CN106631462A - Method for producing liquid seaweed fertilizer by bamboo shoot wastewater - Google Patents

Method for producing liquid seaweed fertilizer by bamboo shoot wastewater Download PDF

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Publication number
CN106631462A
CN106631462A CN201611205141.2A CN201611205141A CN106631462A CN 106631462 A CN106631462 A CN 106631462A CN 201611205141 A CN201611205141 A CN 201611205141A CN 106631462 A CN106631462 A CN 106631462A
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China
Prior art keywords
parts
waste water
bamboo shoots
fermentation
liquid seaweed
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Pending
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CN201611205141.2A
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Chinese (zh)
Inventor
陈肖虎
赵平原
王丽远
鲁圣军
黄碧芳
王芹
权变利
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Guizhou University
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Guizhou University
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Priority to CN201611205141.2A priority Critical patent/CN106631462A/en
Publication of CN106631462A publication Critical patent/CN106631462A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08Magnoliopsida [dicotyledons]
    • A01N65/12Asteraceae or Compositae [Aster or Sunflower family], e.g. daisy, pyrethrum, artichoke, lettuce, sunflower, wormwood or tarragon
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • C05G5/23Solutions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Abstract

The invention provides a method for producing a liquid seaweed fertilizer by bamboo shoot wastewater. The raw materials comprise 30 to 50 parts of fresh bamboo shoot wastewater, 10 to 30 parts of inorganic fertilizers, 5 to 10 parts of sodium alginate, 1 to 5 parts of natural active organic materials, 0.1 to 0.5 part of trace elements, 1 to 5 parts of botanical fungiticide and 1 to 2 parts of natural surfactants. According to a production process, the fresh bamboo shoot wastewater is put into a sealed fermentation tank for fermentation, wherein the fermentation temperature is 45 to 55 DEG C, and the fermentation time is 5 to 10 days; then, the formula materials are added into a mixture after the fermentation; filtering is performed after the uniform mixing through stirring; filter liquid is collected; the liquid fertilizer is obtained. The bamboo shoot wastewater is changed from waste into valuable materials; good economic benefits and ecological benefits are realized.

Description

A kind of method that bamboo shoots waste water produces liquid seaweed manure
Technical field
The invention belongs to fertilizer makes field, and in particular to a kind of method that bamboo shoots waste water produces liquid seaweed manure.
Background technology
In process boiling can produce substantial amounts of waste water to bamboo shoots, containing a large amount of nitrogen, phosphorus etc. in the composition of processing waste water Rich nutritive material, needs to can be only achieved discharge standard after treatment.The main process of wastewater treatment is hydrolysis+catalytic oxidation, The building and facility of auxiliary has grid, sedimentation basin and regulating reservoir, and waste water Jing pipe networks are directly entered grille well, remove larger impurity Enter afterwards in regulating reservoir.Hydrolytic tank is delivered into after adjusted pond regulating water quality, the larger molecular organicses of difficult degradation are converted into More degradable small organic molecule, improves the biodegradability of waste water, while removing partial organic substances.Jing after hydrolysis acidification process Waste water gravity flow enter biological contact oxidation pond, the microorganism on biomembrane using the organic matter in waste water carry out assimilation propagation and Metabolism, so as to remove waste water in organic matter, the COD in waste water is reduced, while in nitrifier and nitrococcus Mineralized nitrogen in waste water is reached the purpose of removal NH3-N under oxidation for nitrate.Biological contact oxidation pond water outlet is entered Entering flocculation sedimentation tank is carried out after mud-water separation, and into second pond, then after a separation of solid and liquid, supernatant gravity flow enters clear water Reach after the short stay of pond《Integrated wastewater discharge standard》.Whole waste water treatment process is numerous and diverse, needs to build substantial amounts for the treatment of facility, Processing cost is higher, for whole bamboo shoot process industry is a difficult problem.
The content of the invention
In order to solve above-mentioned technical problem present in prior art, the present invention provides one kind and bamboo shoots waste water is processed into sea The method of algae liquid fertilizer, turns waste into wealth, with good economic benefit and ecological benefits.
The method that bamboo shoots waste water produces Liquid Fertilizer is the technical scheme is that, its raw material includes new fresh bamboo shoots waste water 30-50 parts, inorganic fertilizer 10-30 parts, sodium alginate 5-10 parts, natural activity organic materials 1-5 parts, trace element 0.1-0.5 Part, botanical pesticide extract 1-5 parts and natural surfactant 1-2 parts;
Above-mentioned new fresh bamboo shoots waste water is put into closed fermentation tank and is fermented, fermentation temperature is 45-55 DEG C, during fermentation Between be 5-10 days, then above-mentioned formula material will be added in the mixture after fermentation, filter after being uniformly mixed, collect filtrate, Obtain Liquid Fertilizer.
The inorganic fertilizer element is nitrogen, phosphorus, potassium;In the inorganic fertilizer containing following mass percent element N >=10%, P2O5>=5%, K2O >=10%.
N element in the inorganic fertilizer element is provided by urea-ammonium nitrate solution;P2O5There is provided by APP solution;K2O It is that potassium sulfate and potassium chloride mixture are provided.
The natural activity organic materials is one or more in amino acid, fulvic acid, citric acid, tartaric acid.
The trace element for Cu, Fe, Zn, Mn, B water soluble compound, its mass ratio for 1-2:1-2:1-2: 0.5-1:0.5-1.
The botanical pesticide extract is divided into:Dalmatian chrysanthemum, rotenone, the mixed extract of matrine;The mixed nucleus Extract is that Dalmatian chrysanthemum, rotenone, matrine are crushed in proportion into 50~100 mesh, with mistake after Solvent Extract methods 12 hours Filter, filtrate concentrated in vacuo to proportion is the concentrate of 1.2-1.3, obtains final product.
The organic solvent for wherein extracting is ethanol or methyl alcohol.
Wherein natural surfactant is one or more in glucitol, mannitol, lactitol
The beneficial effect that the present invention is reached compared with prior art:
(1) in the composition of bamboo shoot process waste water bamboo shoot process waste water is processed into containing rich nutritive materials such as a large amount of nitrogen, phosphorus Liquid Fertilizer, turns waste into wealth, with good economic benefit and ecological benefits.
(2) using self-control botanical pesticide, many problems are brought relative to the Long-Time Service of chemical pesticide, such as insect produces The raw resistance to the action of a drug simultaneously causes continuing to increase for Pesticide use dosage, and residual is produced in crops, is made due to bioconcentration The residual hazard of the wild and domestic animal with these crops as food is increased, and self-control botanical pesticide is nontoxic to person poultry safety, It is free from environmental pollution, noresidue.Any period of plant growth, including the insect pest occurred during maturation are can be applicable to, crop is not affected List marketing.And with very strong selectivity, only target pest is acted on, pest natural enemy and other beneficial organisms are not produced It is raw to affect, be conducive to keeping ecological balance.In the present invention make by oneself botanical pesticide extract raw material be Dalmatian chrysanthemum, rotenone, Matrine, with preferable desinsection and biocidal efficacies, while getting fat pest and disease damage is reduced, and to yield synergistic effect is played, with Traditional fertile medicine gives difference, and the fertile medicine of the present invention simultaneously applies the development and national development liquid manure for more meeting current China's modern agriculture The strategic requirement of integration.
(3) using the liquid fertilizer of various trace elements, relative to traditional solid fertilizer, liquid fertilizer has many excellent Gesture, for example:It is difficult to hinder offspring;Uniform quality is consistent, and stability is high, and simple with detecting, generally surveys proportion and pH value Can monitoring product quality;Easy to use, utilization rate is high, can spray, drip irrigation or pouring;Easily addition trace element, agricultural chemicals are former Medicine or plant growth regulator, easily develop multifunctional fertilizers.
(4) natural activity organic matter, including amino acid, fulvic acid, citric acid, tartaric acid are added with the present invention, it The chelating states of matter element of ring-type can be formed with trace element, have high biologically active Jing after chelating, its work( Effect is tens times of general fertilizer, and the hundred times of inorganic salts are straight into crop body by crop with the absorption of organic molecule state Participation conversion is connect, and with dissolubility is higher, good stability, is not easily runed off, nutrient is supplemented rapidly, increased operation rate.
(5) present invention is added with natural surfactant, with effects such as dispersion, emulsification, solubilising, froth breakings, relative to conjunction Forming surfactants have toxicity low, the advantages of biological degradability is good.
(6) alga fertilizer of the invention also has good effect of increasing production, by taking corn as an example:Can increase 200- per per mu yield 228kg, average growth rate is up to 15.1%.
Specific embodiment
Technical scheme is further limited with reference to specific embodiment, but claimed Scope is not only limited to description.
Embodiment one
The method that bamboo shoots waste water of the present invention produces liquid seaweed manure, its raw material includes 50 parts of new fresh bamboo shoots waste water, urea 10 parts of ammonium nitrate solution, 10 parts of APP solution, 5 parts of sodium alginate, potassium sulfate and potassium chloride it is each 5 parts, 5 parts of citric acid, sulfuric acid Totally 0.5 part of copper, frerrous chloride, zinc chloride, manganese sulfate, boric acid, its mass ratio is 2:1:1:1:0.5,5 parts of botanical fungicide with And 2 parts of glucitol;
Described bamboo shoots waste water is through giving up that immersion, simple boiling, packaging, the procedure of high temperature sterilization four are produced by bamboo shoots Water, then waste water filtering is removed into bamboo shoots waste residue, that is, obtain bamboo shoots waste water;
Its production process is:Weighed new fresh bamboo shoots waste water and be put into closed fermentation tank by above-mentioned formula and fermented, sent out Ferment temperature is 35-45 DEG C, and fermentation time is 10 days, then above-mentioned formula material will be added in the mixture after fermentation, stirring mixing Filter after uniform, collect filtrate, that is, obtain Liquid Fertilizer.
The botanical pesticide extract is:By Dalmatian chrysanthemum, rotenone, matrine by weight 1:1:1 mixing, is crushed to 100 mesh, filter after being extracted at reflux 12 hours with ethanol, and filtrate concentrated in vacuo to proportion is the concentrate of 1.2-1.3.
Embodiment two
The method that bamboo shoots waste water of the present invention produces liquid seaweed manure, its raw material includes 40 parts of new fresh bamboo shoots waste water, urea 5 parts of ammonium nitrate solution, 5 parts of APP solution, 6 parts of sodium alginate, potassium sulfate and potassium chloride it is each 5 parts, 5 parts of amino acid, copper sulphate, Totally 0.2 part of frerrous chloride, zinc chloride, manganese sulfate, boric acid, mass ratio is 1:1:1:0.5:0.5,2 parts of botanical pesticide extract And mannitol and lactitol it is each 1 part;
Described bamboo shoots waste water is through giving up that immersion, simple boiling, packaging, the procedure of high temperature sterilization four are produced by bamboo shoots Water, then waste water filtering is removed into bamboo shoots waste residue, that is, obtain bamboo shoots waste water;
Its production process is:Weighed new fresh bamboo shoots waste water and be put into closed fermentation tank by above-mentioned formula and fermented, sent out Ferment temperature is 35-45 DEG C, and fermentation time is 6 days, then above-mentioned formula material will be added in the mixture after fermentation, and stirring mixing is equal Filter after even, collect filtrate, that is, obtain Liquid Fertilizer.
The botanical pesticide extract is:By Dalmatian chrysanthemum, rotenone, matrine by weight 1:2:1 mixing, is crushed to 60 mesh, filter after being extracted at reflux 12 hours with methyl alcohol, and filtrate concentrated in vacuo to proportion is the concentrate of 1.2-1.3.
Embodiment three
The method that bamboo shoots waste water of the present invention produces Liquid Fertilizer, its raw material includes 40 parts of new fresh bamboo shoots waste water, urea ammonium nitrate 10 parts of solution, 10 parts of APP solution, 7 parts of sodium alginate, potassium sulfate and potassium chloride it is each 6 parts, amino acid/11 part, fulvic acid 1 Part, 1 part of citric acid, 1 part of tartaric acid, totally 0.4 part of copper sulphate, frerrous chloride, zinc chloride, manganese sulfate, boric acid, the model of its mass ratio Enclose for 2:1:2:1:1,2 parts of 3 parts of botanical pesticide extract and mannitol;
Described bamboo shoots waste water is through giving up that immersion, simple boiling, packaging, the procedure of high temperature sterilization four are produced by bamboo shoots Water, then waste water filtering is removed into bamboo shoots waste residue, that is, obtain bamboo shoots waste water;
Its production process is:Weighed new fresh bamboo shoots waste water and be put into closed fermentation tank by above-mentioned formula and fermented, sent out Ferment temperature is 35-45 DEG C, and fermentation time is 7 days, then above-mentioned formula material will be added in the mixture after fermentation, and stirring mixing is equal Filter after even, collect filtrate, that is, obtain Liquid Fertilizer.
The botanical pesticide extract is:By Dalmatian chrysanthemum, rotenone, matrine in proportion 1:3:2 mixing, are crushed to 80 Mesh, filters after being extracted 12 hours at 50-60 DEG C with ethanol, and filtrate concentrated in vacuo to proportion is the concentrate of 1.2-1.3.
Example IV
The method that bamboo shoots waste water of the present invention produces Liquid Fertilizer, its raw material includes 30 parts of new fresh bamboo shoots waste water, urea ammonium nitrate 5 parts of solution, 10 parts of APP solution, 10 parts of sodium alginate, potassium sulfate and potassium chloride is each 10 parts, 2 parts of fulvic acid, citric acid 1 part, 1 part of tartaric acid, micro- copper sulphate, frerrous chloride, zinc chloride, manganese sulfate, totally 0.5 part of boric acid, mass ratio is 2:2:1:0.5: 0.1,2 parts of 5 parts of botanical pesticide extract and mannitol;
Described bamboo shoots waste water is through giving up that immersion, simple boiling, packaging, the procedure of high temperature sterilization four are produced by bamboo shoots Water, then waste water filtering is removed into bamboo shoots waste residue, that is, obtain bamboo shoots waste water;
Its production process is:Weighed new fresh bamboo shoots waste water and be put into closed fermentation tank by above-mentioned formula and fermented, sent out Ferment temperature is 35-45 DEG C, and fermentation time is 5 days, then above-mentioned formula material will be added in the mixture after fermentation, and stirring mixing is equal Filter after even, collect filtrate, that is, obtain Liquid Fertilizer.
The botanical pesticide extract is:It is described mixing nuclear extract be by Dalmatian chrysanthemum, rotenone, matrine in proportion 2:5:2 are crushed to 100 mesh, filter after being extracted under reflux 12 hours with methyl alcohol, and filtrate concentrated in vacuo to proportion is 1.2-1.3's Concentrate.
Embodiment five
To further illustrate advantages of the present invention, it is long to corn that inventor has carried out fertilizer of the present invention in Guiyang City, Guizhou Province Gesture is tested.
Test is located at Guiyang City, Guizhou Province Huaxi District Hu Chao townshiies, belongs to subtropical zone monsoon moist climate.Corn variety is Guizhou Province Single 24, for trying soil for yellow soil, middle fertility.
Test adopts RANDOMIZED BLOCK DESIGN, 3 repetitions, each plot area 660m2.Experimental plot fertilising situation be:Base manure is High-quality fertilizer 30000kg/hm2, calcium magnesium phosphate 375kg/hm2, potassium sulfate 150kg/hm2.Foliage application selects tested fertilizer, Other control measures are with general production.
Material to be tested is the Liquid Fertilizer obtained by embodiment of the present invention 1-4, and fertilizer code is respectively G-1, G-2, G-3, G- 4, control fertilizer is commercially available trace element water-soluble fertilizer:It is 10% containing Zn, Mn, Cu, Mo total amount, fertilizer code is D.
Fertilizing method is:By different Liquid Fertilizers according to the consumption of per hectare 2.5kg, 500 times of dilution is watered, divides 3 times points Do not sprayed at seedling stage, 3 periods of jointing stage and pustulation period, spray that fertilizer liquid measure is total solution amount every time 1/3.
Measure project and method:The heart stage of 6 leaf of corn 1, observe corn growing way.Survey and produce:Field harvests to survey and produces.Experimental field line-spacing 0.6m, nest away from 0.26m, 63000 plants/hm of average planting density2;10-12 rods are taken back at random per cell, are weighed after drying.Test The results are shown in Table 1.
Table 1:The application effect table of alga fertilizer of the present invention
Result of the test shows that alga fertilizer obtained in embodiment of the present invention 1-4 has obvious effect of increasing production, relative to commercially available Trace element water-soluble fertilizer averagely increase production 1213.3kg/hm2, average growth rate is 11.8%.

Claims (8)

1. a kind of method that bamboo shoots waste water produces liquid seaweed manure, it is characterised in that:Its raw material includes new fresh bamboo shoots waste water 30- 50 parts, inorganic fertilizer 10-30 parts, sodium alginate 5-10 parts, natural activity organic materials 1-5 parts, 0.1~0.5 part of trace element, Botanical pesticide extract 1-5 parts and natural surfactant 1-2 parts;
Above-mentioned new fresh bamboo shoots waste water is put into closed fermentation tank and is fermented, fermentation temperature is 45-55 DEG C, fermentation time is 5-10 days, then above-mentioned formula material will be added in the mixture after fermentation, filter after being uniformly mixed, filtrate is collected, obtain final product To Liquid Fertilizer.
2. the method that bamboo shoots waste water according to claim 1 produces liquid seaweed manure, it is characterised in that:The inorganic fertilizer unit Element is nitrogen, phosphorus, potassium;Element N >=10%, P containing following mass percent in the inorganic fertilizer2O5>=5%, K2O >=10%.
3. the method that bamboo shoots waste water according to claim 1 produces liquid seaweed manure, it is characterised in that:The inorganic fertilizer unit N element in element is provided by urea-ammonium nitrate solution;P2O5There is provided by APP solution;K2O is that potassium sulfate and potassium chloride mix Thing is provided.
4. the method that bamboo shoots waste water according to claim 1 produces liquid seaweed manure, it is characterised in that:The natural activity Organic materials is one or more in amino acid, fulvic acid, citric acid, tartaric acid.
5. the method that bamboo shoots waste water according to claim 1 produces liquid seaweed manure, it is characterised in that:The trace element For the water soluble compound of Cu, Fe, Zn, Mn, B, its mass ratio is 1-2:1-2:1-2:0.5-1:0.5-1.
6. the method that bamboo shoots waste water according to claim 1 produces liquid seaweed manure, it is characterised in that:The plant source agriculture The material composition of medicine is:Dalmatian chrysanthemum, rotenone, the mixed extract of matrine;The mixing nuclear extract is by Dalmatian chrysanthemum, fish Rattan ketone, matrine are crushed in proportion 50~100 mesh, are filtered with after Solvent Extract methods 12 hours, filtrate concentrated in vacuo to than Weight is the concentrate of 1.2-1.3, obtains final product.
7. the method that bamboo shoots waste water according to claim 6 produces liquid seaweed manure, it is characterised in that:That what is extracted is organic molten Agent is ethanol or methyl alcohol.
8. the method that bamboo shoots waste water according to claim 1 produces liquid seaweed manure, it is characterised in that:Natural surfactant Agent is one or more in glucitol, mannitol, lactitol.
CN201611205141.2A 2016-12-23 2016-12-23 Method for producing liquid seaweed fertilizer by bamboo shoot wastewater Pending CN106631462A (en)

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CN108530183A (en) * 2018-05-31 2018-09-14 贵州盈丰农业发展有限公司 A kind of preparation method rich in micro- vinasse organic fertilizer
CN108530181A (en) * 2018-05-31 2018-09-14 贵州盈丰农业发展有限公司 A kind of production method for the vinasse fermentation Liquid Fertilizer being exclusively used in Rosa roxburghii Tratt

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
CN108530183A (en) * 2018-05-31 2018-09-14 贵州盈丰农业发展有限公司 A kind of preparation method rich in micro- vinasse organic fertilizer
CN108530181A (en) * 2018-05-31 2018-09-14 贵州盈丰农业发展有限公司 A kind of production method for the vinasse fermentation Liquid Fertilizer being exclusively used in Rosa roxburghii Tratt

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RJ01 Rejection of invention patent application after publication

Application publication date: 20170510

RJ01 Rejection of invention patent application after publication