CN106592199A - 一种连续氧漂精炼剂及其制备方法 - Google Patents

一种连续氧漂精炼剂及其制备方法 Download PDF

Info

Publication number
CN106592199A
CN106592199A CN201611166053.6A CN201611166053A CN106592199A CN 106592199 A CN106592199 A CN 106592199A CN 201611166053 A CN201611166053 A CN 201611166053A CN 106592199 A CN106592199 A CN 106592199A
Authority
CN
China
Prior art keywords
refining agent
oxygen bleaching
continuous
surfactant
bleaching refining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201611166053.6A
Other languages
English (en)
Other versions
CN106592199B (zh
Inventor
党婉蓉
李正雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YAYUN TEXILE AGENTS CO Ltd SHANGHAI
Original Assignee
YAYUN TEXILE AGENTS CO Ltd SHANGHAI
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by YAYUN TEXILE AGENTS CO Ltd SHANGHAI filed Critical YAYUN TEXILE AGENTS CO Ltd SHANGHAI
Priority to CN201611166053.6A priority Critical patent/CN106592199B/zh
Publication of CN106592199A publication Critical patent/CN106592199A/zh
Application granted granted Critical
Publication of CN106592199B publication Critical patent/CN106592199B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/467—Compounds containing quaternary nitrogen atoms derived from polyamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

本发明涉及一种连续氧漂精炼剂及其制备方法。该连续氧漂精炼剂含有稀土催化剂、双氧水稳定剂、生物降解表面活性剂、吉米奇型表面活性剂、超支化型表面活性剂以及水。与常规精炼剂相比，本发明制备的连续氧漂精炼剂精炼剂高效环保，工艺适用性广，NaOH用量较常规精炼剂降低约40％，排放废水COD值降低40％以上，处理后织物的白度、毛效、断裂强力均明显优于常规精炼剂。

Description

一种连续氧漂精炼剂及其制备方法
技术领域
本发明涉及一种印染前处理助剂及其制备方法，特别是一种连续氧漂精炼剂及其制备方法。
背景技术
棉织物以其吸湿透气性深受广大消费者青睐，而棉纤维中含有很多天然杂质，使得棉织物色泽发黄、吸水性很差，同时由于棉籽壳的存在，也影响了织物的外观和手感，因此，棉织物必须进行去除天然杂质为主要目的的精炼和以去除天然色素为主要目的的漂白，经过精炼、漂白的棉织物的外观、手感和染色性能均得以明显改善，服用性能得以提高。棉织物常规煮练、漂白采用的分段连续汽蒸练漂工艺路线长，耗能大，排污大，为扭转这种局面，近年来，行业工作者不断进行技术创新，研发出节能减排的短流程新工艺，将煮练、漂白一浴进行，而传统的前处理精炼剂由于应用环境的变化已不再适用，适用于新工艺的新型氧漂精炼剂成为研究热点。
目前，精炼剂的开发主要集中在生物酶精炼剂和非生物耐碱精炼剂，前者的关键技术在于精练酶种类的选择应用，后者的关键技术在于表面活性剂的选择应用，多集中在烷基(苯)磺酸钠、脂肪醇聚氧乙烯醚等系列表面活性剂，前者生态环保，精练效果不佳，后者精炼效果优良，但不环保。如中国专利CN 102154230 A，发明涉及了一种精练酶在纺织物前处理中的应用，节能环保，但对棉籽壳的去除效果并不理想，不能达到很好的精炼效果；又如中国专利CN 104532556 A，介绍了一种高耐碱性纺织精炼剂及其制备方法，采用烷基磺酸钠、脂肪醇聚氧乙烯醚系列表面活性剂，对天然杂质及棉籽壳的去除效果优良，但精炼剂和NaOH用量大，分别达到10克/L和30克/L，造成排放废水COD值很高，不利于环保。
综上，目前还没有一支精炼剂既适用于短流程新工艺，又同时满足练漂效果并更加环保，因此，开发出一种满足上述要求的连续氧漂精练剂，具有非常重要的现实意义。
发明内容
本发明一个方面在于提供一种连续氧漂精炼剂，其包括以下组分：
剂的总重量为基准。
本发明的另一个方面在于提供一种连续氧漂精炼剂的制备方法，该方法包括以下几个步骤：
1)将上述的双氧水稳定剂、生物降解表面活性剂、吉米奇型表面活性剂、超支化型表面活性剂和水加入反应釜，40-60℃搅拌10-20分钟；
2)在步骤1)中形成的混合物中加入稀土催化剂，升温至50-70℃，继续搅拌1-2小时；和
3)任选地冷却至室温，制得所述连续氧漂精炼剂；
与现已公开的精炼剂及其制备方法相比，该发明独创性表现在如下几个方面：(1)本发明引入催化剂稀土双核双配体配合物，提高催化效率，从而提高练漂效果；(2)引入生物降解表面活性剂代替部分非生物表面活性剂，利于环保；(3)采用吉米奇型和超支化型表面活性剂，其具有非常优异的润湿、乳化和净洗能力，用量小，效率高。(4)以上组分具有协同增效作用，由此制备的连续氧漂精炼剂应用效果好，毛效和白度高，强力损伤小，并且能够大大降低应用工艺中NaOH用量和氧漂精炼剂的用量，以及降低排放废水COD值。
本发明制备的连续氧漂精炼剂精炼剂高效环保，工艺适用性广，NaOH用量较常规精炼剂降低约40％，排放废水COD值降低40％以上，处理后织物的白度、毛效、断裂强力均明显优于常规精炼剂。
具体实施方式
在一个优选的实施方式中，本发明一种连续氧漂精炼剂包括以下组分：
剂的总重量为基准。
在一个更优选的实施方式中，所述催化剂是稀土双核双配体配合物Tb0.5Eu0.5(TTA)3Phen、Pr2(BA)6(Phen)2、Eu0.7La0.3Su3Dipy、或其混合物，其中，TTA表示β—二酮，Phen表示邻菲咯啉，BA表示苯甲酸，Su表示丁二酸，Dipy表示2,2′-联吡啶。
在一个更优选的实施方式中，所述稳定剂是重均分子量为2000-8000的木质素磺酸盐、重均分子量为3000-8000聚羧酸、重均分子量为3000-8000的聚羟基丙烯酸钠、或它们的混合物；
在一个更优选的实施方式中，所述的木质素磺酸盐、聚羧酸、聚羟基丙烯酸钠的质量比为1:(0.5-1.5):(1-1.5)。
在一个更优选的实施方式中，所述生物降解表面活性剂是无患子皂苷、平均聚合度为1.1-1.3的C12-14淀粉糖苷、鼠李糖脂R1、鼠李糖脂R2、鼠李糖脂R3、鼠李糖脂R4、或其混合物。
在一个更优选的实施方式中，所述吉米奇(Gimini)型表面活性剂是N,N′-双月桂酰基乙二胺二乙基磺酸钠、N,N′-双脂肪酰基乙二胺二丙酸钠、4,4′-双酰基乙二醇二苯醚磺酸盐、1,4-丁二醇双聚氧乙烯醚琥珀酸双酯双磺酸盐\或其混合物。
在一个更优选的实施方式中，所述超支化型表面活性剂为烷基芳基磺酸盐超支化聚合物表面活性剂AAS-HBP(式I表示)、烷基磺酸盐超支化聚合物表面活性剂SHBP(式Ⅱ表示)、松香基超支化表面活性剂RHBP(式Ⅲ表示)、或其混合物：
在一个更优选的实施方式中，本发明中所用的水一般是氧漂精炼业中常用的水，优选是去离子水。
在一个更优选的实施方式中，本发明连续氧漂精炼剂的制备方法包括如下步骤：
1)将双氧水稳定剂5-10wt％、生物降解表面活性剂2-5wt％、吉米奇型表面活性剂18-25wt％、超支化型表面活性剂2-4wt％和去离子水50-70wt％加入反应釜，40-60℃搅拌10-20分钟；
2)在步骤1)中形成的混合物中加入稀土催化剂2-8wt％，升温至50-70℃，继续搅拌1-2小时；
3)冷却至室温，制得所述连续氧漂精炼剂。
本发明制备的连续氧漂精炼剂精炼剂高效环保，工艺适用性广，NaOH用量较常规精炼剂降低约40％，排放废水COD值降低40％以上，处理后织物的白度、毛效、断裂强力均明显优于常规精炼剂。
实施例
下面结合具体实施例，进一步阐述本发明。应理解，这些实施例仅用于说明本发明而不用于限制本发明的范围。此外应理解，在阅读了本发明讲授的内容之后，本领域技术人员可以对本发明作各种改动或修改，这些等价形式同样落于本申请所附权利要求书所限定的范围。
所制得产品固含量测定及其在纺织品上的应用与性能测定：
1)含固量：采用HG63型卤素水分测定仪测定；
2)在纺织品的练漂处理应用：
织物：全棉府绸坯布
配方：精练剂3、5克/L；NaOH 8、15克/L，H202(30％)10克/L
工艺：二浸二轧(轧余率90％)→烘干(90℃×2分钟)→汽蒸(100-105℃×2分钟)→热水洗(80℃×5分钟，50℃×5分钟)→冷水充分冲洗，烘干
3)纺织品性能测定标准：
白度：将织物折成4层(织物表面纹路方向尽可能一致，保持织物平整)，在Datacolor 400测色配色仪，D65/10光源下测试织物的4个不同地方的CIE值，取平均值；
毛效：根据《FZ/T 01071-2008》测定；
断裂强力：根据《GB/T3923.1-2013》标准测定；
强力保留率：按照公式(a)计算：
其中，F1为全棉府绸坯布(经过练漂处理)的断裂强力，F0为全棉府绸坯布(未经过练漂处理)的断裂强力；
COD值：收集应用工艺中热水洗的排放废水，参照《化学需氧量(COD)测定仪检定规程》，使用5B-3F型COD快速测定仪进行测定。
实施例1
在四口烧瓶中加入木质素磺酸盐(武汉丰竹林化学科技有限公司，重均分子量2900)2.1克、聚羧酸(湖北信康医药化工有限公司，重均分子量3150)2.0克、聚羟基丙烯酸钠(金锦乐(湖南)化学有限公司，重均分子量3100)2.3克、无患子皂苷(湖南朗林生物制品有限公司)2.8克、N,N′-双月桂酰基乙二胺二乙基磺酸钠21克、AAS-HBP 2克和去离子水65克，45℃搅拌15分钟，加入Tb0.5Eu0.5(TTA)3Phen 4.3克，升温至55℃，继续搅拌1.5小时，冷却至室温，制得所述连续氧漂精炼剂1，测得含固量36.2％。
实施例2
在四口烧瓶中加入木质素磺酸盐(武汉丰竹林化学科技有限公司，重均分子量4200)2.0克、聚羧酸(湖北信康医药化工有限公司，重均分子量3950)1.9克、聚羟基丙烯酸钠(金锦乐(湖南)化学有限公司，重均分子量4100)2.2克、平均聚合度为1.2的C12淀粉糖苷(购自兰州理工大学)3克、N,N′-双脂肪酰基乙二胺二丙酸钠22克、(式I表示)、SHBP 2.3克和去离子水63克，40℃搅拌15分钟，加入Pr2(BA)6(Phen)2 4.8克，升温至55℃，继续搅拌1.5小时，冷却至室温，制得所述连续氧漂精炼剂2，测得含固量35.7％。
实施例3
在四口烧瓶中加入木质素磺酸盐(武汉丰竹林化学科技有限公司，重均分子量4900)2.2克、聚羧酸(湖北信康医药化工有限公司，重均分子量4600)2.2克、聚羟基丙烯酸钠(金锦乐(湖南)化学有限公司，重均分子量4850)2.5克、鼠李糖脂R1(北京华越洋生物科技有限公司)3.5克、4,4′-双酰基乙二醇二苯醚磺酸盐20克、(式Ⅱ表示)、RHBP2.3克和去离子水62克，50℃搅拌10分钟，加入Eu0.7La0.3Su3Dipy 4.2克，升温至60℃，继续搅拌1.5小时，冷却至室温，制得所述连续氧漂精炼剂3，测得含固量36.4％。
实施例4
在四口烧瓶中加入木质素磺酸盐(武汉丰竹林化学科技有限公司，重均分子量4760)2.1克、聚羧酸(湖北信康医药化工有限公司，重均分子量4900)2.0克、聚羟基丙烯酸钠(金锦乐(湖南)化学有限公司，重均分子量5100)2.8克、鼠李糖脂R3(北京华越洋生物科技有限公司)3.2克、1,4-丁二醇双聚氧乙烯醚琥珀酸双酯双磺酸盐20.5克、RHBP 2.1克和去离子水62克，50℃搅拌10分钟(min)，加入Eu0.7La0.3Su3Dipy 4.1克，升温至55℃，继续搅拌1.5小时，冷却至室温，制得所述连续氧漂精炼剂4，测得含固量36.5％。
各实施例的应用效果与市售精炼剂A(含固量37.4％)、市售精炼剂B(含固量38.0％)应用效果对比，如表1所示。
表1应用效果
由表1可以看出，经本发明制备的连续氧漂精炼剂应用时，白度、毛效均优于市场精炼剂，当NaOH用量由25克/L降低为15克/L时，市售精炼剂效果已经不能达到市场基本要求(CIE白度65，毛效8.0cm/30min)，本发明连续氧漂精炼剂仍表现出良好的处理效果，并且，本发明的连续氧漂精炼剂对织物强力损伤小，排放废水COD值远远低于市售精炼剂，更加利于环保。

Claims (10)

1.一种连续氧漂精炼剂，其包括以下组分：
2.如权利要求1所述的连续氧漂精炼剂，其特征在于，所述稀土催化剂是稀土双核双配体配合物Tb0.5Eu0.5(TTA)3Phen、Pr2(BA)6(Phen) 2、Eu0.7La0.3Su3Dipy或其混合物，其中，TTA表示β—二酮，Phen表示邻菲咯啉，BA表示苯甲酸，Su表示丁二酸，Dipy表示2,2′-联吡啶。
3.如权利要求1所述的连续氧漂精炼剂，其特征在于，所述双氧水稳定剂是重均分子量为2000-12000的木质素磺酸盐、重均分子量为3000-13000聚羧酸、重均分子量为3000-13000的聚羟基丙烯酸钠、或它们的混合物。
4.如权利要求1所述的连续氧漂精炼剂，其特征在于，所述木质素磺酸盐、聚羧酸、聚羟基丙烯酸钠的质量比为1:(0.5-2):(1-1.5)。
5.如权利要求1所述的连续氧漂精炼剂，其特征在于，所述生物降解表面活性剂是无患子皂苷、平均聚合度为1.1-1.4的C12-14淀粉糖苷、鼠 李糖脂R1、鼠李糖脂R2、鼠李糖脂R3、鼠李糖脂R4或其混合物。
6.如权利要求1所述的连续氧漂精炼剂，其特征在于，所述吉米奇型表面活性剂是N,N′-双月桂酰基乙二胺二乙基磺酸钠、N,N′-双脂肪酰基乙二胺二丙酸钠、4,4′-双酰基乙二醇二苯醚磺酸盐、1,4-丁二醇双聚氧乙烯醚琥珀酸双酯双磺酸盐的一种或其混合物。
7.如权利要求1所述的连续氧漂精炼剂，其特征在于，所述超支化型表面活性剂为式I表示的烷基芳基磺酸盐超支化聚合物表面活性剂AAS-HBP、式Ⅱ表示的烷基磺酸盐超支化聚合物表面活性剂SHBP、式III表示的松香基超支化表面活性剂RHBP或其混合物：
8.如权利要求1所述的连续氧漂精炼剂，其特征在于，所述水是去离子水。
9.如权利要求1－8中任一项所述的连续氧漂精炼剂的制备方法，其特征在于，它包括如下步骤：
1)将双氧水稳定剂、生物降解表面活性剂、吉米奇型表面活性剂、超支化型表面活性剂和水加入反应釜，40-60℃搅拌10-20分钟；
2)在步骤1)中形成的混合物中加入稀土催化剂，升温至50-70℃，继续搅拌1-2小时；
3)冷却至室温，制得所述连续氧漂精炼剂。
10.如权利要求9所述的方法，其特征在于，所述水是去离子水。
CN201611166053.6A 2016-12-16 2016-12-16 一种连续氧漂精炼剂及其制备方法 Active CN106592199B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611166053.6A CN106592199B (zh) 2016-12-16 2016-12-16 一种连续氧漂精炼剂及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611166053.6A CN106592199B (zh) 2016-12-16 2016-12-16 一种连续氧漂精炼剂及其制备方法

Publications (2)

Publication Number Publication Date
CN106592199A true CN106592199A (zh) 2017-04-26
CN106592199B CN106592199B (zh) 2018-12-18

Family

ID=58802880

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611166053.6A Active CN106592199B (zh) 2016-12-16 2016-12-16 一种连续氧漂精炼剂及其制备方法

Country Status (1)

Country Link
CN (1) CN106592199B (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835849A (zh) * 2019-12-12 2020-02-25 上海雅运新材料有限公司 一种高性能环保精练剂组合物及其制备方法
CN111455709A (zh) * 2020-05-19 2020-07-28 山东太阳纸业股份有限公司 一种apmp的生产工艺
US11441105B2 (en) 2017-12-15 2022-09-13 Rhodia Operations Composition containing lanthanide metal complex

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101665503A (zh) * 2009-05-08 2010-03-10 中国科学院上海硅酸盐研究所 稀土配合物、稀土氧化物及其制备方法
CN101717090A (zh) * 2009-12-07 2010-06-02 上海工程技术大学 超支化季铵盐改性有机蒙脱土及其制备方法
CN102720056A (zh) * 2012-06-25 2012-10-10 河北宁纺集团有限责任公司 一种低温精练剂、其制备方法及其应用
CN102755855A (zh) * 2012-07-03 2012-10-31 陕西科技大学 一种烷基芳基磺酸盐型超支化聚合物表面活性剂及制备方法
CN103276595A (zh) * 2013-06-14 2013-09-04 苏州大学 一种易生物降解的棉织物低温前处理助剂

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101665503A (zh) * 2009-05-08 2010-03-10 中国科学院上海硅酸盐研究所 稀土配合物、稀土氧化物及其制备方法
CN101717090A (zh) * 2009-12-07 2010-06-02 上海工程技术大学 超支化季铵盐改性有机蒙脱土及其制备方法
CN102720056A (zh) * 2012-06-25 2012-10-10 河北宁纺集团有限责任公司 一种低温精练剂、其制备方法及其应用
CN102755855A (zh) * 2012-07-03 2012-10-31 陕西科技大学 一种烷基芳基磺酸盐型超支化聚合物表面活性剂及制备方法
CN103276595A (zh) * 2013-06-14 2013-09-04 苏州大学 一种易生物降解的棉织物低温前处理助剂

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11441105B2 (en) 2017-12-15 2022-09-13 Rhodia Operations Composition containing lanthanide metal complex
CN110835849A (zh) * 2019-12-12 2020-02-25 上海雅运新材料有限公司 一种高性能环保精练剂组合物及其制备方法
CN111455709A (zh) * 2020-05-19 2020-07-28 山东太阳纸业股份有限公司 一种apmp的生产工艺
CN111455709B (zh) * 2020-05-19 2021-12-03 山东太阳纸业股份有限公司 一种apmp的生产工艺

Also Published As

Publication number Publication date
CN106592199B (zh) 2018-12-18

Similar Documents

Publication Publication Date Title
KR101128856B1 (ko) 물세탁 및 드라이 크리닝용 친환경 용제 및 이를 포함한 세탁용 조성물
CN106592199A (zh) 一种连续氧漂精炼剂及其制备方法
CN105155249B (zh) 一种低温精练剂、其制备方法及其用途
CN100432205C (zh) 一种纺织印染皂洗用高效环保皂洗剂组合物及其制备方法
CN103923753A (zh) 一种净洗剂及其制备方法
CN108505318A (zh) 一种新型退浆剂及其制备方法
CN107723118A (zh) 一种酸性还原清洗剂及其制备方法
CN111576043B (zh) 一种防水纱的加工工艺
CN107829321A (zh) 一种耐碱渗透剂及其制备方法
CN110643197B (zh) 分散黑染料组合物、分散黑染料及其制备方法和应用
CN107653671A (zh) 一种环保型多功能精练剂及制备方法
KR100795970B1 (ko) 염색공정에 사용되는 쇼핑유연제 조성물 및 그 제조방법
CN105908527A (zh) 一种阻燃混纺纤维的染色工艺
CN106811954B (zh) 酒店用毛巾彩漂工艺
CN109694783A (zh) 一种护色柔软洗衣液及其制备方法
CN102677449A (zh) 一种低温活化漂白剂及其制备方法和应用
CN107740268A (zh) 一种织物防霉平滑蓬松柔软剂及其制备方法
CN109944055B (zh) 一种织物的环保型退浆方法
CN108192384B (zh) 一种红色活性染料混合物及其应用
CN115162034B (zh) 一种醋酸印花面料水洗防搭色试剂及其使用方法
CN106560509A (zh) 移动洗衣房用环保洗衣助剂及其制备方法和应用
CN110331603A (zh) 一种酸性染料染色及印花用皂洗剂组合物及其制备方法
CN108659980A (zh) 一种无磷护色洗衣液
CN107794753A (zh) 一种耐高温渗透剂及其制备方法
CN104250923B (zh) 一种羊毛干洗漂白药液

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 201804 Cao Lian branch, Huangdu Town, Jiading District, Shanghai, No. 8

Applicant after: Shanghai Ya Yun new materials Co., Ltd.

Address before: 201812 No. 301, Po yuan five road, Jiangqiao industrial West District, Jiading District, Shanghai.

Applicant before: Yayun Texile Agents Co., Ltd., Shanghai

CB02 Change of applicant information
CB02 Change of applicant information

Address after: 201804 No. 301, Po yuan five road, Jiangqiao industrial West District, Jiading District, Shanghai.

Applicant after: Shanghai Ya Yun new materials Co., Ltd.

Address before: 201804 Cao Lian branch, Huangdu Town, Jiading District, Shanghai, No. 8

Applicant before: Shanghai Ya Yun new materials Co., Ltd.

CB02 Change of applicant information
GR01 Patent grant
GR01 Patent grant