CN106511142A - Centella asiatica floral water and preparation method and application thereof - Google Patents
Centella asiatica floral water and preparation method and application thereof Download PDFInfo
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- CN106511142A CN106511142A CN201710037023.3A CN201710037023A CN106511142A CN 106511142 A CN106511142 A CN 106511142A CN 201710037023 A CN201710037023 A CN 201710037023A CN 106511142 A CN106511142 A CN 106511142A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 244000146462 Centella asiatica Species 0.000 title abstract 6
- 235000004032 Centella asiatica Nutrition 0.000 title abstract 6
- 239000012528 membrane Substances 0.000 claims abstract description 6
- 238000004821 distillation Methods 0.000 claims abstract description 5
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 239000000110 cooling liquid Substances 0.000 claims abstract description 4
- 238000001914 filtration Methods 0.000 claims description 5
- 238000002242 deionisation method Methods 0.000 claims description 4
- 230000001815 facial effect Effects 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 238000003306 harvesting Methods 0.000 claims description 4
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 239000006071 cream Substances 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims description 2
- 230000037307 sensitive skin Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 3
- 208000002874 Acne Vulgaris Diseases 0.000 abstract description 2
- 206010061218 Inflammation Diseases 0.000 abstract description 2
- 206010000496 acne Diseases 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 239000008367 deionised water Substances 0.000 abstract description 2
- 229910021641 deionized water Inorganic materials 0.000 abstract description 2
- 238000000605 extraction Methods 0.000 abstract description 2
- 239000003205 fragrance Substances 0.000 abstract description 2
- 230000008439 repair process Effects 0.000 abstract description 2
- 230000036560 skin regeneration Effects 0.000 abstract description 2
- 230000007794 irritation Effects 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 239000003053 toxin Substances 0.000 abstract 1
- 231100000765 toxin Toxicity 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 241000700647 Variola virus Species 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- WYQVAPGDARQUBT-FGWHUCSPSA-N Madecassol Chemical compound O([C@@H]1[C@@H](CO)O[C@H]([C@@H]([C@H]1O)O)OC[C@H]1O[C@H]([C@@H]([C@@H](O)[C@@H]1O)O)OC(=O)[C@]12CC[C@H]([C@@H]([C@H]1C=1[C@@]([C@@]3(CC[C@H]4[C@](C)(CO)[C@@H](O)[C@H](O)C[C@]4(C)[C@H]3CC=1)C)(C)CC2)C)C)[C@@H]1O[C@@H](C)[C@H](O)[C@@H](O)[C@H]1O WYQVAPGDARQUBT-FGWHUCSPSA-N 0.000 description 2
- WYQVAPGDARQUBT-XCWYDTOWSA-N asiaticoside Natural products O=C(O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@H]2[C@H](O)[C@H](O)[C@H](O[C@H]3[C@H](O)[C@H](O)[C@@H](O)[C@H](C)O3)[C@@H](CO)O2)O1)[C@@]12[C@@H]([C@@H](C)[C@H](C)CC1)C=1[C@](C)([C@@]3(C)[C@@H]([C@@]4(C)[C@H]([C@@](CO)(C)[C@@H](O)[C@H](O)C4)CC3)CC=1)CC2 WYQVAPGDARQUBT-XCWYDTOWSA-N 0.000 description 2
- 229940022757 asiaticoside Drugs 0.000 description 2
- QCYLIQBVLZBPNK-UHFFFAOYSA-N asiaticoside A Natural products O1C(C(=O)C(C)C)=CC(C)C(C2(C(OC(C)=O)CC34C5)C)C1CC2(C)C3CCC(C1(C)C)C45CCC1OC1OCC(O)C(O)C1O QCYLIQBVLZBPNK-UHFFFAOYSA-N 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012982 microporous membrane Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- 235000007866 Chamaemelum nobile Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000001263 FEMA 3042 Substances 0.000 description 1
- 244000178870 Lavandula angustifolia Species 0.000 description 1
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 1
- 244000042664 Matricaria chamomilla Species 0.000 description 1
- 235000007232 Matricaria chamomilla Nutrition 0.000 description 1
- 241000282376 Panthera tigris Species 0.000 description 1
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 description 1
- 240000005382 Saccharum spontaneum Species 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000006468 Thea sinensis Nutrition 0.000 description 1
- 230000000172 allergic effect Effects 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002934 diuretic Substances 0.000 description 1
- 230000001882 diuretic effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930003935 flavonoid Natural products 0.000 description 1
- 150000002215 flavonoids Chemical class 0.000 description 1
- 235000017173 flavonoids Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 210000000952 spleen Anatomy 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/004—Aftersun preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/005—Preparations for sensitive skin
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses centella asiatica floral water and a preparation method and application thereof. Fresh centella asiatica is picked, washed, subjected to impurity removal, cut and placed in a distiller, hot deionized water is added for soaking, then the temperature is increased and distillation is conducted, circulating cooling liquid is introduced, condenser distillate is collected, distillation stops when the volume of the collected distillate is 0.8-1.2 times of the mass of fed centella asiatica, the distillate is filtered and sterilized through a microporous filter membrane with the aperture of 0.22 micrometer, and the centella asiatica floral water is obtained. The obtained floral waster is clear and transparent, has the special fragrance of centella asiatica floral water, is stable in quality, and can be stored for one year in a sealed mode at low temperature. Inedible chemical components are not added in the extraction process, and it is guaranteed that the floral water is natural and free of toxin, has a repair function on scarred and wounded skin, has anti-inflammation and antibacterial functions on acne skin, can accelerate skin regeneration, relieves sensitive skin, reduces irritation and meanwhile provides sufficient moisture for skin.
Description
Technical field
The invention belongs to technical field of skin care, is related to a kind of hydrosol and its production and use.
Background technology
Hydrosol, also known as crystal's oil, common are MEIGUI CHUNLU, Camellia sinensis hydrosol, lavandula angustifolia hydrosol, chamomile hydrosol, orange blossom
Hydrosol etc., because which contains the water-soluble substanceses (such as tannic acid and flavonoid) and micro quintessence oil of plant origin, is easily inhaled by skin
Receive, alcohol-free composition does not gently stimulate, and is in recent years emerging daily cosmetics and skincare product.
《Dictionary of medicinal plant》Record：" Herba sambuci chinensis (Herba Centellae), the property of medicine are bitter, cold, enter spleen channel, its effect for promoting blood circulation, detumescence,
Pain relieving, and have the purposes such as heat-clearing and toxic substances removing, diuretic." Herba Centellae is commonly called as tiger grass, injured tiger can roll about on this meadow, rub
Wiping touches leaf juice and can releive and healing of wound, for wound, sun-damaged skin have repair, for small pox skin has antiinflammatory
The effect of antibacterial, can accelerate skin regeneration, for sensitive skin, with more stimulation of releiving, reduce, improve the obscure work(of the colour of skin
Effect.
Skin-protection product majority containing Herba Centellae is adjusted by adding Herba Centellae extract or asiaticoside on the market at present
System is formed, and 104107160 A of CN disclose a kind of wrinkle removal nutritional solution containing Herba Centellae hydrosol, but have no the system of Herba Centellae hydrosol
Preparation Method, and commercially available Herba Centellae hydrosol is mostly the detached by-product of asiaticoside extraction, without the distinctive delicate fragrance of plant itself
Gas, substance content are low, and Consumer's Experience sense is bad.
Compared with prior art, the Herba Centellae hydrosol that the present invention is provided has the distinctive faint scent of plant itself, and clarification is saturating
Bright, easy to operate, steady quality, Nantural non-toxic, to no skin irritation, while also having moisturizing, anti-inflammation, promote skin
The effects such as regeneration.
The content of the invention
The technical problem to be solved, is to provide a kind of preparation method of Herba Centellae hydrosol.
The technical scheme that the present invention solves above-mentioned technical problem is as follows：
A kind of preparation method of Herba Centellae hydrosol, comprises the steps：
(1) Herba Centellae of fresh harvesting is cleaned, removes impurity；
(2) the fresh Herba Centellae cleaned is cut into into segment；
(3) put in distillator, add the deionization hot-water soak of 2～4 times of Herba Centellae quality 30 minutes；
(4) distillator heat temperature raising is distilled, opens the condensation switch of distillator, connect circulating cooling liquid, steam
Condensed by condenser, collect condenser distillate；
(5) stop distillation when 0.8～1.2 times that the distillate quality collected is Herba Centellae quality；
(6) distillate Jing filtering with microporous membranes are degerming, and fill is obtained final product.
Preferably, in step (2), the length of cutting is 0.5～2cm, most preferably 1cm.
Preferably, the hot water temperature for adding in step (3) is 50～60 DEG C.
Further, step (4) can pass through the temperature for adjusting coolant, make the temperature of distillate be less than 40 DEG C.
Preferably, the distillate quality that step (5) is collected is optimal when being 0.8～1.0 times of Herba Centellae quality.
Preferably, the aperture of step (6) microporous filter membrane is 0.22 micron.
Second aspect present invention provides a kind of purposes of Herba Centellae hydrosol obtained in preparation method by mentioned earlier, can use
In astringent, or it is used to allocate emulsion, facial cream or facial film as substrate.
Compared with prior art, the technical scheme that the present invention is provided has the advantage that：
1st, the inventive method uses the way of distillation, is distilled using deionized water, and Jing filtering with microporous membranes are degerming, the hydrosol for obtaining
Appearance transparent is clarified, steady quality, and sealing low temperature can preserve 1 year.
2nd, the temperature that distillate is controlled in still-process of the present invention is less than 40 DEG C, enables hydrosol to retain former plant itself peculiar
Faint scent, give product more preferably using effect.
3rd, Herba Centellae hydrosol sanitary index obtained in the present invention is complied fully with《Cosmetics health specification》(2007 editions) will
Ask, it is as shown in table 1 below.
1 Herba Centellae hydrosol Testing index of table
4th, obtained Herba Centellae does not add any non-edible chemical composition, and zest is little, has no toxic side effect, and is pure day
Right skin protection skin care productss.
Specific embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
The preparation method of the Herba Centellae hydrosol of the present embodiment, comprises the following steps：
(1) the Herba Centellae 10kg of fresh harvesting is taken, silt is washed away, is removed impurity；
(2) the fresh Herba Centellae cleaned is cut into the segment of 1cm；
(3) put in distillator, add 55 DEG C of deionization hot water 25kg to soak 30 minutes；
(4) distillator heat temperature raising is distilled, is opened the condenser of distillating still, connected -10 DEG C of recirculated cooling water,
Collect condenser distillate, 33 DEG C of exposure temperature；
(5) stop distilling when the distillate quality collected is 8kg；
(6) filtering with microporous membrane of 0.22 micron of distillate Jing is degerming, detects qualified, fill, obtains final product.
After testing, its sanitary index meets all standard above shown in table 1 to Herba Centellae hydrosol obtained in embodiment 1.
Obtained hydrosol has the distinctive fragrant of Herba Centellae itself, and clear, steady quality, placement have no muddy for 2 years.
Embodiment 2
The preparation method of the Herba Centellae hydrosol of the present embodiment, comprises the following steps：
(1) the Herba Centellae 20kg of fresh harvesting is taken, silt is washed away, is removed impurity；
(2) the fresh Herba Centellae cleaned is cut into the segment of 1.5cm；
(3) put in distillator, add 60 DEG C of deionization hot water 60kg to soak 30 minutes；
(4) distillator heat temperature raising is distilled, is opened the condenser of distillating still, connected -15 DEG C of recirculated cooling water,
Collect condenser distillate, 30 DEG C of exposure temperature；
(5) stop distilling when the distillate quality collected is 20kg；
(6) filtering with microporous membrane of 0.22 micron of distillate Jing is degerming, detects qualified, fill, obtains final product.
After testing, its sanitary index meets all standard above shown in table 1 to Herba Centellae hydrosol obtained in embodiment 2.
Obtained hydrosol has the distinctive fragrant of Herba Centellae itself, and clear, steady quality, placement have no muddy for 2 years.
Embodiment 3
Experience on probation is carried out to the Herba Centellae hydrosol for preparing of the invention, number of trying out is 50 people (skin sore, small pox skin, solarization
Hinder skin, sensitive skin).Using method：Full face is gently wiped with cotton pads after face cleaning, is used 2 times daily, using 4 weeks.Mainly
Investigate humidity of skin, acne removing, after-sun and the remission effect to sensitive skin.After continuously trying out 30 days, reflection is used
After there is obtained Herba Centellae hydrosol of the invention preferable replenishing water and preserving moisture, skin sore small pox to reduce, reparation is shone rapidly, skin, reduction are quick
The zest of sense skin.After on probation, hydrosol prepared by the present invention does not find allergic phenomena.Data statisticss are shown in Table 2.
The experience result on probation of table 2
Claims (7)
1. a kind of preparation method of Herba Centellae hydrosol, it is characterised in that comprise the following steps：
(1) Herba Centellae of fresh harvesting is cleaned, removes impurity；
(2) the fresh Herba Centellae cleaned is cut into into segment；
(3) put in distillator, add the deionization hot-water soak of 2～4 times of Herba Centellae quality 30 minutes；
(4) distillator heat temperature raising is distilled, opens the condensation switch of distillator, connect circulating cooling liquid, steam is passed through
Condenser is condensed, and collects condenser distillate；
(5) stop distillation when 0.8～1.2 times that the distillate quality collected is Herba Centellae quality；
(6) distillate Jing filtering with microporous membranes are degerming, and fill is obtained final product.
2. preparation method according to claim 1, it is characterised in that in the step (2) length of cutting be 0.5～
2cm。
3. preparation method according to claim 1, it is characterised in that the temperature of step (3) hot water is 50～60 DEG C.
4. preparation method according to claim 1, it is characterised in that the step (4) is by adjusting circulating cooling liquid
Temperature, makes the temperature of distillate be less than 40 DEG C.
5. preparation method according to claim 1, it is characterised in that the aperture of step (6) microporous filter membrane is 0.22
Micron.
6. Herba Centellae hydrosol obtained in a kind of preparation method as described in any one of Claims 1 to 5.
7. the purposes of Herba Centellae hydrosol obtained in a kind of preparation method as described in any one of Claims 1 to 5, its feature exist
In, for astringent, or as substrate be used for allocate emulsion, facial cream or facial film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710037023.3A CN106511142A (en) | 2017-01-18 | 2017-01-18 | Centella asiatica floral water and preparation method and application thereof |
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| CN201710037023.3A CN106511142A (en) | 2017-01-18 | 2017-01-18 | Centella asiatica floral water and preparation method and application thereof |
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| CN201710037023.3A Pending CN106511142A (en) | 2017-01-18 | 2017-01-18 | Centella asiatica floral water and preparation method and application thereof |
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Cited By (7)
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| CN109576062A (en) * | 2019-02-12 | 2019-04-05 | 无锡薇泰药物技术有限公司 | A kind of Chinese yew hydrosol extraction process |
| CN110179727A (en) * | 2019-05-14 | 2019-08-30 | 株洲千金药业股份有限公司 | A kind of skin care compound hydrosol and its preparation method and application |
| CN112210441A (en) * | 2020-10-20 | 2021-01-12 | 梵诗吉生物科技(东莞)有限公司 | Preparation method of joss-stick-flavor hydrolat and in-vitro antioxidant activity evaluation method thereof |
| CN113768834A (en) * | 2021-08-28 | 2021-12-10 | 海南黎草纪新生物科技有限公司 | Preparation method of centella asiatica hydrolat |
| CN115340907A (en) * | 2021-10-08 | 2022-11-15 | 广州摩亚方舟贸易有限公司 | Preparation method of centella asiatica hydrosol and centella asiatica hydrosol |
| CN116261462A (en) * | 2020-07-14 | 2023-06-13 | 科然药业有限公司 | Composition and its use |
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| CN116261462A (en) * | 2020-07-14 | 2023-06-13 | 科然药业有限公司 | Composition and its use |
| CN112210441A (en) * | 2020-10-20 | 2021-01-12 | 梵诗吉生物科技(东莞)有限公司 | Preparation method of joss-stick-flavor hydrolat and in-vitro antioxidant activity evaluation method thereof |
| CN113768834A (en) * | 2021-08-28 | 2021-12-10 | 海南黎草纪新生物科技有限公司 | Preparation method of centella asiatica hydrolat |
| CN115340907A (en) * | 2021-10-08 | 2022-11-15 | 广州摩亚方舟贸易有限公司 | Preparation method of centella asiatica hydrosol and centella asiatica hydrosol |
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