CN106349955A - Rapid photocuring polyester resin - Google Patents
Rapid photocuring polyester resin Download PDFInfo
- Publication number
- CN106349955A CN106349955A CN201610773824.1A CN201610773824A CN106349955A CN 106349955 A CN106349955 A CN 106349955A CN 201610773824 A CN201610773824 A CN 201610773824A CN 106349955 A CN106349955 A CN 106349955A
- Authority
- CN
- China
- Prior art keywords
- polyester resin
- rapid photocuring
- photocuring polyester
- rapid
- defoamer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to the technical field of high polymer materials, and specifically relates to a rapid photocuring polyester resin. The rapid photocuring polyester resin is prepared from the following components according to weight percentage: 10% of phthalic anhydride, 25% of glycerin, 15% of maleic anhydride, 20% of 2-phenoxy ethyl acrylic ester, 25% of alpha-methyl styrene, 2% of phenol, 1% of a flatting agent, 1% of a foaming agent, and 1% of a photoinitiator. A cured product with stable physical characteristics, particularly stable permanent compression set, is formed, the coating shape and the storage stability are excellent, and the rapid photocuring polyester resin is not affected by weather and humidity in the use process.
Description
Technical field
The present invention relates to technical field of polymer materials, especially relate to a kind of rapid photocuring polyester resin.
Background technology
Its cured product of polyester resin has water-fast, resistance to chemical attack, glittering and translucent feature.Polyester resin on the market at present
It is roughly divided into: plane flexible glue, plane ebonite, cambered surface flexible glue, cambered surface ebonite, potting compound, technique vacation water, polishing glue etc..Using water
Brilliant glue can play to artware, ornaments surface beyond the effect of protection moreover it is possible to increase glossiness and the brightness of product surface.This
The rapid photocuring polyester resin of invention is nontoxic, safety, is easy to operate, cost is relatively low.
Content of the invention
It is an object of the invention to provide a kind of solidify the stable, polyester resin of environmental protection.
In order to realize foregoing invention purpose, technical scheme is specific as follows:
A kind of rapid photocuring polyester resin, is obtained by following components in percentage by weight: phthalic anhydride 10%, glycerol
25%th, maleic anhydride 15%, 2- phenoxyethyl acrylate 20%, α-methyl styrene 25%, phenol 2%, levelling agent 1%,
Defoamer 1%, light trigger 1%.
Preferably, described levelling agent be 388,320,358n, one or more in ok, 392,399.
Preferably, described defoamer be 066n, a530, defoamer 6800,141, kv-352, one or more in 354.
Preferably, described light trigger be benzophenone, a kind of or mixing in benzoin ether.
The invention has the advantages that: the present invention can form physical characteristics, the especially stable solidfied material of compression set, and
Its coating shape and bin stability are excellent, are not affected by weather, humidity during use.
Specific embodiment
With reference to embodiment, present disclosure is described in further detail.
Embodiment 1
A kind of rapid photocuring polyester resin, is obtained by following components in percentage by weight: phthalic anhydride 10%, glycerol
25%th, maleic anhydride 15%, 2- phenoxyethyl acrylate 20%, α-methyl styrene 25%, phenol 2%, 388 levelling agents
1%th, kv-352 defoamer 1%, benzophenone 1%.
Embodiment 2
A kind of rapid photocuring polyester resin, is obtained by following components in percentage by weight: phthalic anhydride 10%, glycerol
25%th, maleic anhydride 15%, 2- phenoxyethyl acrylate 20%, α-methyl styrene 25%, phenol 2%, 399 levelling agents
0.5%th, 358n levelling agent 0.5%, 066n defoamer 0.8%, 141 defoamer 0.2%, benzophenone 0.4%, benzoin ether 0.6%.
Embodiment 3
A kind of rapid photocuring polyester resin, is obtained by following components in percentage by weight: phthalic anhydride 10%, glycerol
25%th, maleic anhydride 15%, 2- phenoxyethyl acrylate 20%, α-methyl styrene 25%, phenol 2%, 388 levelling agents
0.1%th, 320 levelling agents 0.2%, 358n levelling agent 0.3%, ok levelling agent 0.3%, 392 levelling agents 0.05%, 399 levelling agents 0.05%,
066n defoamer 0.2%, a530 defoamer 0.2%, 6800 defoamer 0.1%, 141 defoamer 0.1%, kv-352 defoamer 0.2%,
354 defoamer 0.1%, benzoin ether 1%.
Although reference be made herein to invention has been described for the explanatory embodiment of the present invention, and above-described embodiment is only this
Bright preferably embodiment, embodiments of the present invention are simultaneously not restricted to the described embodiments it should be appreciated that people in the art
Member can be designed that a lot of other modifications and embodiment, and these modifications and embodiment will fall in principle disclosed in the present application
Within scope and spirit.
Claims (4)
1. a kind of rapid photocuring polyester resin is it is characterised in that be obtained by following components in percentage by weight: phthalic anhydride
10%th, glycerol 25%, maleic anhydride 15%, 2- phenoxyethyl acrylate 20%, α-methyl styrene 25%, phenol 2%,
Levelling agent 1%, defoamer 1%, light trigger 1%.
2. according to claim 1 rapid photocuring polyester resin it is characterised in that: described levelling agent be 388,320,358n,
One or more in ok, 392,399.
3. according to claim 1 rapid photocuring polyester resin it is characterised in that: described defoamer be 066n, a530, froth breaking
Agent 6800,141, kv-352, one or more in 354.
4. according to claim 1 rapid photocuring polyester resin it is characterised in that: described light trigger be benzophenone, peace
A kind of or mixing in the fragrant ether of breath.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773824.1A CN106349955A (en) | 2016-08-31 | 2016-08-31 | Rapid photocuring polyester resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773824.1A CN106349955A (en) | 2016-08-31 | 2016-08-31 | Rapid photocuring polyester resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106349955A true CN106349955A (en) | 2017-01-25 |
Family
ID=57856979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610773824.1A Withdrawn CN106349955A (en) | 2016-08-31 | 2016-08-31 | Rapid photocuring polyester resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106349955A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109988481A (en) * | 2019-02-25 | 2019-07-09 | 孙建忠 | A kind of low viscous rapid-hardening polyester resin |
-
2016
- 2016-08-31 CN CN201610773824.1A patent/CN106349955A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109988481A (en) * | 2019-02-25 | 2019-07-09 | 孙建忠 | A kind of low viscous rapid-hardening polyester resin |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170125 |
|
| WW01 | Invention patent application withdrawn after publication |