base insecticidal synergist and applied to pears |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106631494A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084151A (en) * | 1993-10-11 | 1994-03-23 | 戴希泽 | A kind of fruit tree leaves leaven |
| CN1513329A (en) * | 2003-08-18 | 2004-07-21 | 杨宝兴 | Agent for greening and improving growth of fruit trees with fungicidal and anti-rottenness function |
| CN104429770A (en) * | 2014-11-24 | 2015-03-25 | 重庆隆玉恒农业发展有限公司 | Cultivation method of pear trees |
| CN104604941A (en) * | 2015-02-15 | 2015-05-13 | 辽宁省抚顺市世纪东方生物质综合技术开发有限公司 | Wood-vinegar alkaline insecticide composition and preparation method thereof |
-
2016
- 2016-12-30 CN CN201611250950.5A patent/CN106631494A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084151A (en) * | 1993-10-11 | 1994-03-23 | 戴希泽 | A kind of fruit tree leaves leaven |
| CN1513329A (en) * | 2003-08-18 | 2004-07-21 | 杨宝兴 | Agent for greening and improving growth of fruit trees with fungicidal and anti-rottenness function |
| CN104429770A (en) * | 2014-11-24 | 2015-03-25 | 重庆隆玉恒农业发展有限公司 | Cultivation method of pear trees |
| CN104604941A (en) * | 2015-02-15 | 2015-05-13 | 辽宁省抚顺市世纪东方生物质综合技术开发有限公司 | Wood-vinegar alkaline insecticide composition and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 贾玉龙等: "苯甲醛L-半胱氨酸席夫碱联合柞木木醋液的杀虫活性", 《厦门大学学报(自然科学版)》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102815999B (en) | Fertilizer special for hybrid rice | |
| CN102816026B (en) | Fertilizer specially used for winter wheat base fertilizer | |
| CN102826922B (en) | Fertilizer special for spring corn base fertilizer | |
| CN102815998B (en) | Special fertilizer for single cropping rice | |
| CN102992837B (en) | Special organic/inorganic composite fertilizer for rape | |
| CN105439739A (en) | Ammonium polyphosphate compound fertilizer and preparation method thereof | |
| CN105777233A (en) | Selenium-rich nutrient solution and preparation method thereof | |
| CN106588486A (en) | Biogenic stimulant capable of enhancing crop stress resistance and synthesis method thereof | |
| CN102826924B (en) | Special base fertilizer for late rice | |
| CN102863295A (en) | Special compound fertilizer for single cropping water oat | |
| CN104045481A (en) | Camellia oleifera dedicated composite biological organic fertilizer and preparation method thereof | |
| CN106316496A (en) | Earthworm solution compounded active water-soluble fertilizer and preparation method thereof | |
| CN102815980A (en) | Iodine-rich spinach special-purposed fertilizer, and method for cultivating spinach with iodine-rich spinach special-purposed fertilizer | |
| CN106631536A (en) | Seaweed polysaccharide anti-transpiration paste leaf fertilizer additive specially used for pear tree | |
| CN106348916A (en) | Special biological fertilizer for moso bamboo with drought resistance and moisture retention effects and production method thereof | |
| CN106187499A (en) | A kind of nursery stock fertilizer with bacteriostasis | |
| CN106631493A (en) | Additive added with azadirachtin-cow dung charcoal suspension liquid for paste leaf fertilizer special for pear trees | |
| CN104262033A (en) | Active, compound and nutritious leaf fertilizer | |
| CN106748215A (en) | A kind of special paste foliage fertilizer additives of pear tree for adding rare earth modified shitosan | |
| CN106631494A (en) | Special paste foliar fertilizer additive containing wood-vinegar base insecticidal synergist and applied to pears | |
| CN106631537A (en) | Selenium methionine chelate humic acid additive for paste foliar fertilizer for pear trees | |
| CN106748214A (en) | A kind of sulfydryl humin suppresses the pear tree Paste Foliage Fertilizer additive of Metal uptake | |
| CN106699391A (en) | Special multi-element pasty leaf fertilizer additive added with leather collagen hydrolysate for pear tree | |
| CN112661562A (en) | Water soluble foliage water flush fertilizer and its production method | |
| CN111763116A (en) | Organic-inorganic compound fertilizer capable of adjusting acid, supplementing magnesium and preventing plant yellowing and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170510 |
|
| WW01 | Invention patent application withdrawn after publication |