CN106587601A - 一种硼酸盐红色发光玻璃及其制备方法 - Google Patents
一种硼酸盐红色发光玻璃及其制备方法 Download PDFInfo
- Publication number
- CN106587601A CN106587601A CN201611166487.6A CN201611166487A CN106587601A CN 106587601 A CN106587601 A CN 106587601A CN 201611166487 A CN201611166487 A CN 201611166487A CN 106587601 A CN106587601 A CN 106587601A
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- CN
- China
- Prior art keywords
- hours
- borate red
- glass
- melting
- borate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011521 glass Substances 0.000 title claims abstract description 75
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims abstract description 13
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 8
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 5
- 238000002844 melting Methods 0.000 claims description 49
- 230000008018 melting Effects 0.000 claims description 49
- 229910052693 Europium Inorganic materials 0.000 claims description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 238000000137 annealing Methods 0.000 abstract description 24
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract description 23
- 239000004327 boric acid Substances 0.000 abstract description 22
- 150000004649 carbonic acid derivatives Chemical class 0.000 abstract description 22
- 238000001816 cooling Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 30
- 238000000227 grinding Methods 0.000 description 28
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 25
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 24
- 229910000831 Steel Inorganic materials 0.000 description 22
- 229910052593 corundum Inorganic materials 0.000 description 22
- 239000010431 corundum Substances 0.000 description 22
- 239000004570 mortar (masonry) Substances 0.000 description 22
- 239000010959 steel Substances 0.000 description 22
- 229910001940 europium oxide Inorganic materials 0.000 description 14
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 description 14
- 229910000019 calcium carbonate Inorganic materials 0.000 description 12
- 239000000395 magnesium oxide Substances 0.000 description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 12
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 239000011787 zinc oxide Substances 0.000 description 12
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 10
- 230000003647 oxidation Effects 0.000 description 10
- 238000007254 oxidation reaction Methods 0.000 description 10
- 238000000295 emission spectrum Methods 0.000 description 7
- 230000005284 excitation Effects 0.000 description 7
- 238000000695 excitation spectrum Methods 0.000 description 7
- 239000003822 epoxy resin Substances 0.000 description 6
- 229920000647 polyepoxide Polymers 0.000 description 6
- 239000012467 final product Substances 0.000 description 5
- 229910052761 rare earth metal Inorganic materials 0.000 description 5
- 239000000741 silica gel Substances 0.000 description 5
- 229910002027 silica gel Inorganic materials 0.000 description 5
- -1 Rare earth ion Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000011575 calcium Substances 0.000 description 3
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 241000218202 Coptis Species 0.000 description 1
- 235000002991 Coptis groenlandica Nutrition 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 241001025261 Neoraja caerulea Species 0.000 description 1
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical class [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- CSSYLTMKCUORDA-UHFFFAOYSA-N barium(2+);oxygen(2-) Chemical class [O-2].[Ba+2] CSSYLTMKCUORDA-UHFFFAOYSA-N 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- ZOCHARZZJNPSEU-UHFFFAOYSA-N diboron Chemical compound B#B ZOCHARZZJNPSEU-UHFFFAOYSA-N 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002223 garnet Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/14—Silica-free oxide glass compositions containing boron
- C03C3/15—Silica-free oxide glass compositions containing boron containing rare earths
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/12—Compositions for glass with special properties for luminescent glass; for fluorescent glass
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Luminescent Compositions (AREA)
- Glass Compositions (AREA)
Abstract
Description
实施例 | 化学组成 |
1 | 1.7BaO-ZnO-2B3O6:0.3Eu3+ |
2 | 1.5BaO-MgO-2B3O6:0.5Eu3+ |
3 | 1.9BaO-CaO-2B3O6:0.1Eu3+ |
4 | BaO-ZnO-B3O6:1.0Eu3+ |
5 | 0.58BaO-2.4ZnO-1.5B3O6:0.02Eu3+ |
6 | 2.37BaO-0.6ZnO-2B3O6:0.03Eu3+ |
7 | 0.8BaO-2.0MgO-1.8B3O6:0.2Eu3+ |
8 | 1.7BaO-0.8MgO-2B3O6:0.5Eu3+ |
9 | 1.4BaO-1.5CaO-1.9B3O6:0.1Eu3+ |
10 | 2.05BaO-0.9CaO-2B3O6:0.05Eu3+ |
11 | 1.6BaO-0.5MgO-0.5ZnO-B3O6:0.4Eu3+ |
12 | 1.92BaO-0.3MgO-0.7ZnO-2B3O6:0.08Eu3+ |
13 | 2.24BaO-0.4MgO-0.3ZnO-2B3O6:0.06Eu3+ |
14 | 1.77BaO-0.6MgO-0.6ZnO-1.3B3O6:0.03Eu3+ |
15 | 1.93BaO-0.5ZnO-0.5CaO-2B3O6:0.07Eu3+ |
16 | 1.85BaO-0.4ZnO-0.6CaO-2B3O6:0.15Eu3+ |
17 | 1.61BaO-ZnO-0.3CaO-B3O6:0.09Eu3+ |
18 | 2.18BaO-0.5ZnO-0.2CaO-1.7B3O6:0.12Eu3+ |
19 | 1.3BaO-0.5MgO-0.5CaO-1.2B3O6:0.7Eu3+ |
20 | 1.7BaO-0.3MgO-0.6CaO-2B3O6:0.4Eu3+ |
21 | 1.2BaO-0.8MgO-0.5CaO-B3O6: 0.5Eu3+ |
22 | 1.65BaO-0.3CaO-0.3MgO-0.4-ZnO-2B3O6:0.35Eu3+ |
Claims (4)
Priority Applications (1)
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CN201611166487.6A CN106587601B (zh) | 2016-12-16 | 2016-12-16 | 一种硼酸盐红色发光玻璃及其制备方法 |
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CN201611166487.6A CN106587601B (zh) | 2016-12-16 | 2016-12-16 | 一种硼酸盐红色发光玻璃及其制备方法 |
Publications (2)
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CN106587601A true CN106587601A (zh) | 2017-04-26 |
CN106587601B CN106587601B (zh) | 2019-03-19 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107814484A (zh) * | 2017-11-16 | 2018-03-20 | 湖南师范大学 | 一种含铕离子自还原能力的发光透明玻璃及其制备方法 |
CN110590158A (zh) * | 2019-09-05 | 2019-12-20 | 广东工业大学 | 一种硼酸盐荧光玻璃及其制备方法和应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102181284A (zh) * | 2011-03-18 | 2011-09-14 | 广东工业大学 | 一种紫外或近紫外激发的硼酸盐荧光粉及其制备方法 |
CN102408195A (zh) * | 2010-09-26 | 2012-04-11 | 海洋王照明科技股份有限公司 | 一种硼酸盐发光玻璃及其制备方法 |
CN102976612A (zh) * | 2012-12-05 | 2013-03-20 | 大连海事大学 | 一种Eu3+掺杂红色激光诱导制冷玻璃体及其制备方法 |
JP2015137283A (ja) * | 2014-01-20 | 2015-07-30 | 株式会社ネモト・ルミマテリアル | 波長変換部材 |
CN104986956A (zh) * | 2015-06-24 | 2015-10-21 | 昆明理工大学 | 一种稀土离子单掺白色上转换发光的氧化物玻璃及其制备方法 |
-
2016
- 2016-12-16 CN CN201611166487.6A patent/CN106587601B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102408195A (zh) * | 2010-09-26 | 2012-04-11 | 海洋王照明科技股份有限公司 | 一种硼酸盐发光玻璃及其制备方法 |
CN102181284A (zh) * | 2011-03-18 | 2011-09-14 | 广东工业大学 | 一种紫外或近紫外激发的硼酸盐荧光粉及其制备方法 |
CN102976612A (zh) * | 2012-12-05 | 2013-03-20 | 大连海事大学 | 一种Eu3+掺杂红色激光诱导制冷玻璃体及其制备方法 |
JP2015137283A (ja) * | 2014-01-20 | 2015-07-30 | 株式会社ネモト・ルミマテリアル | 波長変換部材 |
CN104986956A (zh) * | 2015-06-24 | 2015-10-21 | 昆明理工大学 | 一种稀土离子单掺白色上转换发光的氧化物玻璃及其制备方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107814484A (zh) * | 2017-11-16 | 2018-03-20 | 湖南师范大学 | 一种含铕离子自还原能力的发光透明玻璃及其制备方法 |
CN107814484B (zh) * | 2017-11-16 | 2020-03-31 | 湖南师范大学 | 一种含铕离子自还原能力的发光透明玻璃及其制备方法 |
CN110590158A (zh) * | 2019-09-05 | 2019-12-20 | 广东工业大学 | 一种硼酸盐荧光玻璃及其制备方法和应用 |
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CN106587601B (zh) | 2019-03-19 |
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Address after: 510651 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee after: Institute of rare metals, Guangdong Academy of Sciences Address before: 510651 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee before: GUANGDONG INSTITUTE OF RARE METALS |
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Effective date of registration: 20230327 Address after: 510651 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee after: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Address before: 510651 No. 363, Changxin Road, Guangzhou, Guangdong, Tianhe District Patentee before: Institute of rare metals, Guangdong Academy of Sciences |
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Application publication date: 20170426 Assignee: Aromatic Encyclopedia Biotechnology (Chongqing) Co.,Ltd. Assignor: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Contract record no.: X2023980040853 Denomination of invention: A borate red luminescent glass and its preparation method Granted publication date: 20190319 License type: Common License Record date: 20230831 |
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Application publication date: 20170426 Assignee: FOSHAN ZHENGRONG TECHNOLOGY Co.,Ltd. Assignor: Institute of resource utilization and rare earth development, Guangdong Academy of Sciences Contract record no.: X2023980041273 Denomination of invention: A borate red luminescent glass and its preparation method Granted publication date: 20190319 License type: Common License Record date: 20230906 |