CN106281057A - A kind of UV glue - Google Patents

A kind of UV glue Download PDF

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Publication number
CN106281057A
CN106281057A CN201610775777.4A CN201610775777A CN106281057A CN 106281057 A CN106281057 A CN 106281057A CN 201610775777 A CN201610775777 A CN 201610775777A CN 106281057 A CN106281057 A CN 106281057A
Authority
CN
China
Prior art keywords
glue
defoamer
levelling agent
present
epoxy resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610775777.4A
Other languages
Chinese (zh)
Inventor
黄波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu Nashuo Technology Co Ltd
Original Assignee
Chengdu Nashuo Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chengdu Nashuo Technology Co Ltd filed Critical Chengdu Nashuo Technology Co Ltd
Priority to CN201610775777.4A priority Critical patent/CN106281057A/en
Publication of CN106281057A publication Critical patent/CN106281057A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The present invention relates to technical field of polymer materials, specifically about a kind of UV glue, prepared by following components in percentage by weight: modified bisphenol A epoxy resin 10%, Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 10%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2 phenoxyethyl acrylate 15%, α-methylstyrene 13%, phenol 2%, levelling agent 1%, defoamer 1%, light trigger 1%, p-tert-Butylcatechol 1%.Crosslink density of the present invention is high, has good flexibility and toughness, and each component Synergistic modified bisphenol A epoxy resin makes glue of the present invention have the features such as good anti-contracility, easy to use, and curing efficiency is high, and production cost is low.

Description

A kind of UV glue
Technical field
The present invention relates to technical field of polymer materials, especially relate to a kind of UV glue.
Background technology
Its cured product of polyester resin has water-fast, resistance to chemical attack, glittering and translucent feature.Polyester resin the most on the market It is roughly divided into: plane flexible glue, plane ebonite, cambered surface flexible glue, cambered surface ebonite, potting compound, technique vacation water, polishing glue etc..Use water Artware, ornaments surface can be played beyond the effect of protection by brilliant glue, moreover it is possible to increase glossiness and the brightness of product surface.This The UV glue of invention is nontoxic, safety, it is simple to operation, cost is relatively low.
Summary of the invention
It is an object of the invention to provide the UV glue of a kind of protection against the tide, environmental protection.
In order to realize foregoing invention purpose, technical scheme is specific as follows:
A kind of UV glue, is prepared by following components in percentage by weight: modified bisphenol A epoxy resin 10%, Polyethylene Glycol 3%, receive Rice butadiene-styrene rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 10%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2-Phenoxyethyl Acrylate 15%, α-methyl styrene 13%, phenol 2%, levelling agent 1%, defoamer 1%, light trigger 1%, to tert-butyl o benzene Diphenol 1%.
Preferably, described levelling agent be 388,320,358N, in OK, 392,399 one or more.
Preferably, described defoamer be 066N, A530, defoamer 6800,141, KV-352, in 354 one or more.
Preferably, a kind of or mixing during described light trigger is benzophenone, benzoin ether.
Modified bisphenol A epoxy resin is by the raw material of K, Na, Mg metal mixed powder and bisphenol A epoxide resin in mass ratio Mixing for 1:50-70, heating in water bath 80-85 DEG C reaction prepares.
The method have the benefit that crosslink density of the present invention is high, have good flexibility and toughness, each component Synergistic changes Property bisphenol A epoxide resin make glue of the present invention have the features such as good anti-contracility, easy to use, curing efficiency is high, produces Low cost, that the polyester resin of preparation preserves is convenient, chemical-resistance is good, be unlikely to deform, and its coating shape and bin stability Excellence, is not affected by weather, humidity during use, is added with nano diatomite and enhances toughness, and its porous can strengthen Adhesive.
Detailed description of the invention
Below in conjunction with embodiment, present disclosure is described in further detail.
Embodiment 1
A kind of UV glue, is prepared by following components in percentage by weight: modified bisphenol A epoxy resin 10%, Polyethylene Glycol 3%, receive Rice butadiene-styrene rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 10%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2-Phenoxyethyl Acrylate 15%, α-methyl styrene 13%, phenol 2%, 388 levelling agent 1%, KV-352 defoamer 1%, benzophenone 1%, to uncle Butyl-catechol 1%.
Embodiment 2
A kind of UV glue, is prepared by following components in percentage by weight: modified bisphenol A epoxy resin 10%, Polyethylene Glycol 3%, receive Rice butadiene-styrene rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 10%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2-Phenoxyethyl Acrylate 15%, α-methyl styrene 13%, phenol 2%, 399 levelling agent 0.5%, 358N levelling agent 0.5%, 066N defoamer 0.8%, 141 defoamer 0.2%, benzophenone 0.4%, benzoin ether 0.6%, p-tert-Butylcatechol 1%.
Embodiment 3
A kind of UV glue, is prepared by following components in percentage by weight: modified bisphenol A epoxy resin 10%, Polyethylene Glycol 3%, receive Rice butadiene-styrene rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 10%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2-Phenoxyethyl Acrylate 15%, α-methyl styrene 13%, phenol 2%, 388 levelling agent 0.1%, 320 levelling agent 0.2%, 358N levelling agent 0.3%, OK levelling agent 0.3%, 392 levelling agent 0.05%, 399 levelling agent 0.05%, 066N defoamer 0.2%, A530 defoamer 0.2%, 6800 defoamer 0.1%, 141 defoamer 0.1%, KV-352 defoamer 0.2%, 354 defoamer 0.1%, benzoin ether 1%, P-tert-Butylcatechol 1%.
Although reference be made herein to invention has been described for the explanatory embodiment of the present invention, and above-described embodiment is only this Bright preferably embodiment, embodiments of the present invention are also not restricted to the described embodiments, it should be appreciated that people in the art Member can be designed that a lot of other amendments and embodiment, and these amendments and embodiment will fall in principle disclosed in the present application Within scope and spirit.

Claims (4)

1. a UV glue, it is characterised in that prepared by following components in percentage by weight: modified bisphenol A epoxy resin 10%, Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylation trihydroxy methyl third Alkane triacrylate 5%, pentaerythritol triacrylate 10%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2-phenoxyethyl acrylate 15%, α-methyl styrene 13%, phenol 2%, levelling agent 1%, defoamer 1%, light trigger 1%, P-tert-Butylcatechol 1%.
UV glue the most according to claim 1, it is characterised in that: described levelling agent is 388,320,358N, OK, 392,399 In one or more.
UV glue the most according to claim 1, it is characterised in that: described defoamer is 066N, A530, defoamer 6800, 141, KV-352, in 354 one or more.
UV glue the most according to claim 1, it is characterised in that: described light trigger is in benzophenone, benzoin ether one Plant or mixing.
CN201610775777.4A 2016-08-31 2016-08-31 A kind of UV glue Withdrawn CN106281057A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610775777.4A CN106281057A (en) 2016-08-31 2016-08-31 A kind of UV glue

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610775777.4A CN106281057A (en) 2016-08-31 2016-08-31 A kind of UV glue

Publications (1)

Publication Number Publication Date
CN106281057A true CN106281057A (en) 2017-01-04

Family

ID=57672601

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610775777.4A Withdrawn CN106281057A (en) 2016-08-31 2016-08-31 A kind of UV glue

Country Status (1)

Country Link
CN (1) CN106281057A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777326A (en) * 2019-01-22 2019-05-21 广东天劲新能源科技股份有限公司 A kind of UV glue and its coating method promoting battery core security performance
CN114262590A (en) * 2020-09-16 2022-04-01 志光家具(象州)有限公司 Special glue for veneer pasting

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777326A (en) * 2019-01-22 2019-05-21 广东天劲新能源科技股份有限公司 A kind of UV glue and its coating method promoting battery core security performance
CN114262590A (en) * 2020-09-16 2022-04-01 志光家具(象州)有限公司 Special glue for veneer pasting

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WW01 Invention patent application withdrawn after publication

Application publication date: 20170104

WW01 Invention patent application withdrawn after publication