CN106366958A - Squeeze-resistant UV (ultraviolet) glue - Google Patents
Squeeze-resistant UV (ultraviolet) glue Download PDFInfo
- Publication number
- CN106366958A CN106366958A CN201610773841.5A CN201610773841A CN106366958A CN 106366958 A CN106366958 A CN 106366958A CN 201610773841 A CN201610773841 A CN 201610773841A CN 106366958 A CN106366958 A CN 106366958A
- Authority
- CN
- China
- Prior art keywords
- glue
- squeeze
- resistant
- butadiene
- defoamer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to the technical field of high polymer materials, in particular to squeeze-resistant UV (ultraviolet) glue. The squeeze-resistant UV glue comprises, by weight percentage, 3% of methyl methacrylate-butadiene-allyl benzene copolymers, 10% of modified bisphenol-A epoxy resin, 3% of trifluoro-alkylsiloxane, 3% of polyethylene glycol, 2% of nano butadiene styrene rubber, 4% of phthalic acid dibutyl ester, 1% of nano diatomite, 5% of ethoxylated trimethylolpropane triacrylate, 7% of pentaerythritol triacrylate, 8% of phthalic anhydride, 7% of glycerin, 12% of maleic anhydride, 15% of 2-phenoxyethyl acrylate, 10% of alpha-methyl styrene, 2% of phenol, 1% of flatting agent, 1% of defoaming agent, 1% of photoinitiator and 1% of tert-butyl catechol. The squeeze-resistant UV glue has the advantages that the squeeze-resistant UV glue has high cross-linking density, flexibility, tenacity and squeeze resistance and is resistant to temperature swelling; the components are interactive synergistically, and the glue has high contraction resistance due to the modified bisphenol-A epoxy resin.
Description
Technical field
The present invention relates to technical field of polymer materials, especially relate to a kind of anti-extrusion uv glue.
Background technology
Its cured product of polyester resin has water-fast, resistance to chemical attack, glittering and translucent feature.Polyester resin on the market at present
It is roughly divided into: plane flexible glue, plane ebonite, cambered surface flexible glue, cambered surface ebonite, potting compound, technique vacation water, polishing glue etc..Using water
Brilliant glue can play to artware, ornaments surface beyond the effect of protection moreover it is possible to increase glossiness and the brightness of product surface.This
The anti-extrusion uv glue of invention is nontoxic, safety, is easy to operate, cost is relatively low.
Content of the invention
It is an object of the invention to provide a kind of anti-extrusion uv glue.
In order to realize foregoing invention purpose, technical scheme is specific as follows:
A kind of anti-extrusion uv glue, is obtained by following components in percentage by weight: methyl methacrylate-butadiene-phenylpropyl alcohol
Alkene copolymer 3%, modified bisphenol a epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber
2%th, dibutyl phthalate 4%, nano diatomite 1%, ethoxylated trimethylolpropane triacrylate 5%, tetramethylolmethane
Triacrylate 7%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2- phenoxyethyl acrylate 15%,
α-methyl styrene 10%, phenol 2%, levelling agent 1%, defoamer 1%, light trigger 1%, p-tert-Butylcatechol 1%.
Preferably, described levelling agent be 388,320,358n, one or more in ok, 392,399.
Preferably, described defoamer be 066n, a530, defoamer 6800,141, kv-352, one or more in 354.
Preferably, described light trigger be benzophenone, a kind of or mixing in benzoin ether.
Modified bisphenol a epoxy resin is by the raw material of k, na, mg metal mixed powder and Epoxy Resin of Bisphenol A in mass ratio
Mix for 1:50-70,80-85 DEG C of reaction of heating in water bath is obtained.
The invention has the advantages that: crosslink density of the present invention is high, there is good flexibility and toughness, anti-extrusion ability is strong, resistance to
High-temperature expansion, the features such as each component Synergistic modified bisphenol a epoxy resin makes glue of the present invention have good anti-contracility.
Do not whitened using rear glue, methyl methacrylate-butadiene-phenylpropyl alcohol alkene copolymer further enhances resistance to acids and bases and aging resistance
Property, especially impact and transparency tool are increased significantly.Easy to use, curing efficiency is high, low production cost, the water of preparation
Brilliant glue preserves that convenient, chemical-resistance is good, is unlikely to deform, and its coating shape and bin stability excellent, be not subject to during use
Weather, the impact of humidity, are added with nano diatomite and enhance toughness, and its porous performance enhances adhesive.
Specific embodiment
With reference to embodiment, present disclosure is described in further detail.
Embodiment 1
A kind of anti-extrusion uv glue, is obtained by following components in percentage by weight: methyl methacrylate-butadiene-phenylpropyl alcohol
Alkene copolymer 3%, modified bisphenol a epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber
2%th, dibutyl phthalate 4%, nano diatomite 1%, ethoxylated trimethylolpropane triacrylate 5%, tetramethylolmethane
Triacrylate 7%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2- phenoxyethyl acrylate 15%,
α-methyl styrene 10%, phenol 2%, 388 levelling agents 1%, kv-352 defoamer 1%, benzophenone 1%, p-tert-Butylcatechol
1%.
Embodiment 2
A kind of anti-extrusion uv glue, is obtained by following components in percentage by weight: methyl methacrylate-butadiene-phenylpropyl alcohol
Alkene copolymer 3%, modified bisphenol a epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber
2%th, dibutyl phthalate 4%, nano diatomite 1%, ethoxylated trimethylolpropane triacrylate 5%, tetramethylolmethane
Triacrylate 7%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2- phenoxyethyl acrylate 15%,
α-methyl styrene 10%, phenol 2%, 399 levelling agents 0.5%, 358n levelling agent 0.5%, 066n defoamer 0.8%, 141 defoamer
0.2%th, benzophenone 0.4%, benzoin ether 0.6%, p-tert-Butylcatechol 1%.
Embodiment 3
A kind of anti-extrusion uv glue, is obtained by following components in percentage by weight: methyl methacrylate-butadiene-phenylpropyl alcohol
Alkene copolymer 3%, modified bisphenol a epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%, Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber
2%th, dibutyl phthalate 4%, nano diatomite 1%, ethoxylated trimethylolpropane triacrylate 5%, tetramethylolmethane
Triacrylate 7%, phthalic anhydride 8%, glycerol 7%, maleic anhydride 12%, 2- phenoxyethyl acrylate 15%,
α-methyl styrene 10%, phenol 2%, 388 levelling agents 0.1%, 320 levelling agents 0.2%, 358n levelling agent 0.3%, ok levelling agent
0.3%th, 392 levelling agents 0.05%, 399 levelling agents 0.05%, 066n defoamer 0.2%, a530 defoamer 0.2%, 6800 defoamer
0.1%th, 141 defoamer 0.1%, kv-352 defoamer 0.2%, 354 defoamer 0.1%, benzoin ether 1%, p-tert-Butylcatechol
1%.
Although reference be made herein to invention has been described for the explanatory embodiment of the present invention, and above-described embodiment is only this
Bright preferably embodiment, embodiments of the present invention are simultaneously not restricted to the described embodiments it should be appreciated that people in the art
Member can be designed that a lot of other modifications and embodiment, and these modifications and embodiment will fall in principle disclosed in the present application
Within scope and spirit.
Claims (4)
1. a kind of anti-extrusion uv glue is it is characterised in that be obtained by following components in percentage by weight: methyl methacrylate
Ester-butadiene-phenylpropyl alcohol alkene copolymer 3%, methyl methacrylate-butadiene-phenylpropyl alcohol alkene copolymer 3%, modified bisphenol a asphalt mixtures modified by epoxy resin
Fat 10%, trifluoroalkyl alkylsiloxane 3%, Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%, dibutyl phthalate 4%, nanometer
Kieselguhr 1%, ethoxylated trimethylolpropane triacrylate 5%, pentaerythritol triacrylate 7%, phthalic anhydride
8%th, glycerol 7%, maleic anhydride 12%, 2- phenoxyethyl acrylate 15%, α-methyl styrene 10%, phenol 2%, stream
Flat agent 1%, defoamer 1%, light trigger 1%, p-tert-Butylcatechol 1%.
2. uv glue anti-extrusion according to claim 1 it is characterised in that: described levelling agent be 388,320,358n, ok,
392nd, one or more in 399.
3. uv glue anti-extrusion according to claim 1 it is characterised in that: described defoamer be 066n, a530, defoamer
6800th, 141, kv-352, one or more in 354.
4. uv glue anti-extrusion according to claim 1 it is characterised in that: described light trigger be benzophenone, rest in peace
A kind of or mixing in fragrant ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773841.5A CN106366958A (en) | 2016-08-31 | 2016-08-31 | Squeeze-resistant UV (ultraviolet) glue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773841.5A CN106366958A (en) | 2016-08-31 | 2016-08-31 | Squeeze-resistant UV (ultraviolet) glue |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106366958A true CN106366958A (en) | 2017-02-01 |
Family
ID=57900861
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610773841.5A Withdrawn CN106366958A (en) | 2016-08-31 | 2016-08-31 | Squeeze-resistant UV (ultraviolet) glue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106366958A (en) |
-
2016
- 2016-08-31 CN CN201610773841.5A patent/CN106366958A/en not_active Withdrawn
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102161731B (en) | Preparation method and application method of water-based epoxy resin emulsion | |
| TW201231570A (en) | Colored aqueous UV curable coating composition | |
| US20120178850A1 (en) | Artificial marble and method of manufacturing the same | |
| CN102020913B (en) | Ultraviolet cured wood paint and preparation method thereof | |
| EP3362525B1 (en) | Topcoat composition, method of coating substrates with the same, and substrate | |
| CN105176375B (en) | A kind of LED UV woodenware repairing transparent matt top coat top coat and preparation method | |
| CN107778512A (en) | A kind of solvent-free PVC roller coat UV glossy varnish coating and preparation method thereof | |
| CN105859985B (en) | One kind can quick-setting flexible polymethyl methacrylate materials and its preparation method and application | |
| WO2010108438A1 (en) | Pointing agent for stone | |
| US7329713B2 (en) | Coating, laminating, and casting compositions and methods of producing and curing same | |
| CN112322085B (en) | PMMA waterproof coating for intercity high-speed railway and urban light rail concrete bridge | |
| CN102002315B (en) | Oily UV white bright surface wood paint | |
| CN106366958A (en) | Squeeze-resistant UV (ultraviolet) glue | |
| JP6825222B2 (en) | Thermosetting resin composition and its resin molded product | |
| CN104293119A (en) | High-intensity scratching-resistant ultraviolet light polymerization water paint and preparation method thereof | |
| CN106281057A (en) | A kind of UV glue | |
| CN106433489A (en) | Uniform-solidification UV glue | |
| CN106366957A (en) | Ultraviolet curing adhesive | |
| CN106800890A (en) | A kind of UV glue of high viscosity | |
| CN106366719A (en) | Mildewproof photocuring crystal adhesive | |
| CN109652001A (en) | A kind of UV solidification glue of high transparency, low haze | |
| CN106381076A (en) | Moistureproof light-cured polyester resin | |
| CN106380908A (en) | High-toughness light-cured polyester resin | |
| CN103589302A (en) | Low-odor ultraviolet curing primer | |
| CN106349955A (en) | Rapid photocuring polyester resin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170201 |
|
| WW01 | Invention patent application withdrawn after publication |