CN108659980A - 一种无磷护色洗衣液 - Google Patents

一种无磷护色洗衣液 Download PDF

Info

Publication number
CN108659980A
CN108659980A CN201810703896.8A CN201810703896A CN108659980A CN 108659980 A CN108659980 A CN 108659980A CN 201810703896 A CN201810703896 A CN 201810703896A CN 108659980 A CN108659980 A CN 108659980A
Authority
CN
China
Prior art keywords
liquid detergent
color protection
protection liquid
phosphorus
gleditsia sinensis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810703896.8A
Other languages
English (en)
Inventor
田波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201810703896.8A priority Critical patent/CN108659980A/zh
Publication of CN108659980A publication Critical patent/CN108659980A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C11D3/187—Hydrocarbons aromatic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Abstract

本发明涉及日化领域，具体是公开一种无磷护色洗衣液，由如下质量百分比的原料混合而成：皂角提取液25～40%；茶皂素1～2%；羧酸型表面活性剂3～10%；脂肪醇聚氧乙烯醚多元表面活性剂2～10%；聚4‑乙烯基吡啶氮氧化0.1～1%；柠檬酸钠1～5%；二苯乙烯联苯类荧光增白剂0～0.3%；增稠剂0.1～1%；防腐剂0.1～0.5%；水余量。本发明的无磷护色洗衣液洗涤效果好、减少织物颜色损失、防止织物洗涤串色，而且不含磷，更加环保、安全。

Description

一种无磷护色洗衣液
技术领域
本发明属于日化用品领域，具体是一种无磷护色洗衣液。
背景技术
洗衣服是生活中人人都会面对的事情。用于洗涤衣物的产品中，洗衣粉一直占着主要的地位。但是，洗衣粉在使用过程中并不能完全溶解，洗衣粉的残留物容易损伤衣物，并且不易漂洗；而洗衣液能够完全溶解且溶解速度快，易漂易洗，不会伤及皮肤和衣物；洗衣粉一般呈强碱性，对皮肤有刺激性；而洗衣液PH值偏中性，配方温和不伤手，由此可以看出，洗衣液的技术含量更高，便于添加各种有效成分，洗后可令衣物蓬松、柔软、光滑亮泽，并且具有除菌和持久留香的功效，使用综合成本低，正被人们广泛的接受。
随着生活水平的提高，消费者对洗衣液的诉求也越来越多样化，除了基本的洗涤功能，还期望其对织物有保护和护理等作用。在日常洗涤中常出现有色织物褪色、白色与深色织物混洗串色的现象，这与织物在染色过程中色牢度不足、多次洗涤、高温洗涤、暴晒等因素有关，目前衣物护色解问题最有效的方法是在洗衣液配方中加入能起到护色作用的护色剂。常用护色剂有非离子型和阳离子型两类，但非离子型护色剂护色效果有限，大部分阳离子型护色剂与阴离子表面活性剂、荧光增白剂存在兼容性问题。
磷是洗衣液中经常含有的东西，大家可能会听说过“水体富营养化”，如果一个鱼塘发生了“水体富营养化”，那么首先鱼塘里的藻类等微生物会大量繁殖，然后水中的氧气会大幅减少，然后鱼虾会缺氧而死……整个鱼塘的生态失衡，最后变成一池死水。“磷”在这个过程中，相当于刺激微生物生长的营养成分，对环境的危害极大。此外磷还会影响人体对钙质的吸收，造成软骨病之类。不使用含磷洗衣粉，是因为衣服漂洗过程中要去掉磷质很不容易为了健康，要用更多的水、更多的时间去漂洗。
发明内容
本发明的目的在于解决上述技术问题，提供一种无磷护色洗衣液，洗涤效果好、减少织物颜色损失、防止织物洗涤串色，而且不含磷，更加环保、安全。
为解决上述技术问题，本发明提供了一种无磷护色洗衣液，由如下质量百分比的原料混合而成：
皂角提取液25～40%；茶皂素1～2%；羧酸型表面活性剂3～10%；脂肪醇聚氧乙烯醚多元表面活性剂2～10%；聚4 -乙烯基吡啶氮氧化0.1～1%；柠檬酸钠1～5%；二苯乙烯联苯类荧光增白剂0～0.3%；增稠剂0.1～1%；防腐剂0 .1～0 .5%；水余量。
所述皂角提取液按以下工艺进行制备：将皂角洗净后放入纯化水中浸泡三次，每次浸泡后收集浸提液，合并三次浸提液得到所述皂角提取液；其中，在每次浸泡过程中，所用纯化水的重量是皂量的2-4倍，每次浸泡时间为20～30 h。
所述的增稠剂选用氯化钠、硫酸钠和聚丙烯酸类聚合物中的至少一种。
所述的防腐剂为卡松、多元醇类和苯氧乙醇或异噻唑啉酮中的至少一种
本发明采用的皂角提取液能够达到很好的去污清洁效果，而且配方温和，不伤皮肤和衣物，特别适合应用于婴幼儿衣物的洗护；添加的护色剂聚4 -乙烯基吡啶氮氧化不仅对织物有出色的护色功能，还与羧酸型表面活性剂、脂肪醇聚氧乙烯醚多元表面活性剂和荧光增白剂有良好的相容性，具有更好的洗涤去污能力，能够在满足洗涤性能的同时，保护织物的色泽，减少织物颜色损失，降低织物混合洗涤造成的相互串色；添加的防腐剂可以保证皂角提取液和茶皂素不易发生变质。
具体实施方式
实施例1
一种无磷护色洗衣液，由如下质量百分比的原料混合而成：
皂角提取液25%；茶皂素2%；羧酸型表面活性剂3%；脂肪醇聚氧乙烯醚多元表面活性剂10%；聚4 -乙烯基吡啶氮氧化1%；柠檬酸钠1%；二苯乙烯联苯类荧光增白剂0.3%；氯化钠1%；异噻唑啉酮0 .1%；水56.2%。
I、去污性能测试：
去污性能测试参照GB/T13174-2008《衣料用洗涤剂去污力及循环洗涤性能的测定》进行，配制250 ppm的洗涤用水，采用炭黑JB-01、蛋白JB-02、皮脂JB-03 进行测试，测试结果见表1。
表1本发明的无磷护色洗衣液和普通市售洗衣液的去污性能测试数据
由表1可以看出，本发明的无磷护色洗衣液的去污能力与市售普通洗衣液不相上下，完全可以取代市售普通洗衣液。
II、护色性能测试：
分别取等量的本发明的无磷护色洗衣液、市售普通洗衣液置于小型洗衣机中，加入等量40℃左右的温水，两台洗衣机中各加入一片10 cm×10 cm的EMPA色布和两片10 cm×10cm的白布，浸泡30 min后，按常规洗衣程序洗涤并脱水。
在浸泡前测量EMPA色布和白布的色差值作为原始值，护色实验后，测量晾干后EMPA色布和白布的色差值，抗染料迁移性能即防串色性以白布在洗涤前后其色差值△E1表示，白布△E1越小，防串色性能越好；固色性以色布在洗涤前后其色差值△E2表示，色布△E2越小，固色性能越好。测试结果见表2。
表2 本发明的无磷护色洗衣液和普通市售洗衣液的护色性能测试数据
由表2可以看出，本发明的无磷护色洗衣液混合洗涤后白布△E1数值均较小，说明护色剂对三种EMPA色布染料抗染料迁移作用效果显著，EMPA色布色差△E2整体也较小，说明本发明的无磷护色洗衣液具有较好的护色功能。
实施例2
一种无磷护色洗衣液，由如下质量百分比的原料混合而成：
皂角提取液40%；茶皂素1%；羧酸型表面活性剂5%；脂肪醇聚氧乙烯醚多元表面活性剂2%；聚4 -乙烯基吡啶氮氧化0.1%；柠檬酸钠5%；聚丙烯酸类聚合物1%；卡松0 .5%；水45.4%。
实施例3
一种无磷护色洗衣液，由如下质量百分比的原料混合而成：
皂角提取液30%；茶皂素2%；羧酸型表面活性剂10%；脂肪醇聚氧乙烯醚多元表面活性剂2%；聚4 -乙烯基吡啶氮氧化0.5%；柠檬酸钠3%；二苯乙烯联苯类荧光增白剂0.1%；硫酸钠0.1%；苯氧乙醇0 .3%；水52%。
实施例4
一种无磷护色洗衣液，由如下质量百分比的原料混合而成：
皂角提取液35%；茶皂素2%；羧酸型表面活性剂3%；脂肪醇聚氧乙烯醚多元表面活性剂10%；聚4 -乙烯基吡啶氮氧化1%；柠檬酸钠5%；二苯乙烯联苯类荧光增白剂0.2%；氯化钠0.8%；卡松0 .4%；水42.6%。
实施例和说明书中描述的仅为本发明的优选例，并不用来限制本发明，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都应属于本发明的保护范围内。

Claims (4)

1.一种无磷护色洗衣液，由如下质量百分比的原料混合而成：
皂角提取液25～40%；茶皂素1～2%；羧酸型表面活性剂3～10%；脂肪醇聚氧乙烯醚多元表面活性剂2～10%；聚4 -乙烯基吡啶氮氧化0.1～1%；柠檬酸钠1～5%；二苯乙烯联苯类荧光增白剂0～0.3%；增稠剂0.1～1%；防腐剂0 .1～0 .5%；水余量。
2.根据权利要求1所述的无磷护色洗衣液，其特征在于：所述皂角提取液按以下工艺进行制备：将皂角洗净后放入纯化水中浸泡三次，每次浸泡后收集浸提液，合并三次浸提液得到所述皂角提取液；其中，在每次浸泡过程中，所用纯化水的重量是皂量的2-4倍，每次浸泡时间为20～30 h。
3.根据权利要求1所述的无磷护色洗衣液，其特征在于：所述的增稠剂选用氯化钠、硫酸钠和聚丙烯酸类聚合物中的至少一种。
4.根据权利要求1或3所述的无磷护色洗衣液，其特征在于：所述的防腐剂为卡松、多元醇类和苯氧乙醇或异噻唑啉酮中的至少一种。
CN201810703896.8A 2018-07-01 2018-07-01 一种无磷护色洗衣液 Pending CN108659980A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810703896.8A CN108659980A (zh) 2018-07-01 2018-07-01 一种无磷护色洗衣液

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810703896.8A CN108659980A (zh) 2018-07-01 2018-07-01 一种无磷护色洗衣液

Publications (1)

Publication Number Publication Date
CN108659980A true CN108659980A (zh) 2018-10-16

Family

ID=63773265

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810703896.8A Pending CN108659980A (zh) 2018-07-01 2018-07-01 一种无磷护色洗衣液

Country Status (1)

Country Link
CN (1) CN108659980A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113493724A (zh) * 2021-06-22 2021-10-12 广东菁萃生物科技有限公司 一种高效去污洗衣液及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103805368A (zh) * 2014-02-28 2014-05-21 刘菊 一种护色洗衣液
CN108048238A (zh) * 2017-12-27 2018-05-18 库柏（天津）科技有限公司 一种含有酵素的植物配方洗衣液及其制备方法
CN108130199A (zh) * 2017-12-25 2018-06-08 上海和黄白猫有限公司 高效护色洗衣液及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103805368A (zh) * 2014-02-28 2014-05-21 刘菊 一种护色洗衣液
CN108130199A (zh) * 2017-12-25 2018-06-08 上海和黄白猫有限公司 高效护色洗衣液及其制备方法
CN108048238A (zh) * 2017-12-27 2018-05-18 库柏（天津）科技有限公司 一种含有酵素的植物配方洗衣液及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113493724A (zh) * 2021-06-22 2021-10-12 广东菁萃生物科技有限公司 一种高效去污洗衣液及其制备方法

Similar Documents

Publication Publication Date Title
CN108130199A (zh) 高效护色洗衣液及其制备方法
CN101851564B (zh) 一种用于内衣洗涤的洗衣液
CN102392374B (zh) 一种用于牛仔服装酶洗的防返沾色剂
CN101906356B (zh) 一种洗衣液及制备方法
CN108560264B (zh) 一种衣物护理液及其应用
CN108192760A (zh) 一种无水洗衣液及其制备方法
CN111057624A (zh) 一种杀菌护色防串色浓缩洗衣液及其制备方法
CN102304437A (zh) 一种具有彩漂效果的高效液相洗涤剂
CN109504548A (zh) 一种去除油性污渍的洗衣液及其生产工艺
CN103614900A (zh) 一种织物上的有色污渍的清洗方法
CN108841458A (zh) 一种快速洁净洗衣液
CN109439474A (zh) 一种含阳离子聚合物的清洁皂及其制备方法
CN108659980A (zh) 一种无磷护色洗衣液
CN109609302A (zh) 一种针对衣物黄斑、色素的清洗液及制备方法
CN104450278B (zh) 一种防沾护色洗衣液
CN110511832A (zh) 一种抗菌环保洗衣液及其制备方法
CN106047526A (zh) 一种洗衣片及其制备方法
CN105542999B (zh) 一种杀菌型衣物清洗剂
CN106592199A (zh) 一种连续氧漂精炼剂及其制备方法
CN103046345A (zh) 一种对纺织品织物及成衣进行三防整理的方法
CN106047517A (zh) 一种含有蜗牛提取液的羊毛衫洗涤液
CN108641832A (zh) 一种加酶护色洗衣液
CN109694783A (zh) 一种护色柔软洗衣液及其制备方法
CN104651078B (zh) 一种涂层面料或高密面料羽绒制品的高效去油护绒洗衣液
CN104099185A (zh) 一种内衣专用洗衣液及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20181016

WD01 Invention patent application deemed withdrawn after publication