CN106554465A - 一种表面施胶剂生产工艺 - Google Patents
一种表面施胶剂生产工艺 Download PDFInfo
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- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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Abstract
本发明涉及化工产品生产领域,尤其是表面施胶剂生产领域。表面施胶剂在现代的造纸技术中,已成为纸页表面施胶处理的主要形式,它不仅能改善纸张的印刷适性、抗水能力和表面强度,还能减少造纸化学品的总成本。对氨基苯磺酸和对氨基苯磺酸钠主要用于制造染料、印染助剂和防治麦类锈病及用作香料、食用色素、医药、增白剂、农药等中间体,下游产品很多,在我国的化工合成占据重要地位。
Description
技术领域
本发明涉及化工产品生产领域,尤其是表面施胶剂生产领域。
背景技术
表面施胶剂在现代的造纸技术中,已成为纸页表面施胶处理的主要形式,它不仅能改善纸张的印刷适性、抗水能力和表面强度,还能减少造纸化学品的总成本。对氨基苯磺酸和对氨基苯磺酸钠主要用于制造染料、印染助剂和防治麦类锈病及用作香料、食用色素、医药、增白剂、农药等中间体,下游产品很多,在我国的化工合成占据重要地位。
发明内容
工艺流程
本项目以淀粉、苯乙烯、丙烯酸丁酯、甲基丙烯酸甲酯、甲酸、乳化剂A-102和TMPDE80为原料,以硫酸亚铁和双氧水为引发剂经过反应、过滤制备表面施胶剂,详细工艺流程依次如下:
(1)向单体反应釜中向反应釜中缓慢加入苯乙烯、丙烯酸丁酯、甲基丙烯酸甲酯、甲酸、乳化剂A-102(磺基琥珀酸癸基聚氧乙烯(6)醚酯二钠)和TMPDE 80(三羟甲醛丙烷二烯丙基醚)进行混合均匀后备用。本步骤仅起到混合的作用,无化学反应产生。
(2)向主反应釜中加入脱盐水和淀粉,打开反应釜夹套蒸汽管道阀门通入蒸汽,使体系升温至85℃,并充分搅拌约1h。本项目生产用水采用脱盐水。
(3)向主反应釜中加入硫酸亚铁和双氧水,继续使体系温度保持在85℃,二者进行反应形成主反应的引发剂。本步化学反应为:
(4)将单体反应釜生产得到的料液加入主反应釜中,用2h加完原料,继续使体系温度保持在85℃。在本步骤中,各项原料在常压条件下反应生成交替共聚物。反应方程式如下:
(5)关闭反应釜夹套蒸汽阀门,打开反应釜夹套冷却循环水阀门,使反应釜内物料温度降至60℃后加入卡松(防腐剂)并充分搅拌,本步骤用时约3.5h。
(6)加入防腐剂后的料液通过200m目的滤网过滤后。
Claims (2)
1.本发明涉及的原料成分及配比。
2.本发明涉及的工艺流程:向单体反应釜中向反应釜中缓慢加入苯乙烯、丙烯酸丁酯、甲基丙烯酸甲酯、甲酸、乳化剂A-102(磺基琥珀酸癸基聚氧乙烯(6)醚酯二钠)和TMPDE 80(三羟甲醛丙烷二烯丙基醚)进行混合均匀后备用;本步骤仅起到混合的作用,无化学反应产生;向主反应釜中加入脱盐水和淀粉,打开反应釜夹套蒸汽管道阀门通入蒸汽,使体系升温至85℃,并充分搅拌约1h;本项目生产用水采用脱盐水;向主反应釜中加入硫酸亚铁和双氧水,继续使体系温度保持在85℃,二者进行反应形成主反应的引发剂;)将单体反应釜生产得到的料液加入主反应釜中,用2h加完原料,继续使体系温度保持在85℃;在本步骤中,各项原料在常压条件下反应生成交替共聚物;将单体反应釜生产得到的料液加入主反应釜中,用2h加完原料,继续使体系温度保持在85℃;在本步骤中,各项原料在常压条件下反应生成交替共聚物。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109112887A (zh) * | 2018-08-22 | 2019-01-01 | 襄阳市岩翔化工有限公司 | 一种造纸用壳聚糖/苯丙乳液表面施胶剂 |
Citations (6)
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WO2000023479A1 (en) * | 1998-10-16 | 2000-04-27 | Bayer Corporation | Improved paper sizing agents and methods of making the agents and sizing paper |
US6426381B1 (en) * | 1998-02-18 | 2002-07-30 | Bayer Aktiengesellschaft | Fine-particle polymer dispersions for paper sizing |
CN1446233A (zh) * | 2000-08-11 | 2003-10-01 | 巴斯福股份公司 | 含淀粉的聚合物分散体 |
CN101225623A (zh) * | 2008-01-09 | 2008-07-23 | 杨春先 | 造纸用表面施胶剂 |
CN102656192A (zh) * | 2009-10-02 | 2012-09-05 | 巴斯夫欧洲公司 | 含淀粉的细碎聚合物分散体、其生产方法及其在造纸中作为施胶剂的用途 |
CN104988796A (zh) * | 2015-05-29 | 2015-10-21 | 常州博润新材料科技有限公司 | 一种增强型的造纸用多功能表面施胶助剂及其制备方法 |
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- 2016-06-29 CN CN201610484682.7A patent/CN106554465A/zh active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6426381B1 (en) * | 1998-02-18 | 2002-07-30 | Bayer Aktiengesellschaft | Fine-particle polymer dispersions for paper sizing |
WO2000023479A1 (en) * | 1998-10-16 | 2000-04-27 | Bayer Corporation | Improved paper sizing agents and methods of making the agents and sizing paper |
CN1446233A (zh) * | 2000-08-11 | 2003-10-01 | 巴斯福股份公司 | 含淀粉的聚合物分散体 |
CN101225623A (zh) * | 2008-01-09 | 2008-07-23 | 杨春先 | 造纸用表面施胶剂 |
CN102656192A (zh) * | 2009-10-02 | 2012-09-05 | 巴斯夫欧洲公司 | 含淀粉的细碎聚合物分散体、其生产方法及其在造纸中作为施胶剂的用途 |
CN104988796A (zh) * | 2015-05-29 | 2015-10-21 | 常州博润新材料科技有限公司 | 一种增强型的造纸用多功能表面施胶助剂及其制备方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109112887A (zh) * | 2018-08-22 | 2019-01-01 | 襄阳市岩翔化工有限公司 | 一种造纸用壳聚糖/苯丙乳液表面施胶剂 |
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