CN106395728A - Micro-bridge structure Mn-Co-Ni-O thin film infrared detector and preparation method thereof - Google Patents

Micro-bridge structure Mn-Co-Ni-O thin film infrared detector and preparation method thereof Download PDF

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Publication number
CN106395728A
CN106395728A CN201610893671.4A CN201610893671A CN106395728A CN 106395728 A CN106395728 A CN 106395728A CN 201610893671 A CN201610893671 A CN 201610893671A CN 106395728 A CN106395728 A CN 106395728A
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manganese cobalt
cobalt nickel
nickel oxygen
polyimides
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CN106395728B (en
Inventor
黄志明
张飞
周炜
吴敬
黄敬国
高艳卿
曲越
孙雷
江林
姚娘娟
褚君浩
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Shanghai Institute of Technical Physics of CAS
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Shanghai Institute of Technical Physics of CAS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B1/00Devices without movable or flexible elements, e.g. microcapillary devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00436Shaping materials, i.e. techniques for structuring the substrate or the layers on the substrate
    • B81C1/00444Surface micromachining, i.e. structuring layers on the substrate
    • B81C1/00468Releasing structures
    • B81C1/00476Releasing structures removing a sacrificial layer
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/10Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors
    • G01J5/20Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors using resistors, thermistors or semiconductors sensitive to radiation, e.g. photoconductive devices

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Photometry And Measurement Of Optical Pulse Characteristics (AREA)
  • Radiation Pyrometers (AREA)
  • Solid State Image Pick-Up Elements (AREA)

Abstract

The invention discloses a micro-bridge structure Mn-Co-Ni-O thin film infrared detector and a preparation method thereof. A micro-bridge structure of the detector is a platform. A Mn-Co-Ni-O thin film material is deposited on the platform to prepare the infrared detector. A sacrificial layer of the micro-bridge structure is eliminated in a direct heating mode without depositing a passivation layer on a Mn-Co-Ni-O detection element. The sacrificial layer can form an arched support structure in the internal part. A preparation process is simplified. The cost is saved. A device preparation success rate can be improved. Moreover, the structure strength of the platform is relatively high. The platform is not liable to damage in black paint coating and packaging steps of the infrared element.

Description

A kind of micro-bridge structure manganese cobalt nickel oxygen film Infrared Detectorss and preparation method thereof
Technical field
Patent of the present invention is related to Infrared Detectorss, specifically a kind of infrared detector with micro-bridge structure part and preparation method thereof.
Background technology
Excellent negative temperature resistance characteristic is had with the non-refrigeration type infrared detector that manganese cobalt nickel oxygen film material makes, Have passed through the research and development of decades, its performance is greatly improved.Reduction due to thin-film material thickness can make infrared letter Number absorption weaken, so typically adopting japanning to increase INFRARED ABSORPTION in technique;The reduction of thin-film material thickness also leads to visit The thermal capacitance surveying unit reduces, so that its response time becomes big, responsiveness reduces, and therefore, should reduce the heat conductivity of thin-film material To keep response sensitivity, increase responsiveness simultaneously.
It is used on Infrared Detectorss as the micro-bridge structure of substrate using low-resistance silicon and can reduce thermal conductivity, improve infrared signal Absorbance, the sensitivity for manganese cobalt nickel oxygen film material Infrared Detectorss and the raising of detectivity play an important role.In microbridge In the manufacturing process of structure, need detecting one layer of passivation layer of deposition in unit with PECVD, to carry out reactive ion etching, Expose sacrifice layer.Removal for sacrifice layer often selects oxygen plasma dry etching, easily causes plasma-induced damage Wound, and be difficult to make the micro-bridge structure of high-aspect-ratio;And the reactive ion etching of slab construction is due to adopting high-energy ion bombardment Physical etchings, chemical isotropic is poor.
The preparation method of the microbridge infrared detector that this patent is related to, can improve the intensity of microbridge, so as to spy Survey first japanning, carry out being unlikely to damage micro-bridge structure during device encapsulation;It is at the same time it can also simplify Making programme, cost-effective, Improve the success rate of element manufacturing.
Content of the invention
The present invention is to make a kind of infrared detector with micro-bridge structure and preparation method thereof, detects first material and adopts manganese cobalt nickel Oxygen thin film.The sacrifice layer of the micro-bridge structure of this patent design can internally form the supporting construction of arch, improves microbridge knot The intensity of structure is so as to can be compatible with the processing technology of manganese cobalt nickel oxygen film Infrared Detectorss, and efficiently solves film type The low problem of the response time length of Infrared Detectorss, responsiveness.
A kind of structure chart of infrared detector with micro-bridge structure is as shown in Figure 1, Figure 2 and Fig. 3.It includes manganese cobalt nickel oxygen film 1, dioxy SiClx layer 2, silicon nitride layer 3, polyimide sacrificial layer 4 and low-resistance silicon substrate 5;Described Infrared Detectorss are from low-resistance silicon substrate 5 On be followed successively by polyimide sacrificial layer 4, silicon nitride layer 3, silicon dioxide layer 2 and manganese cobalt nickel oxygen film 1, in manganese cobalt nickel oxygen film There are chromium and golden clad metal electrode 6 on 1;Wherein:
Described polyimide sacrificial layer 4 is domed sacrifice layer, and dome height is 1-3 μm, and sacrificial layer thickness is 1-3 μm, sacrifice layer and silicon dioxide flat contact;
The thickness 50-500nm of described silicon nitride layer 3;
Described, the thickness 50-500nm of silicon dioxide layer 2;
0.1-2 μm of the thickness of described manganese cobalt nickel oxygen film 1.
Micro-bridge structure panel detector structure designed by the present invention is realized by processing step in detail below:
1) a strata imide membrane (PI) is precipitated on low resistance silicon chip as sacrifice layer, sacrificial layer thickness is 1-3 μm;
2) under nitrogen atmosphere protection, imidization process is carried out to polyimides;
3) to polyimides exposure, development, produce polyimides platform;
4) first deposit one layer of silicon nitride using PECVD, redeposited layer of silicon dioxide is as structure sheaf;
5) adopt certain method to deposit certain thickness manganese cobalt nickel oxygen film, and thin film is made annealing treatment;
6) photoetching, burn into development treatment are carried out to the manganese cobalt nickel oxygen film after annealing, polyimides platform is produced Manganese cobalt nickel oxygen film detects unit;
7) adopt photoetching, development treatment, produce the photoresist of the electrode shape at cloudy quarter, using the plating of double ion sputtering method Chrome gold electrode, thickness is respectively 30nm, 150nm;
8) wash away photoresist with acetone, whole device is put into heating in quick anneal oven, heating-up temperature is in 400-800 DEG C, make polyimides decomposition gasification, remove polyimides.
The advantage of this patent is:Remove polyimide sacrificial layer by device is placed on to anneal in quick anneal oven, Can avoid precipitating passivation layer, thus reducing the follow-up step such as photoetching, reactive ion etching, simplify Making programme, saving into This;Meanwhile, the shape of micro-bridge structure can improve its intensity, for keeping when detecting first japanning, carrying out device encapsulation Certain intensity and be not destroyed, improve element manufacturing success rate.
Brief description
Fig. 1 is the profile of the infrared detector with micro-bridge structure part structure before heating sacrifice layer, in figure:1st, manganese cobalt nickel oxygen is thin Film, 2, silicon dioxide layer, 3, silicon nitride layer, 4, polyimide sacrificial layer, 5, low-resistance silicon substrate.
Fig. 2 is the profile of the microbridge infrared device structure after directly heating sacrifice layer.After heating, sacrifice layer is put down in microbridge Platform is internally formed domes.
Fig. 3 is the top view plating microbridge infrared device structure after electrode, in figure:6:Chromium and golden clad metal electrode.
Specific embodiment
Below in conjunction with accompanying drawing, by instantiation, this patent is described in further details, but the protection domain of this patent It is not limited to following instance.
Embodiment 1:
1 precipitates one layer of photosensitive polyimide film (ZKPI) as sacrifice layer in low resistance silicon chip, and the speed of sol evenning machine is adjusted 3000 turns, 20 seconds of system, the sacrificial layer thickness of institute's spin coating is 1 μm.
The 2 pairs of polyimides under nitrogen atmosphere protection respectively at 150 DEG C, 180 DEG C, 250 DEG C insulation 60 minutes so as to sub- Amination.
3 pairs of polyimides exposures, developments, produce 70 × 70 μm2Platform.
4 first deposit the silicon nitride of one layer of 50nm, the silicon dioxide of redeposited one layer of 50nm using PECVD.
5 sputter, using magnetron sputtering method, the manganese cobalt nickel oxygen film that a layer thickness is 100nm, and thin film are carried out annealing treatment Reason, annealing temperature is 200 DEG C, 5 minutes.
Manganese cobalt nickel oxygen film after 6 pairs of annealing carries out photoetching, burn into development treatment, produces on polyimides platform 50×50μm2Manganese cobalt nickel oxygen film detect unit.
7 adopt photoetching, development treatment, produce the photoresist of the electrode shape at cloudy quarter, using double ion sputtering method chromium plating/ Gold electrode, thickness is respectively 30nm, 150nm.
8 wash away photoresist with acetone, and whole device is put in quick anneal oven, heat 10 minutes, make to gather at 400 DEG C Acid imide decomposition gasification, removes polyimides.
Embodiment 2:
1 precipitates one layer of photosensitive polyimide film (ZKPI) as sacrifice layer in low resistance silicon chip, and the speed of sol evenning machine is adjusted 3000 turns, 20 seconds of system, the sacrificial layer thickness of institute's spin coating is 2 μm.
The 2 pairs of polyimides under nitrogen atmosphere protection respectively at 150 DEG C, 180 DEG C, 250 DEG C insulation 60 minutes so as to sub- Amination.
3 pairs of polyimides exposures, developments, produce 70 × 70 μm2Platform.
4 first deposit the silicon nitride of one layer of 200nm, the silicon dioxide of redeposited one layer of 200nm using PECVD.
5 sputter, using magnetron sputtering method, the manganese cobalt nickel oxygen film that a layer thickness is 700nm, and thin film are carried out annealing treatment Reason, annealing temperature is 200 DEG C, 5 minutes.
Manganese cobalt nickel oxygen film after 6 pairs of annealing carries out photoetching, burn into development treatment, produces on polyimides platform 50×50μm2Manganese cobalt nickel oxygen film detect unit.
7 adopt photoetching, development treatment, produce the photoresist of the electrode shape at cloudy quarter, using double ion sputtering method chromium plating/ Gold electrode, thickness is respectively 30nm, 150nm.
8 wash away photoresist with acetone, and whole device is put in quick anneal oven, heat 10 minutes, make to gather at 500 DEG C Acid imide decomposition gasification, removes polyimides.
Embodiment 3:
1 precipitates one layer of photosensitive polyimide film (ZKPI) as sacrifice layer in low resistance silicon chip, and the speed of sol evenning machine is adjusted 3000 turns, 20 seconds of system, the sacrificial layer thickness of institute's spin coating is 3 μm.
The 2 pairs of polyimides under nitrogen atmosphere protection respectively at 150 DEG C, 180 DEG C, 250 DEG C insulation 60 minutes so as to sub- Amination.
3 pairs of polyimides exposures, developments, produce 70 × 70 μm2Platform.
4 first deposit the silicon nitride of one layer of 500nm, the silicon dioxide of redeposited one layer of 500nm using PECVD.
5 sputter, using magnetron sputtering method, the manganese cobalt nickel oxygen film that a layer thickness is 2 μm, and thin film is made annealing treatment, Annealing temperature is 200 DEG C, 5 minutes.
Manganese cobalt nickel oxygen film after 6 pairs of annealing carries out photoetching, burn into development treatment, produces on polyimides platform 50×50μm2Manganese cobalt nickel oxygen film detect unit.
7 adopt photoetching, development treatment, produce the photoresist of the electrode shape at cloudy quarter, using double ion sputtering method chromium plating/ Gold electrode, thickness is respectively 30nm, 150nm.
8 wash away photoresist with acetone, and whole device is put in quick anneal oven, heat 10 minutes, make to gather at 800 DEG C Acid imide decomposition gasification, removes polyimides.

Claims (2)

1. a kind of micro-bridge structure manganese cobalt nickel oxygen film Infrared Detectorss, including manganese cobalt nickel oxygen film (1), silicon dioxide layer (2), nitrogen SiClx layer (3), polyimide sacrificial layer (4) and low-resistance silicon substrate (5);It is characterized in that:
Described Infrared Detectorss be followed successively by from low-resistance silicon substrate (5) polyimide sacrificial layer (4), silicon nitride layer (3), two Silicon oxide layer (2) and manganese cobalt nickel oxygen film (1), have chromium and golden clad metal electrode (6) in manganese cobalt nickel oxygen film (1);
Described polyimide sacrificial layer (4) is domed sacrifice layer, and dome height is 1-3 μm, and sacrificial layer thickness is 1-3 μ M, sacrifice layer and silicon dioxide flat contact;
The thickness 50-500nm of described silicon nitride layer (3);
Described, the thickness 50-500nm of silicon dioxide layer (2);
0.1-2 μm of the thickness of described manganese cobalt nickel oxygen film (1).
2. a kind of prepare a kind of method of micro-bridge structure manganese cobalt nickel oxygen film Infrared Detectorss as claimed in claim 1, it is special Levy and be that method and step is as follows:
1) a strata imide membrane (PI) is precipitated on low resistance silicon chip as sacrifice layer, sacrificial layer thickness is 1-3 μm;
2) under nitrogen atmosphere protection, imidization process is carried out to polyimides;
3) to polyimides exposure, development, produce polyimides platform;
4) first deposit one layer of silicon nitride using PECVD, redeposited layer of silicon dioxide is as structure sheaf;
5) adopt certain method to deposit certain thickness manganese cobalt nickel oxygen film, and thin film is made annealing treatment;
6) photoetching, burn into development treatment are carried out to the manganese cobalt nickel oxygen film after annealing, manganese cobalt is produced on polyimides platform Nickel oxygen thin film detects unit;
7) adopt photoetching, development treatment, produce the photoresist of the electrode shape at cloudy quarter, chrome gold is plated using double ion sputtering method Electrode, thickness is respectively 30nm, 150nm;
8) wash away photoresist with acetone, whole device is put into heating in quick anneal oven, heating-up temperature, at 400-800 DEG C, makes Polyimides decomposition gasification, removes polyimides.
CN201610893671.4A 2016-07-11 2016-10-13 A kind of micro-bridge structure manganese cobalt nickel oxygen film infrared detector and preparation method thereof Active CN106395728B (en)

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Cited By (1)

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CN109238475A (en) * 2018-08-20 2019-01-18 中国科学院上海技术物理研究所 There are the manganese cobalt nickel oxygen thermistor detector and method of bent support leg micro-bridge structure

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CN106044696A (en) * 2016-07-11 2016-10-26 中国科学院上海技术物理研究所 Infrared detector with micro-bridge structure made of manganese-cobalt-nickel-oxygen film and manufacturing method thereof
CN110672211B (en) * 2019-09-11 2020-11-20 中国科学院上海技术物理研究所 Nano-gold modified non-refrigeration infrared detector and manufacturing method thereof
CN110793648A (en) * 2019-11-11 2020-02-14 中国科学院上海技术物理研究所 Aerogel heat insulation structure broadband infrared detector and preparation method thereof

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CN102732848A (en) * 2012-06-25 2012-10-17 中国科学院上海技术物理研究所 Method for preparing single oriented manganese cobalt nickel oxygen film by magnetron sputtering
CN103193190A (en) * 2013-04-11 2013-07-10 电子科技大学 Infrared-terahertz dual-band array detector microbridge structure and production method thereof
CN206142814U (en) * 2016-07-11 2017-05-03 中国科学院上海技术物理研究所 Microbridge structure manganese cobalt nickel oxygen film infrared detector

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US20090278217A1 (en) * 2006-03-20 2009-11-12 Richard Ian Laming Mems device
CN101298313A (en) * 2008-05-30 2008-11-05 中国科学院上海技术物理研究所 Technological process for quickly releasing edge millimeter-level large area film
CN102732848A (en) * 2012-06-25 2012-10-17 中国科学院上海技术物理研究所 Method for preparing single oriented manganese cobalt nickel oxygen film by magnetron sputtering
CN103193190A (en) * 2013-04-11 2013-07-10 电子科技大学 Infrared-terahertz dual-band array detector microbridge structure and production method thereof
CN206142814U (en) * 2016-07-11 2017-05-03 中国科学院上海技术物理研究所 Microbridge structure manganese cobalt nickel oxygen film infrared detector

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Publication number Priority date Publication date Assignee Title
CN109238475A (en) * 2018-08-20 2019-01-18 中国科学院上海技术物理研究所 There are the manganese cobalt nickel oxygen thermistor detector and method of bent support leg micro-bridge structure

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