CN106381076A - Moistureproof light-cured polyester resin - Google Patents
Moistureproof light-cured polyester resin Download PDFInfo
- Publication number
- CN106381076A CN106381076A CN201610773867.XA CN201610773867A CN106381076A CN 106381076 A CN106381076 A CN 106381076A CN 201610773867 A CN201610773867 A CN 201610773867A CN 106381076 A CN106381076 A CN 106381076A
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- CN
- China
- Prior art keywords
- polyester resin
- light
- moistureproof
- cured
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of a high-molecular material, and concretely relates to moistureproof light-cured polyester resin. The polyester resin comprises the following components by weight percentage: 5% of ethoxylated trimethylolpropane triacrylate, 10% of pentaerythritol triacrylate, 10% of phthalic anhydride, 14% of glycerol, 20% of maleic anhydride, 15% of 2-phenoxyl ethyl acrylate, 20% of alpha-methyl styrene, 2% of phenol, 1% of a levelling agent, 1% of an antifoaming agent, 1% of a photoinitiator, and 1% of p-tert-butylcatechol. The polyester resin has the advantages of convenient usage, high solidification efficiency, strong moistureproof capability, and low production cost, the prepared polyester resin can form a condensate with stable physical property and stable compression set, coating shape and storage stability are excellent, while in use, the polyester resin cannot be influenced by weather and humidity.
Description
Technical field
The present invention relates to technical field of polymer materials, especially relate to a kind of protection against the tide light-cured crystal rubber.
Background technology
Its cured product of polyester resin has water-fast, resistance to chemical attack, glittering and translucent feature.Polyester resin on the market at present
It is roughly divided into：Plane flexible glue, plane ebonite, cambered surface flexible glue, cambered surface ebonite, potting compound, technique vacation water, polishing glue etc..Using water
Brilliant glue can play to handicraft, ornaments surface beyond the effect of protection moreover it is possible to increase glossiness and the brightness of product surface.This
The moistureproof light-cured crystal rubber of invention is nontoxic, safety, is easy to operate, cost is relatively low.
Content of the invention
It is an object of the invention to provide a kind of moistureproof, polyester resin of environmental protection.
In order to realize foregoing invention purpose, technical scheme is specific as follows：
A kind of protection against the tide light-cured crystal rubber, is obtained by following components in percentage by weight：Ethoxylated trimethylolpropane 3 third
Olefin(e) acid ester 5%, pentaerythritol triacrylate 10%, phthalic anhydride 10%, glycerine 14%, maleic anhydride 20%, 2- benzene
Epoxide ethyl propylene acid esters 15%, AMS 20%, phenol 2%, levelling agent 1%, defoamer 1%, light trigger 1%, to uncle
Butyl-catechol 1%.
Preferably, described levelling agent be 388,320,358N, one or more in OK, 392,399.
Preferably, described defoamer be 066N, A530, defoamer 6800,141, KV-352, one or more in 354.
Preferably, described light trigger be benzophenone, a kind of or mixing in benzoin ether.
Beneficial effect of the present invention：The present invention is easy to use, and curing efficiency is high, and moisture protection is strong, low production cost, preparation
Polyester resin can form physical characteristic, the especially stable solidfied material of compression set, and its coating shape and storage are stablized
Property is excellent, is not affected by weather, humidity during use.
Specific embodiment
With reference to embodiment, present disclosure is described in further detail.
Embodiment 1
A kind of protection against the tide light-cured crystal rubber, is obtained by following components in percentage by weight：Ethoxylated trimethylolpropane 3 third
Olefin(e) acid ester 5%, pentaerythritol triacrylate 10%, phthalic anhydride 10%, glycerine 14%, maleic anhydride 20%, 2- benzene
Epoxide ethyl propylene acid esters 15%, AMS 20%, phenol 2%, 388 levelling agents 1%, KV-352 defoamer 1%, hexichol first
Ketone 1%, p-tert-Butylcatechol 1%.
Embodiment 2
A kind of protection against the tide light-cured crystal rubber, is obtained by following components in percentage by weight：Ethoxylated trimethylolpropane 3 third
Olefin(e) acid ester 5%, pentaerythritol triacrylate 10%, phthalic anhydride 10%, glycerine 14%, maleic anhydride 20%, 2- benzene
Epoxide ethyl propylene acid esters 15%, AMS 20%, phenol 2%, 399 levelling agents 0.5%, 358N levelling agent 0.5%, 066N
Defoamer 0.8%, 141 defoamers 0.2%, benzophenone 0.4%, benzoin ether 0.6%, p-tert-Butylcatechol 1%.
Embodiment 3
A kind of protection against the tide light-cured crystal rubber, is obtained by following components in percentage by weight：Ethoxylated trimethylolpropane 3 third
Olefin(e) acid ester 5%, pentaerythritol triacrylate 10%, phthalic anhydride 10%, glycerine 14%, maleic anhydride 20%, 2- benzene
Epoxide ethyl propylene acid esters 15%, AMS 20%, phenol 2%, 388 levelling agents 0.1%, 320 levelling agents 0.2%, 358N stream
Flat agent 0.3%, OK levelling agent 0.3%, 392 levelling agents 0.05%, 399 levelling agents 0.05%, 066N defoamer 0.2%, A530 defoamer
0.2%th, 6800 defoamers 0.1%, 141 defoamers 0.1%, KV-352 defoamer 0.2%, 354 defoamers 0.1%, benzoin ether 1%,
P-tert-Butylcatechol 1%.
Although reference be made herein to invention has been described for the explanatory embodiment of the present invention, and above-described embodiment is only this
Bright preferably embodiment, embodiments of the present invention are simultaneously not restricted to the described embodiments it should be appreciated that people in the art
Member can be designed that a lot of other modifications and embodiment, and these modifications and embodiment will fall in principle disclosed in the present application
Within scope and spirit.
Claims (4)
1. a kind of protection against the tide light-cured crystal rubber is it is characterised in that be obtained by following components in percentage by weight：Ethoxylation three hydroxyl
Propane tri 5%, pentaerythritol triacrylate 10%, phthalic anhydride 10%, glycerine 14%, maleic two
Acid anhydrides 20%, 2- phenoxyethyl acrylate 15%, AMS 20%, phenol 2%, levelling agent 1%, defoamer 1%, light draw
Send out agent 1%, p-tert-Butylcatechol 1%.
2. according to claim 1 moistureproof light-cured crystal rubber it is characterised in that：Described levelling agent be 388,320,358N,
One or more in OK, 392,399.
3. according to claim 1 moistureproof light-cured crystal rubber it is characterised in that：Described defoamer is 066N, A530, froth breaking
Agent 6800,141, KV-352, one or more in 354.
4. according to claim 1 moistureproof light-cured crystal rubber it is characterised in that：Described light trigger is benzophenone, peace
A kind of or mixing in the fragrant ether of breath.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773867.XA CN106381076A (en) | 2016-08-31 | 2016-08-31 | Moistureproof light-cured polyester resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773867.XA CN106381076A (en) | 2016-08-31 | 2016-08-31 | Moistureproof light-cured polyester resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106381076A true CN106381076A (en) | 2017-02-08 |
Family
ID=57939254
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610773867.XA Withdrawn CN106381076A (en) | 2016-08-31 | 2016-08-31 | Moistureproof light-cured polyester resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106381076A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108892941A (en) * | 2018-07-25 | 2018-11-27 | 东莞市卓翼新材料科技有限公司 | Nanometer UV stereoscopic crystal glue |
-
2016
- 2016-08-31 CN CN201610773867.XA patent/CN106381076A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108892941A (en) * | 2018-07-25 | 2018-11-27 | 东莞市卓翼新材料科技有限公司 | Nanometer UV stereoscopic crystal glue |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170208 |