CN106366957A - Ultraviolet curing adhesive - Google Patents
Ultraviolet curing adhesive Download PDFInfo
- Publication number
- CN106366957A CN106366957A CN201610773829.4A CN201610773829A CN106366957A CN 106366957 A CN106366957 A CN 106366957A CN 201610773829 A CN201610773829 A CN 201610773829A CN 106366957 A CN106366957 A CN 106366957A
- Authority
- CN
- China
- Prior art keywords
- percent
- methyl
- defoamer
- cured adhesive
- ultraviolet curing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to the technical field of polymer materials and in particular relates to ultraviolet curing adhesive. The ultraviolet curing adhesive is prepared from the following components in percentage by weight: 10 percent of tripropylene glycol diacrylate, 3 percent of methyl methacrylate-butadiene- allyl benzene copolymer, 10 percent of modified bisphenol A epoxy resin, 3 percent of trifluoroalkyl siloxane, 3 percent of polyethylene glycol, 2 percent of nano styrene-butadiene rubber, 4 percent of dibutyl phthalate, 1 percent of nano diatomite, 5 percent of ethoxylated trimethylolpropane triacrylate, 7 percent of pentaerythritol triacrylate, 8 percent of phthalic anhydride, 7 percent of 1-methyl-4-isopropenylbenzene, 6 percent of maleic anhydride, 11 percent of 2-phenoxy ethyl acrylate, 10 percent of alpha-methyl styrene, 2 percent of phenol, 1 percent of leveling agent, 1 percent of defoaming agent, 1 percent of photoinitiator and 1 percent of p-tert-butylcatechol. The ultraviolet curing adhesive disclosed by the invention has the advantages of high crosslinking density, good flexibility and toughness, high extrusion resistance, high-temperature expansion resistance and excellent light resistance.
Description
Technical field
The present invention relates to technical field of polymer materials, especially relate to a kind of ultraviolet cured adhesive.
Background technology
Its cured product of polyester resin has water-fast, resistance to chemical attack, glittering and translucent feature.Polyester resin on the market at present
It is roughly divided into: plane flexible glue, plane ebonite, cambered surface flexible glue, cambered surface ebonite, potting compound, technique vacation water, polishing glue etc..Using water
Brilliant glue can play to artware, ornaments surface beyond the effect of protection moreover it is possible to increase glossiness and the brightness of product surface.This
The ultraviolet cured adhesive of invention is nontoxic, safety, is easy to operate, cost is relatively low.
Content of the invention
It is an object of the invention to provide a kind of ultraviolet cured adhesive.
In order to realize foregoing invention purpose, technical scheme is specific as follows:
A kind of ultraviolet cured adhesive, is obtained by following components in percentage by weight: tri (propylene glycol) diacrylate 10%, first
Base methylacrylate-butadiene-phenylpropyl alcohol alkene copolymer 3%, modified bisphenol a epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%,
Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylation trihydroxy methyl third
Alkane triacrylate 5%, pentaerythritol triacrylate 7%, phthalic anhydride 8%, 1- methyl -4- isopropenylbenzene 7%, suitable fourth
Enedioic acid acid anhydride 6%, 2- phenoxyethyl acrylate 11%, α-methyl styrene 10%, phenol 2%, levelling agent 1%, defoamer 1%,
Light trigger 1%, p-tert-Butylcatechol 1%.
Preferably, described levelling agent be 388,320,358n, one or more in ok, 392,399.
Preferably, described defoamer be 066n, a530, defoamer 6800,141, kv-352, one or more in 354.
Preferably, described light trigger be benzophenone, a kind of or mixing in benzoin ether.
Modified bisphenol a epoxy resin is by the raw material of k, na, mg metal mixed powder and Epoxy Resin of Bisphenol A in mass ratio
Mix for 1:50-70,80-85 DEG C of reaction of heating in water bath is obtained.
The invention has the advantages that: crosslink density of the present invention is high, there is good flexibility and toughness, anti-extrusion ability is strong, resistance to
High-temperature expansion, also has excellent in light-resistance, and each component Synergistic modified bisphenol a epoxy resin makes glue of the present invention have well
Anti- contracility the features such as.Do not whitened using rear glue, methyl methacrylate-butadiene-phenylpropyl alcohol alkene copolymer increases further
Strong resistance to acids and bases and ageing resistance, especially increase significantly to impact and transparency tool.Easy to use, curing efficiency is high,
Low production cost, the solidification glue of preparation preserves that convenient, chemical-resistance is good, is unlikely to deform, and its coating shape and storage steady
Qualitative excellent, do not affected by weather, humidity during use, be added with nano diatomite and enhance toughness, and its porous performance
Enhance adhesive.
Specific embodiment
With reference to embodiment, present disclosure is described in further detail.
Embodiment 1
A kind of ultraviolet cured adhesive, is obtained by following components in percentage by weight: tri (propylene glycol) diacrylate 10%, first
Base methylacrylate-butadiene-phenylpropyl alcohol alkene copolymer 3%, modified bisphenol a epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%,
Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylation trihydroxy methyl third
Alkane triacrylate 5%, pentaerythritol triacrylate 7%, phthalic anhydride 8%, 1- methyl -4- isopropenylbenzene 7%, suitable fourth
Enedioic acid acid anhydride 6%, 2- phenoxyethyl acrylate 11%, α-methyl styrene 10%, phenol 2%, 388 levelling agents 1%, kv-352
Defoamer 1%, benzophenone 1%, p-tert-Butylcatechol 1%.
Embodiment 2
A kind of ultraviolet cured adhesive, is obtained by following components in percentage by weight: tri (propylene glycol) diacrylate 10%, first
Base methylacrylate-butadiene-phenylpropyl alcohol alkene copolymer 3%, modified bisphenol a epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%,
Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylation trihydroxy methyl third
Alkane triacrylate 5%, pentaerythritol triacrylate 7%, phthalic anhydride 8%, 1- methyl -4- isopropenylbenzene 7%, suitable fourth
Enedioic acid acid anhydride 6%, 2- phenoxyethyl acrylate 11%, α-methyl styrene 10%, phenol 2%, 399 levelling agents 0.5%, 358n
Levelling agent 0.5%, 066n defoamer 0.8%, 141 defoamer 0.2%, benzophenone 0.4%, benzoin ether 0.6%, to tert-butyl o
Benzodiazepiness 1%.
Embodiment 3
A kind of ultraviolet cured adhesive, is obtained by following components in percentage by weight: tri (propylene glycol) diacrylate 10%, first
Base methylacrylate-butadiene-phenylpropyl alcohol alkene copolymer 3%, modified bisphenol a epoxy resin 10%, trifluoroalkyl alkylsiloxane 3%,
Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethoxylation trihydroxy methyl third
Alkane triacrylate 5%, pentaerythritol triacrylate 7%, phthalic anhydride 8%, 1- methyl -4- isopropenylbenzene 7%, suitable fourth
Enedioic acid acid anhydride 6%, 2- phenoxyethyl acrylate 11%, α-methyl styrene 10%, phenol 2%, 388 levelling agent 0.1%, 320 stream
Flat agent 0.2%, 358n levelling agent 0.3%, ok levelling agent 0.3%, 392 levelling agents 0.05%, 399 levelling agents 0.05%, 066n defoamer
0.2%th, a530 defoamer 0.2%, 6800 defoamer 0.1%, 141 defoamer 0.1%, kv-352 defoamer 0.2%, 354 defoamer
0.1%th, benzoin ether 1%, p-tert-Butylcatechol 1%.
Although reference be made herein to invention has been described for the explanatory embodiment of the present invention, and above-described embodiment is only this
Bright preferably embodiment, embodiments of the present invention are simultaneously not restricted to the described embodiments it should be appreciated that people in the art
Member can be designed that a lot of other modifications and embodiment, and these modifications and embodiment will fall in principle disclosed in the present application
Scope and spirit.
Claims (4)
1. a kind of ultraviolet cured adhesive is it is characterised in that be obtained by following components in percentage by weight: tripropylene glycol dipropyl
Olefin(e) acid ester 10%, methyl methacrylate-butadiene-phenylpropyl alcohol alkene copolymer 3%, modified bisphenol a epoxy resin 10%, trifluoroalkyl
Alkylsiloxane 3%, Polyethylene Glycol 3%, nanometer butadiene-styrene-vinyl rubber 2%, dibutyl phthalate 4%, nano diatomite 1%, ethyoxyl
Change trimethylolpropane trimethacrylate 5%, pentaerythritol triacrylate 7%, phthalic anhydride 8%, 1- methyl -4- isopropyl
Alkenyl benzene 7%, maleic anhydride 6%, 2- phenoxyethyl acrylate 11%, α-methyl styrene 10%, phenol 2%, levelling agent
1%th, defoamer 1%, light trigger 1%, p-tert-Butylcatechol 1%.
2. according to claim 1 ultraviolet cured adhesive it is characterised in that: described levelling agent be 388,320,358n, ok,
392nd, one or more in 399.
3. according to claim 1 ultraviolet cured adhesive it is characterised in that: described defoamer be 066n, a530, defoamer
6800th, 141, kv-352, one or more in 354.
4. according to claim 1 ultraviolet cured adhesive it is characterised in that: described light trigger be benzophenone, Benzoinum
A kind of or mixing in ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773829.4A CN106366957A (en) | 2016-08-31 | 2016-08-31 | Ultraviolet curing adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773829.4A CN106366957A (en) | 2016-08-31 | 2016-08-31 | Ultraviolet curing adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106366957A true CN106366957A (en) | 2017-02-01 |
Family
ID=57902262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610773829.4A Withdrawn CN106366957A (en) | 2016-08-31 | 2016-08-31 | Ultraviolet curing adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106366957A (en) |
-
2016
- 2016-08-31 CN CN201610773829.4A patent/CN106366957A/en not_active Withdrawn
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170201 |
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| WW01 | Invention patent application withdrawn after publication |