CN110204204A - A kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation - Google Patents
A kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation Download PDFInfo
- Publication number
- CN110204204A CN110204204A CN201811625294.1A CN201811625294A CN110204204A CN 110204204 A CN110204204 A CN 110204204A CN 201811625294 A CN201811625294 A CN 201811625294A CN 110204204 A CN110204204 A CN 110204204A
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- Prior art keywords
- low temperature
- rhodo
- parts
- glaze
- limestone tailing
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Glass Compositions (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention relates to ceramic fabrication technique fields, are specifically related to a kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation.The low temperature rhodo glaze porcelain provided by the invention prepared using limestone tailing, the raw material of low temperature rhodo glaze includes limestone tailing, quartz, kaolin, selenium cadmium red colorant, bone ash etc..The low temperature rhodo glaze porcelain provided by the invention prepared using limestone tailing, a large amount of Quartz Tails are introduced as green body, the raw material of glaze, the low temperature rhodo glaze porcelain of the preparation has the background color of rose, it adopts and is formed by a firing using low-temperature primary, energy conservation and environmental protection, the low temperature rhodo glaze porcelain fired is degradable, has great society, environment protection significance, meet Development Models of Circular Economy in Urban, with positive meaning and there is positive economic benefit to the development of promotion ceramic product.
Description
Technical field
The present invention relates to ceramic fabrication technique fields, are specifically related to a kind of low temperature rhodo prepared using limestone tailing
Glaze porcelain and its manufacture craft.
Background technique
With the rapid development of ceramics, lime stone is largely exploited and is utilized, and generates nearly hundred tons of waste limestone every year
Tailing, these waste residue materials of the tailing for removing of digging up mine include barren rock, tailing, crumb powder etc. and lime stone coating, interlayer,
Mountain skin soil, crack soil etc..These waste residues after exploitation had both occupied stockyard arable land, and had caused secondary environmental pollution, and waste preciousness
Non-renewable mineral resources, there are production safeties and environmentally friendly accident potential, have seriously affected agricultural and people's lives and properties
Safety, greatly waste mineral resources, and destroy ecological environment.Therefore, the comprehensive utilization of waste limestone tailing is concerning weight
Greatly, also become the great difficult problem that Production of Ceramics producer faces, seriously affect the safety of agricultural and people's lives and properties, pole
The earth waste mineral resources, and destroy ecological environment.
To solve the above problems, application No. is the application for a patent for invention of CN201610796119.3 disclose it is a kind of using stone
The rich in variety glaze porcelain and its manufacture craft of lime stone tailing preparation, calcined limestone tailing powder system is introduced in the patent application
It is standby a kind of with red background color, and by glowing purple in red background color, a particle, glaze are uniformly distributed on glaze
The firing temperature of the coarse rich in variety glaze of face feel, this kind riot of colour glaze is 1280-1300 DEG C, belongs to refractory ceramics.With
People's living standard constantly can improve, the variation of aesthetic requirement is also constantly being changed, therefore, if lime can be utilized
Stone tailing prepares more different glazing effects, produces the porcelain of effect unique to improve the added value of ceramic product, right
The waste utilization of the development and limestone tailing that push china industry has positive economic and social benefit.
Summary of the invention
In order to solve the deficiencies in the prior art, the present invention provides a kind of low temperature rhodo glaze prepared using limestone tailing
Porcelain and its manufacture craft.
To achieve the above object, The technical solution adopted by the invention is as follows: a kind of low temperature prepared using limestone tailing
Rhodo glaze porcelain, including ceramic body further include the low temperature rhodo glaze for being set to ceramic body surface, the low temperature rhodo glaze
Parts by weight of raw materials is as follows: 25-35 parts of limestone tailing, 13-18 parts of quartz, 8-12 parts of kaolin, selenium cadmium red colorant 10-15
Part, 3-8 parts of bone ash, 15-20 parts of low temperature frit, 4-6 parts of zinc oxide, 2-4 parts of samarium oxide, 0.2-0.8 parts of copper oxide, oxygen
Change 0.1-0.5 parts cuprous, 0.8-1.5 parts of silicon carbide, phosphorus pentoxide 0.2-0.8,0.3-0.8 parts of carboxymethyl cellulose.
Further, the raw material components using the low temperature rhodo glaze porcelain of limestone tailing preparation are as follows: limestone tailing
31 parts, quartzy 14 parts, 9 parts of kaolin, 12 parts of selenium cadmium red colorant, 5 parts of bone ash, 19 parts of low temperature frit, 4 parts of zinc oxide, samarium oxide 3
Part, 0.4 part of copper oxide, 0.3 part of cuprous oxide, 1.2 parts of silicon carbide, phosphorus pentoxide 0.6,0.5 part of carboxymethyl cellulose.
Further, the raw material components using the low temperature rhodo glaze porcelain of limestone tailing preparation are as follows: limestone tailing
29 parts, quartzy 15 parts, 11 parts of kaolin, 11 parts of selenium cadmium red colorant, 7 parts of bone ash, 16 parts of low temperature frit, 5 parts of zinc oxide, samarium oxide
2.5 parts, 0.7 part of copper oxide, 0.4 part of cuprous oxide, 1.3 parts of silicon carbide, phosphorus pentoxide 0.6, carboxymethyl cellulose 0.5.
A kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation, includes the following steps:
Each raw material of the low temperature rhodo glaze porcelain prepared using limestone tailing is weighed in proportion, mixes, breaks by step 1
Broken, sieving, wet ball mill 20-24h are made and are starched using the low temperature rhodo glaze porcelain of limestone tailing preparation；
The low temperature rhodo glaze porcelain prepared using limestone tailing slurry is repeatedly removed iron by magnetic separator, until benefit by step 2
The iron-content in low temperature rhodo glaze porcelain slurry prepared with limestone tailing is lower than 0.03-0.05%；
Step 3 is applied on the biscuit of ceramics of biscuiting and utilizes the low temperature rhodo of limestone tailing preparation made from step 2
Glaze porcelain slurry；
Biscuit of ceramics after glazing is sent into electrical kiln, is formed by a firing under reducing atmosphere, firing temperature is by step 4
1103-1108 DEG C.
Further, the temperature curve control that electrical kiln is fired in step 4 is as follows: room temperature rises to 340-360 DEG C, time-consuming
4-5h is continuously heating to 820-840 DEG C, time-consuming 2-3h, is finally warming up to firing temperature, time-consuming 1-1.5h.
Further, when starching wet ball mill using the low temperature rhodo glaze porcelain of limestone tailing preparation in step 1, material: ball:
Water=1:1.8-2:0.8-1.
Further, in wet ball mill, ball uses high alumina ballstone, according to big: in: the gradation of small=1:2:1 mass ratio is added.
Further, the concentration of the step 1 low temperature rhodo glaze porcelain slurry obtained using limestone tailing preparation is 40-
50Be。
Further, the magnetic field strength of magnetic separator is 17000-19000GS in step 2.
Further, using the low temperature rhodo glaze porcelain slurry glazing of limestone tailing preparation with a thickness of 0.6-0.8mm.
The low temperature rhodo glaze porcelain provided by the invention prepared using limestone tailing is introduced a large amount of Quartz Tails and made
For green body, the raw material of glaze, the low temperature rhodo glaze porcelain of the preparation is had the background color of rose, adopts and fired using low-temperature primary
Molding, energy conservation and environmental protection, the low temperature rhodo glaze porcelain fired is degradable, has great society, environment protection significance, meets city and follow
Ring Economic Development Mode with positive meaning and has positive economic benefit to the development of promotion ceramic product.
Specific embodiment
Below by way of specific embodiment, the invention will be further described.
A kind of low temperature rhodo glaze porcelain prepared using limestone tailing, including ceramic body, further include being set to ceramics
The low temperature rhodo glaze of billet surface, the parts by weight of raw materials of the low temperature rhodo glaze are as follows: 25-35 parts of limestone tailing, quartz
13-18 parts, 8-12 parts of kaolin, 10-15 parts of selenium cadmium red colorant, 3-8 parts of bone ash, 15-20 parts of low temperature frit, zinc oxide
4-6 parts, 2-4 parts of samarium oxide, 0.2-0.8 parts of copper oxide, 0.1-0.5 parts of cuprous oxide, 0.8-1.5 parts of silicon carbide, five oxygen
Change 0.3-0.8 parts of two phosphorus 0.2-0.8, carboxymethyl cellulose.
A kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation, includes the following steps:
Each raw material of the low temperature rhodo glaze porcelain prepared using limestone tailing is weighed in proportion, mixes, breaks by step 1
Broken, sieving, wet ball mill 20-24h are made and are starched using the low temperature rhodo glaze porcelain of limestone tailing preparation, utilize limestone tailing
When the low temperature rhodo glaze porcelain of preparation starches wet ball mill, material: ball: water=1:1.8-2:0.8-1, in wet ball mill, ball uses high alumina
Ballstone, according to big: in: the gradation of small=1:2:1 mass ratio is added, the low temperature rhodo glaze obtained prepared using limestone tailing
The concentration of porcelain slurry is 40-50Be；
The low temperature rhodo glaze porcelain prepared using limestone tailing slurry is repeatedly removed iron by magnetic separator, until benefit by step 2
The iron-content in low temperature rhodo glaze porcelain slurry prepared with limestone tailing is lower than 0.03-0.05%, the magnetic field strength of magnetic separator
For 17000-19000GS；
Step 3 is applied on the biscuit of ceramics of biscuiting and utilizes the low temperature rhodo of limestone tailing preparation made from step 2
Glaze porcelain slurry, glazing with a thickness of 0.6-0.8mm；
Biscuit of ceramics after glazing is sent into electrical kiln, is formed by a firing under reducing atmosphere, firing temperature is by step 4
1103-1108 DEG C, the temperature curve control that electrical kiln is fired is as follows: room temperature rises to 340-360 DEG C, and time-consuming 4-5h continues to heat up
To 820-840 DEG C, time-consuming 2-3h is finally warming up to firing temperature, time-consuming 1-1.5h.
Specific embodiment one:
A kind of low temperature rhodo glaze porcelain prepared using limestone tailing, including ceramic body, further include being set to ceramics
The low temperature rhodo glaze of billet surface, the parts by weight of raw materials of the low temperature rhodo glaze are as follows: 31 parts of limestone tailing, quartz 14 parts,
9 parts of kaolin, 12 parts of selenium cadmium red colorant, 5 parts of bone ash, 19 parts of low temperature frit, 4 parts of zinc oxide, 3 parts of samarium oxide, copper oxide 0.4
Part, 0.3 part of cuprous oxide, 1.2 parts of silicon carbide, phosphorus pentoxide 0.6,0.5 part of carboxymethyl cellulose.
Specific embodiment two:
A kind of low temperature rhodo glaze porcelain prepared using limestone tailing, including ceramic body, further include being set to ceramics
The low temperature rhodo glaze of billet surface, the parts by weight of raw materials of the low temperature rhodo glaze are as follows: 29 parts of limestone tailing, quartz 15 parts,
11 parts of kaolin, 11 parts of selenium cadmium red colorant, 7 parts of bone ash, 16 parts of low temperature frit, 5 parts of zinc oxide, 2.5 parts of samarium oxide, copper oxide
0.7 part, 0.4 part of cuprous oxide, 1.3 parts of silicon carbide, phosphorus pentoxide 0.6, carboxymethyl cellulose 0.5.
The low temperature rhodo glaze porcelain provided by the invention prepared using limestone tailing is introduced a large amount of Quartz Tails and made
For green body, the raw material of glaze, the low temperature rhodo glaze porcelain of the preparation is had the background color of rose, adopts and fired using low-temperature primary
Molding, energy conservation and environmental protection, the low temperature rhodo glaze porcelain fired is degradable, has great society, environment protection significance, meets city and follow
Ring Economic Development Mode with positive meaning and has positive economic benefit to the development of promotion ceramic product.
It above are only the specific embodiment of the present invention, but the design concept of the present invention is not limited to this, all benefits
It is made a non-material change to the present invention, should all be belonged to behavior that violates the scope of protection of the present invention with this design.
Claims (11)
1. a kind of low temperature rhodo glaze porcelain prepared using limestone tailing, including ceramic body, it is characterised in that: further include setting
It is placed in the low temperature rhodo glaze on ceramic body surface, the parts by weight of raw materials of the low temperature rhodo glaze is as follows: limestone tailing 25-35
Part, 15-20 parts of low temperature frit, 10-15 parts of selenium cadmium red colorant, 15-20 parts of quartz, 5-10 parts of zircon flour, 5-10 parts of kaolin,
1-5 parts of zinc oxide, 0.3-0.8 parts of carboxymethyl cellulose.
2. a kind of low temperature rhodo glaze porcelain prepared using limestone tailing according to claim 1, which is characterized in that institute
It states as follows using the raw material components of the low temperature rhodo glaze porcelain of limestone tailing preparation: 25-35 parts of limestone tailing, quartz 15-
20 parts, 15-20 parts of low temperature frit, 10-15 parts of selenium cadmium red colorant, 5-10 parts of zircon flour, 5-10 parts of kaolin, zinc oxide 1-5
Part, 0.3-0.8 parts of carboxymethyl cellulose.
3. a kind of low temperature rhodo glaze porcelain prepared using limestone tailing according to claim 1, which is characterized in that institute
It states as follows using the raw material components of the low temperature rhodo glaze porcelain of limestone tailing preparation: 25-35 parts of limestone tailing, quartz 15-
20 parts, 15-20 parts of low temperature frit, 10-15 parts of selenium cadmium red colorant, 5-10 parts of zircon flour, 5-10 parts of kaolin, zinc oxide 1-5
Part, 0.3-0.8 parts of carboxymethyl cellulose.
4. a kind of low temperature rhodo glaze porcelain prepared using limestone tailing according to claim 1, which is characterized in that institute
It states as follows using the raw material components of the low temperature rhodo glaze porcelain of limestone tailing preparation: 25-35 parts of limestone tailing, quartz 15-
20 parts, 15-20 parts of low temperature frit, 10-15 parts of selenium cadmium red colorant, 5-10 parts of zircon flour, 5-10 parts of kaolin, zinc oxide 1-5
Part, 0.3-0.8 parts of carboxymethyl cellulose.
5. a kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation, includes the following steps:
Step 1 is weighed in proportion using each raw material of the low temperature rhodo glaze porcelain of limestone tailing preparation, mixes, is crushed, mistake
Sieve, wet ball mill 20-24h；
Step 2, it is blocking in 700-800 DEG C of sintering by limestone tailing, low temperature frit, selenium cadmium red coloring material for mixing, by quartz, zirconium
Sand powder, kaolin, zinc oxide, carboxymethyl cellulose and step 1 is sintered closes very much, obtain low temperature rhodo glaze；
Step 3 applies low temperature rhodo glaze made from step 2 on ceramic body；
Ceramic body after glazing is sent into tunnel oven by step 4, and firing temperature is 900-980 DEG C, and the firing time, 6-8 was small
When.
6. a kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation according to claim 1,
It is characterized by: the temperature curve control that electrical kiln is fired in the step 4 is as follows: room temperature rises to 340-360 DEG C, time-consuming 4-5h,
It is continuously heating to 820-840 DEG C, time-consuming 2-3h, is finally warming up to firing temperature, time-consuming 1-1.5h.
7. a kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation according to claim 1,
It is characterized by: when starching wet ball mill using the low temperature rhodo glaze porcelain of limestone tailing preparation in the step 1, material: ball: water
=1:1.8-2:0.8-1.
8. a kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation according to claim 3,
It is characterized by: ball uses high alumina ballstone, according to big in the wet ball mill: in: the gradation of small=1:2:1 mass ratio is added.
9. a kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation according to claim 1,
It is characterized by: the concentration of the step 1 low temperature rhodo glaze porcelain slurry obtained using limestone tailing preparation is 40-
50Be。
10. a kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation according to claim 1,
It is characterized by: the magnetic field strength of magnetic separator is 17000-19000GS in the step 2.
11. a kind of low temperature rhodo glaze porcelain and its manufacture craft using limestone tailing preparation according to claim 1,
It is characterized by: it is described using limestone tailing preparation low temperature rhodo glaze porcelain slurry glazing with a thickness of 0.6-0.8mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811625294.1A CN110204204B (en) | 2018-12-28 | 2018-12-28 | Low-temperature rose glaze porcelain prepared from limestone tailings and manufacturing process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811625294.1A CN110204204B (en) | 2018-12-28 | 2018-12-28 | Low-temperature rose glaze porcelain prepared from limestone tailings and manufacturing process thereof |
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| CN110204204A true CN110204204A (en) | 2019-09-06 |
| CN110204204B CN110204204B (en) | 2023-09-26 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003327484A (en) * | 2002-05-15 | 2003-11-19 | Fumitaka Fujiwara | Glaze for kimachi stone |
| CN104150965A (en) * | 2014-08-07 | 2014-11-19 | 福建省太古陶瓷有限责任公司 | Copper red glaze formula and manufacturing process of copper red glaze porcelain |
| CN106396382A (en) * | 2016-08-31 | 2017-02-15 | 福建省德化佳诚陶瓷有限公司 | Colorful glazed porcelain prepared from limestone tailings, and manufacture technology thereof |
| CN109020217A (en) * | 2018-09-28 | 2018-12-18 | 佛山科学技术学院 | A kind of red glaze of wide an ancient unit of weight and its method for cooking |
-
2018
- 2018-12-28 CN CN201811625294.1A patent/CN110204204B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003327484A (en) * | 2002-05-15 | 2003-11-19 | Fumitaka Fujiwara | Glaze for kimachi stone |
| CN104150965A (en) * | 2014-08-07 | 2014-11-19 | 福建省太古陶瓷有限责任公司 | Copper red glaze formula and manufacturing process of copper red glaze porcelain |
| CN106396382A (en) * | 2016-08-31 | 2017-02-15 | 福建省德化佳诚陶瓷有限公司 | Colorful glazed porcelain prepared from limestone tailings, and manufacture technology thereof |
| CN109020217A (en) * | 2018-09-28 | 2018-12-18 | 佛山科学技术学院 | A kind of red glaze of wide an ancient unit of weight and its method for cooking |
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