CN106543817A - 一种海上集装箱外部防护用氟涂料 - Google Patents

一种海上集装箱外部防护用氟涂料 Download PDF

Info

Publication number
CN106543817A
CN106543817A CN201610929127.0A CN201610929127A CN106543817A CN 106543817 A CN106543817 A CN 106543817A CN 201610929127 A CN201610929127 A CN 201610929127A CN 106543817 A CN106543817 A CN 106543817A
Authority
CN
China
Prior art keywords
parts
powder
added
fluoro coatings
exterior protection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610929127.0A
Other languages
English (en)
Inventor
张旭
孔德喜
王同章
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI BOTAI FLUORINE MATERIAL TECHNOLOGY Co Ltd
Original Assignee
ANHUI BOTAI FLUORINE MATERIAL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI BOTAI FLUORINE MATERIAL TECHNOLOGY Co Ltd filed Critical ANHUI BOTAI FLUORINE MATERIAL TECHNOLOGY Co Ltd
Priority to CN201610929127.0A priority Critical patent/CN106543817A/zh
Publication of CN106543817A publication Critical patent/CN106543817A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/18—Homopolymers or copolymers of tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

Abstract

本发明公开了一种海上集装箱外部防护用氟涂料，涉及氟涂料技术领域，由如下重量份数的原料制成：超细聚四氟乙烯粉末25‑30份、三聚氰胺甲醛树脂10‑15份、丙烯腈‑丁二烯‑苯乙烯共聚物8‑12份、粉煤灰6‑10份、海泡石粉4‑8份、茶枯粉3‑6份、甘蔗蜡3‑6份、增韧剂3‑6份、聚醚改性硅油2‑4份、竹粉2‑4份、油酸乙酯2‑4份、硫化猪油1‑2份、膨胀石墨粉1‑2份、醋酸丁酯30‑35份、环己酮25‑30份。本发明氟涂料的成膜性和附着性好，能牢固附着于集装箱表面快速干燥形成涂层，该涂层具有优异的防腐性、防水性、耐高温性、耐磨性、抗氧化性和耐候性，适用于严苛的海洋运输环节，从而有效延长集装箱的使用寿命。

Description

一种海上集装箱外部防护用氟涂料
技术领域：
本发明涉及氟涂料技术领域，具体涉及一种海上集装箱外部防护用氟涂料。
背景技术：
集装箱运输有很多优点，如便于港口作业机械化，从而提高装卸效率，大大缩短船舶在港时间，加快船舶周转率，节省包装费用，减少货损，并有利于不同交通线路和运载工具的衔接。目前，常用集装箱由钢材制成，优点是强度大、结构牢、焊接性高、水密性好、价格低廉，缺点是重量大和防腐性差。而海上集装箱在运输过程中处于海洋环境中，腐蚀现象严重，因此需要对集装箱外部进行防护处理，通常方法是在集装箱外部喷涂防腐涂料。该防腐涂料除了需要具备优异的防腐性外，还需具有防水性、耐高温性、耐磨性、抗氧化性和耐候性，从而延长集装箱的使用寿命。
发明内容：
本发明所要解决的技术问题在于提供一种具有优异防腐性、防水性、耐高温性、耐磨性、抗氧化性和耐候性的海上集装箱外部防护用氟涂料，从而有效延长集装箱的使用寿命。
本发明所要解决的技术问题采用以下的技术方案来实现：
一种海上集装箱外部防护用氟涂料，由如下重量份数的原料制成：
超细聚四氟乙烯粉末25-30份、三聚氰胺甲醛树脂10-15份、丙烯腈-丁二烯-苯乙烯共聚物8-12份、粉煤灰6-10份、海泡石粉4-8份、茶枯粉3-6份、甘蔗蜡3-6份、增韧剂3-6份、聚醚改性硅油2-4份、竹粉2-4份、油酸乙酯2-4份、硫化猪油1-2份、膨胀石墨粉1-2份、醋酸丁酯30-35份、环己酮25-30份。
其制备方法包括如下步骤：
(1)向醋酸丁酯中加入三聚氰胺甲醛树脂和丙烯腈-丁二烯-苯乙烯共聚物，充分混合后静置30min，再加热至回流状态保温搅拌15min，然后趁热加入甘蔗蜡和硫化猪油，混合均匀，即得物料I；
(2)向环己酮中加入超细聚四氟乙烯粉末和聚醚改性硅油，并加热至回流状态保温搅拌15min，再加入增韧剂、油酸乙酯和膨胀石墨粉，继续回流保温搅拌5min，即得物料II；
(3)向物料I中加入物料II、粉煤灰和海泡石粉，然后加热至回流状态保温搅拌5min，待温度降至60-70℃后加入茶枯粉和竹粉，充分混合均匀。
所述增韧剂由如下重量份数的原料制成：季戊四醇油酸酯10-15份、聚氯乙烯糊树脂6-11份、聚乙烯醇缩丁醛5-9份、松香粉4-7份、双丙酮丙烯酰胺4-7份、聚乳酸3-5份、石棉粉3-5份、预糊化淀粉2-3份、氯化石蜡2-3份、钛酸乙酯1-2份、茶籽粉0.5-1份、纳米氧化铝0.5-1份，其制备方法为：向季戊四醇油酸酯中加入聚氯乙烯糊树脂和松香粉，先加热至80-90℃保温研磨5min，再加入聚乙烯醇缩丁醛和双丙酮丙烯酰胺，继续加热至120-130℃保温研磨10min，然后将所得混合物在冰水浴下以10℃/min的速度冷却降温，待温度降至0-5℃后保温静置3h，随后于微波频率2450MHz、功率700W下微波处理5min，最后趁热加入聚乳酸、石棉粉、预糊化淀粉、氯化石蜡、钛酸乙酯、茶籽粉和纳米氧化铝，研磨使其充分混合均匀。
该增韧剂能有效降低氟涂料所形成涂层的脆性，增大韧性，提高承载强度和耐疲劳性，从而避免涂层开裂。
所述石棉粉使用前经过改性处理，其处理方法为：先将20-25份石棉粉加入2倍重量份水中，充分分散后静置30min，再加入3-5份磷酸氢二钠和2-3份硅烷偶联剂，混合均匀后利用等离子表面处理机处理15s，处理结束后迅速转入5-10℃环境中静置5h，然后加入2-3份田菁胶、1-2份聚合氯化铝、0.5-1份安息香，充分混合后于微波频率2450MHz、功率700W下微波处理3min，所得混合物送入喷雾干燥机，最后将干燥所得颗粒研磨成粉末即可。
所述等离子表面处理机的工作高频频率18-60Hz、输出功率350-1000W、工作气压范围0.05-0.5MPa、气源要求0.3-1.0MPa。
石棉粉通过改性处理，提高其流变性、相容性和增韧性，从而增强其填充性能。
本发明的有益效果是：本发明以超细聚四氟乙烯粉末为主要原料，辅以三聚氰胺甲醛树脂、丙烯腈-丁二烯-苯乙烯共聚物及多种助剂制得海上集装箱外部防护用氟涂料，该氟涂料的成膜性和附着性好，能牢固附着于集装箱表面快速干燥形成涂层，该涂层具有优异的防腐性、防水性、耐高温性、耐磨性、抗氧化性和耐候性，适用于严苛的海洋运输环节，从而有效延长集装箱的使用寿命。
具体实施方式：
为了使本发明实现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施例，进一步阐述本发明。
实施例1
(1)向30份醋酸丁酯中加入12份三聚氰胺甲醛树脂和8份丙烯腈-丁二烯-苯乙烯共聚物，充分混合后静置30min，再加热至回流状态保温搅拌15min，然后趁热加入3份甘蔗蜡和1份硫化猪油，混合均匀，即得物料I；
(2)向30份环己酮中加入25份超细聚四氟乙烯粉末和3份聚醚改性硅油，并加热至回流状态保温搅拌15min，再加入3份增韧剂、2份油酸乙酯和1份膨胀石墨粉，继续回流保温搅拌5min，即得物料II；
(3)向物料I中加入物料II、8份粉煤灰和8份海泡石粉，然后加热至回流状态保温搅拌5min，待温度降至60-70℃后加入3份茶枯粉和2份竹粉，充分混合均匀。
增韧剂的制备：向10份季戊四醇油酸酯中加入6份聚氯乙烯糊树脂和4份松香粉，先加热至80-90℃保温研磨5min，再加入6份聚乙烯醇缩丁醛和4份双丙酮丙烯酰胺，继续加热至120-130℃保温研磨10min，然后将所得混合物在冰水浴下以10℃/min的速度冷却降温，待温度降至0-5℃后保温静置3h，随后于微波频率2450MHz、功率700W下微波处理5min，最后趁热加入3份聚乳酸、5份石棉粉、2份预糊化淀粉、2份氯化石蜡、1份钛酸乙酯、0.5份茶籽粉和0.5份纳米氧化铝，研磨使其充分混合均匀。
石棉粉的改性处理：先将25份石棉粉加入2倍重量份水中，充分分散后静置30min，再加入3份磷酸氢二钠和2份硅烷偶联剂，混合均匀后利用等离子表面处理机处理15s，处理结束后迅速转入5-10℃环境中静置5h，然后加入3份田菁胶、1份聚合氯化铝、0.5份安息香，充分混合后于微波频率2450MHz、功率700W下微波处理3min，所得混合物送入喷雾干燥机，最后将干燥所得颗粒研磨成粉末即可。
等离子表面处理机的工作高频频率18-60Hz、输出功率350-1000W、工作气压范围0.05-0.5MPa、气源要求0.3-1.0MPa。
实施例2
(1)向35份醋酸丁酯中加入10份三聚氰胺甲醛树脂和10份丙烯腈-丁二烯-苯乙烯共聚物，充分混合后静置30min，再加热至回流状态保温搅拌15min，然后趁热加入5份甘蔗蜡和1份硫化猪油，混合均匀，即得物料I；
(2)向25份环己酮中加入25份超细聚四氟乙烯粉末和3份聚醚改性硅油，并加热至回流状态保温搅拌15min，再加入5份增韧剂、2份油酸乙酯和1份膨胀石墨粉，继续回流保温搅拌5min，即得物料II；
(3)向物料I中加入物料II、10份粉煤灰和6份海泡石粉，然后加热至回流状态保温搅拌5min，待温度降至60-70℃后加入5份茶枯粉和2份竹粉，充分混合均匀。
增韧剂的制备：向15份季戊四醇油酸酯中加入8份聚氯乙烯糊树脂和4份松香粉，先加热至80-90℃保温研磨5min，再加入5份聚乙烯醇缩丁醛和4份双丙酮丙烯酰胺，继续加热至120-130℃保温研磨10min，然后将所得混合物在冰水浴下以10℃/min的速度冷却降温，待温度降至0-5℃后保温静置3h，随后于微波频率2450MHz、功率700W下微波处理5min，最后趁热加入5份聚乳酸、3份石棉粉、2份预糊化淀粉、2份氯化石蜡、1份钛酸乙酯、1份茶籽粉和0.5份纳米氧化铝，研磨使其充分混合均匀。
石棉粉的改性处理：先将20份石棉粉加入2倍重量份水中，充分分散后静置30min，再加入3份磷酸氢二钠和2份硅烷偶联剂，混合均匀后利用等离子表面处理机处理15s，处理结束后迅速转入5-10℃环境中静置5h，然后加入2份田菁胶、2份聚合氯化铝、0.5份安息香，充分混合后于微波频率2450MHz、功率700W下微波处理3min，所得混合物送入喷雾干燥机，最后将干燥所得颗粒研磨成粉末即可。
等离子表面处理机的工作高频频率18-60Hz、输出功率350-1000W、工作气压范围0.05-0.5MPa、气源要求0.3-1.0MPa。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。本发明要求保护范围由所附的权利要求书及其等效物界定。

Claims (5)

1.一种海上集装箱外部防护用氟涂料，其特征在于，由如下重量份数的原料制成：
超细聚四氟乙烯粉末25-30份、三聚氰胺甲醛树脂10-15份、丙烯腈-丁二烯-苯乙烯共聚物8-12份、粉煤灰6-10份、海泡石粉4-8份、茶枯粉3-6份、甘蔗蜡3-6份、增韧剂3-6份、聚醚改性硅油2-4份、竹粉2-4份、油酸乙酯2-4份、硫化猪油1-2份、膨胀石墨粉1-2份、醋酸丁酯30-35份、环己酮25-30份。
2.根据权利要求1所述的海上集装箱外部防护用氟涂料，其特征在于，其制备方法包括如下步骤：
(1)向醋酸丁酯中加入三聚氰胺甲醛树脂和丙烯腈-丁二烯-苯乙烯共聚物，充分混合后静置30min，再加热至回流状态保温搅拌15min，然后趁热加入甘蔗蜡和硫化猪油，混合均匀，即得物料I；
(2)向环己酮中加入超细聚四氟乙烯粉末和聚醚改性硅油，并加热至回流状态保温搅拌15min，再加入增韧剂、油酸乙酯和膨胀石墨粉，继续回流保温搅拌5min，即得物料II；
(3)向物料I中加入物料II、粉煤灰和海泡石粉，然后加热至回流状态保温搅拌5min，待温度降至60-70℃后加入茶枯粉和竹粉，充分混合均匀。
3.根据权利要求1或2所述的海上集装箱外部防护用氟涂料，其特征在于，所述增韧剂由如下重量份数的原料制成：季戊四醇油酸酯10-15份、聚氯乙烯糊树脂6-11份、聚乙烯醇缩丁醛5-9份、松香粉4-7份、双丙酮丙烯酰胺4-7份、聚乳酸3-5份、石棉粉3-5份、预糊化淀粉2-3份、氯化石蜡2-3份、钛酸乙酯1-2份、茶籽粉0.5-1份、纳米氧化铝0.5-1份，其制备方法为：向季戊四醇油酸酯中加入聚氯乙烯糊树脂和松香粉，先加热至80-90℃保温研磨5min，再加入聚乙烯醇缩丁醛和双丙酮丙烯酰胺，继续加热至120-130℃保温研磨10min，然后将所得混合物在冰水浴下以10℃/min的速度冷却降温，待温度降至0-5℃后保温静置3h，随后于微波频率2450MHz、功率700W下微波处理5min，最后趁热加入聚乳酸、石棉粉、预糊化淀粉、氯化石蜡、钛酸乙酯、茶籽粉和纳米氧化铝，研磨使其充分混合均匀。
4.根据权利要求3所述的海上集装箱外部防护用氟涂料，其特征在于：所述石棉粉使用前经过改性处理，其处理方法为：先将20-25份石棉粉加入2倍重量份水中，充分分散后静置30min，再加入3-5份磷酸氢二钠和2-3份硅烷偶联剂，混合均匀后利用等离子表面处理机处理15s，处理结束后迅速转入5-10℃环境中静置5h，然后加入2-3份田菁胶、1-2份聚合氯化铝、0.5-1份安息香，充分混合后于微波频率2450MHz、功率700W下微波处理3min，所得混合物送入喷雾干燥机，最后将干燥所得颗粒研磨成粉末即可。
5.根据权利要求4所述的海上集装箱外部防护用氟涂料，其特征在于：所述等离子表面处理机的工作高频频率18-60Hz、输出功率350-1000W、工作气压范围0.05-0.5MPa、气源要求0.3-1.0MPa。
CN201610929127.0A 2016-10-31 2016-10-31 一种海上集装箱外部防护用氟涂料 Pending CN106543817A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610929127.0A CN106543817A (zh) 2016-10-31 2016-10-31 一种海上集装箱外部防护用氟涂料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610929127.0A CN106543817A (zh) 2016-10-31 2016-10-31 一种海上集装箱外部防护用氟涂料

Publications (1)

Publication Number Publication Date
CN106543817A true CN106543817A (zh) 2017-03-29

Family

ID=58392549

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610929127.0A Pending CN106543817A (zh) 2016-10-31 2016-10-31 一种海上集装箱外部防护用氟涂料

Country Status (1)

Country Link
CN (1) CN106543817A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109054530A (zh) * 2018-06-28 2018-12-21 安徽博泰氟材料科技有限公司 一种高硬度水性氟碳漆
CN111320355A (zh) * 2019-11-21 2020-06-23 佛山科学技术学院 一种用于污泥脱水的高效絮凝剂的制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1197268A2 (en) * 1999-02-19 2002-04-17 E.I. Du Pont De Nemours And Company Abrasion resistant coatings
CN103589251A (zh) * 2013-11-08 2014-02-19 西北永新涂料有限公司 钢质储罐防腐用氟碳涂料及其制备方法
CN104212323A (zh) * 2014-09-18 2014-12-17 江苏海晟涂料有限公司 一种常温自固化防腐涂料及其制备方法
CN104356789A (zh) * 2014-11-13 2015-02-18 无锡伊佩克科技有限公司 镀锌钢板用水溶性耐指纹表面处理剂及其制备方法
CN104817920A (zh) * 2015-04-16 2015-08-05 青岛保利康新材料有限公司 一种管道防腐涂料
CN105400321A (zh) * 2015-12-28 2016-03-16 常熟市五爱电器设备有限公司 金属铠装抽出式开关设备

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1197268A2 (en) * 1999-02-19 2002-04-17 E.I. Du Pont De Nemours And Company Abrasion resistant coatings
CN103589251A (zh) * 2013-11-08 2014-02-19 西北永新涂料有限公司 钢质储罐防腐用氟碳涂料及其制备方法
CN104212323A (zh) * 2014-09-18 2014-12-17 江苏海晟涂料有限公司 一种常温自固化防腐涂料及其制备方法
CN104356789A (zh) * 2014-11-13 2015-02-18 无锡伊佩克科技有限公司 镀锌钢板用水溶性耐指纹表面处理剂及其制备方法
CN104817920A (zh) * 2015-04-16 2015-08-05 青岛保利康新材料有限公司 一种管道防腐涂料
CN105400321A (zh) * 2015-12-28 2016-03-16 常熟市五爱电器设备有限公司 金属铠装抽出式开关设备

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109054530A (zh) * 2018-06-28 2018-12-21 安徽博泰氟材料科技有限公司 一种高硬度水性氟碳漆
CN111320355A (zh) * 2019-11-21 2020-06-23 佛山科学技术学院 一种用于污泥脱水的高效絮凝剂的制备方法

Similar Documents

Publication Publication Date Title
CN104788121B (zh) 一种莫来石质轻质耐火材料及其制备方法
CN106543817A (zh) 一种海上集装箱外部防护用氟涂料
CN104312335B (zh) 一种高附着力抗冲击保温涂料
CN104927646A (zh) 一种叉车发动机排气管用高致密性复合水性有机硅树脂涂料及其制备方法
CN106192481A (zh) 一种皮革制品着色用染料粘合剂
CN103483998A (zh) 钢丝防锈剂及其制备方法
CN104534191A (zh) 一种聚氯乙烯钢塑复合管道及其制备方法
CN103183514A (zh) 铁水脱硫用热态修补料
CN106566330A (zh) 一种混凝土搅拌罐内部维护用氟涂料
CN108084707A (zh) 一种石油内衬管用尼龙料及其制备方法
CN102839370B (zh) 一种陶瓷复合钢管的制备方法
RU2714190C1 (ru) Устойчивое к высоким температурам покрытие на водной основе, препятствующее связыванию титан-сталь, и его применение
CN103357865B (zh) 一种增强掺钛粉末冶金材料及其制备方法
CN107033687A (zh) 一种石油产品储罐内部用粉末型氟涂料
CN104651579A (zh) 一种防锈防腐蚀淬火剂及其制备方法
CN104593554A (zh) 一种绿色环保淬火剂及其制备方法
CN103666188A (zh) 用于金属管道的防锈性涂料
CN106634439A (zh) 一种高粘结强度配电柜外壳用双组份环氧涂料
CN104926329A (zh) 一种铝碳化硅碳砖及其制备方法
CN106634145A (zh) 一种高架支撑模板外部喷涂涂料用有机硅耐候剂
CN105778672A (zh) 一种超快干抗粘连铸管防腐涂料
CN109594076A (zh) 一种烧焊药水
CN102329547B (zh) 一种涂料组合物的制备方法
CN203048853U (zh) 高温防腐涂料的生产工艺装置
CN104927651A (zh) 一种叉车发动机排气管用导热型复合水性氟硅树脂涂料及其制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170329

RJ01 Rejection of invention patent application after publication