CN106478264A - A kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer - Google Patents
A kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer Download PDFInfo
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- CN106478264A CN106478264A CN201610913713.6A CN201610913713A CN106478264A CN 106478264 A CN106478264 A CN 106478264A CN 201610913713 A CN201610913713 A CN 201610913713A CN 106478264 A CN106478264 A CN 106478264A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C5/00—Fertilisers containing other nitrates
- C05C5/04—Fertilisers containing other nitrates containing calcium nitrate
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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Abstract
The invention discloses a kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, in units of weight portion, including following raw material：234 275 parts of marc, 43 58 parts of calcium selenite, 17 21 parts of calcium chloride, 12 16 parts of calcium sulfate, 11 14 parts of calcium nitrate, 33 48 parts of horsehit, 27 45 parts of duck excrement, 22 26 parts of goose excrement, 18 30 parts of earthworm powder, 12 16 parts of compound bacteria, 2.2 3.4 parts of trace element, 2 4.5 parts of organic water retainer, 1.2 2.4 parts of dispersant, 0.9 2 parts of organic conditioner, 0.8 1.8 parts of bleeding agent, 0.6 1 parts of conditioning agent, 1 1.8 parts of tackifier, 0.4 0.8 parts of synergist.The fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer of the present invention can strengthen soil water-retaining performance, improved soil structure, improve efficiency of water application, promote paddy rice quickly to grow up healthy and sound, improve paddy rice selenium content and economic worth.
Description
【Technical field】
The invention belongs to fertilizer preparing technical field, and in particular to a kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer.
【Background technology】
Selenium is one of needed by human 14 kind trace element, is described as " kindling material of life ", " patron saint of heart " and " resists
The king of cancer ", selenium can strengthen immune system to entering internal virus, foreign matter and internal recognition capability, improve immune system thin
The synthesis of born of the same parents' antibody, the propagation of T cell, the level of antibodies in blood, make the phagocytosis of macrophage, sterilizing ability improve twice,
So as to strengthen human body body's immunity.Zoopery finds that selenium has acute injury, the mitigation liver center for reducing aflatoxins Bl
The degree of lobular necrosis and the effect of the death rate.Selenium has very strong affinity with some heavy metal elements, in vivo with metal such as mercury,
Good fortune etc. combines to form metallic selenium albumen composition and detoxifies.Selenium also has the function that protection is cardiovascular, safeguard myocardium health, popular
Disease is learned investigation and is found, the abundant area crowd's incidence of cardiovascular disease of Se content is low；Zoopery confirms selenium to cardiac muscle fibre and micro-
The structure and function of pipe plays an important role.In addition, research shows, selenium deficiency area tumor incidence is significantly higher, stomach trouble
Morbidity is relevant with scarce selenium, and scarce selenium can cause growth retardation, cataract patient and diabetic blindness Selenium Supplement partly can improve
Its visual performance.Therefore, selenium has anti-cancer and cancer-preventing, strengthens immune function of human body, hypoglycemic, protection cardiovascular and cerebrovascular, prevention
And the effects such as anti-aging, therefore by " king of anticancer " in scientist referred to as body trace element.
Paddy rice is mainly distributed on the subtropical and tropical zones in Asia and Africa.Nearly half population in the world, including almost
Whole East Asia and the population in Southeast Asia, all with rice as food.The cultivation history of rice can trace back to 12000-16000 before the about Christian era
Front Hunan China.Paddy rice gradually westwards travels to India after China widely plants, and Middle Ages introduce south of europe.Rice
Major country of production is China, India, Japan, Bangladesh, Indonesia, Thailand and Burma.Eighties of last century late period, world rice
400,000,000,000 kilograms or so of rice annual production average out to, about 1.45 hundred million hectares of cultivated area.The 95% of produced rice is the mankind in the world
Eaten.According to investigations, in addition to Tree in Enshi of Hubei Province rice selenium content is higher, remaining regional rice content is below food
Low critical value 0.06mg/kg of Se content, belongs to low selenium rice.
At this stage, peasant apply fertilizer on paddy rice presence subject matter have blindly fertilising, partially fertilising material, unreasonable fertilising,
Fertilizing method is improper, and concrete manifestation is in the following areas：(1) heavy dressing chemical fertilizer, gently applies or not organic fertilizer, not only destroys soil knot
Structure, reduces the feeder capability of soil, have impact on the quality of rice again；(2) apply partially, heavy nitrogen application, phosphorus potash fertilizer put on the low side, nitrogen
Phosphorus potassium proportion is unreasonable；(3) secondary and micro-element fertilizers put into wretched insufficiency, cause nutrient serious unbalance, physiological and invade
Metachromia disease is often sent out multiple, directly affects rice yield and quality；(4) administration is unreasonable, is mainly manifested in following aspect：Method
Improper, topdress generally spread fertilizer over the fields, top application, cause fertilizer loss serious, utilization rate is low；Dose is excessive, has both reduced the profit of fertilizer
With rate, the paddy rice poor growth due to a lack of other nutrients again, many peasant households amount of application just by increasing urea is promoting water
Rice grows, and not only increased production cost, increases water and soil pollution again；Fertilising not science, topdresses excessive, and opportunity of topdressing holds not
Standard, forms early stage overgrowing, and envelope row is too early, the phenomenon of later stage early ageing.Unreasonable, unscientific fertilising, not only cause fertilizer to waste,
Soil fertility decline, soil compaction, production cost increase, and more cause agricultural environment pollution, and quality of agricultural product declines, meanwhile, also
Increase agricultural product security risk.
At present, the Se content for improving rice by applying fertilizer is one of effective way, but the fertilizer of domestic production selenium-enriched rice
Material is applied mainly by the method for foliage-spray, and advantage is that Crop is fast, but shortcoming is also very notable, such as increased with fertilizer
Cost, contaminated soil and water source, security are poor.
In order to fundamentally solve blindly fertilising, inclined fertilising material, unreasonable fertilising, fertilizing method improperly problem, it is badly in need of
A kind of stable high yield that can realize Rice Production, high-quality and efficient, raising utilization rate of fertilizer, make rational use of resources, protecting ecology
Environment, improved soil, culture fertility, promote the dedicated fertilizer of agricultural sustainable development.
【Content of the invention】
The present invention provides a kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, to solve side of the paddy rice by foliage-spray
Method, the problems such as cause increase fertilizer cost, contaminated soil and water source, security difference.The fruit fermentation residue selenium-enriched high-calcium of the present invention
Environmental protection fertilizer can strengthen soil water-retaining performance, improved soil structure, improve efficiency of water application, promote the quick health of paddy rice to become
Long, improve paddy rice selenium content and economic worth.
For solving above technical problem, the present invention is employed the following technical solutions：
A kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, in units of weight portion, including following raw material：Marc
234-275 part, calcium selenite 43-58 part, calcium chloride 17-21 part, calcium sulfate 12-16 part, calcium nitrate 11-14 part, horsehit 33-48
Part, duck excrement 27-45 part, goose excrement 22-26 part, earthworm powder 18-30 part, compound bacteria 12-16 part, trace element 2.2-3.4 part, organic
Water-loss reducer 2-4.5 part, dispersant 1.2-2.4 part, organic conditioner 0.9-2 part, bleeding agent 0.8-1.8 part, conditioning agent 0.6-1
Part, tackifier 1-1.8 part, synergist 0.4-0.8 part.
Further, the compound bacteria is in units of weight portion, including following raw material：Bacillus 7-14 part, nitrobacteria
5-8 part, Aspergillus 3-5 part, saccharomycete 2-4 part, actinomyces 2-4 part, rhizobium 3-6 part, phosphobacteria 2-3.5 part, B. mucilaginocus 2-
3.2 parts, phosphate solubilizing bacteria 1.5-2.8 part.
Further, described micro- in units of weight portion, including following raw material：Manganese element 0.4-0.8 part, chlorine unit
Plain 0.4-0.6 part, ferro element 0.5-0.9 part, Zn-ef ficiency 0.3-0.7 part, boron element 0.4-0.6 part, molybdenum element 0.2-0.4 part.
Further, the dispersant is N- lauroyl glutamate potassium.
Further, the bleeding agent is alkyl sulfate potassium.
Further, the conditioning agent is esters of acrylic acid conditioning agent.
Further, the tackifier are glycidoxy-propyltrimethoxy silane.
Further, the synergist is Octacide 264 diethyl aminoethyl hexanoate.
The present invention also provides a kind of preparation method of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, comprises the following steps：
S1：By marc, calcium selenite, calcium chloride, calcium sulfate, calcium nitrate, horsehit, duck excrement, goose excrement, earthworm powder, it is combined
Bacterium, trace element, dispersant, bleeding agent, conditioning agent mixing, are 229-368W in ultrasonic power, and temperature is to enter at 52-65 DEG C
Row fermentation, fermentation were obtained zymotic fluid after 4-6 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium carries out at temperature is for 28-32 DEG C activating, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 300-500 part water and mix,
Temperature is at 34-38 DEG C after culture 11-16h, is centrifugation under 3000-5000r/min in rotating speed, compound bacteria is obtained；Described
Biological nutritive agent in units of weight portion, including following raw material：Yeast extract 30-50 part, sodium gluconate 30-45 part, peptone
15-20 part, potassium acetate 15-20 part, sodium phosphate 10-15 part；The biological growth stimulant in units of weight portion, including following
Raw material：Cerous sulfate 30-50 part, aluminum sulfate 20-30 part；
S2：Zymotic fluid standing obtained in step S1 is abandoned precipitation, and remaining ferment liquid is concentrated at 61-67 DEG C, obtain
Concentrate, the concentrate is dry to water content≤6.1% at 65-83 DEG C, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, cross 100-200 mesh sieve after with organic water retainer, organic conditioner,
Tackifier, synergist are mixed, and make 0.3-2.2mm particle, and fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water standing clarification, obtain supernatant, then the supernatant is heated to 92-95 DEG C
Being evaporated concentrating, pH value being concentrated into for 1.8-2.2, stop heating, under room temperature, standing activation 7.2-7.8h, is subsequently adding carbonic acid
Ammonium adjusts pH value to 5.1-5.3, obtains humic acid liquid I, and humic acid liquid I is dry to water content≤8%, powder at 88-102 DEG C
100-300 mesh sieve is crossed after broken, humic acid I is obtained；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios constitute, and are 1 in solid-liquid ratio:12-16, ultrasonic power are 160-180W, second
Determining alcohol is 60%-80%, and Extracting temperature is to extract I 40-60min of liquid at 60-70 DEG C, and gained liquid I filters, be concentrated into and contain
Mixture I is obtained after the water yield≤18%, gained mixture I is dry to water content≤6% at 88-102 DEG C, cross 100- after crushing
300 mesh sieve, are obtained Pesticidal combination I；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, mixes to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios constitute,
The mixture II is carried out making 0.9-2.6mm particle and dry to water content≤6%, prepared organic guarantor at 88-102 DEG C
Aqua.
Further, the preparation method of organic conditioner described in step S3, comprises the following steps：
(1) by the waste liquid standing clarification of vinegar factory, supernatant is obtained, then the supernatant is heated to 68-82 DEG C is carried out
Be concentrated by evaporation, pH value is concentrated into for 2.2-3.6, stops heating, standing activation 12-15h under room temperature, it is subsequently adding ammonium carbonate regulation
PH value obtains humic acid liquid a to 6.1-7.3, humic acid liquid a is dry to water content≤6% at 82-104 DEG C, mistake after crushing
100-300 mesh sieve, is obtained humic acid a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Become, be 1 in solid-liquid ratio:14-16, ultrasonic power are 150-170W, and concentration of alcohol is 65%-75%, and Extracting temperature is 62-74
Extract liquid a45-65min, gained liquid a to filter, be concentrated into after water content≤21% to obtain mixture a, gained mixture a at DEG C
Dry to water content≤6% at 86-102 DEG C, after crushing, 100-300 mesh sieve is crossed, Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, mix to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
Example composition, the mixture b is carried out making 1.2-2.6mm particle and is dry to water content≤6% at 86-102 DEG C, be obtained
Organic conditioner.
The invention has the advantages that：
(1) the fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer of the present invention uses water-loss reducer, can strengthen soil water-retaining performance,
Improved soil structure, the deep percolation for reducing water and loss of soil nutrient, raising efficiency of water application；
(2) the fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer of the present invention uses dispersant, can reduce fruit fermentation residue rich
Selenium high calcium environmental protection fertilizer particle and the viscosity of high molecular polymer, can make fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer particle
It is quickly dispersed in water, is conducive to plant absorption；
(3) the fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer of the present invention is had using bleeding agent makes fertilizer efficiency and drug effect synergy
Effect；
(4) the fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer of the present invention can not only effectively preventing disease and pest, and can be all
Weighing apparatus nutrition, promotes paddy rice quickly to grow up healthy and sound, improves paddy rice selenium content and economic worth；
(5) the fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer ecological, environmental protective of the present invention, improves soil environment, to environment nothing
Pollution.
【Specific embodiment】
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the present invention's
Protection domain, but do not limit the scope of the invention.
In an embodiment, the fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, in units of weight portion, including following original
Material：Marc 234-275 part, calcium selenite 43-58 part, calcium chloride 17-21 part, calcium sulfate 12-16 part, calcium nitrate 11-14 part,
Horsehit 33-48 part, duck excrement 27-45 part, goose excrement 22-26 part, earthworm powder 18-30 part, compound bacteria 12-16 part, trace element 2.2-
3.4 parts, organic water retainer 2-4.5 part, dispersant 1.2-2.4 part, organic conditioner 0.9-2 part, bleeding agent 0.8-1.8 part, tune
Section agent 0.6-1 part, tackifier 1-1.8 part, synergist 0.4-0.8 part；
The compound bacteria in units of weight portion, including following raw material：Bacillus 7-14 part, nitrobacteria 5-8 part, aspergillus
Bacterium 3-5 part, saccharomycete 2-4 part, actinomyces 2-4 part, rhizobium 3-6 part, phosphobacteria 2-3.5 part, B. mucilaginocus 2-3.2 part, phosphorus decomposing
Bacterium 1.5-2.8 part；
Described micro- in units of weight portion, including following raw material：Manganese element 0.4-0.8 part, chlorine element 0.4-0.6
Part, ferro element 0.5-0.9 part, Zn-ef ficiency 0.3-0.7 part, boron element 0.4-0.6 part, molybdenum element 0.2-0.4 part；
The dispersant is N- lauroyl glutamate potassium；
The bleeding agent is alkyl sulfate potassium；
The conditioning agent is esters of acrylic acid conditioning agent；
The tackifier are glycidoxy-propyltrimethoxy silane；
The synergist is Octacide 264 diethyl aminoethyl hexanoate；
The preparation method of described fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, comprises the following steps：
S1：By marc, calcium selenite, calcium chloride, calcium sulfate, calcium nitrate, horsehit, duck excrement, goose excrement, earthworm powder, it is combined
Bacterium, trace element, dispersant, bleeding agent, conditioning agent mixing, are 229-368W in ultrasonic power, and temperature is to enter at 52-65 DEG C
Row fermentation, fermentation were obtained zymotic fluid after 4-6 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium carries out at temperature is for 28-32 DEG C activating, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 300-500 part water and mix,
Temperature is at 34-38 DEG C after culture 11-16h, is centrifugation under 3000-5000r/min in rotating speed, compound bacteria is obtained；Described
Biological nutritive agent in units of weight portion, including following raw material：Yeast extract 30-50 part, sodium gluconate 30-45 part, peptone
15-20 part, potassium acetate 15-20 part, sodium phosphate 10-15 part；The biological growth stimulant in units of weight portion, including following
Raw material：Cerous sulfate 30-50 part, aluminum sulfate 20-30 part；
S2：Zymotic fluid standing obtained in step S1 is abandoned precipitation, and remaining ferment liquid is concentrated at 61-67 DEG C, obtain
Concentrate, the concentrate is dry to water content≤6.1% at 65-83 DEG C, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, cross 100-200 mesh sieve after with organic water retainer, organic conditioner,
Tackifier, synergist are mixed, and make 0.3-2.2mm particle, and fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water standing clarification, obtain supernatant, then the supernatant is heated to 92-95 DEG C
Being evaporated concentrating, pH value being concentrated into for 1.8-2.2, stop heating, under room temperature, standing activation 7.2-7.8h, is subsequently adding carbonic acid
Ammonium adjusts pH value to 5.1-5.3, obtains humic acid liquid I, and humic acid liquid I is dry to water content≤8%, powder at 88-102 DEG C
100-300 mesh sieve is crossed after broken, humic acid I is obtained；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios constitute, and are 1 in solid-liquid ratio:12-16, ultrasonic power are 160-180W, second
Determining alcohol is 60%-80%, and Extracting temperature is to extract I 40-60min of liquid at 60-70 DEG C, and gained liquid I filters, be concentrated into and contain
Mixture I is obtained after the water yield≤18%, gained mixture I is dry to water content≤6% at 88-102 DEG C, cross 100- after crushing
300 mesh sieve, are obtained Pesticidal combination I；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, mixes to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios constitute,
The mixture II is carried out making 0.9-2.6mm particle and dry to water content≤6%, prepared organic guarantor at 88-102 DEG C
Aqua；
Described in step S3, the preparation method of organic conditioner, comprises the following steps：
(1) by the waste liquid standing clarification of vinegar factory, supernatant is obtained, then the supernatant is heated to 68-82 DEG C is carried out
Be concentrated by evaporation, pH value is concentrated into for 2.2-3.6, stops heating, standing activation 12-15h under room temperature, it is subsequently adding ammonium carbonate regulation
PH value obtains humic acid liquid a to 6.1-7.3, humic acid liquid a is dry to water content≤6% at 82-104 DEG C, mistake after crushing
100-300 mesh sieve, is obtained humic acid a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Become, be 1 in solid-liquid ratio:14-16, ultrasonic power are 150-170W, and concentration of alcohol is 65%-75%, and Extracting temperature is 62-74
Extract liquid a45-65min, gained liquid a to filter, be concentrated into after water content≤21% to obtain mixture a, gained mixture a at DEG C
Dry to water content≤6% at 86-102 DEG C, after crushing, 100-300 mesh sieve is crossed, Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, mix to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
Example composition, the mixture b is carried out making 1.2-2.6mm particle and is dry to water content≤6% at 86-102 DEG C, be obtained
Organic conditioner.
It is illustrated below by more specifically embodiment.
Embodiment 1
A kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, in units of weight portion, including following raw material：Marc
260 parts, 50 parts of calcium selenite, 18 parts of calcium chloride, 15 parts of calcium sulfate, 14 parts of calcium nitrate, 40 parts of horsehit, 35 parts of duck excrement, goose excrement 25
Part, 25 parts of earthworm powder, 15 parts of compound bacteria, 2.8 parts of trace element, 3.2 parts of organic water retainer, 1.8 parts of dispersant, organic conditioner
1.5 parts, 1.2 parts of bleeding agent, 0.8 part of conditioning agent, 1.4 parts of tackifier, 0.6 part of synergist；
The compound bacteria in units of weight portion, including following raw material：10 parts of Bacillus, 7 parts of nitrobacteria, Aspergillus 4
Part, 3 parts of saccharomycete, 3 parts of actinomyces, 5 parts of rhizobium, 3 parts of phosphobacteria, 2.6 parts of B. mucilaginocus, 2.2 parts of phosphate solubilizing bacteria；
Described micro- in units of weight portion, including following raw material：0.6 part of manganese element, 0.5 part of chlorine element, iron unit
0.7 part of element, 0.5 part of Zn-ef ficiency, 0.5 part of boron element, 0.3 part of molybdenum element；
The dispersant is N- lauroyl glutamate potassium；
The bleeding agent is alkyl sulfate potassium；
The conditioning agent is esters of acrylic acid conditioning agent；
The tackifier are glycidoxy-propyltrimethoxy silane；
The synergist is Octacide 264 diethyl aminoethyl hexanoate；
The preparation method of described fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, comprises the following steps：
S1：By marc, calcium selenite, calcium chloride, calcium sulfate, calcium nitrate, horsehit, duck excrement, goose excrement, earthworm powder, it is combined
Bacterium, trace element, dispersant, bleeding agent, conditioning agent mixing, are 378W in ultrasonic power, and temperature is to be fermented at 69 DEG C,
Fermentation was obtained zymotic fluid after 4 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium temperature be carry out activating at 30 DEG C, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 400 parts of water and mix, in temperature
After culture 14h at 36 DEG C, it is centrifugation under 4000r/min in rotating speed, compound bacteria is obtained；The biological nutritive agent is with weight
Part is unit, including following raw material：40 parts of yeast extract, 36 parts of sodium gluconate, 18 parts of peptone, 18 parts of potassium acetate, sodium phosphate
12 parts；The biological growth stimulant in units of weight portion, including following raw material：40 parts of cerous sulfate, 25 parts of aluminum sulfate；
S2：Zymotic fluid standing obtained in step S1 is abandoned precipitation, and remaining ferment liquid is concentrated at 68 DEG C, concentrated
Thing, it is 7% the concentrate to be dry at 80 DEG C to water content, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, with organic water retainer, organic conditioner, thickening after 150 mesh sieve excessively
Agent, synergist are mixed, and make 1.5mm particle, and fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water standing clarification, obtain supernatant, then the supernatant is heated to 93 DEG C and enters
Row is concentrated by evaporation, and is concentrated into pH value for 2, stops heating, standing activation 7.5h under room temperature, be subsequently adding ammonium carbonate adjust pH value to
5.2, humic acid liquid I is obtained, it is 8% that humic acid liquid I is dry to water content at 95 DEG C, crosses 200 mesh sieve after crushing, is obtained
Humic acid I；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios constitute, and are 1 in solid-liquid ratio:14, ultrasonic power is 170W, and concentration of alcohol is
70%, Extracting temperature is to extract I 50min of liquid at 65 DEG C, and gained liquid I filters, be concentrated into water content for mixing after 18%
Thing I, it is 6% that gained mixture I is dry to water content at 95 DEG C, crosses 200 mesh sieve after crushing, and Pesticidal combination I is obtained；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, mixes to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios constitute,
It is 6% that the mixture II is carried out making 0.9-1mm particle and drying to water content at 95 DEG C, and organic water retainer is obtained；
Described in step S3, the preparation method of organic conditioner, comprises the following steps：
(1) by the waste liquid standing clarification of vinegar factory, supernatant is obtained, then the supernatant is heated to 75 DEG C and is evaporated
Concentrate, it is 3 to be concentrated into pH value, stops heating, standing activation 14h under room temperature, ammonium carbonate regulation pH value is subsequently adding to 6.7, obtains
Humic acid liquid a is obtained, and it is 6% that humic acid liquid a is dry to water content at 95 DEG C, 200 mesh sieve is crossed after crushing, and humic acid is obtained
a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Become, be 1 in solid-liquid ratio:15, ultrasonic power is 160W, and concentration of alcohol is 70%, and Extracting temperature is to extract liquid at 68 DEG C
A55min, gained liquid a filter, be concentrated into water content for after 21% mixture a, gained mixture a are dry extremely at 95 DEG C
Water content is 6%, crosses 100-300 mesh sieve after crushing, and Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, mix to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
Example composition, it is 6% that the mixture b is carried out making 1.2-1.8mm particle and drying to water content at 95 DEG C, is obtained organic
Conditioner.
Embodiment 2
A kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, in units of weight portion, including following raw material：Marc
234 parts, 43 parts of calcium selenite, 17 parts of calcium chloride, 12 parts of calcium sulfate, 11 parts of calcium nitrate, 33 parts of horsehit, 27 parts of duck excrement, goose excrement 22
Part, 18 parts of earthworm powder, 12 parts of compound bacteria, 2.2 parts of trace element, 2 parts of organic water retainer, 1.2 parts of dispersant, organic conditioner
0.9 part, 0.8 part of bleeding agent, 0.6 part of conditioning agent, 1 part of tackifier, 0.4 part of synergist；
The compound bacteria in units of weight portion, including following raw material：7 parts of Bacillus, 5 parts of nitrobacteria, Aspergillus 3
Part, 2 parts of saccharomycete, 2 parts of actinomyces, 3 parts of rhizobium, 2 parts of phosphobacteria, 2 parts of B. mucilaginocus, 1.5 parts of phosphate solubilizing bacteria；
Described micro- in units of weight portion, including following raw material：0.4 part of manganese element, 0.4 part of chlorine element, iron unit
0.5 part of element, 0.3 part of Zn-ef ficiency, 0.4 part of boron element, 0.2 part of molybdenum element；
The dispersant is N- lauroyl glutamate potassium；
The bleeding agent is alkyl sulfate potassium；
The conditioning agent is esters of acrylic acid conditioning agent；
The tackifier are glycidoxy-propyltrimethoxy silane；
The synergist is Octacide 264 diethyl aminoethyl hexanoate；
The preparation method of described fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, comprises the following steps：
S1：By marc, calcium selenite, calcium chloride, calcium sulfate, calcium nitrate, horsehit, duck excrement, goose excrement, earthworm powder, it is combined
Bacterium, trace element, dispersant, bleeding agent, conditioning agent mixing, are 229W in ultrasonic power, and temperature is to be fermented at 52 DEG C,
Fermentation was obtained zymotic fluid after 6 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium temperature be carry out activating at 28 DEG C, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 300 parts of water and mix, in temperature
After culture 16h at 34 DEG C, it is centrifugation under 3000r/min in rotating speed, compound bacteria is obtained；The biological nutritive agent is with weight
Part is unit, including following raw material：30 parts of yeast extract, 30 parts of sodium gluconate, 15 parts of peptone, 15 parts of potassium acetate, sodium phosphate
10 parts；The biological growth stimulant in units of weight portion, including following raw material：30 parts of cerous sulfate, 20 parts of aluminum sulfate；
S2：Zymotic fluid standing obtained in step S1 is abandoned precipitation, and remaining ferment liquid is concentrated at 61 DEG C, concentrated
Thing, it is 5.8% the concentrate to be dry at 65 DEG C to water content, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, with organic water retainer, organic conditioner, thickening after 100 mesh sieve excessively
Agent, synergist are mixed, and make 2.2mm particle, and fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water standing clarification, obtain supernatant, then the supernatant is heated to 92 DEG C and enters
Row is concentrated by evaporation, and it is 1.8 to be concentrated into pH value, stops heating, and standing activation 7.2h under room temperature is subsequently adding ammonium carbonate regulation pH value
To 5.1, humic acid liquid I is obtained, it is 7% that humic acid liquid I is dry to water content at 88 DEG C, after crushing, cross 100 mesh sieve, system
Obtain humic acid I；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios constitute, and are 1 in solid-liquid ratio:12, ultrasonic power is 160W, and concentration of alcohol is
60%, Extracting temperature is to extract I 40min of liquid at 60 DEG C, and gained liquid I filters, be concentrated into water content for mixing after 16%
Thing I, it is 5% that gained mixture I is dry to water content at 88 DEG C, crosses 100 mesh sieve after crushing, and Pesticidal combination I is obtained；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, mixes to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios constitute,
It is 5% that the mixture II is carried out making 1-2.6mm particle and drying to water content at 88 DEG C, and organic water retainer is obtained；
Described in step S3, the preparation method of organic conditioner, comprises the following steps：
(1) by the waste liquid standing clarification of vinegar factory, supernatant is obtained, then the supernatant is heated to 68 DEG C and is evaporated
Concentrate, it is 2.2 to be concentrated into pH value, stops heating, standing activation 15h under room temperature, ammonium carbonate regulation pH value is subsequently adding to 6.1,
Humic acid liquid a is obtained, it is 5% that humic acid liquid a is dry to water content at 82 DEG C, 100 mesh sieve is crossed after crushing, rotten plant is obtained
Sour a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Become, be 1 in solid-liquid ratio:14, ultrasonic power is 150W, and concentration of alcohol is 65%, and Extracting temperature is to extract liquid at 62 DEG C
A65min, gained liquid a filter, be concentrated into water content for after 20% mixture a, gained mixture a are dry extremely at 86 DEG C
Water content is 5%, crosses 100 mesh sieve after crushing, and Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, mix to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
Example composition, it is 4% that the mixture b is carried out making 1.4-2.6mm particle and drying to water content at 86 DEG C, is obtained organic
Conditioner.
Embodiment 3
A kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, in units of weight portion, including following raw material：Marc
275 parts, 58 parts of calcium selenite, 21 parts of calcium chloride, 16 parts of calcium sulfate, 14 parts of calcium nitrate, 48 parts of horsehit, 45 parts of duck excrement, goose excrement 26
Part, 30 parts of earthworm powder, 16 parts of compound bacteria, 3.4 parts of trace element, 4.5 parts of organic water retainer, 2.4 parts of dispersant, organic conditioner
2 parts, 1.8 parts of bleeding agent, 1 part of conditioning agent, 1.8 parts of tackifier, 0.8 part of synergist；
The compound bacteria in units of weight portion, including following raw material：14 parts of Bacillus, 8 parts of nitrobacteria, Aspergillus 5
Part, 4 parts of saccharomycete, 4 parts of actinomyces, 6 parts of rhizobium, 3.5 parts of phosphobacteria, 3.2 parts of B. mucilaginocus, 2.8 parts of phosphate solubilizing bacteria；
Described micro- in units of weight portion, including following raw material：0.8 part of manganese element, 0.6 part of chlorine element, iron unit
0.9 part of element, 0.7 part of Zn-ef ficiency, 0.6 part of boron element, 0.4 part of molybdenum element；
The dispersant is N- lauroyl glutamate potassium；
The bleeding agent is alkyl sulfate potassium；
The conditioning agent is esters of acrylic acid conditioning agent；
The tackifier are glycidoxy-propyltrimethoxy silane；
The synergist is Octacide 264 diethyl aminoethyl hexanoate；
The preparation method of described fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, comprises the following steps：
S1：By marc, calcium selenite, calcium chloride, calcium sulfate, calcium nitrate, horsehit, duck excrement, goose excrement, earthworm powder, it is combined
Bacterium, trace element, dispersant, bleeding agent, conditioning agent mixing, are 368W in ultrasonic power, and temperature is to be fermented at 65 DEG C,
Fermentation was obtained zymotic fluid after 4 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, solution
Phosphorus bacterium temperature be carry out activating at 32 DEG C, Amplification Culture, with standby；
B, by the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 500 parts of water and mix, in temperature
After culture 11h at 38 DEG C, it is centrifugation under 5000r/min in rotating speed, compound bacteria is obtained；The biological nutritive agent is with weight
Part is unit, including following raw material：50 parts of yeast extract, 45 parts of sodium gluconate, 20 parts of peptone, 20 parts of potassium acetate, sodium phosphate
15 parts；The biological growth stimulant in units of weight portion, including following raw material：50 parts of cerous sulfate, 30 parts of aluminum sulfate；
S2：Zymotic fluid standing obtained in step S1 is abandoned precipitation, and remaining ferment liquid is concentrated at 67 DEG C, concentrated
Thing, it is 5.3% the concentrate to be dry at 83 DEG C to water content, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, with organic water retainer, organic conditioner, thickening after 200 mesh sieve excessively
Agent, synergist are mixed, and make 2.2mm particle, and fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water standing clarification, obtain supernatant, then the supernatant is heated to 95 DEG C and enters
Row is concentrated by evaporation, and it is 2.2 to be concentrated into pH value, stops heating, and standing activation 7.8h under room temperature is subsequently adding ammonium carbonate regulation pH value
To 5.3, humic acid liquid I is obtained, it is 6% that humic acid liquid I is dry to water content at 102 DEG C, 300 mesh sieve is crossed after crushing,
Prepared humic acid I；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding,
The cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe are pressed in units of weight portion
35:35:35:35:35:35:25:25:25 ratios constitute, and are 1 in solid-liquid ratio:16, ultrasonic power is 180W, and concentration of alcohol is
80%, Extracting temperature is to extract I 40min of liquid at 70 DEG C, and gained liquid I filters, be concentrated into water content for mixing after 14%
Thing I, it is 5% that gained mixture I is dry to water content at 102 DEG C, crosses 300 mesh sieve after crushing, and Pesticidal combination I is obtained；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and steaming obtained in humic acid I, step B obtained in step A respectively
Distilled water, mixes to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid
Ith, Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios constitute,
It is 4% that the mixture II is carried out making 1-2.6mm particle and drying to water content at 102 DEG C, and organic water retainer is obtained；
Described in step S3, the preparation method of organic conditioner, comprises the following steps：
(1) by the waste liquid standing clarification of vinegar factory, supernatant is obtained, then the supernatant is heated to 82 DEG C and is evaporated
Concentrate, it is 3.6 to be concentrated into pH value, stops heating, standing activation 12h under room temperature, ammonium carbonate regulation pH value is subsequently adding to 7.3,
Humic acid liquid a is obtained, and it is 4% that humic acid liquid a is dry to water content at 104 DEG C, 300 mesh sieve is crossed after crushing, and corruption is obtained
Phytic acid a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, cigarette
Grass, leaf of Pterocarya Stenoptera co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum,
Sabadilla, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratio groups
Become, be 1 in solid-liquid ratio:16, ultrasonic power is 170W, and concentration of alcohol is 75%, and Extracting temperature is to extract liquid at 74 DEG C
A45min, gained liquid a filter, be concentrated into water content for after 17% mixture a, gained mixture a are dry extremely at 102 DEG C
Water content is 4%, crosses 300 mesh sieve after crushing, and Pesticidal combination a is obtained；
(3) weigh respectively humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner,
Mould inhibitor a and distilled water, mix to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, described
Humic acid a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratios
Example composition, it is 4% that the mixture b is carried out making 1.8-2.6mm particle and drying to water content at 102 DEG C, and being obtained has
Machine conditioner.
For verifying the effect of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer of the present invention, by following experimental verification.
The basically identical paddy rice ground of six block specifications is chosen in certain agricultural base, be set to paddy rice ground a, paddy rice ground b, paddy rice ground c,
Paddy rice ground d, paddy rice ground e, paddy rice ground f, plant paddy rice on six pieces of ground, and wherein paddy rice ground a, paddy rice ground b, paddy rice ground c are using commonly having
Machine fertilizer, paddy rice ground d, paddy rice ground e, paddy rice ground fruit fermentation residue selenium-enriched high-calcium environmental protection of the f respectively using embodiment 1,2,3 are organic
Fertilizer, is calculated with per mu of fertilising 50kg, observes the paddy growth situation on six pieces of paddy rice ground.As a result show：Paddy rice ground a, paddy rice ground b,
Rice plant gloss difference that paddy rice ground c kind is planted, unhealthy, the speed of growth is slow, and plant is little, yields poorly, and paddy rice ground d, paddy rice ground
Rice plant good luster that e, paddy rice ground f kind are planted, health, fast growth, plant are big, and yield is high, and are not produced using the present invention
Compare to the paddy rice of product, per mu of volume increase 347.34-432.47kg, improve 20-57 times of Se content, and the water using product of the present invention
Pest and disease damage in rice field does not have substantially, it is seen that the fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer of the present invention effectively can not only be prevented
Pest and disease damage, and energy nutrition is balanced, improves soil environment, promotes paddy rice quickly to grow up healthy and sound, shortens growth cycle, improves paddy rice
Yield and selenium content.
Above content it cannot be assumed that the present invention is embodied as being confined to these explanations, for the technical field of the invention
Those of ordinary skill for, under the premise of without departing from present inventive concept, some simple deduction or replace can also be made, all answered
When being considered as belonging to the scope of patent protection that the present invention is determined by the claims that is submitted to.
Claims (10)
1. a kind of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer, it is characterised in that in units of weight portion, including following original
Material：Marc 234-275 part, calcium selenite 43-58 part, calcium chloride 17-21 part, calcium sulfate 12-16 part, calcium nitrate 11-14 part,
Horsehit 33-48 part, duck excrement 27-45 part, goose excrement 22-26 part, earthworm powder 18-30 part, compound bacteria 12-16 part, trace element 2.2-
3.4 parts, organic water retainer 2-4.5 part, dispersant 1.2-2.4 part, organic conditioner 0.9-2 part, bleeding agent 0.8-1.8 part, tune
Section agent 0.6-1 part, tackifier 1-1.8 part, synergist 0.4-0.8 part.
2. fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer according to claim 1, it is characterised in that the compound bacteria with
Weight portion is unit, including following raw material：Bacillus 7-14 part, nitrobacteria 5-8 part, Aspergillus 3-5 part, saccharomycete 2-4 part,
Actinomyces 2-4 part, rhizobium 3-6 part, phosphobacteria 2-3.5 part, B. mucilaginocus 2-3.2 part, phosphate solubilizing bacteria 1.5-2.8 part.
3. fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer according to claim 1, it is characterised in that the trace element
In units of weight portion, including following raw material：Manganese element 0.4-0.8 part, chlorine element 0.4-0.6 part, ferro element 0.5-0.9 part,
Zn-ef ficiency 0.3-0.7 part, boron element 0.4-0.6 part, molybdenum element 0.2-0.4 part.
4. fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer according to claim 1, it is characterised in that the dispersant is
N- lauroyl glutamate potassium.
5. fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer according to claim 1, it is characterised in that the bleeding agent is
Alkyl sulfate potassium.
6. fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer according to claim 1, it is characterised in that the conditioning agent is
Esters of acrylic acid conditioning agent.
7. fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer according to claim 1, it is characterised in that the tackifier are
Glycidoxy-propyltrimethoxy silane.
8. fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer according to claim 1, it is characterised in that the synergist is
Octacide 264 diethyl aminoethyl hexanoate.
9. a kind of preparation method of the fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer according to any one of claim 1-8,
Characterized in that, comprising the following steps：
S1：By marc, calcium selenite, calcium chloride, calcium sulfate, calcium nitrate, horsehit, duck excrement, goose excrement, earthworm powder, compound bacteria, micro-
Secondary element, dispersant, bleeding agent, conditioning agent mixing, are 229-368W in ultrasonic power, and temperature is to carry out sending out at 52-65 DEG C
Ferment, fermentation were obtained zymotic fluid after 4-6 days；
The preparation method of compound bacteria described in step S1, comprises the following steps：
A, respectively by Bacillus, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphobacteria, B. mucilaginocus, phosphate solubilizing bacteria
Carry out at temperature is for 28-32 DEG C activating, Amplification Culture, with standby；
B, will be thin to the Bacillus after step a Amplification Culture, nitrobacteria, Aspergillus, saccharomycete, actinomyces, rhizobium, phosphorus
Bacterium, B. mucilaginocus, phosphate solubilizing bacteria mix and add biological growth stimulant, biological nutritive agent, 300-500 part water and mix, in temperature
Spend for, after culture 11-16h at 34-38 DEG C, being centrifugation under 3000-5000r/min in rotating speed, compound bacteria is obtained；The life
Thing nutritional agents in units of weight portion, including following raw material：Yeast extract 30-50 part, sodium gluconate 30-45 part, peptone 15-
20 parts, potassium acetate 15-20 part, sodium phosphate 10-15 part；The biological growth stimulant in units of weight portion, including following original
Material：Cerous sulfate 30-50 part, aluminum sulfate 20-30 part；
S2：Zymotic fluid standing obtained in step S1 is abandoned precipitation, and remaining ferment liquid is concentrated at 61-67 DEG C, concentrated
Thing, the concentrate is dry to water content≤6.1% at 65-83 DEG C, and mixture is obtained；
S3：Mixture obtained in step S2 is crushed, with organic water retainer, organic conditioner, thickening excessively after 100-200 mesh sieve
Agent, synergist are mixed, and make 0.3-2.2mm particle, and fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer is obtained；
The preparation method of organic water retainer described in step S3, comprises the following steps：
A, by starch industry production waste water standing clarification, obtain supernatant, then the supernatant is heated to 92-95 DEG C is carried out
Be concentrated by evaporation, pH value is concentrated into for 1.8-2.2, stops heating, standing activation 7.2-7.8h under room temperature, it is subsequently adding ammonium carbonate tune
Section pH value obtains humic acid liquid I to 5.1-5.3, humic acid liquid I is dry to water content≤8% at 88-102 DEG C, after crushing
100-300 mesh sieve is crossed, humic acid I is obtained；
B, by cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe co-grinding, described
Cacumen biotae, peppermint, lettuce, Herba Anabasis aphyllae, paulownia leaves, Sophora alopecuroide, absinth, yellow ginger, aloe press 35 in units of weight portion:
35:35:35:35:35:25:25:25 ratios constitute, and are 1 in solid-liquid ratio:12-16, ultrasonic power are 160-180W, and ethanol is dense
Spend for 60%-80%, Extracting temperature is to extract I 40-60min of liquid at 60-70 DEG C, and gained liquid I is filtered, is concentrated into water content
Mixture I is obtained after≤18%, gained mixture I is dry to water content≤6% at 88-102 DEG C, cross 100-300 mesh after crushing
Sieve, is obtained Pesticidal combination I；
C, weigh Pesticidal combination I, water-loss reducer, mould inhibitor and distillation obtained in humic acid I, step B obtained in step A respectively
Water, mixes to obtain mixture II, and the water-loss reducer is polybutene acid ammonium, and the mould inhibitor is quinoxyfen, the humic acid I,
Pesticidal combination I, water-loss reducer, mould inhibitor and distilled water press 32 in units of weight portion:0.04:38:0.09:8 ratios constitute, will
The mixture II is carried out making 0.9-2.6mm particle and is dry to water content≤6% at 88-102 DEG C, and organic water conservation is obtained
Agent.
10. the preparation method of fruit fermentation residue selenium-enriched high-calcium environmental protection fertilizer according to claim 9, it is characterised in that
Described in step S3, the preparation method of organic conditioner, comprises the following steps：
(1) by the waste liquid standing clarification of vinegar factory, supernatant is obtained, then the supernatant is heated to 68-82 DEG C and is evaporated
Concentrate, pH value is concentrated into for 2.2-3.6, stops heating, standing activation 12-15h under room temperature, it is subsequently adding ammonium carbonate and adjusts pH value
To 6.1-7.3, humic acid liquid a is obtained, humic acid liquid a is dry to water content≤6% at 82-104 DEG C, after crushing, cross 100-
300 mesh sieve, are obtained humic acid a；
(2) will print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, sabadilla, tobacco, maple
Poplar leaves co-grinding, the print chinaberry, the bark of ash, kuh-seng, Roots of Euphorbia soongarica, tea free, datura, Dalmatian chrysanthemum, capsicum, Sabah lamb's-quarters
Reed, tobacco, leaf of Pterocarya Stenoptera press 32 in units of weight portion:32:32:32:32:30:24:24:23:20:20 ratios constitute, in material
Liquor ratio is 1:14-16, ultrasonic power are 150-170W, and concentration of alcohol is 65%-75%, and Extracting temperature is to carry at 62-74 DEG C
Taking liquid a45-65min, gained liquid a filter, is concentrated into after water content≤21% to obtain mixture a, and gained mixture a is in 86-
Dry to water content≤6% at 102 DEG C, after crushing, 100-300 mesh sieve is crossed, Pesticidal combination a is obtained；
(3) humic acid a obtained in step (1), Pesticidal combination a obtained in step (2), soil conditioner, mould proof is weighed respectively
Agent a and distilled water, mix to obtain mixture b, and the conditioner is earthworm powder, and the mould inhibitor a is triazolone, the rotten plant
Sour a, Pesticidal combination a, conditioner, mould inhibitor a and distilled water press 30 in units of weight portion:0.05:35:0.07:6 ratio groups
Become, the mixture b is carried out making 1.2-2.6mm particle and is dry to water content≤6% at 86-102 DEG C, be obtained organic
Conditioner.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107188634A (en) * | 2017-05-24 | 2017-09-22 | 桂永帅 | A kind of production method of selenium-enriched high-calcium large-fruited Chinese hawthorn |
| CN107311780A (en) * | 2017-08-18 | 2017-11-03 | 广西南宁桂启科技发展有限公司 | A kind of common property culture medium, preparation method and applications |
| CN107337541A (en) * | 2017-08-18 | 2017-11-10 | 广西南宁桂启科技发展有限公司 | A kind of culture medium for golden mushroom and its method for coproduction asparagus and roxburgh anoectochilus terminal bud |
| CN107473818A (en) * | 2017-08-18 | 2017-12-15 | 广西南宁桂启科技发展有限公司 | A kind of culture medium and its application in asparagus and roxburgh anoectochilus terminal bud cultivation |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105967919A (en) * | 2016-08-01 | 2016-09-28 | 韦波 | Potato organic fertilizer |
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2016
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105967919A (en) * | 2016-08-01 | 2016-09-28 | 韦波 | Potato organic fertilizer |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107188634A (en) * | 2017-05-24 | 2017-09-22 | 桂永帅 | A kind of production method of selenium-enriched high-calcium large-fruited Chinese hawthorn |
| CN107311780A (en) * | 2017-08-18 | 2017-11-03 | 广西南宁桂启科技发展有限公司 | A kind of common property culture medium, preparation method and applications |
| CN107337541A (en) * | 2017-08-18 | 2017-11-10 | 广西南宁桂启科技发展有限公司 | A kind of culture medium for golden mushroom and its method for coproduction asparagus and roxburgh anoectochilus terminal bud |
| CN107473818A (en) * | 2017-08-18 | 2017-12-15 | 广西南宁桂启科技发展有限公司 | A kind of culture medium and its application in asparagus and roxburgh anoectochilus terminal bud cultivation |
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