CN106495856A - A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer - Google Patents
A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer Download PDFInfo
- Publication number
- CN106495856A CN106495856A CN201610912890.2A CN201610912890A CN106495856A CN 106495856 A CN106495856 A CN 106495856A CN 201610912890 A CN201610912890 A CN 201610912890A CN 106495856 A CN106495856 A CN 106495856A
- Authority
- CN
- China
- Prior art keywords
- parts
- calcium
- water
- fermentation residue
- selenium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C5/00—Fertilisers containing other nitrates
- C05C5/04—Fertilisers containing other nitrates containing calcium nitrate
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/70—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting wettability, e.g. drying agents
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
Abstract
The invention discloses a kind of cassava fermentation residue selenium-enriched high-calcium fertilizer, in units of weight portion, including following raw material：230 280 parts of manioc waste, 40 60 parts of sodium selenite, 15 20 parts of calcium glycine, 12 18 parts of calcium nitrate, 10 16 parts of the calcium in sulfuric acid Asia, 30 50 parts of pig manure, 25 45 parts of chicken manure, 20 28 parts of duck excrement, 18 30 parts of earthworm powder, 12 16 parts of compound bacteria, 2.2 3.4 parts of trace element, 2 4.5 parts of organic water retainer, 1.2 2.4 parts of dispersant, 0.9 2 parts of organic conditioner, 0.8 1.8 parts of bleeding agent, 0.6 1 parts of conditioning agent, 1 1.8 parts of tackifier, 0.4 0.8 parts of synergist.The cassava fermentation residue selenium-enriched high-calcium fertilizer of the present invention can strengthen soil water-retaining performance, improved soil structure, improve efficiency of water application, promote paddy rice quickly to grow up healthy and sound, improve paddy rice selenium content and economic worth.
Description
【Technical field】
The invention belongs to fertilizer preparing technical field, and in particular to a kind of cassava fermentation residue selenium-enriched high-calcium fertilizer.
【Background technology】
Selenium is one of needed by human 14 kind trace element, is described as " kindling material of life ", " patron saint of heart " and " resists
The king of cancer ", selenium can strengthen immune system to entering internal virus, foreign matter and internal recognition capability, improve immune system thin
The synthesis of born of the same parents' antibody, the propagation of T cell, the level of antibodies in blood, make the phagocytosis of macrophage, sterilizing ability improve twice,
So as to strengthen human body body's immunity.Zoopery finds that selenium has to be reduced the acute injury of aflatoxins Bl, mitigate liver center
The degree of lobular necrosis and the effect of the death rate.Selenium and some heavy metal elements have very strong affinity, in vivo with metal such as mercury,
Good fortune etc. combines to form metallic selenium albumen composition and detoxifies.Selenium also has the function that protection is cardiovascular, safeguard myocardium health, popular
Disease is learned investigation and is found, the abundant area crowd's incidence of cardiovascular disease of Se content is low；Zoopery confirms selenium to cardiac muscle fibre and micro-
The structure and function of pipe plays an important role.In addition, research shows, selenium deficiency area tumor incidence is significantly higher, stomach trouble
Morbidity is relevant with scarce selenium, and scarce selenium can cause growth retardation, cataract patient and diabetic blindness Selenium Supplement partly can improve
Its visual performance.Therefore, selenium has anti-cancer and cancer-preventing, strengthens immune function of human body, hypoglycemic, protection cardiovascular and cerebrovascular, prevention
And the effects such as anti-aging, therefore by " king of anticancer " in scientist referred to as body trace element.
Paddy rice is mainly distributed on the subtropical and tropical zones in Asia and Africa.Nearly half population in the world, including almost
Whole East Asia and the population in Southeast Asia, all with rice as food.The cultivation history of rice can trace back to 12000-16000 before the about Christian era
Front Hunan China.Paddy rice gradually westwards travels to India after China widely plants, and Middle Ages introduce south of europe.Rice
Major country of production is China, India, Japan, Bangladesh, Indonesia, Thailand and Burma.Eighties of last century late period, world rice
400,000,000,000 kilograms or so of rice annual production average out to, about 1.45 hundred million hectares of cultivated area.The 95% of produced rice is the mankind in the world
Eaten.According to investigations, in addition to Tree in Enshi of Hubei Province rice selenium content is higher, remaining regional rice content is below food
Low critical value 0.06mg/kg of Se content, belongs to low selenium rice.
At this stage, peasant apply fertilizer on paddy rice presence subject matter have blindly fertilising, partially fertilising material, unreasonable fertilising,
Fertilizing method is improper, and concrete manifestation is in the following areas：(1) heavy dressing chemical fertilizer, gently applies or not organic fertilizer, not only destroys soil knot
Structure, reduces the feeder capability of soil, have impact on the quality of rice again；(2) apply partially, heavy nitrogen application, phosphorus potash fertilizer put on the low side, nitrogen
Phosphorus potassium proportion is unreasonable；(3) secondary and micro-element fertilizers input wretched insufficiency, causes nutrient serious unbalance, physiological and invades
Metachromia disease is often sent out multiple, directly affects rice yield and quality；(4) administration is unreasonable, is mainly manifested in following aspect：Method
Improper, topdress generally spread fertilizer over the fields, top application, cause fertilizer loss serious, utilization rate is low；Dose is excessive, has both reduced the profit of fertilizer
With rate, the paddy rice poor growth due to a lack of other nutrients again, many peasant households amount of application just by increasing urea is promoting water
Rice grows, and not only increased production cost, increases water and soil pollution again；Fertilising not science, topdresses excessive, and opportunity of topdressing holds not
Standard, forms early stage overgrowing, and envelope row is too early, the phenomenon of later stage early ageing.Unreasonable, unscientific fertilising, not only cause fertilizer to waste,
Soil fertility decline, soil compaction, production cost increase, and more cause agricultural environment pollution, quality of agricultural product to decline, meanwhile, also
Increase agricultural product security risk.
At present, the Se content for improving rice by applying fertilizer is one of effective way, but the fertilizer of domestic production selenium-enriched rice
Material is applied mainly by the method for foliage-spray, and advantage is that Crop is fast, but shortcoming is also very significantly, such as increased with fertilizer
Cost, contaminated soil and water source, security are poor.
In order to fundamentally solve blindly fertilising, inclined fertilising material, unreasonable fertilising, fertilizing method improperly problem, it is badly in need of
A kind of stable high yield that can realize Rice Production, high-quality and efficient, raising utilization rate of fertilizer, make rational use of resources, protecting ecology
Environment, improved soil, culture fertility promote the dedicated fertilizer of agricultural sustainable development.
【Content of the invention】
The present invention provides a kind of cassava fermentation residue selenium-enriched high-calcium fertilizer, to solve method of the paddy rice by foliage-spray,
The problems such as causing increase fertilizer cost, contaminated soil and water source, security difference.The cassava fermentation residue selenium-enriched high-calcium of the present invention is organic
Fertilizer can strengthen soil water-retaining performance, improved soil structure, improve efficiency of water application, promote paddy rice quickly to grow up healthy and sound, improve water
Rice selenium content and economic worth.
For solving above technical problem, the present invention is employed the following technical solutions：
A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer, in units of weight portion, including following raw material：Manioc waste 230-
280 parts, sodium selenite 40-60 parts, calcium glycine 15-20 parts, calcium nitrate 12-18 parts, sulfuric acid Asia calcium 10-16 parts, pig manure 30-50
Part, chicken manure 25-45 parts, duck excrement 20-28 part, earthworm powder 18-30 parts, compound bacteria 12-16 part, trace element 2.2-3.4 parts, organic
Water-loss reducer 2-4.5 parts, dispersant 1.2-2.4 parts, organic conditioner 0.9-2 parts, bleeding agent 0.8-1.8 parts, conditioning agent 0.6-1
Part, tackifier 1-1.8 parts, synergist 0.4-0.8 parts.
Further, the compound bacteria is in units of weight portion, including following raw material：Bacillus 7-14 parts, nitrobacteria
5-8 parts, Aspergillus 3-5 part, saccharomycete 2-4 parts, actinomyces 2-4 parts, rhizobium 3-6 parts, phosphobacteria 2-3.5 parts, B. mucilaginocus 2-
3.2 parts, phosphate solubilizing bacteria 1.5-2.8 parts.
Further, described micro- in units of weight portion, including following raw material：Manganese element 0.4-0.8 parts, chlorine unit
Plain 0.4-0.6 parts, ferro element 0.5-0.9 parts, Zn-ef ficiency 0.3-0.7 parts, boron element 0.4-0.6 parts, molybdenum element 0.2-0.4 parts.
Further, the dispersant is N- lauroyl glutamate potassium.
Further, the bleeding agent is alkyl sulfate potassium.
Further, the conditioning agent is esters of acrylic acid conditioning agent.
Further, the tackifier are glycidoxy-propyltrimethoxy silane.
Further, the synergist is Octacide 264 diethyl aminoethyl hexanoate.
The present invention also provides a kind of preparation method of cassava fermentation residue selenium-enriched high-calcium fertilizer, comprises the following steps：
S1：By manioc waste, sodium selenite, calcium glycine, calcium nitrate, sulfuric acid Asia calcium, pig manure, chicken manure, duck excrement, earthworm powder,
Compound bacteria, trace element, dispersant, bleeding agent, conditioning agent mixing, are 206-385W in ultrasonic power, and temperature is 52-62 DEG C
Under fermented, fermentation 4-6 days after be obtained zymotic fluid；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium temperature be carry out activating at 28-32 DEG C, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 300-500 part water and be well mixed,
Temperature is at 34-38 DEG C after culture 11-16h, is centrifugation under 3000-5000r/min in rotating speed, compound bacteria is obtained；Described
Biological nutritive agent in units of weight portion, including following raw material：Yeast extract 30-50 parts, sodium gluconate 30-45 parts, peptone
15-20 parts, potassium acetate 15-20 parts, sodium phosphate 10-15 parts；The biological growth stimulant in units of weight portion, including following
Raw material：Cerous sulfate 30-50 parts, aluminum sulfate 20-30 parts；
S2：Zymotic fluid obtained in step S1 is stood and abandons precipitation, and remaining ferment liquid is concentrated at 67-69 DEG C, obtained
Concentrate, the concentrate is dried to water content≤7% at 75-83 DEG C, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, cross 100-200 mesh sieve after with organic water retainer, organic conditioner,
Tackifier, synergist are well mixed, and make 0.3-2.5mm particles, and cassava fermentation residue selenium-enriched high-calcium fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water stand clarification, obtain supernatant, the supernatant is heated to 92-95 DEG C then
Concentration is evaporated, pH value is concentrated into for 1.8-2.2, is stopped heating, stand activation 7.2-7.8h, be subsequently adding carbonic acid under room temperature
Ammonium adjusts pH value to 5.1-5.3, obtains humic acid liquid I, and humic acid liquid I is dried to water content≤8%, powder at 88-102 DEG C
100-300 mesh sieve is crossed after broken, humic acid I is obtained；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios are constituted, and are 1 in solid-liquid ratio:12-16, ultrasonic power is 160-180W, second
Determining alcohol is 60%-80%, and Extracting temperature is to extract I 40-60min of liquid at 60-70 DEG C, and gained liquid I filters, be concentrated into and contain
Mixture I is obtained after the water yield≤18%, gained mixture I is dried to water content≤6% at 88-102 DEG C, cross 100- after crushing
300 mesh sieve, are obtained Pesticidal combination I；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, is well mixed to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios are constituted,
Carry out making 0.9-2.6mm particles and dry to water content≤6%, prepared organic guarantor at 88-102 DEG C by the mixture II
Aqua.
Further, the preparation method of organic conditioner described in step S3, comprises the following steps：
(1) vinegar factory waste liquid is stood clarification, obtains supernatant, the supernatant is heated to 68-82 DEG C then is carried out
Be concentrated by evaporation, pH value be concentrated into for 2.2-3.6, stop heating, stand activation 12-15h under room temperature, be subsequently adding ammonium carbonate regulation
PH value obtains humic acid liquid a to 6.1-7.3, humic acid liquid a is dried to water content≤6% at 82-104 DEG C, mistake after crushing
100-300 mesh sieve, is obtained humic acid a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Into, solid-liquid ratio be 1:14-16, ultrasonic power are 150-170W, and concentration of alcohol is 65%-75%, and Extracting temperature is 62-74
Extract liquid a45-65min at DEG C, gained liquid a filters, be concentrated into after water content≤21% to obtain mixture a, gained mixture a
Dry to water content≤6% at 86-102 DEG C, after crushing, cross 100-300 mesh sieve, Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, are well mixed to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
The mixture b is carried out making 1.2-2.6mm particles and is dried to water content≤6% at 86-102 DEG C, is obtained by example composition
Organic conditioner.
The invention has the advantages that：
(1) cassava fermentation residue selenium-enriched high-calcium fertilizer of the invention uses water-loss reducer, can strengthen soil water-retaining performance, improvement
Soil texture, the deep percolation and loss of soil nutrient that reduce water, raising efficiency of water application；
(2) cassava fermentation residue selenium-enriched high-calcium fertilizer of the invention uses dispersant, can reduce cassava fermentation residue selenium-rich high
Calcium fertilizer particle and the viscosity of high molecular polymer, can make cassava fermentation residue selenium-enriched high-calcium fertilizer particle be quickly dispersed in water
In, be conducive to plant absorption；
(3) cassava fermentation residue selenium-enriched high-calcium fertilizer of the invention has the work for making fertilizer efficiency and drug effect synergy using bleeding agent
With；
(4) cassava fermentation residue selenium-enriched high-calcium fertilizer of the invention can not only effectively preventing disease and pest, and can balanced battalion
Support, promote paddy rice quickly to grow up healthy and sound, improve paddy rice selenium content and economic worth；
(5) cassava fermentation residue selenium-enriched high-calcium fertilizer ecological, environmental protective of the invention, improves soil environment, to environment without dirt
Dye.
【Specific embodiment】
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the present invention's
Protection domain, but do not limit the scope of the invention.
In an embodiment, the cassava fermentation residue selenium-enriched high-calcium fertilizer, in units of weight portion, including following raw material：
Manioc waste 230-280 parts, sodium selenite 40-60 parts, calcium glycine 15-20 parts, calcium nitrate 12-18 parts, sulfuric acid Asia calcium 10-16
Part, pig manure 30-50 parts, chicken manure 25-45 parts, duck excrement 20-28 part, earthworm powder 18-30 parts, compound bacteria 12-16 part, trace element
2.2-3.4 parts, organic water retainer 2-4.5 parts, dispersant 1.2-2.4 parts, organic conditioner 0.9-2 parts, bleeding agent 0.8-1.8
Part, conditioning agent 0.6-1 parts, tackifier 1-1.8 parts, synergist 0.4-0.8 parts；
The compound bacteria in units of weight portion, including following raw material：Bacillus 7-14 parts, nitrobacteria 5-8 parts, aspergillus
Bacterium 3-5 parts, saccharomycete 2-4 parts, actinomyces 2-4 parts, rhizobium 3-6 parts, phosphobacteria 2-3.5 parts, B. mucilaginocus 2-3.2 parts, phosphorus decomposing
Bacterium 1.5-2.8 parts；
Described micro- in units of weight portion, including following raw material：Manganese element 0.4-0.8 parts, chlorine element 0.4-0.6
Part, ferro element 0.5-0.9 parts, Zn-ef ficiency 0.3-0.7 parts, boron element 0.4-0.6 parts, molybdenum element 0.2-0.4 parts；
The dispersant is N- lauroyl glutamate potassium；
The bleeding agent is alkyl sulfate potassium；
The conditioning agent is esters of acrylic acid conditioning agent；
The tackifier are glycidoxy-propyltrimethoxy silane；
The synergist is Octacide 264 diethyl aminoethyl hexanoate；
The preparation method of described cassava fermentation residue selenium-enriched high-calcium fertilizer, comprises the following steps：
S1：By manioc waste, sodium selenite, calcium glycine, calcium nitrate, sulfuric acid Asia calcium, pig manure, chicken manure, duck excrement, earthworm powder,
Compound bacteria, trace element, dispersant, bleeding agent, conditioning agent mixing, are 206-385W in ultrasonic power, and temperature is 52-62 DEG C
Under fermented, fermentation 4-6 days after be obtained zymotic fluid；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium temperature be carry out activating at 28-32 DEG C, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 300-500 part water and be well mixed,
Temperature is at 34-38 DEG C after culture 11-16h, is centrifugation under 3000-5000r/min in rotating speed, compound bacteria is obtained；Described
Biological nutritive agent in units of weight portion, including following raw material：Yeast extract 30-50 parts, sodium gluconate 30-45 parts, peptone
15-20 parts, potassium acetate 15-20 parts, sodium phosphate 10-15 parts；The biological growth stimulant in units of weight portion, including following
Raw material：Cerous sulfate 30-50 parts, aluminum sulfate 20-30 parts；
S2：Zymotic fluid obtained in step S1 is stood and abandons precipitation, and remaining ferment liquid is concentrated at 67-69 DEG C, obtained
Concentrate, the concentrate is dried to water content≤7% at 75-83 DEG C, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, cross 100-200 mesh sieve after with organic water retainer, organic conditioner,
Tackifier, synergist are well mixed, and make 0.3-2.5mm particles, and cassava fermentation residue selenium-enriched high-calcium fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water stand clarification, obtain supernatant, the supernatant is heated to 92-95 DEG C then
Concentration is evaporated, pH value is concentrated into for 1.8-2.2, is stopped heating, stand activation 7.2-7.8h, be subsequently adding carbonic acid under room temperature
Ammonium adjusts pH value to 5.1-5.3, obtains humic acid liquid I, and humic acid liquid I is dried to water content≤8%, powder at 88-102 DEG C
100-300 mesh sieve is crossed after broken, humic acid I is obtained；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios are constituted, and are 1 in solid-liquid ratio:12-16, ultrasonic power is 160-180W, second
Determining alcohol is 60%-80%, and Extracting temperature is to extract I 40-60min of liquid at 60-70 DEG C, and gained liquid I filters, be concentrated into and contain
Mixture I is obtained after the water yield≤18%, gained mixture I is dried to water content≤6% at 88-102 DEG C, cross 100- after crushing
300 mesh sieve, are obtained Pesticidal combination I；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, is well mixed to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios are constituted,
Carry out making 0.9-2.6mm particles and dry to water content≤6%, prepared organic guarantor at 88-102 DEG C by the mixture II
Aqua；
Described in step S3, the preparation method of organic conditioner, comprises the following steps：
(1) vinegar factory waste liquid is stood clarification, obtains supernatant, the supernatant is heated to 68-82 DEG C then is carried out
Be concentrated by evaporation, pH value be concentrated into for 2.2-3.6, stop heating, stand activation 12-15h under room temperature, be subsequently adding ammonium carbonate regulation
PH value obtains humic acid liquid a to 6.1-7.3, humic acid liquid a is dried to water content≤6% at 82-104 DEG C, mistake after crushing
100-300 mesh sieve, is obtained humic acid a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Into, solid-liquid ratio be 1:14-16, ultrasonic power are 150-170W, and concentration of alcohol is 65%-75%, and Extracting temperature is 62-74
Extract liquid a45-65min at DEG C, gained liquid a filters, be concentrated into after water content≤21% to obtain mixture a, gained mixture a
Dry to water content≤6% at 86-102 DEG C, after crushing, cross 100-300 mesh sieve, Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, are well mixed to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
The mixture b is carried out making 1.2-2.6mm particles and is dried to water content≤6% at 86-102 DEG C, is obtained by example composition
Organic conditioner.
It is illustrated below by more specifically embodiment.
Embodiment 1
A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer, in units of weight portion, including following raw material：260 parts of manioc waste,
50 parts of sodium selenite, 18 parts of calcium glycine, 15 parts of calcium nitrate, sulfuric acid Asia 14 parts of calcium, 40 parts of pig manure, 35 parts of chicken manure, 25 parts of duck excrement,
25 parts of earthworm powder, 15 parts of compound bacteria, 2.8 parts of trace element, 3.2 parts of organic water retainer, 1.8 parts of dispersant, organic conditioner 1.5
Part, 1.2 parts of bleeding agent, 0.8 part of conditioning agent, 1.4 parts of tackifier, 0.6 part of synergist；
The compound bacteria in units of weight portion, including following raw material：10 parts of Bacillus, 7 parts of nitrobacteria, Aspergillus 4
Part, 3 parts of saccharomycete, 3 parts of actinomyces, 5 parts of rhizobium, 3 parts of phosphobacteria, 2.6 parts of B. mucilaginocus, 2.2 parts of phosphate solubilizing bacteria；
Described micro- in units of weight portion, including following raw material：0.6 part of manganese element, 0.5 part of chlorine element, iron unit
0.7 part of element, 0.5 part of Zn-ef ficiency, 0.5 part of boron element, 0.3 part of molybdenum element；
The dispersant is N- lauroyl glutamate potassium；
The bleeding agent is alkyl sulfate potassium；
The conditioning agent is esters of acrylic acid conditioning agent；
The tackifier are glycidoxy-propyltrimethoxy silane；
The synergist is Octacide 264 diethyl aminoethyl hexanoate；
The preparation method of described cassava fermentation residue selenium-enriched high-calcium fertilizer, comprises the following steps：
S1：By manioc waste, sodium selenite, calcium glycine, calcium nitrate, sulfuric acid Asia calcium, pig manure, chicken manure, duck excrement, earthworm powder,
Compound bacteria, trace element, dispersant, bleeding agent, conditioning agent mixing, are 305W in ultrasonic power, and temperature is to carry out at 58 DEG C
Fermentation, fermentation were obtained zymotic fluid after 5 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium temperature be carry out activating at 30 DEG C, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 400 parts of water and be well mixed, in temperature
After for culture 14h at 36 DEG C, it is centrifugation under 4000r/min in rotating speed, compound bacteria is obtained；The biological nutritive agent is with weight
Part is unit, including following raw material：40 parts of yeast extract, 36 parts of sodium gluconate, 18 parts of peptone, 18 parts of potassium acetate, sodium phosphate
12 parts；The biological growth stimulant in units of weight portion, including following raw material：40 parts of cerous sulfate, 25 parts of aluminum sulfate；
S2：Zymotic fluid obtained in step S1 is stood and abandons precipitation, and remaining ferment liquid is concentrated at 68 DEG C, concentrated
Thing, it is 7% the concentrate to be dried at 80 DEG C to water content, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, with organic water retainer, organic conditioner, thickening after 150 mesh sieve excessively
Agent, synergist are well mixed, and make 1.5mm particles, and cassava fermentation residue selenium-enriched high-calcium fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water stand clarification, obtain supernatant, the supernatant is heated to 93 DEG C then and is entered
Row is concentrated by evaporation, and is concentrated into pH value for 2, stops heating, stands activation 7.5h under room temperature, be subsequently adding ammonium carbonate adjust pH value to
5.2, humic acid liquid I is obtained, it is 8% that humic acid liquid I is dried to water content at 95 DEG C, crosses 200 mesh sieve after crushing, is obtained
Humic acid I；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios are constituted, and are 1 in solid-liquid ratio:14, ultrasonic power is 170W, and concentration of alcohol is
70%, Extracting temperature is to extract I 50min of liquid at 65 DEG C, and gained liquid I filters, be concentrated into water content for must mix after 18%
Thing I, it is 6% that gained mixture I is dried to water content at 95 DEG C, crosses 200 mesh sieve after crushing, and Pesticidal combination I is obtained；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, is well mixed to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios are constituted,
It is 6% to carry out making 0.9-1mm particles and drying to water content at 95 DEG C the mixture II, and organic water retainer is obtained；
Described in step S3, the preparation method of organic conditioner, comprises the following steps：
(1) vinegar factory waste liquid is stood clarification, obtains supernatant, the supernatant is heated to 75 DEG C then and is evaporated
Concentration, it is 3 to be concentrated into pH value, stops heating, stands activation 14h under room temperature, is subsequently adding ammonium carbonate regulation pH value to 6.7, obtains
Humic acid liquid a is obtained, and it is 6% that humic acid liquid a is dried to water content at 95 DEG C, 200 mesh sieve is crossed after crushing, and humic acid is obtained
a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Into, solid-liquid ratio be 1:15, ultrasonic power is 160W, and concentration of alcohol is 70%, and Extracting temperature is to extract liquid at 68 DEG C
A55min, gained liquid a filter, be concentrated into water content for after 21% mixture a, gained mixture a dried extremely at 95 DEG C
Water content is 6%, crosses 100-300 mesh sieve after crushing, and Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, are well mixed to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
Example composition, it is 6% to carry out making 1.2-1.8mm particles and drying to water content at 95 DEG C the mixture b, is obtained organic
Conditioner.
Embodiment 2
A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer, in units of weight portion, including following raw material：Manioc waste 2300
Part, 40 parts of sodium selenite, 15 parts of calcium glycine, 12 parts of calcium nitrate, sulfuric acid Asia, 10 parts of calcium, 30 parts of pig manure, 25 parts of chicken manure, duck excrement 20
Part, 18 parts of earthworm powder, 12 parts of compound bacteria, 2.2 parts of trace element, 2 parts of organic water retainer, 1.2 parts of dispersant, organic conditioner
0.9 part, 0.8 part of bleeding agent, 0.6 part of conditioning agent, 1 part of tackifier, 0.4 part of synergist；
The compound bacteria in units of weight portion, including following raw material：7 parts of Bacillus, 5 parts of nitrobacteria, Aspergillus 3
Part, 2 parts of saccharomycete, 2 parts of actinomyces, 3 parts of rhizobium, 2 parts of phosphobacteria, 2 parts of B. mucilaginocus, 1.5 parts of phosphate solubilizing bacteria；
Described micro- in units of weight portion, including following raw material：0.4 part of manganese element, 0.4 part of chlorine element, iron unit
0.5 part of element, 0.3 part of Zn-ef ficiency, 0.4 part of boron element, 0.2 part of molybdenum element；
The dispersant is N- lauroyl glutamate potassium；
The bleeding agent is alkyl sulfate potassium；
The conditioning agent is esters of acrylic acid conditioning agent；
The tackifier are glycidoxy-propyltrimethoxy silane；
The synergist is Octacide 264 diethyl aminoethyl hexanoate；
The preparation method of described cassava fermentation residue selenium-enriched high-calcium fertilizer, comprises the following steps：
S1：By manioc waste, sodium selenite, calcium glycine, calcium nitrate, sulfuric acid Asia calcium, pig manure, chicken manure, duck excrement, earthworm powder,
Compound bacteria, trace element, dispersant, bleeding agent, conditioning agent mixing, are 206W in ultrasonic power, and temperature is to carry out at 52 DEG C
Fermentation, fermentation were obtained zymotic fluid after 6 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium temperature be carry out activating at 28 DEG C, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 300 parts of water and be well mixed, in temperature
After for culture 16h at 34 DEG C, it is centrifugation under 3000r/min in rotating speed, compound bacteria is obtained；The biological nutritive agent is with weight
Part is unit, including following raw material：30 parts of yeast extract, 30 parts of sodium gluconate, 15 parts of peptone, 15 parts of potassium acetate, sodium phosphate
10 parts；The biological growth stimulant in units of weight portion, including following raw material：30 parts of cerous sulfate, 20 parts of aluminum sulfate；
S2：Zymotic fluid obtained in step S1 is stood and abandons precipitation, and remaining ferment liquid is concentrated at 67 DEG C, concentrated
Thing, it is 6.8% the concentrate to be dried at 75 DEG C to water content, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, with organic water retainer, organic conditioner, thickening after 100 mesh sieve excessively
Agent, synergist are well mixed, and make 0.3mm particles, and cassava fermentation residue selenium-enriched high-calcium fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water stand clarification, obtain supernatant, the supernatant is heated to 92 DEG C then and is entered
Row is concentrated by evaporation, and it is 1.8 to be concentrated into pH value, stops heating, stands activation 7.2h under room temperature, is subsequently adding ammonium carbonate regulation pH value
To 5.1, humic acid liquid I is obtained, it is 7% that humic acid liquid I is dried to water content at 88 DEG C, after crushing, cross 100 mesh sieve, system
Obtain humic acid I；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios are constituted, and are 1 in solid-liquid ratio:12, ultrasonic power is 160W, and concentration of alcohol is
60%, Extracting temperature is to extract I 40min of liquid at 60 DEG C, and gained liquid I filters, be concentrated into water content for must mix after 16%
Thing I, it is 5% that gained mixture I is dried to water content at 88 DEG C, crosses 100 mesh sieve after crushing, and Pesticidal combination I is obtained；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, is well mixed to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios are constituted,
It is 5% to carry out making 1-2.6mm particles and drying to water content at 88 DEG C the mixture II, and organic water retainer is obtained；
Described in step S3, the preparation method of organic conditioner, comprises the following steps：
(1) vinegar factory waste liquid is stood clarification, obtains supernatant, the supernatant is heated to 68 DEG C then and is evaporated
Concentration, it is 2.2 to be concentrated into pH value, stops heating, stands activation 15h under room temperature, is subsequently adding ammonium carbonate regulation pH value to 6.1,
Humic acid liquid a is obtained, it is 5% that humic acid liquid a is dried to water content at 82 DEG C, 100 mesh sieve is crossed after crushing, rotten plant is obtained
Sour a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Into, solid-liquid ratio be 1:14, ultrasonic power is 150W, and concentration of alcohol is 65%, and Extracting temperature is to extract liquid at 62 DEG C
A65min, gained liquid a filter, be concentrated into water content for after 20% mixture a, gained mixture a dried extremely at 86 DEG C
Water content is 5%, crosses 100 mesh sieve after crushing, and Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, are well mixed to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
Example composition, it is 4% to carry out making 1.4-2.6mm particles and drying to water content at 86 DEG C the mixture b, is obtained organic
Conditioner.
Embodiment 3
A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer, in units of weight portion, including following raw material：280 parts of manioc waste,
60 parts of sodium selenite, 20 parts of calcium glycine, 18 parts of calcium nitrate, sulfuric acid Asia 16 parts of calcium, 50 parts of pig manure, 45 parts of chicken manure, 28 parts of duck excrement,
30 parts of earthworm powder, 16 parts of compound bacteria, 3.4 parts of trace element, 4.5 parts of organic water retainer, 2.4 parts of dispersant, organic conditioner 2
Part, 1.8 parts of bleeding agent, 1 part of conditioning agent, 1.8 parts of tackifier, 0.8 part of synergist；
The compound bacteria in units of weight portion, including following raw material：14 parts of Bacillus, 8 parts of nitrobacteria, Aspergillus 5
Part, 4 parts of saccharomycete, 4 parts of actinomyces, 6 parts of rhizobium, 3.5 parts of phosphobacteria, 3.2 parts of B. mucilaginocus, 2.8 parts of phosphate solubilizing bacteria；
Described micro- in units of weight portion, including following raw material：0.8 part of manganese element, 0.6 part of chlorine element, iron unit
0.9 part of element, 0.7 part of Zn-ef ficiency, 0.6 part of boron element, 0.4 part of molybdenum element；
The dispersant is N- lauroyl glutamate potassium；
The bleeding agent is alkyl sulfate potassium；
The conditioning agent is esters of acrylic acid conditioning agent；
The tackifier are glycidoxy-propyltrimethoxy silane；
The synergist is Octacide 264 diethyl aminoethyl hexanoate；
The preparation method of described cassava fermentation residue selenium-enriched high-calcium fertilizer, comprises the following steps：
S1：By manioc waste, sodium selenite, calcium glycine, calcium nitrate, sulfuric acid Asia calcium, pig manure, chicken manure, duck excrement, earthworm powder,
Compound bacteria, trace element, dispersant, bleeding agent, conditioning agent mixing, are 385W in ultrasonic power, and temperature is to carry out at 62 DEG C
Fermentation, fermentation were obtained zymotic fluid after 4 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium temperature be carry out activating at 32 DEG C, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 500 parts of water and be well mixed, in temperature
After for culture 11h at 38 DEG C, it is centrifugation under 5000r/min in rotating speed, compound bacteria is obtained；The biological nutritive agent is with weight
Part is unit, including following raw material：50 parts of yeast extract, 45 parts of sodium gluconate, 20 parts of peptone, 20 parts of potassium acetate, sodium phosphate
15 parts；The biological growth stimulant in units of weight portion, including following raw material：50 parts of cerous sulfate, 30 parts of aluminum sulfate；
S2：Zymotic fluid obtained in step S1 is stood and abandons precipitation, and remaining ferment liquid is concentrated at 69 DEG C, concentrated
Thing, it is 5.3% the concentrate to be dried at 83 DEG C to water content, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, with organic water retainer, organic conditioner, thickening after 200 mesh sieve excessively
Agent, synergist are well mixed, and make 2.5mm particles, and cassava fermentation residue selenium-enriched high-calcium fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water stand clarification, obtain supernatant, the supernatant is heated to 95 DEG C then and is entered
Row is concentrated by evaporation, and it is 2.2 to be concentrated into pH value, stops heating, stands activation 7.8h under room temperature, is subsequently adding ammonium carbonate regulation pH value
To 5.3, humic acid liquid I is obtained, it is 6% that humic acid liquid I is dried to water content at 102 DEG C, 300 mesh sieve is crossed after crushing,
Prepared humic acid I；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios are constituted, and are 1 in solid-liquid ratio:16, ultrasonic power is 180W, and concentration of alcohol is
80%, Extracting temperature is to extract I 40min of liquid at 70 DEG C, and gained liquid I filters, be concentrated into water content for must mix after 14%
Thing I, it is 5% that gained mixture I is dried to water content at 102 DEG C, crosses 300 mesh sieve after crushing, and Pesticidal combination I is obtained；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, is well mixed to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios are constituted,
It is 4% to carry out making 1-2.6mm particles and drying to water content at 102 DEG C the mixture II, and organic water retainer is obtained；
Described in step S3, the preparation method of organic conditioner, comprises the following steps：
(1) vinegar factory waste liquid is stood clarification, obtains supernatant, the supernatant is heated to 82 DEG C then and is evaporated
Concentration, it is 3.6 to be concentrated into pH value, stops heating, stands activation 12h under room temperature, is subsequently adding ammonium carbonate regulation pH value to 7.3,
Humic acid liquid a is obtained, and it is 4% that humic acid liquid a is dried to water content at 104 DEG C, 300 mesh sieve is crossed after crushing, and corruption is obtained
Phytic acid a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Into, solid-liquid ratio be 1:16, ultrasonic power is 170W, and concentration of alcohol is 75%, and Extracting temperature is to extract liquid at 74 DEG C
A45min, gained liquid a filter, be concentrated into water content for after 17% mixture a, gained mixture a dried extremely at 102 DEG C
Water content is 4%, crosses 300 mesh sieve after crushing, and Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, are well mixed to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
Example composition, it is 4% to carry out making 1.8-2.6mm particles and drying to water content at 102 DEG C the mixture b, and being obtained has
Machine conditioner.
For verifying the effect of cassava fermentation residue selenium-enriched high-calcium fertilizer of the present invention, by following experimental verification.
The basically identical paddy rice ground of six block specifications is chosen in certain agricultural base, be set to paddy rice ground a, paddy rice ground b, paddy rice ground c,
Paddy rice ground d, paddy rice ground e, paddy rice ground f, plant paddy rice on six pieces of ground, and wherein paddy rice ground a, paddy rice ground b, paddy rice ground c are using commonly having
Machine fertilizer, paddy rice ground d, paddy rice ground e, paddy rice ground f respectively using the cassava fermentation residue selenium-enriched high-calcium fertilizer of embodiment 1,2,3, with
Per mu of fertilising 50kg is calculated, and observes the paddy growth situation on six pieces of paddy rice ground.As a result show：Paddy rice ground a, paddy rice ground b, paddy rice ground
The rice plant gloss difference, unhealthy that c kinds are planted, the speed of growth are slow, and plant is little, yields poorly, and paddy rice ground d, paddy rice ground e, paddy rice
The rice plant good luster of ground f kind plants, health, fast growth, plant are big, and yield is high, the water with unused product of the present invention
Rice field is compared, per mu of volume increase 315.36-461.78kg, improves 23-52 times of Se content, and uses in the paddy rice ground of product of the present invention
Pest and disease damage do not have substantially, it is seen that the cassava fermentation residue selenium-enriched high-calcium fertilizer of the present invention can not only effectively preventing disease and pest, and
And energy nutrition is balanced, improves soil environment, promotes paddy rice quickly to grow up healthy and sound, shorten growth cycle, improve rice yield and contain
Selenium amount.
Above content it cannot be assumed that the present invention is embodied as being confined to these explanations, for the technical field of the invention
Those of ordinary skill for, under the premise of without departing from present inventive concept, some simple deduction or replace can also be made, all answered
When being considered as belonging to the scope of patent protection that determined by the claims that is submitted to of the present invention.
Claims (10)
1. a kind of cassava fermentation residue selenium-enriched high-calcium fertilizer, it is characterised in that in units of weight portion, including following raw material：Wood
Potato slag 230-280 parts, sodium selenite 40-60 parts, calcium glycine 15-20 parts, calcium nitrate 12-18 parts, sulfuric acid Asia calcium 10-16 parts,
Pig manure 30-50 parts, chicken manure 25-45 parts, duck excrement 20-28 part, earthworm powder 18-30 parts, compound bacteria 12-16 part, trace element 2.2-
3.4 parts, organic water retainer 2-4.5 parts, dispersant 1.2-2.4 parts, organic conditioner 0.9-2 parts, bleeding agent 0.8-1.8 parts, tune
Section agent 0.6-1 parts, tackifier 1-1.8 parts, synergist 0.4-0.8 parts.
2. cassava fermentation residue selenium-enriched high-calcium fertilizer according to claim 1, it is characterised in that the compound bacteria is with weight
Part is unit, including following raw material：Bacillus 7-14 parts, nitrobacteria 5-8 parts, Aspergillus 3-5 part, saccharomycete 2-4 parts, unwrapping wire
Bacterium 2-4 parts, rhizobium 3-6 parts, phosphobacteria 2-3.5 parts, B. mucilaginocus 2-3.2 parts, phosphate solubilizing bacteria 1.5-2.8 parts.
3. cassava fermentation residue selenium-enriched high-calcium fertilizer according to claim 1, it is characterised in that the trace element is with weight
Amount part is unit, including following raw material：Manganese element 0.4-0.8 parts, chlorine element 0.4-0.6 part, ferro element 0.5-0.9 parts, zinc unit
Plain 0.3-0.7 parts, boron element 0.4-0.6 parts, molybdenum element 0.2-0.4 parts.
4. cassava fermentation residue selenium-enriched high-calcium fertilizer according to claim 1, it is characterised in that the dispersant is the N- months
Osmanthus acyl glutamic acid potassium.
5. cassava fermentation residue selenium-enriched high-calcium fertilizer according to claim 1, it is characterised in that the bleeding agent is alkyl
Sulfuric ester potassium.
6. cassava fermentation residue selenium-enriched high-calcium fertilizer according to claim 1, it is characterised in that the conditioning agent is propylene
Esters of gallic acid conditioning agent.
7. cassava fermentation residue selenium-enriched high-calcium fertilizer according to claim 1, it is characterised in that the tackifier are epoxy
Third oxygen propyl trimethoxy silicane.
8. cassava fermentation residue selenium-enriched high-calcium fertilizer according to claim 1, it is characterised in that the synergist is synergy
Amine diethyl aminoethyl hexanoate.
9. a kind of preparation method of the cassava fermentation residue selenium-enriched high-calcium fertilizer according to any one of claim 1-8, its are special
Levy and be, comprise the following steps：
S1：By manioc waste, sodium selenite, calcium glycine, calcium nitrate, sulfuric acid Asia calcium, pig manure, chicken manure, duck excrement, earthworm powder, compound
Bacterium, trace element, dispersant, bleeding agent, conditioning agent mixing, are 206-385W in ultrasonic power, and temperature is to enter at 52-62 DEG C
Row fermentation, fermentation were obtained zymotic fluid after 4-6 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, phosphate solubilizing bacteria
Temperature be carry out activating at 28-32 DEG C, Amplification Culture, with standby；
B, will be thin to the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 300-500 part water and be well mixed, in temperature
After spending for culture 11-16h at 34-38 DEG C, it is centrifugation under 3000-5000r/min in rotating speed, compound bacteria is obtained；The life
Thing nutritional agents in units of weight portion, including following raw material：Yeast extract 30-50 parts, sodium gluconate 30-45 parts, peptone 15-
20 parts, potassium acetate 15-20 parts, sodium phosphate 10-15 parts；The biological growth stimulant in units of weight portion, including following original
Material：Cerous sulfate 30-50 parts, aluminum sulfate 20-30 parts；
S2：Zymotic fluid obtained in step S1 is stood and abandons precipitation, and remaining ferment liquid is concentrated at 67-69 DEG C, concentrated
Thing, the concentrate is dried to water content≤7% at 75-83 DEG C, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, with organic water retainer, organic conditioner, thickening excessively after 100-200 mesh sieve
Agent, synergist are well mixed, and make 0.3-2.5mm particles, and cassava fermentation residue selenium-enriched high-calcium fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water stand clarification, obtain supernatant, the supernatant is heated to 92-95 DEG C then is carried out
Be concentrated by evaporation, pH value be concentrated into for 1.8-2.2, stop heating, stand activation 7.2-7.8h under room temperature, be subsequently adding ammonium carbonate tune
Section pH value obtains humic acid liquid I to 5.1-5.3, humic acid liquid I is dried to water content≤8% at 88-102 DEG C, after crushing
100-300 mesh sieve is crossed, humic acid I is obtained；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, described
Cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe press 35 in units of weight portion:
35:35:35:35:35:25:25:25 ratios are constituted, and are 1 in solid-liquid ratio:12-16, ultrasonic power is 160-180W, and ethanol is dense
Spend for 60%-80%, Extracting temperature is to extract I 40-60min of liquid at 60-70 DEG C, and gained liquid I is filtered, is concentrated into water content
Mixture I is obtained after≤18%, gained mixture I is dried to water content≤6% at 88-102 DEG C, cross 100-300 mesh after crushing
Sieve, is obtained Pesticidal combination I；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and distillation obtained in humic acid I, step B obtained in step A respectively
Water, is well mixed to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid I,
Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios are constituted, will
The mixture II is carried out making 0.9-2.6mm particles and is dried to water content≤6% at 88-102 DEG C, and organic water conservation is obtained
Agent.
10. the preparation method of cassava fermentation residue selenium-enriched high-calcium fertilizer according to claim 9, it is characterised in that step
Described in S3, the preparation method of organic conditioner, comprises the following steps：
(1) vinegar factory waste liquid is stood clarification, obtains supernatant, the supernatant is heated to 68-82 DEG C then and is evaporated
Concentration, is concentrated into pH value for 2.2-3.6, stops heating, stands activation 12-15h under room temperature, is subsequently adding ammonium carbonate and adjusts pH value
To 6.1-7.3, humic acid liquid a is obtained, humic acid liquid a is dried to water content≤6% at 82-104 DEG C, after crushing, cross 100-
300 mesh sieve, are obtained humic acid a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, tobacco, maple
Poplar leaves co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, Sabah lamb's-quarters
Reed, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratios are constituted, in material
Liquor ratio is 1:14-16, ultrasonic power are 150-170W, and concentration of alcohol is 65%-75%, and Extracting temperature is to carry at 62-74 DEG C
Taking liquid a45-65min, gained liquid a filter, is concentrated into after water content≤21% to obtain mixture a, and gained mixture a is in 86-
Dry to water content≤6% at 102 DEG C, after crushing, cross 100-300 mesh sieve, Pesticidal combination a is obtained；
(3) humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner, mould proof is weighed respectively
Agent a and distilled water, are well mixed to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, the rotten plant
Sour a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratio groups
Into carrying out making 1.2-2.6mm particles by the mixture b and dry to water content≤6% at 86-102 DEG C, be obtained organic
Conditioner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610912890.2A CN106495856A (en) | 2016-10-19 | 2016-10-19 | A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610912890.2A CN106495856A (en) | 2016-10-19 | 2016-10-19 | A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106495856A true CN106495856A (en) | 2017-03-15 |
Family
ID=58317992
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610912890.2A Pending CN106495856A (en) | 2016-10-19 | 2016-10-19 | A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106495856A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107347407A (en) * | 2017-07-25 | 2017-11-17 | 广西壮族自治区农业科学院经济作物研究所 | A kind of cultural method of selenium-enriched high-calcium purple sweetpotato |
| CN107347406A (en) * | 2017-07-25 | 2017-11-17 | 广西壮族自治区农业科学院经济作物研究所 | A kind of interplanting method of selenium-enriched high-calcium purple sweetpotato |
| CN108739233A (en) * | 2018-04-28 | 2018-11-06 | 广西金茂生物化工有限公司 | A kind of processing method of the waste generated with cassava production alcohol |
| CN108934909A (en) * | 2018-04-28 | 2018-12-07 | 广西金茂生物化工有限公司 | A kind of processing method of the waste generated with cassava fermentation alcohol |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105967919A (en) * | 2016-08-01 | 2016-09-28 | 韦波 | Potato organic fertilizer |
-
2016
- 2016-10-19 CN CN201610912890.2A patent/CN106495856A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105967919A (en) * | 2016-08-01 | 2016-09-28 | 韦波 | Potato organic fertilizer |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107347407A (en) * | 2017-07-25 | 2017-11-17 | 广西壮族自治区农业科学院经济作物研究所 | A kind of cultural method of selenium-enriched high-calcium purple sweetpotato |
| CN107347406A (en) * | 2017-07-25 | 2017-11-17 | 广西壮族自治区农业科学院经济作物研究所 | A kind of interplanting method of selenium-enriched high-calcium purple sweetpotato |
| CN108739233A (en) * | 2018-04-28 | 2018-11-06 | 广西金茂生物化工有限公司 | A kind of processing method of the waste generated with cassava production alcohol |
| CN108934909A (en) * | 2018-04-28 | 2018-12-07 | 广西金茂生物化工有限公司 | A kind of processing method of the waste generated with cassava fermentation alcohol |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102951963B (en) | Special organic-inorganic composite biological pesticide-fertilizer for tea and preparation method thereof | |
| CN101585740B (en) | Natural soil fertilizer conditioner | |
| CN103787776B (en) | A kind of biological defense fertilization material and preparation method thereof | |
| CN101768031B (en) | Preparation method of humic acid organic fertilizer | |
| CN103755430B (en) | A kind of production method of Environmental protection type full-nutrition organic cultivation media | |
| CN102851032B (en) | Alkaline earth improving agent prepared by using monosodium glutamate production waste liquid, and preparation method thereof | |
| CN106495855A (en) | A kind of edible fungus fermented slag selenium-enriched high-calcium ecological organic fertilier | |
| CN105348005A (en) | Production method of biological carbon-based ecological fertilizer | |
| CN104261981A (en) | Preparation method of seaweed organic fertilizer and organic fertilizer prepared by using method | |
| CN102584467B (en) | Biological organic fertilizer prepared by municipal sludge and preparation method thereof | |
| CN106518488A (en) | Fertilizer | |
| CN104130075A (en) | Novel seaweed biological bacterial fertilizer and production method thereof | |
| CN106495856A (en) | A kind of cassava fermentation residue selenium-enriched high-calcium fertilizer | |
| CN106478264A (en) | A kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer | |
| CN103274841A (en) | Special composite microbial fertilizer for garlic and preparation method thereof | |
| CN107500825A (en) | A kind of Se-enriched bio fertilizer and its preparation and application | |
| CN107285950A (en) | A kind of liquid organic water-soluble fertilizer and preparation method thereof | |
| CN103864526A (en) | Oyster mushroom dreg culture base stock and production method thereof | |
| CN102515975A (en) | Prescription of tobacco microorganism organic fertilizer and preparation method thereof | |
| CN106495857A (en) | A kind of sugared fermentation residue selenium-enriched high-calcium paddy rice fertilizer | |
| CN101844946A (en) | Culture medium for planting pholiota adipose and preparation method thereof | |
| CN106495936A (en) | A kind of organic fertilizer | |
| CN106854101A (en) | A kind of wine-growing fertilizer and preparation method thereof | |
| CN104177168A (en) | Organic fertilizer prepared from antiviral granule medicine dregs and preparation method thereof | |
| CN108002950A (en) | The preparation method of NEW TYPE OF COMPOSITE fertilizer based on rice |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170315 |
|
| RJ01 | Rejection of invention patent application after publication |