CN106592210A - 一种用于纺织物的抗菌整理剂及其制备方法 - Google Patents
一种用于纺织物的抗菌整理剂及其制备方法 Download PDFInfo
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Abstract
本发明公开了一种用于纺织物的抗菌整理剂及其制备方法,其以顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯、三羟甲基丙烷三辛酸酯为主要成分,通过加入乙烯碳酸酯、磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺、磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠、氨基硅油、二甘醇、乙基香兰素、表面活性剂、增稠剂、去离子水,辅以加热、搅拌、超声分散、球磨、氮气环境下反应等工艺,使得制备而成的整理剂使用后使纺织物具备优异的抗菌效果,同时保湿效果良好,能够满足行业的要求,具有较好的应用前景。
Description
技术领域
本发明涉及纺织染整技术领域,特别涉及用于纺织物的抗菌整理剂及其制备方法。
背景技术
纺织品的功能整理是为了满足纺织品的某些特殊使用要求而赋予纺织物优良的使用、安全、外观等性能的特殊整理加工方法。纺织品的功能性整理剂则是随化学、生物医学、高分子复合材料学、光化学、热力学、电学、生态学等多学科技术的发展而发展起来的一类产品。由于纺织品的功能整理是针对纺织品某些特定的性能的,因而目的性强,效果好,产品的附加值也高。纺织品经功能性整理后,其使用目的和范围明确,也深受消费者欢迎。据统计,世界功能纺织品的需求量超过500亿米,我国功能纺织品的需求量近50亿米。纺织加工和整理用化学品的世界需求量每年增加4.2%,年销售额现已达数百亿美元。功能性纺织品的应用范围较为广泛,如用作生物医学的组织和器官;用于预防医学的抗菌防病,保健美容的理疗塑身;特种行业的阻燃,防静电,高低温防护;家居环境改善,吸尘防噪,妇幼生理卫生,杀螨防污,拒油拒水,各类射线防护等等。并且,从发展来看,功能性纺织品的整理内容和应用范围还在不断扩大,正逐渐渗透到普通产品的生产与整理过程中。
与此相对应地,纺织品整理剂也主要有以下种类:(1)抗静电整理剂:纺织品带静电后的吸尘和易沾污现象,服装与服装,服装与人体的相互吸附现象,轻则产生针刺感、电火花,重则使用合纤织物会引起以外火灾和爆炸事故。抗静电织物主要有嵌织导电金属丝和织物表面整理,后者是织物经抗静电剂覆盖整理,可中和静电负荷,降低表面电阻,减少静电聚集,增强织物吸湿性从而达到消除静电的效果。(2)耐高温阻燃整理剂:利用碳纤维耐高温、耐辐射、耐腐蚀的特点性能,大量用于航空器材、建筑工程;采用耐高温、阻燃和高韧性的芳纶纤维制成防护服、消防服和防弹服。含磷聚酯作阻燃纺织品,用于医院、保健业和装饰行业;加有阻燃剂的丙纶用作窗帘、墙布装饰;三聚氰胺纤维耐高温,柔韧性很好,具有一定的阻燃功效,用于消防领域。(3)抗菌整理剂:在和织物之间的理想气候下,细菌能不受阻碍地大量繁殖,引起皮肤感染,导致卫生状况恶化和疾病的传播与蔓延。奥地利蒙黛尔纤维素织物采用纳米微胶囊抗菌除臭技术对金黄色葡萄球菌、淋球菌、大肠杆菌等抑菌率达99%以上,保护皮肤延缓皮肤衰老。使用广泛的有机硅季铵盐类具有良好的抗微生物效用,可有效抑制和杀灭引起感染或病原性革兰氏阴性、阳性菌、金黄色葡萄球菌、白色念珠菌和大肠杆菌等病毒。多用于内衣裤、毛巾、床单、鞋店、地毯和医用织物的抗菌整理。(4)防蛀整理剂:羊毛、蚕丝、羽绒、毛皮等虫蛀侵食投诉率达7.7%,仅次于变色、褪色、沾污、缩水,列第5位,防蛀剂曾用萘、对二氯苯和樟脑,现在通常用拟除虫菊酯处理。(5)紫外线防护整理剂:最有危害的紫外辐射是在300~310的UV-B峰。穿透织物的紫外辐射由两种波组成:一种会不改变的穿过织物,另一种分散波会同织物发生反应。紫外线防护整理有紫外线吸收和紫外线屏蔽两类。(6)pH调节整理剂:汗液中有40多种物质:氯化钠、尿素、乳酸和氨基酸,皮肤表面一般pH=6,出汗初期pH下降至4.4,大量出汗pH=7,时间长了,尿素分解出NH3,pH达到8.0。酸雨的pH值低于5.6。pH整理剂采用纳米陶瓷微粒与纤维结合,能调节pH值,并且兼有杀菌消臭、紫外线屏蔽作用。(7)蓄热保温整理剂:织物保温一般方法有:纺丝原液中加碳化锆陶瓷粉末,吸收光线放出热量、反射人体发射的远红外线从而保温蓄热;中空纤维保温和自动保温整理等。已研究成功的自动保温主要原理是利用催化剂使异丁烷和丙烷混合物无焰燃烧,每个加热部件重约495g。
虽然目前已经有了上述不同特点的整理剂,但具体到每个门类,其具有的使用效果还有待进一步提高。因此,针对纺织品所需要的不同特性而开发相应的纺织品整理剂以期大幅提高纺织品的性能就显得尤为必要。
发明内容
为解决上述技术问题,本发明提供用于纺织物的抗菌整理剂,通过采用特定的原料进行组合,配合特定的生产工艺,使得制备而成的整理剂使用后使纺织物具备优异的抗菌效果,同时保湿效果良好,能够满足行业的要求,具有较好的应用前景。
本发明的目的可以通过以下技术方案实现:
用于纺织物的抗菌整理剂,由下列重量份的原料制成:顺丁烯二酸酐40-50份、间苯二甲酸二苯酯35-45份、聚甘油单硬脂酸酯35-45份、三羟甲基丙烷三辛酸酯20-30份、乙烯碳酸酯15-25份、磺酸酯淀粉12-18份、十二烷基酚聚氧乙醚10-16份、羟甲基丙烯酰胺8-12份、磺化琥珀酸二甲酸钠8-10份、海藻酸钠6-8份、乙二胺四乙酸二钠5-7份、氨基硅油4-6份、二甘醇3-5份、乙基香兰素1-3份、表面活性剂3-5份、增稠剂3-5份、去离子水300份。
优选地,所述表面活性剂选自脂肪醇聚氧乙烯醚、α烯烃磺酸盐、羟乙基磺酸盐中的任意一种。
优选地,所述增稠剂选自羧甲基纤维素、卡拉胶、气相二氧化硅中的任意一种。
所述的用于纺织物的抗菌整理剂的制备方法,包括以下步骤:
(1)按所述重量份准确称取各原料;
(2)取去离子水100份,向其中加入磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺,加热至55℃,温度稳定后进行磁力搅拌,磁力搅拌转速为200 rpm,搅拌至均匀,得到混合液A;
(3)将去离子水200份与顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯混合,升温至90-110℃,加入磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠,在250-350W 的功率下超声分散0.5-1.5小时,得到混合液B;
(4)将混合液A和混合液B合并,送入球磨机,球磨1.5-2.5小时,使混合液中各组分完全均匀分散,随后加入三羟甲基丙烷三辛酸酯、乙烯碳酸酯、氨基硅油、二甘醇、乙基香兰素,通入氮气,在温度90℃下磁力搅拌反应3小时;
(5)反应结束后,待降温至60℃时,向反应液中再加入表面活性剂、增稠剂,随后进行磁力搅拌,直至所有的成分混合均匀,得到成品。
优选地,所述步骤(3)中,超声分散的功率为300W,超声时间为1小时。
优选地,所述步骤(4)中,磁力搅拌的速率为150-250 r/min。
本发明与现有技术相比,其有益效果为:
(1)本发明的用于纺织物的抗菌整理剂以顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯、三羟甲基丙烷三辛酸酯为主要成分,通过加入乙烯碳酸酯、磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺、磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠、氨基硅油、二甘醇、乙基香兰素、表面活性剂、增稠剂、去离子水,辅以加热、搅拌、超声分散、球磨、氮气环境下反应等工艺,使得制备而成的整理剂使用后使纺织物具备优异的抗菌效果,同时保湿效果良好,能够满足行业的要求,具有较好的应用前景。
(2)本发明的用于纺织物的抗菌整理剂原料廉价、工艺简单,适于大规模工业化运用,实用性强。
具体实施方式
下面结合具体实施例对发明的技术方案进行详细说明。
实施例1
(1)按所述重量份准确称取顺丁烯二酸酐40份、间苯二甲酸二苯酯35份、聚甘油单硬脂酸酯35份、三羟甲基丙烷三辛酸酯20份、乙烯碳酸酯15份、磺酸酯淀粉12份、十二烷基酚聚氧乙醚10份、羟甲基丙烯酰胺8份、磺化琥珀酸二甲酸钠8份、海藻酸钠6份、乙二胺四乙酸二钠5份、氨基硅油4份、二甘醇3份、乙基香兰素1份、脂肪醇聚氧乙烯醚3份、羧甲基纤维素3份、去离子水300份;
(2)取去离子水100份,向其中加入磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺,加热至55℃,温度稳定后进行磁力搅拌,磁力搅拌转速为200 rpm,搅拌至均匀,得到混合液A;
(3)将去离子水200份与顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯混合,升温至90℃,加入磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠,在300W 的功率下超声分散1小时,得到混合液B;
(4)将混合液A和混合液B合并,送入球磨机,球磨1.5小时,使混合液中各组分完全均匀分散,随后加入三羟甲基丙烷三辛酸酯、乙烯碳酸酯、氨基硅油、二甘醇、乙基香兰素,通入氮气,在温度90℃下以150r/min的速率磁力搅拌反应3小时;
(5)反应结束后,待降温至60℃时,向反应液中再加入脂肪醇聚氧乙烯醚、羧甲基纤维素,随后进行磁力搅拌,直至所有的成分混合均匀,得到成品。
制得的用于纺织物的抗菌整理剂的性能测试结果如表1所示。
实施例2
(1)按所述重量份准确称取顺丁烯二酸酐45份、间苯二甲酸二苯酯40份、聚甘油单硬脂酸酯40份、三羟甲基丙烷三辛酸酯25份、乙烯碳酸酯20份、磺酸酯淀粉15份、十二烷基酚聚氧乙醚13份、羟甲基丙烯酰胺10份、磺化琥珀酸二甲酸钠9份、海藻酸钠7份、乙二胺四乙酸二钠6份、氨基硅油5份、二甘醇4份、乙基香兰素2份、α烯烃磺酸盐4份、卡拉胶4份、去离子水300份;
(2)取去离子水100份,向其中加入磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺,加热至55℃,温度稳定后进行磁力搅拌,磁力搅拌转速为200 rpm,搅拌至均匀,得到混合液A;
(3)将去离子水200份与顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯混合,升温至100℃,加入磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠,在300W 的功率下超声分散1小时,得到混合液B;
(4)将混合液A和混合液B合并,送入球磨机,球磨2小时,使混合液中各组分完全均匀分散,随后加入三羟甲基丙烷三辛酸酯、乙烯碳酸酯、氨基硅油、二甘醇、乙基香兰素,通入氮气,在温度90℃下以200 r/min的速率磁力搅拌反应3小时;
(5)反应结束后,待降温至60℃时,向反应液中再加入α烯烃磺酸盐、卡拉胶,随后进行磁力搅拌,直至所有的成分混合均匀,得到成品。
制得的用于纺织物的抗菌整理剂的性能测试结果如表1所示。
实施例3
(1)按所述重量份准确称取顺丁烯二酸酐50份、间苯二甲酸二苯酯45份、聚甘油单硬脂酸酯45份、三羟甲基丙烷三辛酸酯30份、乙烯碳酸酯25份、磺酸酯淀粉18份、十二烷基酚聚氧乙醚16份、羟甲基丙烯酰胺12份、磺化琥珀酸二甲酸钠10份、海藻酸钠8份、乙二胺四乙酸二钠7份、氨基硅油6份、二甘醇5份、乙基香兰素3份、羟乙基磺酸盐5份、气相二氧化硅5份、去离子水300份;
(2)取去离子水100份,向其中加入磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺,加热至55℃,温度稳定后进行磁力搅拌,磁力搅拌转速为200 rpm,搅拌至均匀,得到混合液A;
(3)将去离子水200份与顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯混合,升温至110℃,加入磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠,在300W 的功率下超声分散1小时,得到混合液B;
(4)将混合液A和混合液B合并,送入球磨机,球磨2.5小时,使混合液中各组分完全均匀分散,随后加入三羟甲基丙烷三辛酸酯、乙烯碳酸酯、氨基硅油、二甘醇、乙基香兰素,通入氮气,在温度90℃下以250 r/min的速率磁力搅拌反应3小时;
(5)反应结束后,待降温至60℃时,向反应液中再加入羟乙基磺酸盐、气相二氧化硅,随后进行磁力搅拌,直至所有的成分混合均匀,得到成品。
制得的用于纺织物的抗菌整理剂的性能测试结果如表1所示。
实施例4
(1)按所述重量份准确称取顺丁烯二酸酐50份、间苯二甲酸二苯酯35份、聚甘油单硬脂酸酯45份、三羟甲基丙烷三辛酸酯20份、乙烯碳酸酯25份、磺酸酯淀粉12份、十二烷基酚聚氧乙醚16份、羟甲基丙烯酰胺8份、磺化琥珀酸二甲酸钠10份、海藻酸钠6份、乙二胺四乙酸二钠7份、氨基硅油4份、二甘醇5份、乙基香兰素1份、脂肪醇聚氧乙烯醚5份、气相二氧化硅3份、去离子水300份;
(2)取去离子水100份,向其中加入磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺,加热至55℃,温度稳定后进行磁力搅拌,磁力搅拌转速为200 rpm,搅拌至均匀,得到混合液A;
(3)将去离子水200份与顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯混合,升温至110℃,加入磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠,在300W 的功率下超声分散1小时,得到混合液B;
(4)将混合液A和混合液B合并,送入球磨机,球磨1.5小时,使混合液中各组分完全均匀分散,随后加入三羟甲基丙烷三辛酸酯、乙烯碳酸酯、氨基硅油、二甘醇、乙基香兰素,通入氮气,在温度90℃下以250 r/min的速率磁力搅拌反应3小时;
(5)反应结束后,待降温至60℃时,向反应液中再加入脂肪醇聚氧乙烯醚、气相二氧化硅,随后进行磁力搅拌,直至所有的成分混合均匀,得到成品。
制得的用于纺织物的抗菌整理剂的性能测试结果如表1所示。
对比例1
(1)按所述重量份准确称取顺丁烯二酸酐45份、间苯二甲酸二苯酯40份、聚甘油单硬脂酸酯40份、三羟甲基丙烷三辛酸酯25份、乙烯碳酸酯20份、磺酸酯淀粉15份、十二烷基酚聚氧乙醚13份、羟甲基丙烯酰胺10份、海藻酸钠7份、乙二胺四乙酸二钠6份、氨基硅油5份、二甘醇4份、α烯烃磺酸盐4份、卡拉胶4份、去离子水300份;
(2)取去离子水100份,向其中加入磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺,加热至55℃,温度稳定后进行磁力搅拌,磁力搅拌转速为200 rpm,搅拌至均匀,得到混合液A;
(3)将去离子水200份与顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯混合,升温至100℃,加入海藻酸钠、乙二胺四乙酸二钠,在300W 的功率下超声分散1小时,得到混合液B;
(4)将混合液A和混合液B合并,送入球磨机,球磨2小时,使混合液中各组分完全均匀分散,随后加入三羟甲基丙烷三辛酸酯、乙烯碳酸酯、氨基硅油、二甘醇,通入氮气,在温度90℃下以200 r/min的速率磁力搅拌反应3小时;
(5)反应结束后,待降温至60℃时,向反应液中再加入α烯烃磺酸盐、卡拉胶,随后进行磁力搅拌,直至所有的成分混合均匀,得到成品。
制得的用于纺织物的抗菌整理剂的性能测试结果如表1所示。
对比例2
(1)按所述重量份准确称取顺丁烯二酸酐50份、间苯二甲酸二苯酯35份、聚甘油单硬脂酸酯45份、三羟甲基丙烷三辛酸酯20份、乙烯碳酸酯25份、磺酸酯淀粉12份、十二烷基酚聚氧乙醚16份、羟甲基丙烯酰胺8份、磺化琥珀酸二甲酸钠10份、海藻酸钠6份、乙二胺四乙酸二钠7份、乙基香兰素1份、脂肪醇聚氧乙烯醚5份、气相二氧化硅3份、去离子水300份;
(2)取去离子水100份,向其中加入磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺,加热至55℃,温度稳定后进行磁力搅拌,磁力搅拌转速为200 rpm,搅拌至均匀,得到混合液A;
(3)将去离子水200份与顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯混合,升温至110℃,加入磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠,在300W 的功率下超声分散1小时,得到混合液B;
(4)将混合液A和混合液B合并,送入球磨机,球磨1.5小时,使混合液中各组分完全均匀分散,随后加入三羟甲基丙烷三辛酸酯、乙烯碳酸酯、乙基香兰素,通入氮气,在温度90℃下以250 r/min的速率磁力搅拌反应3小时;
(5)反应结束后,待降温至60℃时,向反应液中再加入脂肪醇聚氧乙烯醚、气相二氧化硅,随后进行磁力搅拌,直至所有的成分混合均匀,得到成品。
制得的用于纺织物的抗菌整理剂的性能测试结果如表1所示。
将实施例1-4和对比例1-2的用于纺织物的抗菌整理剂对棉纤维织物施用后分别按照国标进行棉纤维织物抗大肠杆菌、抗金黄色葡萄球菌以及棉纤维织物回潮率这几项性能测定。
表1
大肠杆菌抑菌率(%) | 金黄色葡萄球菌抑菌率(%) | 洗涤30次后回潮率(%) | |
实施例1 | 99.61 | 96.33 | 9.87 |
实施例2 | 99.79 | 96.54 | 10.15 |
实施例3 | 99.58 | 96.30 | 9.91 |
实施例4 | 99.64 | 96.47 | 10.43 |
对比例1 | 95.38 | 92.85 | 6.53 |
对比例2 | 94.29 | 91.96 | 6.61 |
本发明的用于纺织物的抗菌整理剂以顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯、三羟甲基丙烷三辛酸酯为主要成分,通过加入乙烯碳酸酯、磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺、磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠、氨基硅油、二甘醇、乙基香兰素、表面活性剂、增稠剂、去离子水,辅以加热、搅拌、超声分散、球磨、氮气环境下反应等工艺,使得制备而成的整理剂使用后使纺织物具备优异的抗菌效果,同时保湿效果良好,能够满足行业的要求,具有较好的应用前景。本发明的用于纺织物的抗菌整理剂原料廉价、工艺简单,适于大规模工业化运用,实用性强。
以上所述仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书内容所作的等效结构或等效流程变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。
Claims (6)
1.一种用于纺织物的抗菌整理剂,其特征在于:由下列重量份的原料制成:顺丁烯二酸酐40-50份、间苯二甲酸二苯酯35-45份、聚甘油单硬脂酸酯35-45份、三羟甲基丙烷三辛酸酯20-30份、乙烯碳酸酯15-25份、磺酸酯淀粉12-18份、十二烷基酚聚氧乙醚10-16份、羟甲基丙烯酰胺8-12份、磺化琥珀酸二甲酸钠8-10份、海藻酸钠6-8份、乙二胺四乙酸二钠5-7份、氨基硅油4-6份、二甘醇3-5份、乙基香兰素1-3份、表面活性剂3-5份、增稠剂3-5份、去离子水300份。
2.根据权利要求1所述的用于纺织物的抗菌整理剂,其特征在于:所述表面活性剂选自脂肪醇聚氧乙烯醚、α烯烃磺酸盐、羟乙基磺酸盐中的任意一种。
3.根据权利要求1所述的用于纺织物的抗菌整理剂,其特征在于:所述增稠剂选自羧甲基纤维素、卡拉胶、气相二氧化硅中的任意一种。
4.根据权利要求1-3任一所述的用于纺织物的抗菌整理剂的制备方法,其特征在于,包括以下步骤:
(1)按所述重量份准确称取各原料;
(2)取去离子水100份,向其中加入磺酸酯淀粉、十二烷基酚聚氧乙醚、羟甲基丙烯酰胺,加热至55℃,温度稳定后进行磁力搅拌,磁力搅拌转速为200 rpm,搅拌至均匀,得到混合液A;
(3)将去离子水200份与顺丁烯二酸酐、间苯二甲酸二苯酯、聚甘油单硬脂酸酯混合,升温至90-110℃,加入磺化琥珀酸二甲酸钠、海藻酸钠、乙二胺四乙酸二钠,在250-350W 的功率下超声分散0.5-1.5小时,得到混合液B;
(4)将混合液A和混合液B合并,送入球磨机,球磨1.5-2.5小时,使混合液中各组分完全均匀分散,随后加入三羟甲基丙烷三辛酸酯、乙烯碳酸酯、氨基硅油、二甘醇、乙基香兰素,通入氮气,在温度90℃下磁力搅拌反应3小时;
(5)反应结束后,待降温至60℃时,向反应液中再加入表面活性剂、增稠剂,随后进行磁力搅拌,直至所有的成分混合均匀,得到成品。
5.根据权利要求4所述的用于纺织物的抗菌整理剂的制备方法,其特征在于,所述步骤(3)中,超声分散的功率为300W,超声时间为1小时。
6.根据权利要求4所述的用于纺织物的抗菌整理剂的制备方法,其特征在于,所述步骤(4)中,磁力搅拌的速率为150-250 r/min。
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112813681A (zh) * | 2021-02-20 | 2021-05-18 | 康文广 | 一种具有抗菌防霉的服装面料及其制备方法 |
CN115053909A (zh) * | 2022-06-22 | 2022-09-16 | 湖南工业大学 | 一种生物基绿色复合抗菌剂及其制备方法和应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104727149A (zh) * | 2015-03-19 | 2015-06-24 | 苏州陈恒织造有限公司 | 一种织物拒油拒水整理剂及其制备方法 |
CN104846641A (zh) * | 2015-05-25 | 2015-08-19 | 青岛德翕拓创高新技术有限公司 | 一种改进的纺织品抗菌整理剂 |
CN104846633A (zh) * | 2015-05-23 | 2015-08-19 | 青岛东昌瑞纺织品有限公司 | 一种纺织抗菌整理剂 |
CN104862958A (zh) * | 2015-05-25 | 2015-08-26 | 青岛保利康新材料有限公司 | 一种用于纺织品的抗菌整理剂 |
-
2016
- 2016-12-15 CN CN201611161232.0A patent/CN106592210A/zh active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104727149A (zh) * | 2015-03-19 | 2015-06-24 | 苏州陈恒织造有限公司 | 一种织物拒油拒水整理剂及其制备方法 |
CN104846633A (zh) * | 2015-05-23 | 2015-08-19 | 青岛东昌瑞纺织品有限公司 | 一种纺织抗菌整理剂 |
CN104846641A (zh) * | 2015-05-25 | 2015-08-19 | 青岛德翕拓创高新技术有限公司 | 一种改进的纺织品抗菌整理剂 |
CN104862958A (zh) * | 2015-05-25 | 2015-08-26 | 青岛保利康新材料有限公司 | 一种用于纺织品的抗菌整理剂 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112813681A (zh) * | 2021-02-20 | 2021-05-18 | 康文广 | 一种具有抗菌防霉的服装面料及其制备方法 |
CN115053909A (zh) * | 2022-06-22 | 2022-09-16 | 湖南工业大学 | 一种生物基绿色复合抗菌剂及其制备方法和应用 |
CN115053909B (zh) * | 2022-06-22 | 2024-04-19 | 湖南工业大学 | 一种生物基绿色复合抗菌剂及其制备方法和应用 |
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