CN106410159A - 一种聚苯胺凝胶包覆锡铜纳米管复合材料的制备方法 - Google Patents
一种聚苯胺凝胶包覆锡铜纳米管复合材料的制备方法 Download PDFInfo
- Publication number
- CN106410159A CN106410159A CN201610983553.2A CN201610983553A CN106410159A CN 106410159 A CN106410159 A CN 106410159A CN 201610983553 A CN201610983553 A CN 201610983553A CN 106410159 A CN106410159 A CN 106410159A
- Authority
- CN
- China
- Prior art keywords
- tin
- solution
- copper
- polyaniline
- nanotube
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 239000002071 nanotube Substances 0.000 title claims abstract description 40
- 229920000767 polyaniline Polymers 0.000 title claims abstract description 32
- 239000002131 composite material Substances 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 25
- 239000000126 substance Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 26
- 239000000463 material Substances 0.000 claims description 25
- 239000008367 deionised water Substances 0.000 claims description 22
- 229910021641 deionized water Inorganic materials 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 18
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 16
- 235000014121 butter Nutrition 0.000 claims description 12
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 10
- 238000003760 magnetic stirring Methods 0.000 claims description 9
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 239000012279 sodium borohydride Substances 0.000 claims description 7
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 6
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- XWULEGJMNMPRCI-UHFFFAOYSA-N [bis(phosphonooxymethyl)amino]methyl dihydrogen phosphate Chemical compound OP(O)(=O)OCN(COP(O)(O)=O)COP(O)(O)=O XWULEGJMNMPRCI-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 230000004044 response Effects 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract description 21
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 21
- 229920001940 conductive polymer Polymers 0.000 abstract description 11
- 239000007772 electrode material Substances 0.000 abstract description 10
- 238000007599 discharging Methods 0.000 abstract description 8
- 238000011065 in-situ storage Methods 0.000 abstract description 7
- 239000003638 chemical reducing agent Substances 0.000 abstract description 6
- 239000002322 conducting polymer Substances 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 6
- 238000006722 reduction reaction Methods 0.000 abstract description 6
- 239000011159 matrix material Substances 0.000 abstract description 2
- 238000005054 agglomeration Methods 0.000 abstract 1
- 230000002776 aggregation Effects 0.000 abstract 1
- 239000006185 dispersion Substances 0.000 abstract 1
- 239000007773 negative electrode material Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 48
- 238000005253 cladding Methods 0.000 description 15
- 239000000047 product Substances 0.000 description 10
- 238000001291 vacuum drying Methods 0.000 description 8
- 239000011149 active material Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 6
- 230000000379 polymerizing effect Effects 0.000 description 6
- 230000005540 biological transmission Effects 0.000 description 5
- 238000011549 displacement method Methods 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000006073 displacement reaction Methods 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- -1 methylene tri phosphoric acid Chemical compound 0.000 description 4
- 229940048102 triphosphoric acid Drugs 0.000 description 4
- GFLJTEHFZZNCTR-UHFFFAOYSA-N 3-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OCCCOC(=O)C=C GFLJTEHFZZNCTR-UHFFFAOYSA-N 0.000 description 3
- 239000010406 cathode material Substances 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 239000006258 conductive agent Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 3
- 229910001290 LiPF6 Inorganic materials 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000011889 copper foil Substances 0.000 description 2
- 238000000840 electrochemical analysis Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 229940021013 electrolyte solution Drugs 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 229920000128 polypyrrole Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000011366 tin-based material Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/387—Tin or alloys based on tin
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
- H01M4/602—Polymers
- H01M4/606—Polymers containing aromatic main chain polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Nanotechnology (AREA)
- Composite Materials (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
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CN201610983553.2A CN106410159B (zh) | 2016-11-09 | 2016-11-09 | 一种聚苯胺凝胶包覆锡铜纳米管复合材料的制备方法 |
Applications Claiming Priority (1)
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CN201610983553.2A CN106410159B (zh) | 2016-11-09 | 2016-11-09 | 一种聚苯胺凝胶包覆锡铜纳米管复合材料的制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN106410159A true CN106410159A (zh) | 2017-02-15 |
CN106410159B CN106410159B (zh) | 2019-07-19 |
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CN201610983553.2A Active CN106410159B (zh) | 2016-11-09 | 2016-11-09 | 一种聚苯胺凝胶包覆锡铜纳米管复合材料的制备方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019114373A1 (zh) * | 2017-12-12 | 2019-06-20 | 中国科学院物理研究所 | 一种复合包覆的纳米锡负极材料及其制备方法和应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102244254A (zh) * | 2011-06-17 | 2011-11-16 | 天津大学 | 一种中空纳米线-聚合物膜核壳结构复合材料及其制备方法 |
CN105295038A (zh) * | 2015-11-05 | 2016-02-03 | 天津大学 | 导电聚苯胺凝胶的制备方法及其在超级电容器中的应用 |
-
2016
- 2016-11-09 CN CN201610983553.2A patent/CN106410159B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102244254A (zh) * | 2011-06-17 | 2011-11-16 | 天津大学 | 一种中空纳米线-聚合物膜核壳结构复合材料及其制备方法 |
CN105295038A (zh) * | 2015-11-05 | 2016-02-03 | 天津大学 | 导电聚苯胺凝胶的制备方法及其在超级电容器中的应用 |
Non-Patent Citations (2)
Title |
---|
PING WU 等: "Solvothermal synthesis of carbon-coated tin nanorods for superior reversible lithium ion storage", 《MATERIALS RESEARCH BULLETIN》 * |
范欣: "锡/聚吡咯三维纳米结构锂离子电池负极材料的制备及稳定性研究", 《万方数据知识服务平台》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019114373A1 (zh) * | 2017-12-12 | 2019-06-20 | 中国科学院物理研究所 | 一种复合包覆的纳米锡负极材料及其制备方法和应用 |
US11362328B2 (en) | 2017-12-12 | 2022-06-14 | Institute Of Physics, Chinese Academy Of Sciences | Composite-coated nano-tin negative electrode material and preparation method and use thereof |
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Publication number | Publication date |
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CN106410159B (zh) | 2019-07-19 |
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Application publication date: 20170215 Assignee: Tianjin aisida New Material Technology Co.,Ltd. Assignor: Beijing Legend Yousheng Culture Media Co.,Ltd. Contract record no.: X2023980040791 Denomination of invention: A preparation method of polyaniline gel coated tin copper nanotube composite Granted publication date: 20190719 License type: Common License Record date: 20230829 |
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Application publication date: 20170215 Assignee: TIANJIN ZHUJIN TECHNOLOGY DEVELOPMENT Corp. Assignor: Beijing Legend Yousheng Culture Media Co.,Ltd. Contract record no.: X2024980004064 Denomination of invention: A preparation method of polyaniline gel coated tin copper nanotube composite Granted publication date: 20190719 License type: Common License Record date: 20240408 |
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