CN106396382B - Utilize the rich in variety glaze porcelain and its manufacture craft of limestone tailing preparation - Google Patents

Utilize the rich in variety glaze porcelain and its manufacture craft of limestone tailing preparation Download PDF

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Publication number
CN106396382B
CN106396382B CN201610796119.3A CN201610796119A CN106396382B CN 106396382 B CN106396382 B CN 106396382B CN 201610796119 A CN201610796119 A CN 201610796119A CN 106396382 B CN106396382 B CN 106396382B
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parts
glaze
rich
variety
limestone tailing
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CN106396382A (en
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苏建源
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Fujian Province Dehua Jiacheng Ceramics Co Ltd
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Fujian Province Dehua Jiacheng Ceramics Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Adornments (AREA)

Abstract

The invention belongs to technical field of ceramic production, and in particular to a kind of rich in variety glaze porcelain and its manufacture craft using limestone tailing preparation.The rich in variety glaze porcelain that this kind is prepared using limestone tailing, including ceramic body and the rich in variety glaze being set on ceramic body, rich in variety glaze includes calcined limestone tailing powder, quartz, Red Stone Ware, nickel oxide, zirconium silicate powder, talcum, lead silicate, titanium oxide, lithium carbonate, di-iron trioxide, copper oxide, manganese oxide.It is above-mentioned to prepare desert glaze porcelain using Quartz Tails, its glaze paint is unglazed, with red background color, and by glowing purple in red background color, a particle is uniformly distributed in glaze paint, glaze paint feel is coarse, give deep, starry sky impression, this kind riot of colour glaze is prepared using limestone tailing, using waste material, reduces energy consumption, with great society, environment protection significance, meet Development Models of Circular Economy in Urban.

Description

Utilize the rich in variety glaze porcelain and its manufacture craft of limestone tailing preparation
Technical field
The invention belongs to technical field of ceramic production, and in particular to a kind of rich in variety glaze prepared using limestone tailing Porcelain and its manufacture craft.
Background technique
With the rapid development of ceramics, lime stone is largely exploited and is utilized, and generates nearly hundred tons of waste limestone every year Tailing, these waste residue materials of the tailing for removing of digging up mine include barren rock, tailing, crumb powder etc. and lime stone coating, interlayer, Mountain skin soil, crack soil etc..These waste residues after exploitation had both occupied stockyard arable land, and had caused secondary environmental pollution, and waste preciousness Non-renewable mineral resources, there are production safeties and environmentally friendly accident potential, have seriously affected agricultural and people's lives and properties Safety, greatly waste mineral resources, and destroy ecological environment.
Therefore, the comprehensive utilization of waste limestone tailing is essential, also becomes the weight that Production of Ceramics producer faces Hang-up.
Summary of the invention
To solve the above-mentioned problems, the present invention provides a kind of rich in variety glaze porcelains prepared using limestone tailing.
For achieving the above object, the present invention provides using limestone tailing preparation rich in variety glaze porcelain, It is characterized in that, including ceramic body and the rich in variety glaze being set on ceramic body, the riot of colour glaze is according to parts by weight It counts as follows: calcined limestone tailing powder 30-40,10-15 parts of quartz, 10-15 parts of Red Stone Ware, 5-10 parts of nickel oxide, zirconium silicate 5-10 parts of powder, 5-10 parts of talcum, 1-5 parts of lead silicate, 1-5 parts of titanium oxide, 1-5 parts of lithium carbonate, 1-5 parts of di-iron trioxide, oxygen Change copper 1-5,1-5 parts of manganese oxide.
Optimization, rich in variety glaze is as follows in parts by weight: calcined limestone tailing powder 38, quartzy 11 parts, boccaro 14 parts of soil, 5 parts of nickel oxide, 9 parts of zirconium silicate powder, 6 parts of talcum, 2 parts of lead silicate, 5 parts of titanium oxide, 2 parts of lithium carbonate, three oxidations two 4 parts of iron, copper oxide 3,1 part of manganese oxide.
Optimization, rich in variety glaze is as follows in parts by weight: calcined limestone tailing powder 33, quartzy 13 parts, boccaro Soil 14 parts, 8 parts of nickel oxide, 9 parts of zirconium silicate powder, 5 parts of talcum, 3 parts of lead silicate, 3 parts of titanium oxide, 3 parts of lithium carbonate, three oxidation Two 2 parts of iron, copper oxide 3,4 parts of manganese oxide.
Optimization, rich in variety glaze is as follows in parts by weight: calcined limestone tailing powder 35, quartzy 14 parts, boccaro 12 parts of soil, 6 parts of nickel oxide, 7 parts of zirconium silicate powder, 8 parts of talcum, 5 parts of lead silicate, 4 parts of titanium oxide, 2 parts of lithium carbonate, three oxidations two 2 parts of iron, copper oxide 3,2 parts of manganese oxide.
Utilize the manufacture craft of the rich in variety glaze porcelain of limestone tailing preparation, which comprises the following steps:
Step 1 will be sieved after limestone tailing screening, crushing, calcining;
Raw material is uniformly mixed, is crushed, wet ball mill according to rich in variety glaze composition of raw materials weighing and proportioning by step 2, is made Glaze slip;
Step 3 makes ceramic body, waits ceramic body surface natural air drying;
Ceramic body made from step 3 is put into biscuiting in kiln and formed, biscuit is made by step 4;
Step 5 applies riot of colour glaze glaze slip made from step 2 after band biscuit is cooling on biscuit;
Step 6, kiln-firing after ceramic blank drying, strongly reducing atmosphere firing, firing temperature are 1280-1300 DEG C, kiln After furnace is warming up to firing temperature, cease fire, slow cooling.
Further, in step 1 limestone tailing calcination temperature be 200-300 DEG C, calcination time 1-2 hours, after calcining 100 mesh of fruit.
Further, expect when rich in variety glaze wet ball mill in step 2: ball: water=1:2:1.2
Further, glaze slip is adjusted to 45-60 Baume degrees when step 4 glazing.
Further, in step 4 glazing with a thickness of 1-1.5mm.
Further, after kiln reaches firing temperature, 30-40 minutes are kept the temperature, in slow cooling.
Seen from the above description, provided by the invention to prepare desert glaze porcelain using Quartz Tails, glaze paint is unglazed, has Red background color, and by glowing purple in red background color, a particle is uniformly distributed in glaze paint, glaze paint feel is coarse, Give deep, starry sky impression, this kind riot of colour glaze is prepared using limestone tailing, using waste material, reduces energy consumption, tool There are great society, environment protection significance, meets Development Models of Circular Economy in Urban.
Specific embodiment
For a better understanding of the technical solution of the present invention, being discussed further below with reference to embodiment to the present invention.
The present invention provides the rich in variety glaze porcelains using limestone tailing preparation, including ceramic body and are set to pottery Rich in variety glaze on porcelain billet body, the riot of colour glaze are as follows in parts by weight: calcined limestone tailing powder 30-40, 10-15 parts quartzy, 10-15 parts of Red Stone Ware, 5-10 parts of nickel oxide, 5-10 parts of zirconium silicate powder, 5-10 parts of talcum, lead silicate 1-5 Part, 1-5 parts of titanium oxide, 1-5 parts of lithium carbonate, 1-5 parts of di-iron trioxide, copper oxide 1-5,1-5 parts of manganese oxide.
Utilize the manufacture craft of the rich in variety glaze porcelain of limestone tailing preparation, comprising the following steps:
Step 1 will be sieved after limestone tailing screening, crushing, calcining, and limestone tailing calcination temperature is 200-300 DEG C, calcination time 1-2 hours, calcine 100 mesh of consequence;
Raw material is uniformly mixed, is crushed, wet ball mill according to rich in variety glaze composition of raw materials weighing and proportioning by step 2, is made Glaze slip, when purple thousand red glaze wet ball mill, expect: ball: water=1:2:1.2;
Step 3 makes ceramic body, waits ceramic body surface natural air drying;
Ceramic body made from step 3 is put into biscuiting in kiln and formed, biscuit is made by step 4;
Step 5 after band biscuit is cooling, applies riot of colour glaze glaze slip made from step 2 on biscuit, glaze slip tune when glazing Whole is 45-60 Baume degrees, glazing with a thickness of 1-1.5mm;
Step 6, kiln-firing after ceramic blank drying, strongly reducing atmosphere firing, firing temperature are 1280-1300 DEG C, kiln Furnace keeps the temperature 30-40 minutes after being warming up to firing temperature, in slow cooling, ceases fire, slow cooling.
Specific embodiment one:
Rich in variety glaze is as follows in parts by weight: calcined limestone tailing powder 38, quartz 11 parts, 14 parts of Red Stone Ware, 5 parts of nickel oxide, 9 parts of zirconium silicate powder, 6 parts of talcum, 2 parts of lead silicate, 5 parts of titanium oxide, 2 parts of lithium carbonate, 4 parts of di-iron trioxide, 1 part of copper oxide 3, manganese oxide.
Specific embodiment two:
Rich in variety glaze is as follows in parts by weight: calcined limestone tailing powder 33, quartz 13 parts, 14 parts of Red Stone Ware, 8 parts of nickel oxide, 9 parts of zirconium silicate powder, 5 parts of talcum, 3 parts of lead silicate, 3 parts of titanium oxide, 3 parts of lithium carbonate, di-iron trioxide 2 Part, copper oxide 3,4 parts of manganese oxide.
Specific embodiment three:
Rich in variety glaze is as follows in parts by weight: calcined limestone tailing powder 35, quartz 14 parts, 12 parts of Red Stone Ware, 6 parts of nickel oxide, 7 parts of zirconium silicate powder, 8 parts of talcum, 5 parts of lead silicate, 4 parts of titanium oxide, 2 parts of lithium carbonate, 2 parts of di-iron trioxide, 2 parts of copper oxide 3, manganese oxide.
Seen from the above description, provided by the invention to prepare desert glaze porcelain using Quartz Tails, glaze paint is unglazed, has Red background color, and by glowing purple in red background color, a particle is uniformly distributed in glaze paint, glaze paint feel is coarse, Give deep, starry sky impression, this kind riot of colour glaze is prepared using limestone tailing, using waste material, reduces energy consumption, tool There are great society, environment protection significance, meets Development Models of Circular Economy in Urban.
The above is only the preferred embodiment of the present invention, therefore cannot be limited the scope of implementation of the present invention with this, i.e., according to Equivalent changes and modifications made by scope of the present invention patent and description should still belong to the model that the invention patent covers In enclosing.

Claims (4)

1. utilizing the rich in variety glaze porcelain of limestone tailing preparation, which is characterized in that including ceramic body and be set to ceramics Rich in variety glaze on green body, the riot of colour glaze are as follows in parts by weight: calcined limestone tailing powder 30-40, stone 10-15 parts of English, 10-15 parts of Red Stone Ware, 5-10 parts of nickel oxide, 5-10 parts of zirconium silicate powder, 5-10 parts of talcum, 1-5 parts of lead silicate, 1-5 parts of titanium oxide, 1-5 parts of lithium carbonate, 1-5 parts of di-iron trioxide, copper oxide 1-5,1-5 parts of manganese oxide.
2. the rich in variety glaze porcelain according to claim 1 prepared using limestone tailing, which is characterized in that described ten thousand Purple thousand red glaze are as follows in parts by weight: calcined limestone tailing powder 38,11 parts of quartz, 14 parts of Red Stone Ware, 5 parts of nickel oxide, 9 parts of zirconium silicate powder, 6 parts of talcum, 2 parts of lead silicate, 5 parts of titanium oxide, 2 parts of lithium carbonate, 4 parts of di-iron trioxide, copper oxide 3, oxygen Change 1 part of manganese.
3. the rich in variety glaze porcelain according to claim 1 prepared using limestone tailing, which is characterized in that described ten thousand Purple thousand red glaze are as follows in parts by weight: calcined limestone tailing powder 33,13 parts of quartz, 14 parts of Red Stone Ware, 8 parts of nickel oxide, 9 parts of zirconium silicate powder, 5 parts of talcum, 3 parts of lead silicate, 3 parts of titanium oxide, 3 parts of lithium carbonate, 2 parts of di-iron trioxide, copper oxide 3, oxygen Change 4 parts of manganese.
4. the rich in variety glaze porcelain according to claim 1 prepared using limestone tailing, which is characterized in that described ten thousand Purple thousand red glaze are as follows in parts by weight: calcined limestone tailing powder 35,14 parts of quartz, 12 parts of Red Stone Ware, 6 parts of nickel oxide, 7 parts of zirconium silicate powder, 8 parts of talcum, 5 parts of lead silicate, 4 parts of titanium oxide, 2 parts of lithium carbonate, 2 parts of di-iron trioxide, copper oxide 3, oxygen Change 2 parts of manganese.
CN201610796119.3A 2016-08-31 2016-08-31 Utilize the rich in variety glaze porcelain and its manufacture craft of limestone tailing preparation Active CN106396382B (en)

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Publication number Priority date Publication date Assignee Title
CN108328926A (en) * 2018-03-28 2018-07-27 福建省德化县艺韵陶瓷有限公司 A kind of starry sky series glaze formula
CN110204204B (en) * 2018-12-28 2023-09-26 福建泉州顺美集团有限责任公司 Low-temperature rose glaze porcelain prepared from limestone tailings and manufacturing process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1044638A (en) * 1989-01-31 1990-08-15 林承焕 The production method of deep dark color glaze stocks and correlated product thereof
EP1970357A1 (en) * 2007-03-14 2008-09-17 Colorobbia Italia S.p.a. Materials for coating ceramic bodies, preparation and use thereof and ceramic bodies comprising them
CN104150965A (en) * 2014-08-07 2014-11-19 福建省太古陶瓷有限责任公司 Copper red glaze formula and manufacturing process of copper red glaze porcelain
CN104844154A (en) * 2015-05-29 2015-08-19 苏州拓科仪器设备有限公司 Underglaze red ceramic

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1044638A (en) * 1989-01-31 1990-08-15 林承焕 The production method of deep dark color glaze stocks and correlated product thereof
EP1970357A1 (en) * 2007-03-14 2008-09-17 Colorobbia Italia S.p.a. Materials for coating ceramic bodies, preparation and use thereof and ceramic bodies comprising them
CN104150965A (en) * 2014-08-07 2014-11-19 福建省太古陶瓷有限责任公司 Copper red glaze formula and manufacturing process of copper red glaze porcelain
CN104844154A (en) * 2015-05-29 2015-08-19 苏州拓科仪器设备有限公司 Underglaze red ceramic

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