CN102910892A - Black ceramic plate prepared by natural minerals and extracted vanadium tailings and preparation method of black ceramic plate - Google Patents
Black ceramic plate prepared by natural minerals and extracted vanadium tailings and preparation method of black ceramic plate Download PDFInfo
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- CN102910892A CN102910892A CN2012103682821A CN201210368282A CN102910892A CN 102910892 A CN102910892 A CN 102910892A CN 2012103682821 A CN2012103682821 A CN 2012103682821A CN 201210368282 A CN201210368282 A CN 201210368282A CN 102910892 A CN102910892 A CN 102910892A
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Abstract
A black ceramic plate prepared by natural minerals and vanadium tailings comprises, by weight, 0-10% of the extracted vanadium tailings, 0-10% of chromite, 0-10% of manganese oxide ore, 58-65% of clay, 9-20% of feldspar, 5-10% of sand, 1-3% of additives and the balance inevitable trace impurities. A preparation method of the black ceramic plate includes the steps: drying for dewatering, crushing and sieving 0-10% of the extracted vanadium tailings, 0-10% of the chromite and 0-10% of the manganese oxide ore to form mixed powder; mixing and proportioning the mixed powder with 58-65% of the clay, 9-20% of the feldspar, 5-10% of the sand and 1-3% of the additives to prepare mud pellets with the water content of 14%-19%, forming by dry pressing or wet extrusion; and drying a formed green body in a drying kiln of a production line at the temperature of not more than 150 DEG C, and sintering at the temperature of 1000-1200 DEG C after drying so that the black ceramic plate is prepared.
Description
Technical field
The invention belongs to technical field of construction and decoration materials, especially a kind of black pottery plate that utilizes natural mineral raw and tailings in vanadium extraction preparation and preparation method thereof.
Background technology
The pottery plate is as main raw material take natural potter's clay, by mixing other compositions such as quartz, float stone, feldspar and colorant outward, fire under the high temperature through wet-method extrusion moulding, cryodrying and 1000-1200 ℃ and form, have environmental protection, radiationless, color and luster is gentle, do not bring the characteristics such as light pollution.Therefore, ceramic plate curtain wall just more and more is subject to the welcome in market as energy-saving environment protection curtain wall.In conjunction with the requirement of the market requirement and actual production technique, need to use the pottery panel products that multiple ceramic pigment is produced different tones in the production of pottery plate.For example occupy the black pottery plate of the larger market share, need to use the traditional ceramics black pigment, but because the traditional ceramics black pigment is expensive, thereby so that black pottery plate production cost is high; On the other hand, the production of traditional ceramics black pigment not only produces energy consumption, and can bring the pollution to environment.Thereby a kind of energy-conserving and environment-protective pottery plate purposes black pigment of following searching seems particularly urgent.
Chromite and manganese oxide ore all are natural mineral raws, and ore contains the non-ferrous components such as Cr, Fe, Mn, can be used as the environmental protection and energy saving main raw material of black ceramic colorant.In addition, tailings in vanadium extraction is remaining waste residue behind the industrial abstract vanadic salts, tailings in vanadium extraction is rich in the complex compound of the period 4 elements such as Fe, Cr, Mn, V, Ti, mineral composition and crystalline structure are complicated and stablize, until present black under the condition of melting, be suitable as a kind of ceramic black pigment with low cost at normal temperature, high temperature.Chinese patent (CN 102167598 A) provides a kind of method of utilizing tailings in vanadium extraction to make vanadium titanium pottery, utilize tailings in vanadium extraction preparation to have the vanadium titanium function ceramics of good optical-thermal conversion material, have water-fast, high strength, corrosion-resistant, anti-aging, life-span length, high sunlight absorption rate, high photo-thermal conversion efficiency and the higher characteristics such as low temp. infrared radiation rate.But for pottery plate special producing technique and to the multifarious demand of product colour, single mineral are difficult to satisfy product color development demand, and also someone proposes to utilize natural mineral or tailings to prepare the preparation method of black pottery plate at present.
Chinese patent (CN102617116A) discloses a kind of method of utilizing industrial slag to prepare ceramic black material, industrial slag 80～95%, cobalt oxide 0～5%, chromic oxide 5～15%.Through mixing, calcining, pulverizing, washing, oven dry, pulverizing, dry acquisition colorant goods, wherein calcining temperature is 1000～1100 ℃, soaking time 60min.Can generate (Fe through solid state reaction
0.6Cr
0.4)
2O
3Xenocryst mixed type spinel particle, SiO
2And NiTiO
3Its sosoloid all absorbs the visible light of 380～780nm section, thereby obtains being colour-stable, the ceramic black material that colourity is pure, and its cost is low, colorimetric purity is high, and it is colour-stable that high temperature is.Can be widely used in various high low temperature daily, building, art pottery enamel and blank colorant, and Industry Waste slag charge recycling is significant, its patent has effectively solved the problem that prior art exists, but it only is a kind of colorant preparation method who industrial residue and nonferrous metal oxides is treated as ceramic pigment, its the finished product are ceramic pigment, and fail to realize directly utilizing industrial waste and the natural mineral color development in ceramic body, on the other hand owing to need to prepare ceramic pigment by additional technique, so the method must cause extra energy consumption.
Summary of the invention
The present invention is directed to above-mentioned technical problem, provide a kind of energy-conserving and environment-protective, technological process simple, be fit to scale operation, can freely allocate the preparation method of the black pottery plate of different black tone.
The present invention is for solving the problems of the technologies described above, a kind of black pottery plate that utilizes natural mineral and tailings in vanadium extraction preparation is provided, its raw material comprises that weight percent is: 0 ~ 10% tailings in vanadium extraction, 0 ~ 10% chromite, 0 ~ 10% manganese oxide ore, 58 ~ 65% clay, 9 ~ 20% feldspar, 5 ~ 10% sand, 1 ~ 3% additive, all the other are inevitable trace impurity.
Described additive is ceramic powder binding agent, for example Natvosol.
Provide following preparation method for preparing above-mentioned black pottery plate: a kind of black pottery plate preparation method who utilizes natural mineral and tailings in vanadium extraction preparation, may further comprise the steps: (1) with 0 ~ 10% tailings in vanadium extraction, 0 ~ 10% chromite, 0 ~ 10% manganese oxide ore carry out drying and dehydrating, fragmentation, the processing of sieving, form mixed powder;
(2) clay of above-mentioned powder and 58 ~ 65%, 9 ~ 20% feldspar, 5 ~ 10% sand, 1 ~ 3% additive are carried out mixing match, make the walk of water ratio 14% ~ 19%, with dry-pressing formed or wet method extrusion molding;
(3) base substrate after the above-mentioned moulding is carried out drying at the production line dry kiln, dried dry Wen Du＜=150 ℃ carries out sintering after the drying under temperature 1000-1200 ℃, preparation black pottery plate.
Preferred as the present invention, tailings in vanadium extraction is treated to water ratio Zai＜=2% and median size D
50Powder less than 147 μ m.
Preferred as the present invention, chromite and manganese oxide ore are treated to water ratio Zai＜=1% and median size D
50Powder less than 43 μ m.
Beneficial effect of the present invention:
1. preparation method of the present invention is take natural mineral and tailings as main color development raw material, and wherein chromite and manganese oxide ore raw material are natural mineral, stop to produce the colorant process to the pollution of environment; The recycling of tailings in vanadium extraction can be finished simultaneously, tailings in vanadium extraction can be solved to the pollution problem of environment.
2. preparation method of the present invention saves the ceramic pigment manufacturing procedure, realizes low-carbon energy-saving.
3. preparation method of the present invention can select dry-pressing formed or the wet method extrusion molding, and ceramic molding is had general adaptability, therefore can use in all kinds of ceramic moldings.
4. the employed tailings in vanadium extraction of preparation method of the present invention alternative pottery black pigment not only has simultaneously low temperature and helps and melt effect, can reduce in the Production of Ceramics demand to feldspar equal solvent class raw material.
5. preparation method of the present invention can prepare the architectural terra-cotta (ATC) with different blackness and tone by adjusting adding kind and the add-on of the raw materials such as chromite, manganese oxide ore and tailings in vanadium extraction, satisfies the rich of product.
6. preparation method of the present invention utilizes the raw materials such as chromite, manganese oxide ore and tailings in vanadium extraction to prepare black pottery plate, because it is natural mineral or industrial waste, therefore can significantly reduce black pottery plate cost.
Embodiment
A kind of black pottery plate that utilizes natural mineral and tailings in vanadium extraction preparation, its raw material comprises that weight percent is: the clay of the tailings in vanadium extraction of 0-10%, the chromite of 0-10%, 0-10% manganese oxide ore, 58-65%, the feldspar of 9-20%, the sand of 5-10%, the additive of 1-3%, all the other are inevitable trace impurity.Described additive is the ceramic powder binding agent, preferred Natvosol.
A kind of black pottery plate preparation method who utilizes natural mineral and tailings in vanadium extraction preparation may further comprise the steps:
(1) 0 ~ 10% tailings in vanadium extraction, 0 ~ 10% chromite, 0 ~ 10% manganese oxide ore are carried out drying and dehydrating, fragmentation, the processing of sieving, form mixed powder;
(2) clay of above-mentioned powder and 58 ~ 65%, 9 ~ 20% feldspar, 5 ~ 10% sand, 1 ~ 3% additive are carried out mixing match, make the walk of water ratio 14% ~ 19%, with dry-pressing formed or wet method extrusion molding;
(3) base substrate after the above-mentioned moulding is carried out drying at the production line dry kiln, do dry Wen Du＜=150 ℃, under 1000 ~ 1200 ℃ of temperature, carry out sintering, preparation black pottery plate after dry.
As preferably, tailings in vanadium extraction is treated to water ratio Zai＜=2% and median size D
50Powder less than 147 μ m.
As preferably, chromite and manganese oxide ore are treated to water ratio Zai＜=1% and median size D
50Powder less than 43 μ m.
More than be basic embodiment of the present invention, below the preferred embodiments of the present invention are introduced in detailed annotation:
Embodiment 1:
Get at first that some chromites carry out fragmentation and the processing of sieving, chromite is treated to water ratio Zai＜=1% and median size less than the powder of 43 μ m.Chromite powder and clay, feldspar, sand class are carried out weighing in the ratio of example in the table 11, and use mixer and pug mill that it is disperseed, be made into water ratio at 14 %-19 % walks, then be made into the pottery clay plates of 300 * 120 * 18 mm with extrusion shaping machine.Putting it into five layers of dry kiln of production line after the moulding carries out drying (is 300 min drying cycle, Gao Wendu＜=150 ℃), the drying water that product goes out behind the dry kiln is divided into＜1 %, be 1170 ℃ in top temperature at last, firing period is the sintering of finishing pottery clay plates in the roller kiln of 255 min.Based on identical preparation method, the contrast of the physicals of mineral color development black pottery clay plates and traditional architecture pottery clay plates and cost is as shown in table 2 behind the sintering.
Embodiment two:
Get at first that some tailings in vanadium extraction carry out drying and dehydrating, fragmentation and the processing of sieving, tailings in vanadium extraction is treated to water ratio Zai＜=2 % and median size less than the powder of 147 μ m; Get that some chromites carry out fragmentation and the processing of sieving, chromite is treated to water ratio Zai＜=1 % and median size less than the powder of 43 μ m.Tailings in vanadium extraction, chromite powder and clay, feldspar, sand class are carried out weighing in the ratio of example in the table 12, and use mixer and pug mill that it is disperseed, be made into water ratio at the 14%-19% walk, then be made into the pottery clay plates of 300 * 120 * 18 mm with extrusion shaping machine.Putting it into five layers of dry kiln of production line after the moulding carries out drying (is 300 min drying cycle, top temperature is 150 ℃), the drying water that product goes out behind the dry kiln is divided into＜1 %, be 1170 ℃ in top temperature at last, firing period is the sintering of finishing pottery clay plates in the roller kiln of 255 min.Based on identical preparation method, the contrast of the physicals of mineral color development black pottery clay plates and traditional architecture pottery clay plates and cost is as shown in table 2 behind the sintering.
Embodiment three:
Get at first that some tailings in vanadium extraction carry out drying and dehydrating, fragmentation and the processing of sieving, tailings in vanadium extraction is treated to water ratio Zai＜=2 % and median size less than the powder of 147 μ m; Get that some chromites carry out fragmentation and the processing of sieving, chromite is treated to water ratio Zai＜=1% and median size less than the powder of 43 μ m.Tailings in vanadium extraction, chromite powder and clay, feldspar, sand class are carried out weighing in the ratio of example in the table 13, and use mixer and pug mill that it is disperseed, be made into water ratio at 14 %-19 % walks, then be made into the pottery clay plates of 300 * 120 * 18 mm with extrusion shaping machine.Putting it into five layers of dry kiln of production line after the moulding carries out drying (is 300 min drying cycle, top temperature is 150 ℃), the drying water that product goes out behind the dry kiln is divided into＜1 %, be 1170 ℃ in top temperature at last, firing period is the sintering of finishing pottery clay plates in the roller kiln of 255 min.Based on identical preparation method, the contrast of the physicals of mineral color development black pottery clay plates and traditional architecture pottery clay plates and cost is as shown in table 2 behind the sintering.
Embodiment four:
Get at first that some tailings in vanadium extraction carry out drying and dehydrating, fragmentation and the processing of sieving, tailings in vanadium extraction is treated to water ratio Zai＜=2% and median size less than the powder of 147 μ m; Get some chromites and manganese oxide ore and carry out respectively fragmentation and the processing of sieving, chromite and manganese oxide ore are treated to respectively water ratio Zai＜=1% and median size less than the powder of 43 μ m.Tailings in vanadium extraction, chromite powder, manganese oxide ore and clay, feldspar, sand class are carried out weighing in the ratio of example in the table 14, and use mixer and pug mill that it is disperseed, be made into water ratio at the 14%-19% walk, then be made into the pottery clay plates of 300 * 120 * 18mm with extrusion shaping machine.Putting it into five layers of dry kiln of production line after the moulding carries out drying (is 300min drying cycle, top temperature is 150 ℃), the drying water that product goes out behind the dry kiln is divided into＜1 %, is 1170 ℃ in top temperature at last, and firing period is the sintering of finishing pottery clay plates in the roller kiln of 255min.Based on identical preparation method, the contrast of the physicals of mineral color development black pottery clay plates and traditional architecture pottery clay plates and cost is as shown in table 2 behind the sintering.
Embodiment five:
Get at first that some tailings in vanadium extraction carry out drying and dehydrating, fragmentation and the processing of sieving, tailings in vanadium extraction is treated to water ratio Zai＜=2% and median size less than the powder of 147 μ m; Get some chromites and manganese oxide ore and carry out respectively fragmentation and the processing of sieving, chromite and manganese oxide ore are treated to respectively water ratio Zai＜=1% and median size less than the powder of 43 μ m.Tailings in vanadium extraction, chromite powder, manganese oxide ore and clay, feldspar, sand class are carried out weighing in the ratio of example in the table 14, and use mixer and pug mill that it is disperseed, be made into water ratio at the 14%-19% walk, then be made into the pottery clay plates of 300 * 120 * 18mm with extrusion shaping machine.Putting it into five layers of dry kiln of production line after the moulding carries out drying (is 300min drying cycle, top temperature is 150 ℃), the drying water that product goes out behind the dry kiln is divided into＜1 %, is 1000 ℃ in top temperature at last, and firing period is the sintering of finishing pottery clay plates in the roller kiln of 255min.Based on identical preparation method, the contrast of the physicals of mineral color development black pottery clay plates and traditional architecture pottery clay plates and cost is as shown in table 2 behind the sintering.
Embodiment six:
Get at first that some tailings in vanadium extraction carry out drying and dehydrating, fragmentation and the processing of sieving, tailings in vanadium extraction is treated to water ratio Zai＜=2% and median size less than the powder of 147 μ m; Get some manganese oxide ores and carry out respectively fragmentation and the processing of sieving, manganese oxide ore is treated to respectively water ratio Zai＜=1% and median size less than the powder of 43 μ m.Manganese oxide ore, tailings in vanadium extraction and clay, feldspar, sand class are carried out weighing in the ratio of example in the table 14, and use mixer and pug mill that it is disperseed, be made into water ratio at the 14%-19% walk, then be made into the pottery clay plates of 300 * 120 * 18mm with extrusion shaping machine.Putting it into five layers of dry kiln of production line after the moulding carries out drying (is 300min drying cycle, top temperature is 150 ℃), the drying water that product goes out behind the dry kiln is divided into＜1 %, is 1200 ℃ in top temperature at last, and firing period is the sintering of finishing pottery clay plates in the roller kiln of 255min.Based on identical preparation method, the contrast of the physicals of mineral color development black pottery clay plates and traditional architecture pottery clay plates and cost is as shown in table 2 behind the sintering.
Embodiment seven:
Get that some chromites carry out fragmentation and the processing of sieving, chromite is treated to water ratio Zai＜=1% and median size less than the powder of 43 μ m.Chromite and clay, feldspar, sand class are carried out weighing in the ratio of example in the table 11, and use mixer and pug mill that it is disperseed, be made into water ratio at 14 %-19 % walks, then be made into the pottery clay plates of 300 * 120 * 18 mm with extrusion shaping machine.Putting it into five layers of dry kiln of production line after the moulding carries out drying (is 300 min drying cycle, Gao Wendu＜=150 ℃), the drying water that product goes out behind the dry kiln is divided into＜1 %, be 1170 ℃ in top temperature at last, firing period is the sintering of finishing pottery clay plates in the roller kiln of 255 min.Based on identical preparation method, the contrast of the physicals of mineral color development black pottery clay plates and traditional architecture pottery clay plates and cost is as shown in table 2 behind the sintering.
Embodiment eight:
Get at first that some tailings in vanadium extraction carry out drying and dehydrating, fragmentation and the processing of sieving, tailings in vanadium extraction is treated to water ratio Zai＜=2% and median size less than the powder of 147 μ m; Get some chromites and manganese oxide ore and carry out respectively fragmentation and the processing of sieving, chromite and manganese oxide ore are treated to respectively water ratio Zai＜=1% and median size less than the powder of 43 μ m.Tailings in vanadium extraction, chromite powder, manganese oxide ore and clay, feldspar, sand class are carried out weighing in the ratio of example in the table 14, and use mixer and pug mill that it is disperseed, be made into water ratio at the 14%-19% walk, then be made into the pottery clay plates of 300 * 120 * 18mm with extrusion shaping machine.Putting it into five layers of dry kiln of production line after the moulding carries out drying (is 300min drying cycle, top temperature is 150 ℃), the drying water that product goes out behind the dry kiln is divided into＜1 %, is 1000 ℃ in top temperature at last, and firing period is the sintering of finishing pottery clay plates in the roller kiln of 255min.Based on identical preparation method, the contrast of the physicals of mineral color development black pottery clay plates and traditional architecture pottery clay plates and cost is as shown in table 2 behind the sintering.
Table 1
[0030]Product performance contrast behind table 2 sintering
Claims (6)
1. black pottery plate that utilizes the preparation of natural mineral and tailings in vanadium extraction, its raw material comprises that weight percent is: 0 ~ 10% tailings in vanadium extraction, 0 ~ 10% chromite, 0 ~ 10% manganese oxide ore, 58 ~ 65% clay, 9 ~ 20% feldspar, 5 ~ 10% sand, 1 ~ 3% additive, all the other are inevitable trace impurity.
2. a kind of black pottery plate that utilizes natural mineral and tailings in vanadium extraction preparation according to claim 1 is characterized in that described additive is the ceramic powder binding agent.
3. a kind of black pottery plate that utilizes natural mineral and tailings in vanadium extraction preparation according to claim 2 is characterized in that the ceramic powder binding agent is Natvosol.
4. a kind of black pottery plate preparation method who utilizes the preparation of natural mineral and tailings in vanadium extraction according to claim 1, may further comprise the steps: (1) with 0 ~ 10% tailings in vanadium extraction, 0 ~ 10% chromite, 0 ~ 10% manganese oxide ore carry out drying and dehydrating, fragmentation, the processing of sieving, form mixed powder;
(2) clay of above-mentioned powder and 58 ~ 65%, 9 ~ 20% feldspar, the sand of 5-10%, the additive of 1-3% are carried out mixing match, make the walk of water ratio 14% ~ 19%, with dry-pressing formed or wet method extrusion molding;
(3) base substrate after the above-mentioned moulding is carried out drying at the production line dry kiln, do dry Wen Du＜=150 ℃, under 1000 ~ 1200 ℃ of temperature, carry out sintering, preparation black pottery plate after dry.
5. a kind of black pottery plate preparation method who utilizes natural mineral and tailings in vanadium extraction preparation according to claim 3 is characterized in that tailings in vanadium extraction is treated to water ratio Zai＜=2% and median size D
50Powder less than 147 μ m.
6. a kind of black pottery plate preparation method who utilizes natural mineral and tailings in vanadium extraction preparation according to claim 3 is characterized in that chromite and manganese oxide ore are treated to water ratio Zai＜=1% and median size D
50Powder less than 43 μ m.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103979932A (en) * | 2014-05-08 | 2014-08-13 | 山东雅美特建陶有限公司 | Black ceramic plate and making method thereof |
| CN104961501A (en) * | 2015-07-29 | 2015-10-07 | 陈文源 | Black glaze prepared by utilizing manganese ore tailing residue as main raw material |
| CN106747333A (en) * | 2016-12-21 | 2017-05-31 | 周易 | A kind of high tenacity ceramic material and preparation method thereof |
| CN106830884A (en) * | 2016-12-21 | 2017-06-13 | 周易 | A kind of oxidation resistance ceramics and preparation method thereof |
| CN107056247A (en) * | 2016-12-21 | 2017-08-18 | 周易 | A kind of high tenacity ceramic material and preparation method thereof |
| CN107056246A (en) * | 2016-12-21 | 2017-08-18 | 周易 | A kind of high temperature ceramic material and preparation method thereof |
| CN107417255A (en) * | 2017-09-12 | 2017-12-01 | 山东省科学院新材料研究所 | The recycling treatment Application way of chromium slag, tailings in vanadium extraction waste pollutant |
| CN114891376A (en) * | 2022-05-07 | 2022-08-12 | 武汉科技大学 | High-emissivity infrared radiation coating based on chromium chemical slag, coating and preparation method thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103979932A (en) * | 2014-05-08 | 2014-08-13 | 山东雅美特建陶有限公司 | Black ceramic plate and making method thereof |
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| CN104961501A (en) * | 2015-07-29 | 2015-10-07 | 陈文源 | Black glaze prepared by utilizing manganese ore tailing residue as main raw material |
| CN106747333A (en) * | 2016-12-21 | 2017-05-31 | 周易 | A kind of high tenacity ceramic material and preparation method thereof |
| CN106830884A (en) * | 2016-12-21 | 2017-06-13 | 周易 | A kind of oxidation resistance ceramics and preparation method thereof |
| CN107056247A (en) * | 2016-12-21 | 2017-08-18 | 周易 | A kind of high tenacity ceramic material and preparation method thereof |
| CN107056246A (en) * | 2016-12-21 | 2017-08-18 | 周易 | A kind of high temperature ceramic material and preparation method thereof |
| CN107417255A (en) * | 2017-09-12 | 2017-12-01 | 山东省科学院新材料研究所 | The recycling treatment Application way of chromium slag, tailings in vanadium extraction waste pollutant |
| CN114891376A (en) * | 2022-05-07 | 2022-08-12 | 武汉科技大学 | High-emissivity infrared radiation coating based on chromium chemical slag, coating and preparation method thereof |
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Application publication date: 20130206 |