CN106520048A - Adhesive applied to stone curtain wall - Google Patents

Adhesive applied to stone curtain wall Download PDF

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Publication number
CN106520048A
CN106520048A CN201611090405.4A CN201611090405A CN106520048A CN 106520048 A CN106520048 A CN 106520048A CN 201611090405 A CN201611090405 A CN 201611090405A CN 106520048 A CN106520048 A CN 106520048A
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CN
China
Prior art keywords
parts
component
curtain wall
stone curtain
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201611090405.4A
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Chinese (zh)
Inventor
谢林玲
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Guangxi University
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Guangxi University
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Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201611090405.4A priority Critical patent/CN106520048A/en
Publication of CN106520048A publication Critical patent/CN106520048A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C09J163/10—Epoxy resins modified by unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses an adhesive applied to a stone curtain wall. The adhesive comprises a component A and a component B, wherein the mass ratio of the component A to the component B is (1-5): 1. The component A is composed of, by mass, 11-25 parts of bisphenol fluorene epoxy resin, 10-20 parts of polyurethane elastomer toughened bisphenol A type vinyl ester resin, 20-50 parts of glyceride epoxy resin, 1-12 parts of titanium dioxide, 5-19 parts of nanometer silicon dioxide, 1-5 parts of carbon fibers, 6-18 parts of activated calcium oxide, 3-6 parts of acrylonitrile-butadiene copolymer, 1-5 parts of a curing agent, 0.1-2 parts of a dispersing agent, 0.1-1 part of a low shrinkage agent, 0.1-3 parts of a coupling agent, 0.1-1 part of an accelerant and 0.1-3 parts of a defoaming agent. The component B is composed of, by mass, 3-9 parts of phthalate, 6-9 parts of bis-amine fluorene, 10-15 parts of tert-butyl peroxybenzoate and 10-20 parts of diaminodiphenylmethane. The adhesive applied to the stone curtain wall is high in bonding strength, impact toughness, heat resistance and corrosion resistance and capable of resisting to water, and an adhesive film is high in shock absorption performance.

Description

A kind of stone curtain wall adhesive
Technical field
The present invention relates to adhesive technical field, and in particular to a kind of stone curtain wall adhesive.
Background technology
In curtain wall dried hanging construction technology, the stone material of one piece tens jin even hundreds of kilogram weights is bonded to into stainless steel On, the quality of adhesive directly affects the installation quality and effect of curtain wall, and the bad adhesive of glueability is present greatly pacifies Full hidden danger, the main component of current curtain wall adhesive is epoxy resin, and coordinates curing agent to use, the performance to adhesive Require with anticorrosion, high temperature resistant, anti-aging, intensity is high, fastness is good, and under the temperature difference and vibration condition, stretch, sedimentation is produced Raw displacement is less, is difficult permeability.
The content of the invention
It is an object of the present invention to be directed to the deficiencies in the prior art, there is provided a kind of adhesivity is strong, heat resistance is high, infiltration A kind of strong stone curtain wall adhesive of property.
For achieving the above object, the present invention takes technical scheme below：
A kind of stone curtain wall adhesive, including component A, B component, wherein, component A is 1～5 with the mass ratio of B component：1；
Component A is made up of the raw material of mass parts：11～25 parts of bisphenol fluorene epoxy resin, polyurethane elastomer toughness reinforcing bisphenol A-type second 10～20 parts of alkenyl esters resin, 20～50 parts of glycerine ester epoxy resin, 1～12 part of titanium dioxide, 5～19 parts of nano silicon, 1～5 part of carbon fiber, 6～18 parts of active calcium oxide, 3～6 parts of acrylonitrile-butadiene copolymer, 1～5 part of curing agent, dispersant 0.1～2 part, 0.1～1 part of shrinking agent, 0.1～3 part of coupling agent, 0.1～1 part of accelerator, 0.1～3 part of defoamer；
B component is made up of the raw material of mass parts：3～9 parts of phthalic acid ester, 6～9 parts of diamine fluorenes, the tertiary fourth of perbenzoic acid 10～15 parts of ester, MDA 10-20 parts.
Preferably, dispersant be ethanol, acetone, it is terebinthine one or more.
Preferably, lower shrinkage is one or more of polystyrene, thermoplastic polyester, polyvinyl acetate.
Preferably, coupling agent is silane coupler or titanate coupling agent.
Preferably, accelerator is cobalt naphthenate or cobalt iso-octoate.
Preferably, curing agent is styrene, divinylbenzene, methyl methacrylate, tripropylene glycol diacrylate One or more.
Preferably, described defoamer is polyoxyethylene polyoxypropylene glycerin ether, one kind of dimethyl silicone polymer or several Kind.
Further, a kind of preparation method of stone curtain wall adhesive of the invention is comprised the following steps：
(1) by bisphenol fluorene epoxy resin, polyurethane elastomer toughness reinforcing bisphenol A-type vinyl ester resin, glycerine ester epoxy resin, low Contracting agent, acrylonitrile-butadiene copolymer, curing agent, coupling agent, defoamer, accelerator and dispersant add stainless true In empty high-speed dispersing kettle, it is pre-dispersed to carry out vacuum under the rotating speed of 800r/min, then adds nano silicon, carbon fiber, activity Calcium oxide, under the rotating speed of 1500r/min, high-speed vacuum dispersion, obtains masterbatch, adds titanium dioxide, obtain component A in masterbatch；
(2) phthalic acid ester, diamine fluorenes, peroxidized t-butyl perbenzoate, MDA are sufficiently mixed, obtain glue Glutinous agent
(3) component B that component A and step (2) for obtaining step (1) is obtained mixes in parts by weight and obtains final product a kind of stone curtain wall and use Adhesive.
Wherein, bisphenol fluorene epoxy resin, polyurethane elastomer toughness reinforcing bisphenol A-type vinyl ester resin, glyceride asphalt mixtures modified by epoxy resin Respective customer service itself weakness of fat compound use, can strengthen the viscosity of adhesive, while use with carbon fiber and nano silicon, The corrosion resistance and anti-impact force and compression strength of adhesive can be improved.
Wherein, active calcium oxide, titanium dioxide, nano silicon can not only reduce the consumption of resin, reduces cost, with third Alkene nitrile-butadiene copolymer, bisphenol fluorene epoxy resin, polyurethane elastomer toughness reinforcing bisphenol A-type vinyl ester resin, glyceride ring The effect of oxygen tree fat can significantly improve adhesive physical property, increase toughness, and glued membrane shock-absorbing effect is good, and waterproof effect pole For excellent.
The invention has the beneficial effects as follows：The adhesive adhesion strength of the present invention is high, the toughness with superior performance, Glued membrane shock-absorbing performance, heat resistance, corrosion resistance and waterproof effect.
Specific embodiment
With reference to specific embodiment, to further instruction of the present invention.
Embodiment 1
A kind of stone curtain wall adhesive is 1 by mass ratio：1 component A is constituted with B component, the original of component A and B component Material composition is as follows：
Component A is made up of the raw material of mass parts：
B component is made up of the raw material of mass parts：
3 parts of phthalic acid ester, 9 parts of diamine fluorenes
10 parts of peroxidized t-butyl perbenzoate, 20 parts of MDA.
In the present embodiment, dispersant is ethanol, acetone, turpentine oil；Lower shrinkage is polystyrene, thermoplastic polyester, poly-vinegar acid second Alkene ester；Coupling agent is silane coupler；Accelerator is cobalt naphthenate；Curing agent is styrene, divinylbenzene, methacrylic acid Methyl esters, tripropylene glycol diacrylate；Defoamer is polyoxyethylene polyoxypropylene glycerin ether, dimethyl silicone polymer.
Its preparation method is comprised the following steps：
(1) by bisphenol fluorene epoxy resin, polyurethane elastomer toughness reinforcing bisphenol A-type vinyl ester resin, glycerine ester epoxy resin, low Contracting agent, acrylonitrile-butadiene copolymer, curing agent, coupling agent, defoamer, accelerator and dispersant add stainless true In empty high-speed dispersing kettle, it is pre-dispersed to carry out vacuum under the rotating speed of 800r/min, then adds nano silicon, carbon fiber, activity Calcium oxide, under the rotating speed of 1500r/min, high-speed vacuum dispersion, obtains masterbatch, adds titanium dioxide, obtain component A in masterbatch；
(2) phthalic acid ester, diamine fluorenes, peroxidized t-butyl perbenzoate, MDA are sufficiently mixed, obtain glue Glutinous agent
(3) component B that component A and step (2) for obtaining step (1) is obtained mixes in parts by weight and obtains final product a kind of stone curtain wall and use Adhesive.
Embodiment 2
A kind of stone curtain wall adhesive is 5 by mass ratio：1 component A is constituted with B component, the original of component A and B component Material composition is as follows：
Component A is made up of the raw material of mass parts：
B component is made up of the raw material of mass parts：
3～9 parts of phthalic acid ester, 6～9 parts of diamine fluorenes
10～15 parts of MDA 10-20 parts of peroxidized t-butyl perbenzoate.
In the present embodiment, dispersant is ethanol, acetone, turpentine oil；Lower shrinkage is polystyrene, thermoplastic polyester, poly-vinegar acid second Alkene ester；Coupling agent is silane coupler or titanate coupling agent；Accelerator is cobalt naphthenate or cobalt iso-octoate；Curing agent is benzene second Alkene, divinylbenzene, methyl methacrylate, tripropylene glycol diacrylate；Defoamer is polyoxyethylene polyoxypropylene glycerine Ether, dimethyl silicone polymer.
Its preparation method is with embodiment 1.
Embodiment 3
A kind of stone curtain wall adhesive is 3 by mass ratio：1 component A is constituted with B component, the original of component A and B component Material composition is as follows：
Component A is made up of the raw material of mass parts：
B component is made up of the raw material of mass parts：
9 parts of phthalic acid ester, 6 parts of diamine fluorenes
15 parts of MDA 10-20 parts of peroxidized t-butyl perbenzoate.
In the present embodiment, dispersant is ethanol；Lower shrinkage is polystyrene and thermoplastic polyester；Coupling agent is coupled for titanate esters Agent；Accelerator is cobalt iso-octoate；Curing agent is methyl methacrylate；Defoamer is polyoxyethylene polyoxypropylene glycerin ether.
Its preparation method is with embodiment 1.
Embodiment 3
A kind of stone curtain wall adhesive is 2 by mass ratio：1 component A is constituted with B component, the original of component A and B component Material composition is as follows：
Component A is made up of the raw material of mass parts：
B component is made up of the raw material of mass parts：
3～9 parts of phthalic acid ester, 6～9 parts of diamine fluorenes
10～15 parts of MDA 10-20 parts of peroxidized t-butyl perbenzoate.
In the present embodiment, dispersant is turpentine oil；Lower shrinkage is polystyrene；Coupling agent is titanate coupling agent；Accelerator is Cobalt naphthenate；Curing agent is styrene and tripropylene glycol diacrylate；Defoamer is dimethyl silicone polymer.
Its preparation method is with embodiment 1.

Claims (8)

1. the matter of a kind of stone curtain wall adhesive, it is characterised in which includes component A, B component, wherein component A and B component Amount is than being 1～5：1；
Component A is made up of the raw material of mass parts：11～25 parts of bisphenol fluorene epoxy resin, polyurethane elastomer toughness reinforcing bisphenol A-type second 10～20 parts of alkenyl esters resin, 20～50 parts of glycerine ester epoxy resin, 1～12 part of titanium dioxide, 5～19 parts of nano silicon, 1～5 part of carbon fiber, 6～18 parts of active calcium oxide, 3～6 parts of acrylonitrile-butadiene copolymer, 1～5 part of curing agent, dispersant 0.1～2 part, 0.1～1 part of shrinking agent, 0.1～3 part of coupling agent, 0.1～1 part of accelerator, 0.1～3 part of defoamer；
B component is made up of the raw material of mass parts：3～9 parts of phthalic acid ester, 6～9 parts of diamine fluorenes, the tertiary fourth of perbenzoic acid 10～15 parts of ester, MDA 10-20 parts.
2. a kind of stone curtain wall adhesive according to claim 1, it is characterised in that described dispersant be ethanol, Acetone, it is terebinthine one or more.
3. a kind of stone curtain wall adhesive according to claim 1, it is characterised in that described lower shrinkage is polyphenyl second One or more of alkene, thermoplastic polyester, polyvinyl acetate.
4. a kind of stone curtain wall adhesive according to claim 1, it is characterised in that described coupling agent is silane idol Connection agent or titanate coupling agent.
5. a kind of stone curtain wall adhesive according to claim 1, it is characterised in that described accelerator is aphthenic acids Cobalt or cobalt iso-octoate.
6. a kind of stone curtain wall adhesive according to claim 1, it is characterised in that described curing agent is benzene second One or more of alkene, divinylbenzene, methyl methacrylate, tripropylene glycol diacrylate.
7. a kind of stone curtain wall adhesive according to claim 1, it is characterised in that described defoamer is polyoxy third One or more of alkene polyoxyethylene glycerol ether, dimethyl silicone polymer.
8. the preparation method according to a kind of arbitrary described stone curtain wall adhesive of claim 1-7, it is characterised in that include Following steps：
(1) by bisphenol fluorene epoxy resin, polyurethane elastomer toughness reinforcing bisphenol A-type vinyl ester resin, glycerine ester epoxy resin, low Contracting agent, acrylonitrile-butadiene copolymer, curing agent, coupling agent, defoamer, accelerator and dispersant add stainless true In empty high-speed dispersing kettle, it is pre-dispersed to carry out vacuum under the rotating speed of 800r/min, then adds nano silicon, carbon fiber, activity Calcium oxide, under the rotating speed of 1500r/min, high-speed vacuum dispersion, obtains masterbatch, adds titanium dioxide, obtain component A in masterbatch；
(2) phthalic acid ester, diamine fluorenes, peroxidized t-butyl perbenzoate, MDA are sufficiently mixed, obtain glue Glutinous agent
(3) component B that component A and step (2) for obtaining step (1) is obtained mixes in parts by weight and obtains final product a kind of stone curtain wall and use Adhesive.
CN201611090405.4A 2016-11-29 2016-11-29 Adhesive applied to stone curtain wall Withdrawn CN106520048A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611090405.4A CN106520048A (en) 2016-11-29 2016-11-29 Adhesive applied to stone curtain wall

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611090405.4A CN106520048A (en) 2016-11-29 2016-11-29 Adhesive applied to stone curtain wall

Publications (1)

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CN106520048A true CN106520048A (en) 2017-03-22

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107418452A (en) * 2017-09-15 2017-12-01 镇江市龙门石刻艺术工程有限公司 A kind of curtain wall adhesive
CN108329845A (en) * 2018-03-09 2018-07-27 海南鑫申绿色建筑科技有限公司 A kind of assembled wall board adhesive and preparation method thereof
CN108611037A (en) * 2018-05-25 2018-10-02 合肥昂诺新材料有限公司 A kind of epoxide-resin glue of elasticity and toughness promotion
CN110145107A (en) * 2019-05-28 2019-08-20 广州市设计院工程建设总承包公司 The method for paving of stone floor
CN111087965A (en) * 2019-12-31 2020-05-01 深圳市真彩软胶科技有限公司 Traceless removable adhesive for electronic equipment and preparation method thereof
CN111471426A (en) * 2019-01-24 2020-07-31 昆山玛冀电子有限公司 High-reliability integrally-formed adhesive for inductor and preparation method thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107418452A (en) * 2017-09-15 2017-12-01 镇江市龙门石刻艺术工程有限公司 A kind of curtain wall adhesive
CN108329845A (en) * 2018-03-09 2018-07-27 海南鑫申绿色建筑科技有限公司 A kind of assembled wall board adhesive and preparation method thereof
CN108611037A (en) * 2018-05-25 2018-10-02 合肥昂诺新材料有限公司 A kind of epoxide-resin glue of elasticity and toughness promotion
CN111471426A (en) * 2019-01-24 2020-07-31 昆山玛冀电子有限公司 High-reliability integrally-formed adhesive for inductor and preparation method thereof
CN110145107A (en) * 2019-05-28 2019-08-20 广州市设计院工程建设总承包公司 The method for paving of stone floor
CN111087965A (en) * 2019-12-31 2020-05-01 深圳市真彩软胶科技有限公司 Traceless removable adhesive for electronic equipment and preparation method thereof

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Application publication date: 20170322