CN106631537A - Selenium methionine chelate humic acid additive for paste foliar fertilizer for pear trees - Google Patents
Selenium methionine chelate humic acid additive for paste foliar fertilizer for pear trees Download PDFInfo
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- CN106631537A CN106631537A CN201611250983.XA CN201611250983A CN106631537A CN 106631537 A CN106631537 A CN 106631537A CN 201611250983 A CN201611250983 A CN 201611250983A CN 106631537 A CN106631537 A CN 106631537A
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- Prior art keywords
- added
- humic acid
- stirring
- methionine
- paste
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
Abstract
The invention discloses a selenium methionine chelate humic acid additive for paste foliar fertilizer for pear trees. Methionine and sodium selenite react to produce selenium methionine, decavitamin C and jujube polysaccharide are added for product preparation under the synergistic effect, the additive is added to the fertilizer, the prepared special paste foliar fertilizer for the pear trees can obviously increase the selenium content, total sugar content and vitamin content of pears, the size of the pears is increased, the pulp fineness is increased, and the pear quality is improved.
Description
Technical field
The present invention relates to technical field of fertilizers, more particularly to a kind of selenium methionine chelating corruption for pear tree Paste Foliage Fertilizer
Grow acid additive.
Background technology
Foliage fertilizer is that nutrient is applied to crops blade surface, and one kind of base function is played by the absorption of blade
Fertilizer type, the pore of blade surface is the passage that foliage fertilizer enters blade, with absorb it is fast, act on strong, low-consuming, efficiency high
The characteristics of, the deficiency of root fertilising can be supplemented, in process of crop growth, crop has shown some nutrient deficiencies
Disease, due to needing the regular hour using soil application, nutrient could be absorbed by crops, it is impossible to alleviates the nutritional deficiency disease of crop in time
Shape, at this moment using foliage dressing, then can make nutrient run through blade and enter plant, solve the problems, such as nutritional deficiency；And for example, some
Fruit tree and other deep some nutrient uptakes of root system crop are fewer, if being difficult to be applied to root using traditional fertilizing method
It is absorption site, its fertilizer efficiency can not be given full play to, and foliage-spray can then obtain preferable effect.Pear tree production is for consumption
Person provide high-quality fruit, it is relatively stringent to nutrient, pear tree growth growing process in from extraneous absorbed nitrogen, phosphorus, potassium,
The mineral nutritions such as calcium, magnesium and rare earth, by the specific metabolic process of tree body different parts, affect Growth status, yield and quality.
《Impact of the foliage application to ' early golden pastry ' pear fruit organic acid content》Spray on fruit tree growth season blade face in one text
1% urea, 0.2% potassium dihydrogen phosphate, 1% potassium sulfate, 0.1% calcium chloride, 1% magnesium sulfate, 0.05% rare-earth compound foliage fertilizer are applied, is carried
High fruit mass and fruit longitudinal and transverse demeter, increase fruit, improve fruit quality.Foliage fertilizer adopts liquid formulations in article,
Its nutrient content is low, easy crystallization is separated out, and is easily lost on blade face is imposed on, and causes the waste of fertilizer, and paste-form fertilizer is to be situated between
Form between solid fertilizer and liquid fertilizer, with its mobility increase of the increase of water content, overcomes solid fertilizer easy
Moisture absorption caking, dissolving is slow when using and liquid fertilizer nutrient content is low, the shortcoming that easy crystallization is separated out.Life of the present invention for pear tree
Long demand, researches and develops a kind of foliar fertilizer additive, in being added to Paste Foliage Fertilizer, makes foliage fertilizer collection nutrition, regulation, safety and environmental protection
In one, improve can Crop utilization rate, absorption speeds, adjust Growth of Pear Trees development, improve fruit quality.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of egg ammonia for pear tree Paste Foliage Fertilizer
Sour selenium chelates humic acid additive.
The present invention is achieved by the following technical solutions：
A kind of selenium methionine for pear tree Paste Foliage Fertilizer chelates humic acid additive, and by the raw material of following weight portion system is prepared
Into：Anhydrous calcium chloride 0.3-0.31, anhydrous magnesium chloride 0.139-0.14, basic element of cell division 6-7, methyl alcohol 31-34, agriculture breast
6021.2-1.3, appropriate deionized water, isopropanol 0.15-0.18, Surfactin 0.8-1, urea 29-32, humic acid potassium 15-
17th, dipotassium hydrogen phosphate 9-11, appropriate ammonium sulfate, white sugar 2-3, methionine 3-3.5, sodium selenite 1.3-1.4, vitamin C 0.5-
0.52nd, the sodium hydroxide solution of methyl alcohol 40-45,0.1mol/L is appropriate, date polysaccharide 0.1-0.15, ferric trichloride 0.5-0.6.
A kind of selenium methionine for pear tree Paste Foliage Fertilizer chelates humic acid additive, by step system in detail below
Into：
（1）The basic element of cell division is added in methyl alcohol, stirs stand-by to after being completely dissolved；Anhydrous calcium chloride is mixed with anhydrous magnesium chloride
Close, add in the deionized water that total amount 200-220 times is measured while stirring so as to be completely dissolved, form self-control hard water, be heated to
25-30 DEG C, agriculture breast 602 is added while stirring with 120-150 rev/min of speed, continue to be added after stirring the 30-40 seconds after adding
In stating solution, isopropanol is continuously added, ultrasonic disperse 30-40 minutes, obtain basic element of cell division emulsion；
（2）Humic acid potassium is put into ball milling in ball mill, is then mixed with dipotassium hydrogen phosphate after 80 mesh sieves excessively and is put into reactor,
Urea is added while stirring with 300-400 rev/min of speed, addition moderate amount of sulfuric acid ammonium regulation system pH value is 8.5-9, is added
White sugar, room temperature condition chelatropic reaction 20-30 minutes under stirring, obtains chelating humic acid synergist；
（3）Methionine is mixed with sodium selenite, in adding the deionized water that total amount 20-22 times is measured, is added after dispersed with stirring is uniform
Plus sodium hydroxide solution regulation system pH of appropriate 0.1mol/L is to 7, adds methyl alcohol after continuing to react 60-90 minutes and tied
Crystalline substance, then carries out decompression suction filtration, then filter cake is put into baking oven and is dried with 50-60 DEG C, obtains selenium methionine；
（4）By step（1）（2）（3）The product mixing for obtaining, adds remaining residual components, is stirred with 500-600 rev/min of speed
Mix to be uniformly dispersed and obtain final product.
It is an advantage of the invention that：The present invention adds suitable emulsifying agent and makes with good dispersion with the basic element of cell division
Basic element of cell division emulsion, promotes the differentiation and growth of cell, compounds the addition of Surfactin, and good surface-active is lived
Property, the membrane permeability of blade surface, the increase of pore perforate degree can be significantly improved, synergy can promote blade to nutrient
Absorption and photosynthetic enhancing；Also with urea as chelate, potassium humate and potassium dihydrogen phosphate provide part to the present invention
Ion, white granulated sugar prepares chelating humic acid synergist, it is possible to increase the absorptivity of fertilizer, activity as system stabilizers,
Fruit individual characters can also be improved, make blade plumpness dark green, color and luster health enhances the resistance against diseases of pear tree, reduces pest and disease damage
Generation；Product of the present invention is added in Paste Foliage Fertilizer, and dispersive property is good, can arbitrarily increase and decrease the addition control cream of moisture
The mobility of shape fertilizer such that it is able to improve the engagement capacity of foliage fertilizer and blade face, improves the absorption efficiency of foliage fertilizer.
The present invention carries out reaction and generates selenium methionine using methionine and sodium selenite, B B-complex C, date polysaccharide
Addition, synergy be added in the preparation of product, this additive is added in fertilizer, made by the special paste blade face of pear tree
Fertilizer can significantly improve the Se content of pear fruit, and total sugar content, vitamin content increase fruit, improve pulp fineness,
Improve fruit quality.
Specific embodiment
A kind of selenium methionine for pear tree Paste Foliage Fertilizer chelates humic acid additive, by following weight portion（Kilogram）'s
Raw material is made：Anhydrous calcium chloride 0.3, anhydrous magnesium chloride 0.139, the basic element of cell division 6, methyl alcohol 31, agriculture breast 6021.2, go from
It is sub- appropriate amount of water, isopropanol 0.15, Surfactin 0.8, urea 29, humic acid potassium 15, dipotassium hydrogen phosphate 9, appropriate ammonium sulfate, white
Sugar 2, methionine 3, sodium selenite 1.3, vitamin C 0.5, methyl alcohol 40,0.1mol/L sodium hydroxide solution is appropriate, date polysaccharide
0.1st, ferric trichloride 0.5.
A kind of selenium methionine for pear tree Paste Foliage Fertilizer chelates humic acid additive, by step system in detail below
Into：
（1）The basic element of cell division is added in methyl alcohol, stirs stand-by to after being completely dissolved；Anhydrous calcium chloride is mixed with anhydrous magnesium chloride
Close, during the deionized water of 200 times of amounts of total amount is added while stirring so as to be completely dissolved, form self-control hard water, be heated to 25 DEG C,
Agriculture breast 602 is added while stirring with 120 revs/min of speed, continues to be added in above-mentioned solution after stirring 30 seconds after adding, continue to add
Enter isopropanol, ultrasonic disperse 30 minutes obtains basic element of cell division emulsion；
（2）Humic acid potassium is put into ball milling in ball mill, is then mixed with dipotassium hydrogen phosphate after 80 mesh sieves excessively and is put into reactor,
Urea is added while stirring with 300 revs/min of speed, addition moderate amount of sulfuric acid ammonium regulation system pH value is 8.5, adds white sugar,
Room temperature condition chelatropic reaction 20 minutes under stirring, obtain chelating humic acid synergist；
（3）Methionine is mixed with sodium selenite, in adding the deionized water of 20 times of amounts of total amount, dispersed with stirring is uniformly added afterwards suitable
Sodium hydroxide solution regulation system pH of the 0.1mol/L of amount is added methyl alcohol and is crystallized, then to 7 after continuing to react 60 minutes
Decompression suction filtration is carried out, then filter cake is put into baking oven and is dried with 50 DEG C, obtain selenium methionine；
（4）By step（1）（2）（3）The product mixing for obtaining, adds remaining residual components, with 500 revs/min of speed stirring point
Dissipate and uniformly obtain final product.
After the present embodiment product is applied, comprehensive nutrition, good absorbing, instant effect, fertilizer efficiency is lasting, the equal output increased of pear tree
20.2%, pest and disease damage incidence drops to 4.6% by 9.2%.
Claims (2)
1. a kind of selenium methionine for pear tree Paste Foliage Fertilizer chelates humic acid additive, it is characterised in that by following weight
The raw material of part is made：Anhydrous calcium chloride 0.3-0.31, anhydrous magnesium chloride 0.139-0.14, basic element of cell division 6-7, methyl alcohol
31-34, agriculture breast 6021.2-1.3, appropriate deionized water, isopropanol 0.15-0.18, Surfactin 0.8-1, urea 29-32,
Humic acid potassium 15-17, dipotassium hydrogen phosphate 9-11, appropriate ammonium sulfate, white sugar 2-3, methionine 3-3.5, sodium selenite 1.3-1.4,
Vitamin C 0.5-0.52, methyl alcohol 40-45,0.1mol/L sodium hydroxide solution is appropriate, date polysaccharide 0.1-0.15, tri-chlorination
Iron 0.5-0.6.
2. according to claim 1 a kind of selenium methionine for pear tree Paste Foliage Fertilizer chelates humic acid additive, and it is special
Levy and be, be made up of step in detail below：
（1）The basic element of cell division is added in methyl alcohol, stirs stand-by to after being completely dissolved；Anhydrous calcium chloride is mixed with anhydrous magnesium chloride
Close, add in the deionized water that total amount 200-220 times is measured while stirring so as to be completely dissolved, form self-control hard water, be heated to
25-30 DEG C, agriculture breast 602 is added while stirring with 120-150 rev/min of speed, continue to be added after stirring the 30-40 seconds after adding
In stating solution, isopropanol is continuously added, ultrasonic disperse 30-40 minutes, obtain basic element of cell division emulsion；
（2）Humic acid potassium is put into ball milling in ball mill, is then mixed with dipotassium hydrogen phosphate after 80 mesh sieves excessively and is put into reactor,
Urea is added while stirring with 300-400 rev/min of speed, addition moderate amount of sulfuric acid ammonium regulation system pH value is 8.5-9, is added
White sugar, room temperature condition chelatropic reaction 20-30 minutes under stirring, obtains chelating humic acid synergist；
（3）Methionine is mixed with sodium selenite, in adding the deionized water that total amount 20-22 times is measured, is added after dispersed with stirring is uniform
Plus sodium hydroxide solution regulation system pH of appropriate 0.1mol/L is to 7, adds methyl alcohol after continuing to react 60-90 minutes and tied
Crystalline substance, then carries out decompression suction filtration, then filter cake is put into baking oven and is dried with 50-60 DEG C, obtains selenium methionine；
（4）By step（1）（2）（3）The product mixing for obtaining, adds remaining residual components, is stirred with 500-600 rev/min of speed
Mix to be uniformly dispersed and obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611250983.XA CN106631537A (en) | 2016-12-30 | 2016-12-30 | Selenium methionine chelate humic acid additive for paste foliar fertilizer for pear trees |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611250983.XA CN106631537A (en) | 2016-12-30 | 2016-12-30 | Selenium methionine chelate humic acid additive for paste foliar fertilizer for pear trees |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106631537A true CN106631537A (en) | 2017-05-10 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611250983.XA Withdrawn CN106631537A (en) | 2016-12-30 | 2016-12-30 | Selenium methionine chelate humic acid additive for paste foliar fertilizer for pear trees |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108947625A (en) * | 2017-05-17 | 2018-12-07 | 四川施邦威生物科技发展有限公司 | A kind of fertilizer additive increasing disease-resistant crops, insect pest ability |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788192A (en) * | 2015-04-10 | 2015-07-22 | 中国科学院北方粳稻分子育种联合研究中心 | Special fertilizer for rice seedling raising |
| CN105309256A (en) * | 2015-10-21 | 2016-02-10 | 安徽牧马湖农业开发集团有限公司 | Planting method for high-quality selenium-rich rice |
| CN105481573A (en) * | 2015-12-28 | 2016-04-13 | 芜湖润蓝生物科技有限公司 | Modified choline chloride high-efficiency fertilizer capable of enhancing stress tolerance of celery and ensuring growth vigor of celery and preparation method thereof |
| CN106069481A (en) * | 2016-06-20 | 2016-11-09 | 湘乡市金薮乡洪新果油茶种植专业合作社 | A kind of implantation methods of oil tea |
-
2016
- 2016-12-30 CN CN201611250983.XA patent/CN106631537A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104788192A (en) * | 2015-04-10 | 2015-07-22 | 中国科学院北方粳稻分子育种联合研究中心 | Special fertilizer for rice seedling raising |
| CN105309256A (en) * | 2015-10-21 | 2016-02-10 | 安徽牧马湖农业开发集团有限公司 | Planting method for high-quality selenium-rich rice |
| CN105481573A (en) * | 2015-12-28 | 2016-04-13 | 芜湖润蓝生物科技有限公司 | Modified choline chloride high-efficiency fertilizer capable of enhancing stress tolerance of celery and ensuring growth vigor of celery and preparation method thereof |
| CN106069481A (en) * | 2016-06-20 | 2016-11-09 | 湘乡市金薮乡洪新果油茶种植专业合作社 | A kind of implantation methods of oil tea |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108947625A (en) * | 2017-05-17 | 2018-12-07 | 四川施邦威生物科技发展有限公司 | A kind of fertilizer additive increasing disease-resistant crops, insect pest ability |
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Application publication date: 20170510 |
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| WW01 | Invention patent application withdrawn after publication |