CN106396382A - Colorful glazed porcelain prepared from limestone tailings, and manufacture technology thereof - Google Patents
Colorful glazed porcelain prepared from limestone tailings, and manufacture technology thereof Download PDFInfo
- Publication number
- CN106396382A CN106396382A CN201610796119.3A CN201610796119A CN106396382A CN 106396382 A CN106396382 A CN 106396382A CN 201610796119 A CN201610796119 A CN 201610796119A CN 106396382 A CN106396382 A CN 106396382A
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- Prior art keywords
- parts
- glaze
- wanziqianhong
- limestone
- tailing
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Adornments (AREA)
Abstract
The invention belongs to the technical field of ceramic production, and particularly relates to colorful glazed porcelain prepared from limestone tailings, and a manufacture technology thereof. The colorful glazed porcelain prepared from the limestone tailings comprises a ceramic green body and colorful glaze arranged on the ceramic green body, wherein the colorful glaze is prepared from calcined limestone tailings powder, quartz, purple clay, nickel oxide, zirconium silicate powder, talcum, lead silicate, titanium oxide, lithium carbonate, iron sesquioxide, copper oxide and manganese oxide. The desert glazed porcelain prepared from the limestone tailings is characterized in that the glaze of the porcelain is unglazed, a bottom color is red, purple is developed from the red bottom color, particles are evenly distributed on the glaze, and the hand feeling of the glaze is rough so as to give deep starry sky feeling for people. The colorful glazed porcelain is prepared from the limestone tailings, waste materials are used, energy consumption is reduced, and the colorful glazed porcelain has a significant social and environmentally-friendly meaning, and conforms to the circular economy developing mode of a city.
Description
Technical field
The invention belongs to technical field of ceramic production and in particular to a kind of utilization limestone tailing preparation WANZIQIANHONG glaze
Porcelain and its processing technology.
Background technology
Developing rapidly with ceramics, limestone is exploited in a large number and is utilized, the annual waste limestone producing nearly hundred tons
Mine tailing, mining peel off these waste residue material of mine tailing include barren rock, mine tailing, crumb powder etc., and limestone cover layer, interlayer,
Mountain skin soil, crack soil etc..These waste residues after exploitation, had both taken stockyard arable land, and had caused secondary environmental pollution, waste preciousness again
Non-renewable mineral resources, there is production safety and environmental protection accident potential, had a strong impact on agricultural and people's lives and properties
Safety, greatly waste mineral resources, again destroy ecological environment.
Therefore, the comprehensive utilization of waste limestone mine tailing is essential, also becomes the weight that Production of Ceramics producer faces
Hang-up.
Content of the invention
In order to solve the above problems, the invention provides a kind of WANZIQIANHONG glaze porcelain of utilization limestone tailing preparation.
For achieving the above object, the invention provides utilizing the WANZIQIANHONG glaze porcelain of limestone tailing preparation, its
It is characterised by, including ceramic body and the WANZIQIANHONG glaze being arranged on ceramic body, described WANZIQIANHONG glaze is according to weight portion
Meter is as follows：Calcined limestone mine tailing powder 30-40, quartzy 10-15 part, Red Stone Ware 10-15 part, nickel oxide 5-10 part, Zirconium orthosilicate.
Powder 5-10 part, Talcum 5-10 part, lead silicate 1-5 part, titanium oxide 1-5 part, lithium carbonate 1-5 part, iron sesquioxide 1-5 part, oxygen
Change copper 1-5, manganese oxide 1-5 part.
Optimize, WANZIQIANHONG glaze is as follows in parts by weight：Calcined limestone mine tailing powder 38, quartzy 11 parts, boccaro
14 parts of soil, 5 parts of nickel oxide, 9 parts of Zirconium orthosilicate. powder, 6 parts of Talcum, 2 parts of lead silicate, 5 parts of titanium oxide, 2 parts of lithium carbonate, three oxidations two
4 parts of ferrum, copper oxide 3,1 part of manganese oxide.
Optimize, WANZIQIANHONG glaze is as follows in parts by weight：Calcined limestone mine tailing powder 33, quartzy 13 parts, boccaro
Soil 14 parts, 8 parts of nickel oxide, 9 parts of Zirconium orthosilicate. powder, 5 parts of Talcum, 3 parts of lead silicate, 3 parts of titanium oxide, 3 parts of lithium carbonate, three oxidation
Two 2 parts of ferrum, copper oxide 3,4 parts of manganese oxide.
Optimize, WANZIQIANHONG glaze is as follows in parts by weight：Calcined limestone mine tailing powder 35, quartzy 14 parts, boccaro
12 parts of soil, 6 parts of nickel oxide, 7 parts of Zirconium orthosilicate. powder, 8 parts of Talcum, 5 parts of lead silicate, 4 parts of titanium oxide, 2 parts of lithium carbonate, three oxidations two
2 parts of ferrum, copper oxide 3,2 parts of manganese oxide.
The processing technology of the WANZIQIANHONG glaze porcelain prepared using limestone tailing is it is characterised in that comprise the following steps：
Step one, limestone tailing is sieved, pulverizes, calcine after sieve；
Step 2, according to WANZIQIANHONG glaze composition of raw materials weighing and proportioning, raw material is uniformly mixed, pulverizes, wet ball mill, is obtained
Glaze slip；
Step 3, makes ceramic body, waits ceramic body surface natural air drying；
Step 4, the ceramic body that step 3 is obtained puts into biscuiting molding in kiln, makes biscuit；
Step 5, after band biscuit cooling, applies the WANZIQIANHONG glaze glaze slip that step 2 is obtained on biscuit；
Step 6, kiln-firing after ceramic blank drying, strongly reducing atmosphere is burnt till, and firing temperature is 1280-1300 DEG C, kiln
After stove is warming up to firing temperature, cease fire, slow cooling.
Further, in step one, limestone tailing calcining heat is 200-300 DEG C, and calcination time 1-2 hour, after calcining
Really 100 mesh sieve.
Further, expect during WANZIQIANHONG glaze wet ball mill in step 2：Ball：Water=1:2:1.2
Further, during step 4 glazing, glaze slip is adjusted to 45-60 Baume degrees.
Further, in step 4, glazing thickness is 1-1.5mm.
Further, after kiln reaches firing temperature, it is incubated 30-40 minute, in slow cooling.
Seen from the above description, the utilization Quartz Tails preparation desert glaze porcelain that the present invention provides, its glaze paint is unglazed, has
Red background color, and glow purple by red background color, a granule is uniformly distributed with glaze paint, glaze paint feel is coarse,
Give deep, starry sky impression, this kind of WANZIQIANHONG glaze utilizes limestone tailing to prepare, and it utilizes waste material, reduces energy consumption, tool
There are great society, environment protection significance, meet Development Models of Circular Economy in Urban.
Specific embodiment
In order to be better understood from technical scheme, with reference to embodiment, the present invention is discussed further.
The invention provides using limestone tailing preparation WANZIQIANHONG glaze porcelain, include ceramic body be arranged at pottery
WANZIQIANHONG glaze on porcelain base substrate, described WANZIQIANHONG glaze is as follows in parts by weight：Calcined limestone mine tailing powder 30-40,
Quartzy 10-15 part, Red Stone Ware 10-15 part, nickel oxide 5-10 part, Zirconium orthosilicate. powder 5-10 part, Talcum 5-10 part, lead silicate 1-5
Part, titanium oxide 1-5 part, lithium carbonate 1-5 part, iron sesquioxide 1-5 part, copper oxide 1-5, manganese oxide 1-5 part.
Using the processing technology of the WANZIQIANHONG glaze porcelain of limestone tailing preparation, comprise the following steps：
Step one, limestone tailing is sieved, pulverizes, calcine after sieve, limestone tailing calcining heat be 200-300
DEG C, calcination time 1-2 hour, calcine consequence 100 mesh sieve；
Step 2, according to WANZIQIANHONG glaze composition of raw materials weighing and proportioning, raw material is uniformly mixed, pulverizes, wet ball mill, is obtained
Glaze slip, material during purple thousand red glaze wet ball mill：Ball：Water=1:2:1.2；
Step 3, makes ceramic body, waits ceramic body surface natural air drying；
Step 4, the ceramic body that step 3 is obtained puts into biscuiting molding in kiln, makes biscuit；
Step 5, after band biscuit cooling, applies the WANZIQIANHONG glaze glaze slip that step 2 is obtained, during glazing, glaze slip is adjusted on biscuit
Whole is 1-1.5mm for 45-60 Baume degrees, glazing thickness；
Step 6, kiln-firing after ceramic blank drying, strongly reducing atmosphere is burnt till, and firing temperature is 1280-1300 DEG C, kiln
Stove is incubated 30-40 minute after being warming up to firing temperature, in slow cooling, ceases fire, slow cooling.
Specific embodiment one：
WANZIQIANHONG glaze is as follows in parts by weight：Calcined limestone mine tailing powder 38, quartz 11 parts, 14 parts of Red Stone Ware,
5 parts of nickel oxide, 9 parts of Zirconium orthosilicate. powder, 6 parts of Talcum, 2 parts of lead silicate, 5 parts of titanium oxide, 2 parts of lithium carbonate, 4 parts of iron sesquioxide,
1 part of copper oxide 3, manganese oxide.
Specific embodiment two：
WANZIQIANHONG glaze is as follows in parts by weight：Calcined limestone mine tailing powder 33, quartz 13 parts, 14 parts of Red Stone Ware,
8 parts of nickel oxide, 9 parts of Zirconium orthosilicate. powder, 5 parts of Talcum, 3 parts of lead silicate, 3 parts of titanium oxide, 3 parts of lithium carbonate, iron sesquioxide 2
Part, copper oxide 3,4 parts of manganese oxide.
Specific embodiment three：
WANZIQIANHONG glaze is as follows in parts by weight：Calcined limestone mine tailing powder 35, quartz 14 parts, 12 parts of Red Stone Ware,
6 parts of nickel oxide, 7 parts of Zirconium orthosilicate. powder, 8 parts of Talcum, 5 parts of lead silicate, 4 parts of titanium oxide, 2 parts of lithium carbonate, 2 parts of iron sesquioxide,
2 parts of copper oxide 3, manganese oxide.
Seen from the above description, the utilization Quartz Tails preparation desert glaze porcelain that the present invention provides, its glaze paint is unglazed, has
Red background color, and glow purple by red background color, a granule is uniformly distributed with glaze paint, glaze paint feel is coarse,
Give deep, starry sky impression, this kind of WANZIQIANHONG glaze utilizes limestone tailing to prepare, and it utilizes waste material, reduces energy consumption, tool
There are great society, environment protection significance, meet Development Models of Circular Economy in Urban.
The above, only present pre-ferred embodiments, therefore can not with this limit the present invention enforcement scope, that is, according to
Equivalence changes and modification that scope of the present invention patent and description are made, all should still belong to the model that patent of the present invention covers
In enclosing.
Claims (10)
1. using limestone tailing preparation WANZIQIANHONG glaze porcelain it is characterised in that including ceramic body and be arranged at pottery
WANZIQIANHONG glaze on base substrate, described WANZIQIANHONG glaze is as follows in parts by weight：Calcined limestone mine tailing powder 30-40, stone
English 10-15 part, Red Stone Ware 10-15 part, nickel oxide 5-10 part, Zirconium orthosilicate. powder 5-10 part, Talcum 5-10 part, lead silicate 1-5 part,
Titanium oxide 1-5 part, lithium carbonate 1-5 part, iron sesquioxide 1-5 part, copper oxide 1-5, manganese oxide 1-5 part.
2. the WANZIQIANHONG glaze porcelain of utilization limestone tailing according to claim 1 preparation is it is characterised in that described ten thousand
Purple thousand red glaze are as follows in parts by weight：Calcined limestone mine tailing powder 38, quartz 11 parts, 14 parts of Red Stone Ware, 5 parts of nickel oxide,
9 parts of Zirconium orthosilicate. powder, 6 parts of Talcum, 2 parts of lead silicate, 5 parts of titanium oxide, 2 parts of lithium carbonate, 4 parts of iron sesquioxide, copper oxide 3, oxygen
Change 1 part of manganese.
3. the WANZIQIANHONG glaze porcelain of utilization limestone tailing according to claim 1 preparation is it is characterised in that described ten thousand
Purple thousand red glaze are as follows in parts by weight：Calcined limestone mine tailing powder 33, quartz 13 parts, 14 parts of Red Stone Ware, 8 parts of nickel oxide,
9 parts of Zirconium orthosilicate. powder, 5 parts of Talcum, 3 parts of lead silicate, 3 parts of titanium oxide, 3 parts of lithium carbonate, 2 parts of iron sesquioxide, copper oxide 3, oxygen
Change 4 parts of manganese.
4. the WANZIQIANHONG glaze porcelain of utilization limestone tailing according to claim 1 preparation is it is characterised in that described ten thousand
Purple thousand red glaze are as follows in parts by weight：Calcined limestone mine tailing powder 35, quartz 14 parts, 12 parts of Red Stone Ware, 6 parts of nickel oxide,
7 parts of Zirconium orthosilicate. powder, 8 parts of Talcum, 5 parts of lead silicate, 4 parts of titanium oxide, 2 parts of lithium carbonate, 2 parts of iron sesquioxide, copper oxide 3, oxygen
Change 2 parts of manganese.
5. the processing technology of the WANZIQIANHONG glaze porcelain prepared using limestone tailing is it is characterised in that comprise the following steps：
Step one, limestone tailing is sieved, pulverizes, calcine after sieve；
Step 2, according to WANZIQIANHONG glaze composition of raw materials weighing and proportioning, raw material is uniformly mixed, pulverizes, wet ball mill, prepared glaze
Slurry；
Step 3, makes ceramic body, waits ceramic body surface natural air drying；
Step 4, the ceramic body that step 3 is obtained puts into biscuiting molding in kiln, makes biscuit；
Step 5, after band biscuit cooling, applies the WANZIQIANHONG glaze glaze slip that step 2 is obtained on biscuit；
Step 6, kiln-firing after ceramic blank drying, strongly reducing atmosphere is burnt till, and firing temperature is 1280-1300 DEG C, kiln liter
Temperature, to firing temperature, is ceased fire, slow cooling.
6. the processing technology of the WANZIQIANHONG glaze porcelain of utilization limestone tailing preparation according to claim 5, its feature
It is：In step one, limestone tailing calcining heat is 200-300 DEG C, calcination time 1-2 hour, calcines consequence 100 mesh sieve.
7. the processing technology of the WANZIQIANHONG glaze porcelain of utilization limestone tailing preparation according to claim 5, its feature
It is：Expect during WANZIQIANHONG glaze wet ball mill in step 2：Ball：Water=1:2:1.2.
8. the processing technology of the WANZIQIANHONG glaze porcelain of utilization limestone tailing preparation according to claim 5, its feature
It is：During step 4 glazing, glaze slip is adjusted to 45-60 Baume degrees.
9. the processing technology of the WANZIQIANHONG glaze porcelain of utilization limestone tailing preparation according to claim 5 or 7, it is special
Levy and be：In step 4, glazing thickness is 1-1.5mm.
10. the processing technology of the WANZIQIANHONG glaze porcelain of utilization limestone tailing preparation according to claim 5, its feature
It is：After kiln reaches firing temperature, it is incubated 30-40 minute, in slow cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610796119.3A CN106396382B (en) | 2016-08-31 | 2016-08-31 | Utilize the rich in variety glaze porcelain and its manufacture craft of limestone tailing preparation |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610796119.3A CN106396382B (en) | 2016-08-31 | 2016-08-31 | Utilize the rich in variety glaze porcelain and its manufacture craft of limestone tailing preparation |
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| Publication Number | Publication Date |
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| CN106396382A true CN106396382A (en) | 2017-02-15 |
| CN106396382B CN106396382B (en) | 2018-12-18 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108328926A (en) * | 2018-03-28 | 2018-07-27 | 福建省德化县艺韵陶瓷有限公司 | A kind of starry sky series glaze formula |
| CN110204204A (en) * | 2018-12-28 | 2019-09-06 | 福建泉州顺美集团有限责任公司 | A kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044638A (en) * | 1989-01-31 | 1990-08-15 | 林承焕 | The production method of deep dark color glaze stocks and correlated product thereof |
| EP1970357A1 (en) * | 2007-03-14 | 2008-09-17 | Colorobbia Italia S.p.a. | Materials for coating ceramic bodies, preparation and use thereof and ceramic bodies comprising them |
| CN104150965A (en) * | 2014-08-07 | 2014-11-19 | 福建省太古陶瓷有限责任公司 | Copper red glaze formula and manufacturing process of copper red glaze porcelain |
| CN104844154A (en) * | 2015-05-29 | 2015-08-19 | 苏州拓科仪器设备有限公司 | Underglaze red ceramic |
-
2016
- 2016-08-31 CN CN201610796119.3A patent/CN106396382B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1044638A (en) * | 1989-01-31 | 1990-08-15 | 林承焕 | The production method of deep dark color glaze stocks and correlated product thereof |
| EP1970357A1 (en) * | 2007-03-14 | 2008-09-17 | Colorobbia Italia S.p.a. | Materials for coating ceramic bodies, preparation and use thereof and ceramic bodies comprising them |
| CN104150965A (en) * | 2014-08-07 | 2014-11-19 | 福建省太古陶瓷有限责任公司 | Copper red glaze formula and manufacturing process of copper red glaze porcelain |
| CN104844154A (en) * | 2015-05-29 | 2015-08-19 | 苏州拓科仪器设备有限公司 | Underglaze red ceramic |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108328926A (en) * | 2018-03-28 | 2018-07-27 | 福建省德化县艺韵陶瓷有限公司 | A kind of starry sky series glaze formula |
| CN110204204A (en) * | 2018-12-28 | 2019-09-06 | 福建泉州顺美集团有限责任公司 | A kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation |
| CN110204204B (en) * | 2018-12-28 | 2023-09-26 | 福建泉州顺美集团有限责任公司 | Low-temperature rose glaze porcelain prepared from limestone tailings and manufacturing process thereof |
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| Publication number | Publication date |
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| CN106396382B (en) | 2018-12-18 |
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