CN1066159C - 偶联的不对称聚合物的制备方法 - Google Patents

偶联的不对称聚合物的制备方法 Download PDF

Info

Publication number
CN1066159C
CN1066159C CN94193711A CN94193711A CN1066159C CN 1066159 C CN1066159 C CN 1066159C CN 94193711 A CN94193711 A CN 94193711A CN 94193711 A CN94193711 A CN 94193711A CN 1066159 C CN1066159 C CN 1066159C
Authority
CN
China
Prior art keywords
vinyl aromatic
aromatic hydrocarbon
molecular weight
block copolymer
asymmetric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN94193711A
Other languages
English (en)
Chinese (zh)
Other versions
CN1133052A (zh
Inventor
M·A·马西
S·S·钦
C·A·史蒂文斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of CN1133052A publication Critical patent/CN1133052A/zh
Application granted granted Critical
Publication of CN1066159C publication Critical patent/CN1066159C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/046—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes polymerising vinyl aromatic monomers and isoprene, optionally with other conjugated dienes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
CN94193711A 1993-09-10 1994-09-09 偶联的不对称聚合物的制备方法 Expired - Lifetime CN1066159C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/120,116 US5360875A (en) 1993-09-10 1993-09-10 Method for producing coupled asymmetric polymers
US08/120116 1993-09-10

Publications (2)

Publication Number Publication Date
CN1133052A CN1133052A (zh) 1996-10-09
CN1066159C true CN1066159C (zh) 2001-05-23

Family

ID=22388363

Family Applications (1)

Application Number Title Priority Date Filing Date
CN94193711A Expired - Lifetime CN1066159C (zh) 1993-09-10 1994-09-09 偶联的不对称聚合物的制备方法

Country Status (14)

Country Link
US (1) US5360875A (enExample)
EP (1) EP0717756B1 (enExample)
JP (1) JP3436935B2 (enExample)
KR (1) KR100346567B1 (enExample)
CN (1) CN1066159C (enExample)
AT (1) ATE164382T1 (enExample)
AU (1) AU7781394A (enExample)
BR (1) BR9407436A (enExample)
DE (1) DE69409246T2 (enExample)
DK (1) DK0717756T3 (enExample)
ES (1) ES2114702T3 (enExample)
GR (1) GR3026736T3 (enExample)
TW (1) TW262477B (enExample)
WO (1) WO1995007307A1 (enExample)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5446093A (en) * 1993-11-10 1995-08-29 Shell Oil Company Method for producing statistically coupled asymmetric radial polymers
US5616542A (en) * 1996-04-03 1997-04-01 Shell Oil Company Oil with asymmetric radial polymer having block copolymer arm
ATE342292T1 (de) * 1999-08-31 2006-11-15 Nippon Soda Co Sternblockcopolymer
JP4623690B2 (ja) * 1999-08-31 2011-02-02 日本曹達株式会社 星型ブロックコポリマー
US6579940B1 (en) 1999-10-28 2003-06-17 Edwards Lifesciences Corporation Thermoplastic elastomeric material as a replacement for natural rubber latex
DE60030551T2 (de) * 2000-07-20 2007-06-06 Dynasol Elastomeros, S.A. Styrol-1,3-Butadienblockcopolymere und Wasserdichtmembranen hergestellt davon
US6613838B1 (en) 2000-08-30 2003-09-02 Edwards Lifesciences Corporation Synthetic rubber elastomers as replacements for natural rubber latex
EP2259934B1 (en) * 2008-03-13 2014-05-14 Kraton Polymers US LLC Novel miktopolymer compositions
US8604136B2 (en) * 2009-10-16 2013-12-10 Exxonmobil Research And Engineering Company Process for making dendritic hydrocarbon polymers
US20110214909A1 (en) * 2010-03-05 2011-09-08 International Business Machines Corporation Hydrophobic Silane Coating for Preventing Conductive Anodic Filament (CAF) Growth in Printed Circuit Boards
US8629217B2 (en) 2011-11-22 2014-01-14 Exxonmobil Chemical Patents Inc. Modified polyethylene blown film compositions having excellent bubble stability
CN103254544B (zh) * 2012-02-21 2015-10-21 中国石油化工股份有限公司 单乙烯基芳烃-共轭二烯烃共聚物组合物和聚合方法及由该方法制备的聚合物
EP3143056B1 (en) 2014-05-16 2021-01-13 Kraton Polymers U.S. LLC Polyalkenyl coupling agent and conjugated diene polymers prepared therefrom
TWI604002B (zh) * 2015-03-09 2017-11-01 科騰聚合物美國有限責任公司 用於固化嵌段共聚物乳膠薄膜之改良硫化系統
US10212812B2 (en) 2016-01-15 2019-02-19 International Business Machines Corporation Composite materials including filled hollow glass filaments
CN109181813B (zh) * 2018-07-31 2021-07-06 沈阳化工研究院有限公司 一种用于润滑油的星形黏度指数改进剂及其制备方法
KR102849963B1 (ko) * 2020-05-18 2025-08-27 주식회사 엘지화학 블록 공중합체 조성물, 이의 제조방법 및 이를 포함하는 점착제 조성물
US11608404B2 (en) * 2020-05-22 2023-03-21 Kraton Corporation Block copolymers and polymer modified bitumen therefrom

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4391949A (en) * 1981-11-12 1983-07-05 Shell Oil Company Asymmetric block copolymers and corresponding adhesive formulations
US4600736A (en) * 1985-03-11 1986-07-15 Phillips Petroleum Company Pigment concentrates for resins

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3639517A (en) * 1969-09-22 1972-02-01 Phillips Petroleum Co Resinous branched block copolymers
US3939112A (en) * 1974-11-18 1976-02-17 Phillips Petroleum Company Thermoplastic resin composition having high impact strength
US4167545A (en) * 1975-11-08 1979-09-11 Basf Aktiengesellschaft Branched block copolymers and their manufacture
DE2550226C2 (de) * 1975-11-08 1984-12-13 Basf Ag, 6700 Ludwigshafen Verzweigte Blockcopolymerisate und Verfahren zu ihrer Herstellung
US4080407A (en) * 1975-11-10 1978-03-21 Phillips Petroleum Company Resinous linear copolymers having blocks with a heterogeneity index of 2.3 to 4.5
US4091053A (en) * 1976-06-24 1978-05-23 Phillips Petroleum Company Coupled resinous diene copolymer with good integral hinge flex life and high hardness
US4180530A (en) * 1979-02-05 1979-12-25 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248983A (en) * 1979-02-05 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248982A (en) * 1979-04-30 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248981A (en) * 1979-04-30 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4248984A (en) * 1979-05-11 1981-02-03 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4221884A (en) * 1979-05-14 1980-09-09 Arco Polymers, Inc. Clear impact resistant thermoplastic star-block copolymers
US4390663A (en) * 1981-02-17 1983-06-28 Atlantic Richfield Company Semi-continuous process for making star-block copolymers
US4720514A (en) * 1985-03-11 1988-01-19 Phillips Petroleum Company Pigment concentrates for resins
US4788232A (en) * 1985-03-11 1988-11-29 Phillips Petroleum Company Pigment concentrates for resins
DE3537772A1 (de) * 1985-10-24 1987-04-30 Basf Ag Transparente, schlagzaehe styrol-block-polymerisate und verfahren zu ihrer herstellung
IT1196517B (it) * 1986-07-17 1988-11-16 Montedipe Spa Copolimeri a blocco radiali e bimodali aventi ottime proprieta' ottiche e reistenza agli urti e processo per la loro preparazione
CA1335614C (en) * 1987-10-30 1995-05-16 Ronald James Hoxmeier Method for preparing asymmetric radial copolymers
DE3738748A1 (de) * 1987-11-14 1989-05-24 Basf Ag Verfahren zur diskontinuierlichen herstellung von unsymmetrisch aufgebauten, sternfoermig verzweigten blockcopolymerisaten und ihre verwendung
DE3833760A1 (de) * 1988-10-05 1990-04-12 Huels Chemische Werke Ag Ungesaettigte, elastomere, asymmetrisch gekuppelte blockcopolymere, ein eintopfverfahren zu ihrer herstellung und ihre verwendung zur herstellung von reifenbauteilen
US5212249A (en) * 1991-10-28 1993-05-18 Shell Oil Company Method for preparing asymmetric radial polymers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4391949A (en) * 1981-11-12 1983-07-05 Shell Oil Company Asymmetric block copolymers and corresponding adhesive formulations
US4391949B1 (enExample) * 1981-11-12 1987-08-04
US4600736A (en) * 1985-03-11 1986-07-15 Phillips Petroleum Company Pigment concentrates for resins

Also Published As

Publication number Publication date
CN1133052A (zh) 1996-10-09
DK0717756T3 (da) 1998-05-11
EP0717756B1 (en) 1998-03-25
US5360875A (en) 1994-11-01
ATE164382T1 (de) 1998-04-15
AU7781394A (en) 1995-03-27
JPH09502217A (ja) 1997-03-04
BR9407436A (pt) 1996-04-09
KR100346567B1 (ko) 2002-11-30
GR3026736T3 (en) 1998-07-31
EP0717756A1 (en) 1996-06-26
DE69409246D1 (de) 1998-04-30
DE69409246T2 (de) 1998-07-23
JP3436935B2 (ja) 2003-08-18
TW262477B (enExample) 1995-11-11
ES2114702T3 (es) 1998-06-01
WO1995007307A1 (en) 1995-03-16

Similar Documents

Publication Publication Date Title
CN1066159C (zh) 偶联的不对称聚合物的制备方法
Peters et al. Termination of living anionic polymerizations using chlorosilane derivatives: a general synthetic methodology for the synthesis of end-functionalized polymers
CA1057889A (en) Star polymers and process for the preparation thereof
AU608016B2 (en) Block polymers of methacrylates and derivatives thereof
CN1479758A (zh) 线性嵌段共聚体的制备方法
Luxton et al. Star-branched polymers: 2. Linking reaction involving 2-and 4-vinyl pyridine and dienyland styryllithium chain ends
JPH05214013A (ja) 非対称放射型ポリマーの製造方法
US5270394A (en) Anionically polymerized polymers coupled with fullerenes
EP0675916B1 (en) Star-shaped polydimethylsiloxane block copolymers and process for the preparation thereof
MXPA96002030A (en) Procedure to produce copolymers in asimetri blockwise
BR0317881B1 (pt) Processo para preparar um polímero ou bloco de copolímero de dieno conjugado
JP2004131707A (ja) ３元ブロック共重合体及び製造方法
JP3561036B2 (ja) 非対称ラジアルポリマーの製造方法
US5369175A (en) Method for preparing asymmetric radial copolymers having four first arms and two second arms
CA1194641A (en) Coupling process
JP3877836B2 (ja) テトラヒドロピラニルメタノールのアルキルエーテルの存在下での共役ジエンとビニルアレーンのアニオン共重合
JPH07188360A (ja) 不斉ラジアルポリマーの製造方法
EP0002012A1 (en) Coupled hydrocarbon polymers and process for their preparation
JPH08231659A (ja) 多腕非対称ラジアルブロックコポリマーを製造するためのプロセス
EP1266916B1 (en) Multiblock copolymer and the preparing method thereof
CN100537626C (zh) 偶联低乙烯基嵌段共聚物组合物的制造方法和所得组合物
KR100995681B1 (ko) 방향족 비닐계 단량체 및 공역디엔계 단량체 유래의 공중합체, 트리블록 중합체 및 스타 폴리머가 혼재된 중합물의 중합방법 및 중합물
KR100758155B1 (ko) 헤테로-브랜치를 갖는 라디알 폴리스티렌-폴리이소프렌블록 공중합체 및 그 제조 방법
JPH05148324A (ja) 共重合体及びその製造方法
USH1902H (en) Asymmetric radial polymers with acrylic monomer arms

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CX01 Expiry of patent term

Expiration termination date: 20140909

Granted publication date: 20010523