CN106800890A - A kind of UV glue of high viscosity - Google Patents
A kind of UV glue of high viscosity Download PDFInfo
- Publication number
- CN106800890A CN106800890A CN201710119377.2A CN201710119377A CN106800890A CN 106800890 A CN106800890 A CN 106800890A CN 201710119377 A CN201710119377 A CN 201710119377A CN 106800890 A CN106800890 A CN 106800890A
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- CN
- China
- Prior art keywords
- glue
- high viscosity
- defoamer
- epoxy resin
- present
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention relates to technical field of polymer materials, a kind of specifically UV glue on high viscosity is obtained by following components in percentage by weight：Methyl methacrylate pentadiene phenylpropyl alcohol alkene copolymer 3%, modified bisphenol A epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, polyethylene glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%, dibutyl phthalate 4%, Nano carbon white 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 7%, phthalic anhydride 8%, glycerine 7%, maleic anhydride 12%, 2 phenoxyethyl acrylates 15%, α-methylstyrene 10%, phenol 2%, levelling agent 1%, defoamer 1%, light trigger 1%, p-tert-Butylcatechol 1%.Crosslink density of the present invention is high, and with good flexibility and toughness, anti-extrusion ability is strong, high temperature resistant expansion, the features such as each component Synergistic modified bisphenol A epoxy resin makes glue of the present invention have good anti-contracility.
Description
Technical field
The present invention relates to technical field of polymer materials, more particularly, to a kind of UV glue of high viscosity.
Background technology
Polyester resin its cured product has water-fast, resistant to chemical etching, glittering and translucent feature.Current polyester resin on the market
It is roughly divided into：Plane flexible glue, plane ebonite, cambered surface flexible glue, cambered surface ebonite, potting compound, technique vacation water, polishing glue etc..Use water
Brilliant glue can play a part of beyond protection to handicraft, ornaments surface, moreover it is possible to increase glossiness and the brightness of product surface.This
The UV glue of the high viscosity of invention is nontoxic, safety, is easy to operation, and cost is relatively low.
The content of the invention
It is an object of the invention to provide a kind of UV glue of high viscosity.
In order to realize foregoing invention purpose, technical scheme is specific as follows：
A kind of UV glue of high viscosity, is obtained by following components in percentage by weight：Ethyl ester-pentadiene-propenyl benzene is common
Polymers 3%, modified bisphenol A epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, polyethylene glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%,
AIBN4%, Nano carbon white 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 7%, neighbour
Phthalate anhydride 8%, glycerine 7%, maleic anhydride 12%, 2- phenoxyethyl acrylates 15%, AMS
10%th, phenol 2%, levelling agent 1%, defoamer 1%, light trigger 1%, p-tert-Butylcatechol 1%.
Preferably, the levelling agent be 388,320,358N, one or more in OK, 392,399.
Preferably, the defoamer is one or more in 066N, A530, defoamer 6800,141, KV-352,354.
Preferably, the light trigger is a kind of or mixing in benzophenone, benzoin ether.
Modified bisphenol A epoxy resin be by the raw material of K, Na, Mg metal mixed powder and bisphenol A epoxide resin in mass ratio
It is 1:50-70 mixes, and 80-85 DEG C of reaction of heating water bath is obtained.
Beneficial effect of the present invention：Crosslink density of the present invention is high, and with good flexibility and toughness, anti-extrusion ability is strong, resistance to
High-temperature expansion, the features such as each component Synergistic modified bisphenol A epoxy resin makes glue of the present invention have good anti-contracility.
Do not whitened using rear glue, ethyl ester-pentadiene-phenylpropyl alcohol alkene copolymer further enhances resistance to acids and bases and ageing resistance,
Especially impact and transparency tool are increased significantly.Easy to use, curing efficiency is high, low production cost, the crystal of preparation
That glue is preserved is convenient, chemical-resistance is good, be unlikely to deform, and its coating shape and bin stability are excellent, and day is not received when using
The influence of gas, humidity, is added with Nano carbon white and enhances toughness, and its porous performance enhances adhesive.
Specific embodiment
With reference to embodiment, the present invention will be further described.These embodiments are only that typical case of the invention is retouched
State, but the invention is not restricted to this.Test method used unless otherwise specified, is conventional method in following embodiments, is made
Raw material, reagent etc., unless otherwise specified, are the raw material and reagent that can be obtained from commercial sources such as conventional markets.
Embodiment 1
A kind of UV glue of high viscosity, is obtained by following components in percentage by weight：Ethyl ester-pentadiene-propenyl benzene is common
Polymers 3%, modified bisphenol A epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, polyethylene glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%,
AIBN4%, Nano carbon white 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 7%, neighbour
Phthalate anhydride 8%, glycerine 7%, maleic anhydride 12%, 2- phenoxyethyl acrylates 15%, AMS
10%th, phenol 2%, 388 levelling agents 1%, KV-352 defoamers 1%, benzophenone 1%, p-tert-Butylcatechol 1%.
Embodiment 2
A kind of UV glue of high viscosity, is obtained by following components in percentage by weight：Ethyl ester-pentadiene-propenyl benzene is common
Polymers 3%, modified bisphenol A epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, polyethylene glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%,
AIBN4%, Nano carbon white 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 7%, neighbour
Phthalate anhydride 8%, glycerine 7%, maleic anhydride 12%, 2- phenoxyethyl acrylates 15%, AMS
10%th, phenol 2%, 399 levelling agents 0.5%, 358N levelling agents 0.5%, 066N defoamers 0.8%, 141 defoamers 0.2%, benzophenone
0.4%th, benzoin ether 0.6%, p-tert-Butylcatechol 1%.
Embodiment 3
A kind of UV glue of high viscosity, is obtained by following components in percentage by weight：Ethyl ester-pentadiene-propenyl benzene is common
Polymers 3%, modified bisphenol A epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, polyethylene glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%,
AIBN4%, Nano carbon white 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 7%, neighbour
Phthalate anhydride 8%, glycerine 7%, maleic anhydride 12%, 2- phenoxyethyl acrylates 15%, AMS
10%th, phenol 2%, 388 levelling agents 0.1%, 320 levelling agents 0.2%, 358N levelling agents 0.3%, OK levelling agents 0.3%, 392 levelling agents
0.05%th, 399 levelling agents 0.05%, 066N defoamers 0.2%, A530 defoamers 0.2%, 6800 defoamers 0.1%, 141 defoamers
0.1%th, KV-352 defoamers 0.2%, 354 defoamers 0.1%, benzoin ether 1%, p-tert-Butylcatechol 1%.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (4)
1. the UV glue of a kind of high viscosity, it is characterised in that be obtained by following components in percentage by weight：Ethyl ester-fourth
Diene-phenylpropyl alcohol alkene copolymer 3%, modified bisphenol A epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, polyethylene glycol 3%, nanometer
Butadiene-styrene rubber 2%, AIBN 4%, Nano carbon white 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythrite 3 third
Olefin(e) acid ester 7%, phthalic anhydride 8%, glycerine 7%, maleic anhydride 12%, 2- phenoxyethyl acrylates 15%, α-first
Base styrene 10%, phenol 2%, levelling agent 1%, defoamer 1%, light trigger 1%, p-tert-Butylcatechol 1%.
2. the UV glue of high viscosity according to claim 1, it is characterised in that：The levelling agent be 388,320,358N, OK,
392nd, one or more in 399.
3. the UV glue of high viscosity according to claim 1, it is characterised in that：The defoamer is 066N, A530, defoamer
6800th, 141, one or more in KV-352,354.
4. the UV glue of high viscosity according to claim 1, it is characterised in that：The light trigger is benzophenone, rests in peace
A kind of or mixing in fragrant ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710119377.2A CN106800890A (en) | 2017-03-02 | 2017-03-02 | A kind of UV glue of high viscosity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710119377.2A CN106800890A (en) | 2017-03-02 | 2017-03-02 | A kind of UV glue of high viscosity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106800890A true CN106800890A (en) | 2017-06-06 |
Family
ID=58988791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710119377.2A Withdrawn CN106800890A (en) | 2017-03-02 | 2017-03-02 | A kind of UV glue of high viscosity |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106800890A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111621233A (en) * | 2020-06-22 | 2020-09-04 | 上海朝荟新材料科技有限公司 | Formula and preparation method of anti-aging UV (ultraviolet) glue |
-
2017
- 2017-03-02 CN CN201710119377.2A patent/CN106800890A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111621233A (en) * | 2020-06-22 | 2020-09-04 | 上海朝荟新材料科技有限公司 | Formula and preparation method of anti-aging UV (ultraviolet) glue |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170606 |