CN106479740A - 一种环保型皮革清洗剂及其制备方法 - Google Patents

一种环保型皮革清洗剂及其制备方法 Download PDF

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CN106479740A
CN106479740A CN201610781101.6A CN201610781101A CN106479740A CN 106479740 A CN106479740 A CN 106479740A CN 201610781101 A CN201610781101 A CN 201610781101A CN 106479740 A CN106479740 A CN 106479740A
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姜培育
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ANHUI GALAXY LEATHER Co Ltd
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Abstract

本发明公开一种环保型皮革清洗剂，由以下重量份的原料组成：蓖麻油聚氧乙烯醚8‑12份、脂肪胺聚氧乙烯醚6‑10份、山梨醇脂肪酸酯3‑5份、烷基酚聚氧乙烯醚1‑3份、棕榈蜡1‑2份、固色剂0.5‑1份、甲基丙烯酸甲酯0.2‑1份、聚乙二醇1.7‑3.8份、异丙醇2‑3份、抗氧剂0.1‑0.5份、氨基甘油1‑5份、其它助剂1‑2份。本发明采用蓖麻油聚氧乙烯醚、脂肪胺聚氧乙烯醚、山梨醇脂肪酸酯、烷基酚聚氧乙烯醚之间具有复配作用，效果优于单一表面活性剂；加入固色剂，配合氨基甘油，具有很好的固色作用，在多次清洗的情况下，皮革仍然保持原来的颜色，延长皮革使用寿命；本发明清洗剂安全无毒，绿色环保。

Description

一种环保型皮革清洗剂及其制备方法
技术领域
本发明涉及皮革清洁技术领域，具体是一种环保型皮革清洗剂及其制备方法。
背景技术
皮革是经脱毛和鞣质等物理、化学加工所得到的已经变性且不易腐烂的动物皮，具有自然的粒纹和光泽，手感舒适，其包括生活用革，如用于制作服装和箱包等生活用品的皮革、国防用革、工农业用革和文化体育用品革等。在生活用革等皮革应用中，为了达到增加装饰效果等目的，经染料或颜料染色的有色皮革常被广泛使用。
目前，通常采用皮革清洗剂清洗皮革。现有的皮革清洗剂主要由洗涤剂和溶剂组成，对皮革具有一定的去污、去垢、除脂、去渍等作用，但是，有色皮革在清洗后，或多或少都存在染料或颜料被溶解的现象，从而导致有色皮革掉色或颜色变浅、变旧。在染料或颜料的色牢度较好的情况下，单次清洗的掉色现象通常肉眼可忽略不计，并不影响有色皮革的整体颜色；但是当清洗频率较高时，或者清洗次数累计到一定数量时，有色皮革表现为整体掉色或颜色变浅、变旧，直至皮革洗旧报废。虽然可以将变旧的有色皮革进行涂饰翻新，但在翻新次数稍多后，皮革的皮面上就会积累成很厚的涂层，从而失去原有的粒面的风格，犹如人造革，且皮面变厚变硬，甚至报废。
发明内容
本发明的目的在于提供一种环保型皮革清洗剂及其制备方法。
本发明的目的可以通过以下技术方案实现：
一种环保型皮革清洗剂，由以下重量份的原料组成：蓖麻油聚氧乙烯醚8-12份、脂肪胺聚氧乙烯醚6-10份、山梨醇脂肪酸酯3-5份、烷基酚聚氧乙烯醚1-3份、棕榈蜡1-2份、固色剂0.5-1份、甲基丙烯酸甲酯0.2-1份、聚乙二醇1.7-3.8份、异丙醇2-3份、抗氧剂0.1-0.5份、氨基甘油1-5份、其它助剂1-2份。
进一步方案，所述抗氧剂为2，6-三级丁基-4-甲基苯酚、双(3，5-三级丁基-4-羟基苯基)硫醚、四〔β-(3，5-三级丁基-4-羟基苯基)丙酸〕季戊四醇酯中的一种。
进一步方案，所述固色剂为氯化十六烷基吡啶。
进一步方案，所述其它助剂为消泡剂、流平剂、抗菌剂中的至少一种。
本发明还提供一种环保型皮革清洗剂的制备方法，包括以下步骤：
(1)将棕榈蜡、甲基丙烯酸甲酯、聚乙二醇、异丙醇混合均匀；
(2)依次加入蓖麻油聚氧乙烯醚、脂肪胺聚氧乙烯醚、山梨醇脂肪酸酯、烷基酚聚氧乙烯醚，在500r/min转速下搅拌20min；
(3)最后加入氨基甘油、固色剂、抗氧剂、其它助剂，升温至50-60℃，保温2h，冷却至室温，得环保型皮革清洗剂。
本发明的有益效果：本发明采用蓖麻油聚氧乙烯醚、脂肪胺聚氧乙烯醚、山梨醇脂肪酸酯、烷基酚聚氧乙烯醚之间具有复配作用，效果优于单一表面活性剂；加入固色剂，配合氨基甘油，具有很好的固色作用，在多次清洗的情况下，皮革仍然保持原来的颜色，延长皮革使用寿命；本发明清洗剂安全无毒，绿色环保。
具体实施方式
下面结合具体实施例对本发明作进一步详细描述。
实施例1
将棕榈蜡1kg、甲基丙烯酸甲酯0.2kg、聚乙二醇1.7kg、异丙醇2kg混合均匀；
依次加入蓖麻油聚氧乙烯醚8kg、脂肪胺聚氧乙烯醚10kg、山梨醇脂肪酸酯3kg、烷基酚聚氧乙烯醚1kg，在500r/min转速下搅拌20min；
最后加入氨基甘油1kg、固色剂氯化十六烷基吡啶0.5kg、抗氧剂2，6-三级丁基-4-甲基苯酚0.1kg、消泡剂1kg，升温至50-60℃，保温2h，冷却至室温，得环保型皮革清洗剂。
实施例2
将棕榈蜡1.5kg、甲基丙烯酸甲酯0.6kg、聚乙二醇2.4kg、异丙醇2.5kg混合均匀；
依次加入蓖麻油聚氧乙烯醚10kg、脂肪胺聚氧乙烯醚6kg、山梨醇脂肪酸酯4kg、烷基酚聚氧乙烯醚2kg，在500r/min转速下搅拌20min；
最后加入氨基甘油3kg、固色剂氯化十六烷基吡啶0.8kg、抗氧剂双(3，5-三级丁基-4-羟基苯基)硫醚0.3kg、消泡剂1kg、抗菌剂1kg，升温至50-60℃，保温2h，冷却至室温，得环保型皮革清洗剂。
实施例3
将棕榈蜡2kg、甲基丙烯酸甲酯1kg、聚乙二醇3.8kg、异丙醇3kg混合均匀；
依次加入蓖麻油聚氧乙烯醚12kg、脂肪胺聚氧乙烯醚8kg、山梨醇脂肪酸酯5kg、烷基酚聚氧乙烯醚3kg，在500r/min转速下搅拌20min；
最后加入氨基甘油5kg、固色剂氯化十六烷基吡啶1kg、抗氧剂四〔β-(3，5-三级丁基-4-羟基苯基)丙酸〕季戊四醇酯0.5kg、流平剂0.5份、抗菌剂1kg，升温至50-60℃，保温2h，冷却至室温，得环保型皮革清洗剂。
上述的对实施例的描述是为便于该技术领域的普通技术人员能理解和应用本发明。熟悉本领域技术的人员显然可以容易地对实施案例做出各种修改，并把在此说明的一般原理应用到其他实施例中而不必经过创造性的劳动。因此，本发明不限于这里的实施案例，本领域技术人员根据本发明的揭示，不脱离本发明范畴所做出的改进和修改都应该在本发明的保护范围之内。

Claims (5)

1.一种环保型皮革清洗剂，其特征在于，由以下重量份的原料组成：蓖麻油聚氧乙烯醚8-12份、脂肪胺聚氧乙烯醚6-10份、山梨醇脂肪酸酯3-5份、烷基酚聚氧乙烯醚1-3份、棕榈蜡1-2份、固色剂0.5-1份、甲基丙烯酸甲酯0.2-1份、聚乙二醇1.7-3.8份、异丙醇2-3份、抗氧剂0.1-0.5份、氨基甘油1-5份、其它助剂1-2份。
2.根据权利要求1所述的环保型皮革清洗剂，其特征在于，所述抗氧剂为2，6-三级丁基-4-甲基苯酚、双(3，5-三级丁基-4-羟基苯基)硫醚、四〔β-(3，5-三级丁基-4-羟基苯基)丙酸〕季戊四醇酯中的一种。
3.根据权利要求1所述的环保型皮革清洗剂，其特征在于，所述固色剂为氯化十六烷基吡啶。
4.根据权利要求1所述的环保型皮革清洗剂，其特征在于，所述其它助剂为消泡剂、流平剂、抗菌剂中的至少一种。
5.一种制备如权利要求1-3任一项所述的环保型皮革清洗剂的方法，其特征在于，包括以下步骤：
(1)将棕榈蜡、甲基丙烯酸甲酯、聚乙二醇、异丙醇混合均匀；
(2)依次加入蓖麻油聚氧乙烯醚、脂肪胺聚氧乙烯醚、山梨醇脂肪酸酯、烷基酚聚氧乙烯醚，在500r/mi n转速下搅拌20mi n；
(3)最后加入氨基甘油、固色剂、抗氧剂、其它助剂，升温至50-60℃，保温2h，冷却至室温，得环保型皮革清洗剂。
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Cited By (2)

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CN107034698A (zh) * 2017-04-25 2017-08-11 江西展邦科技有限公司 一种适用于合成革的水性湿法用固色剂
CN107502466A (zh) * 2017-08-31 2017-12-22 太仓雄鹰皮具有限公司 一种皮革制品用环保清香无刺激清洗剂及其制备方法

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